As the hydrogen market is projected to grow in the next decades, the development of more efficient and better-performing polymer electrolyte membrane fuel cells (PEMFCs) is certainly needed. Water management is one of the main issues faced by these devices and is strictly related to the employment of fluorinated materials in the gas diffusion medium (GDM). Fluorine-based polymers are added as hydrophobic agents for gas diffusion layers (GDL) or in the ink composition of microporous layers (MPL), with the goal of reducing the risk of membrane dehydration and cell flooding. In this review, the state of the art of fluorinated polymers for fuel cells is presented. The most common ones are polytetrafluoroethylene (PTFE) and fluorinated ethylene propylene (FEP), however, other compounds such as PFA, PVDF, PFPE, and CF4 have been studied and reported. The effects of these materials on device performances are analyzed and described. Particular attention is dedicated to the influence of polymer... [more]

The thermal performance of a large-format (52.3 Ah) Li-ion pouch battery with an n-octadecane PCM was investigated. A simplified 1D model was employed to estimate the transient thermal behavior. Two design parameters, the thickness and the thermal conductivity of the PCM, were considered. A 0.5 mm thick n-octadecane PCM integrated with aluminum foam reduced the battery temperature to 34.3 °C and 50.7 °C at the end stage of discharging under 3C and 5C discharge rates, respectively. The 1D results compared to the 3D results were able to predict the temperature dissipation by the PCM method at the end of discharging. The 1D approach clearly produced reliable results in predicting the thermal behavior of the PCM cooling and was superior in practical applications with its low cost and time consumption. A 3D CFD simulation was able to describe the detailed temperature uniformity in the cell, which is an important factor in the design and evaluation of a battery cooling system.

Thermal energy storage (TES) system plays an essential role in the utilization and exploitation of renewable energy sources. Over the last two decades, single-tank thermocline technology has received much attention due to its high cost-effectiveness compared to the conventional two-tank storage systems. The present paper focuses on clarifying the performance indicators and the effects of different influencing factors for the thermocline TES systems. We collect the various performance indicators used in the existing literature, and classify them into three categories: (1) ones directly reflecting the quantity or quality of the stored thermal energy; (2) ones describing the thermal stratification level of the hot and cold regions; (3) ones characterizing the thermo-hydrodynamic features within the thermocline tanks. The detailed analyses on these three categories of indicators are conducted. Moreover, the relevant influencing factors, including injecting flow rate of heat transfer fluid,... [more]

Saving energy and looking for alternative energy sources are both elements of energy efficiency management, which is still a significant challenge for many companies around the world. Unfortunately, energy efficiency in companies is often equated only with thermo-modernization or the replacement of lighting. However, one of the most important methods of improving energy use in manufacturing companies may be the modernization of the machine park. Therefore, the main purpose of the paper was to investigate the activities of enterprises in the field of the modernization of machines and the impact of this on the actual improvement of energy efficiency. The modernization of machines in production plants is understood as adapting new parts to the old device or rebuilding the machine in such a way that it can cooperate with its new subassemblies. Companies usually decide to modernize the machinery fleet, bearing in mind the benefits of production efficiency, and they do not always combine thi... [more]

According to United Nations data, half of the world’s population lives in cities and forecasts indicate that by the middle of the 21st century, this percentage will have increased to 65%. The increase in the urban population favors the creation of a network of interactions that entails a series of material and energy flows. These cause environmental impacts that affect the quality of life of citizens and the environment as a whole. According to data from the International Energy Agency, cities occupy 3% of the planet’s surface and are responsible for 67% of global energy consumption. The effects caused by this consumption, as well as its impact on the depletion of resources, make it necessary to carry out an exhaustive study of renewable energies and new energy saving systems. This Special Issue aims to present new advances and developments in renewable energy and energy saving systems that allow cities to evolve in a sustainable way.

Electric and hybrid-electric aircraft propulsion are rapidly revolutionising mobility technologies. Air travel has become a major focus point with respect to reducing greenhouse gas emissions. The electrification of aircraft components can bring several benefits such as reduced mass, environmental impact, fuel consumption, increased reliability and quicker failure resolution. Propulsion, actuation and power generation are the three key areas of focus in more electric aircraft technologies, due to the increasing demand for power-dense, efficient and fault-tolerant flight components. The necessity of having environmentally friendly aircraft systems has promoted the aerospace industry to use electrically powered drive systems, rather than the conventional mechanical, pneumatic or hydraulic systems. In this context, this paper reviews the current state of art and future advances in more electric technologies, in conjunction with a number of industrially relevant discussions. In this study,... [more]

The location of smart sustainable city multi-floor manufacturing (CMFM) directly in the residential area of a megapolis reduces the delivery time of goods to consumers, has a favorable effect on urban traffic and the environment, and contributes to the rational use of land resources. An important factor in the transformation of a smart city is the development of CMFM clusters and their city logistics nodes (CLNs); the key elements of the logistics system of a megapolis. The primary goal of this study was to examine the role of the CLN4.0, as a lead sustainability and smart service provider of a CMFM cluster within the Industry 4.0 paradigm, as well as its value in the system of logistics facilities and networks of a megalopolis. This paper presents an innovative model of a CLN4.0 under supply uncertainty using a material flow analysis (MFA) methodology, which allows for specific parameters of throughput capacity within the CMFM cluster and the management of supply chains (SCs) under un... [more]

The indoor air quality (IAQ) of severely polluted toilets is associated with the transmission of diseases. Computational fluid dynamics (CFD) methods and experimental measurements were used to analyze the diffusion characteristics of pollutants. This study investigated the diffusion characteristics and normalized concentration of ammonia and hydrogen sulfide pollutants under three ventilation systems—mixing ventilation (MV), personalized ventilation (PV), and impinging jet ventilation (IJV)—in a public toilet. The mean age of air (MAA) and air exchange efficiency (AEE) were also analyzed in our study. The results show that the MV scheme has a poor removal effect on pollutants compared with PV and IJV. IJV has advantages in reducing the normalized concentration of pollutants and improving the IAQ. Increasing the number of air changes per hour (ACH) may lead to a longer MAA and reduced air exchange efficiency. Choosing an appropriate number of air changes is very important to improve the... [more]

This article presents the analysis of the convergence of energy use from renewable sources among chosen European countries using a spatio-temporal approach. The high energy dependence of European countries on the economies of other continents makes the development of the use of renewable sources for energy production an important factor of their economic and social progress. The economic growth of every country is determined, among other factors, by an increase in the energy inputs. Therefore, in order to avoid excessive degradation of the environment, the use of renewable energy sources is increasingly becoming the crucial goal of governments worldwide. The analysis was conducted using data for 32 selected European countries in the years 1995−2019. In order to check progress in the case of the homogenization of renewable energy use, the β-convergence models for pooled cross-sectional and time-series data (TSCS) and also spatio-temporal β-convergence models were estimated. Absolute and... [more]

Liming surface water is a fairly popular method of increasing the pH values and decreasing the concentration of phosphates and heavy metals. According to the Environmental Protection Agency (EPA) recommendations, the increase of water pH should not exceed 1.5. If surface water is the source of water supply, liming is a process that reduces water contamination. This should prevent the creation of an additional load for the water treatment plants in urban settlements. This article is an interdisciplinary research study aiming to (1) determine and compare the doses of new dispersed, thermally activated limestone and natural limestone, (2) find the relation between dose value and initial water parameters (pH, Eh and total mineralization), and (3) create an artificial neural network (ANN) model to predict changes in water pH values according to EPA recommendations. Recommended doses were obtained from experimental studies, and those of dispersed, thermally activated limestone were lower tha... [more]

Vuilleumier refrigerators provide cooling power by utilizing a heat source at temperatures above the ambient. This is particularly helpful in situations where waste heat is available and other power sources are limited. Vuilleumier refrigerators come in different technical configurations; here we analyze the thermodynamic performance of a configuration utilizing two displacer pistons with integrated regenerators. More specifically, we optimize the cooling power by optimizing the piston movement for a range of operation speeds. The optimization is based on the AS motion class for cyclic dynamics and uses an endoreversible model for the refrigerator. Our focus is on the influence of the regeneration extent present, and we find performance gains of about 17% for high regeneration extent and of about 28% for lower regeneration extent.

The aim of the study was to assess the effect of anode materials, namely a carbon nanotube (CNT)-buckypaper and a commercial carbon paper (CP) on the performance of a two-chamber microbial electrolysis cell (MEC), in terms of hydrogen production and main electrochemical characteristics. The experiments were performed using both acetate-based synthetic wastewater and real wastewater, specifically the effluent of a dark fermentative hydrogenogenic reactor (fermentation effluent), using cheese whey (CW) as substrate. The results showed that CP led to higher hydrogen production efficiency and current density compared to the CNT-buckypaper anode, which was attributed to the better colonization of the CP electrode with electroactive microorganisms, due to the negative effects of CNT-based materials on the bacteria metabolism. By using the fermentation effluent as substrate, a two-stage process is developed, where dark fermentation (DF) of CW for hydrogen production occurs in the first step,... [more]

For some time, renewable solar energy generations using cellular photovoltaic panels have stood out among the options, especially in the segment of micro and small companies, where the return on investment is usually higher. In this context, when micro and small companies do not have the capital for the enterprises, several others, mainly small ones, have emerged to finance. However, significant difficulties occur for financiers in selecting investment portfolios, especially when considering the trade-off between return and risk and the covariations of return on investment, which are very common. In this type of selection, the Capital Asset Pricing Model criteria using the Gini risk can help significantly because this one is a more robust risk coefficient for assessments of non-normal probability distributions. However, searches for methods that meet the selection needs using the adjacent criteria are unsuccessful. Thus, this work seeks to help minimize the gap by presenting a new meth... [more]

The use of primary energy saving techniques and renewable energy systems has become mandatory to tackle the effects of global temperature rise. As a result, a transition is taking place from centralized energy generation to distributed energy generation. Starting from the experience concerning a 15 kW micro-CHP plant previously designed at DII, this paper addresses the development of a 1 kW micro-CHP system fueled by natural gas for single-family users. Specifically, the paper presents a wide experimental investigation aimed at optimizing performance and emissions of a small scale two-stroke spark ignition gasoline engine properly modified to be fueled with natural gas to make the engine more suitable for cogeneration purposes. The described activity was carried out at the DII of the University of Naples Federico II. Rigorous laboratory tests were conducted with the engine in order to characterize both gasoline and CNG operation in terms of brake mechanical power, overall efficiency an... [more]

Our study evaluated the specific methane yield (SMY) of selected wetland species subjected to wet and dry anaerobic digestion: Carex elata All. (CE), a mixture (~50/50) of Carex elata All. and Carex acutiformis L. (CA), Phragmites australis (Cav.) Trin. ex Steud. (PA), Typha latifolia L. (TL) and Phalaris arundinacea L. (PAr). Plants were harvested in late September, and therefore, the study material was characterised by high lignin content. The highest lignin content (36.40 ± 1.04% TS) was observed in TL, while the lowest (16.03 ± 1.54% TS) was found in CA. PAr was characterised by the highest hemicellulose content (37.55 ± 1.04% TS), while the lowest (19.22 ± 1.22% TS) was observed in TL. Cellulose content was comparable in almost all plant species studied and ranged from 25.32 ± 1.48% TS to 29.37 ± 0.87% TS, except in PAr (16.90 ± 1.29% TS). The methane production potential differed significantly among species and anaerobic digestion (AD) technologies. The lowest SMY was observed fo... [more]

This study investigated the prioritization and ranking problem of the appropriate locations at which to deploy solar photovoltaic (PV) farms. Although different Multicriteria Decision Making (MCDM) methods can be found in the literature to address this problem, a comparative analysis of those methods is missing. The aim of this study is to compare four different MCDM approaches to evaluate and rank suitable areas for the deployment of solar PV farms, with the island of Rhodes (Greece) being used as an example. Feasible areas for the location of such facilities were identified with the use of Geographical Information Systems (GIS), by applying certain exclusion criteria found either in the national legislative framework or in the international literature. Data were obtained from Greek open geospatial data. The feasible sites were evaluated and ranked using four different MCDM methods: the Analytical Hierarchy Process (AHP), the Technique for Order Preference by Similarity to Ideal Solut... [more]

This study aimed to propose individual phase voltage regulation strategies using the sparrow search algorithm (SSA) in the IEEE 8500-node large-scale unbalanced distribution network with high photovoltaic (PV) penetration. The proposed approach is capable of individual phase regulation, which coordinates the on-load tap changer (OLTC), voltage regulator (VR), switched capacitor bank (SCB), and volt−var setting controlled by a smart inverter to improve voltage variation and unbalance. Consequently, the change time of VRs, the switched times of SCBs, and the individual phase voltage magnitude and unbalance ratio are considered in the fitness function for the SSA. The simulation scenarios fully consider the unbalanced load conditions and PV power output patterns, and the numerical results demonstrate that the voltage variation and unbalance are clearly improved, by 15% and 26%, respectively. The fitness values, operation times of OLTC, VR, and SCB, and the settings of the volt−var control... [more]

When a compressor is throttled to the near stall point, rotating instability (RI) is often observed as significant increases of amplitude within a narrow frequency band which can be regarded as a pre-stall disturbance. In the current study, a single compressor rotor row with varying blade tip clearance (1.3%, 2.6% and 4.3% chord length) was numerically simulated using the zonal large eddy simulation model. The mesh with six blade passages was selected to capture the proper dynamic feature after being validated in comparison to the measured data, and the dynamic mode decomposition (DMD) approach was applied to the numerical temporal snapshots. In the experimental results, RIs are detected in the configurations with middle and large tip gaps (2.6% and 4.3% chord length), and the corresponding characterized frequencies are about 1/2 and 1/3 of the blade passing frequency, respectively. Simulations provide remarkable performance in capturing the measured flow features, and the DMD modes co... [more]

The lignocellulosic perennial crop miscanthus, especially Miscanthus × giganteus, is particularly interesting for bioenergy production as it combines high biomass production with low environmental impact. However, there are several varieties that pose a hazard due to susceptibility to disease. This review contains links showing genotype and ecological variability of important characteristics related to yield and biomass composition of miscanthus that may be useful in plant breeding programs to increase bioenergy production. Some clones of Miscanthus × giganteus and Miscanthus sinensis are particularly interesting due to their high biomass production per hectare. Although the compositional requirements for industrial biomass have not been fully defined for the various bioenergy conversion processes, the lignin-rich species Miscanthus × giganteus and Miscanthus sacchariflorus seem to be more suitable for thermochemical conversion processes. At the same time, the species Miscanthus sinens... [more]

This article provides data on the environmental properties of biofuels obtained by the simultaneous extraction of oil from spoiled rapeseed and transesterification, with the addition of mineral diesel to the reaction mixture. The resulting reaction product contained 10% biodiesel: fatty acid methyl, ethyl, or butyl esters in mixtures with mineral diesel. The addition of biodiesel has been found to increase the rate of biodegradation of fuels. Such fuels are classified as partially biodegradable, according to the OECD classification. Life cycle analysis showed that the mixtures of biodiesel and mineral diesel have lower negative environmental impacts, compared to pure mineral diesel. The values of indicators such as abiotic depletion, acidification, global warming, ozone depletion, and human toxicity for these mixtures were 40−58% lower compared to the corresponding values for mineral diesel.

Hydrogen (H2) has become an important energy vector for mitigating the effects of climate change since it can be obtained from renewable sources and can be fed to fuel cells for producing power. Bioethanol can become a green H2 source via Ethanol Steam Reforming (ESR) but several variables influence the power production in the fuel cell. Herein, we explored and optimized the main variables that affect this power production. The process includes biomass fermentation, bioethanol purification, H2 production via ESR, syngas cleaning by a CO-removal reactor, and power production in a high temperature proton exchange membrane fuel cell (HT-PEMFC). Among the explored variables, the steam-to-ethanol molar ratio (S/E) employed in the ESR has the strongest influence on power production, process efficiency, and energy consumption. This effect is followed by other variables such as the inlet ethanol concentration and the ESR temperature. Although the CO-removal reactor did not show a significant e... [more]

The use of solar radiation in the urban environment is becoming increasingly important for the sustainable development of cities and human societies. Several factors influence the distribution of solar radiation in urban areas, including urban morphology and the physical properties of urban materials. Most of these factors can be modeled with a relatively high accuracy using 2D and 3D solar radiation models. In this paper, the r.sun and v.sun solar radiation models are used to calculate solar radiation for the city of Košice in Eastern Slovakia to assess the accuracy of both approaches for vertical surfaces frequently found in urban areas. The results were validated by pyranometer measurements. The results showed relatively good estimates by the 3D v.sun model and poor estimates by the 2D r.sun model. This can be attributed to an improper representation of vertical surfaces by a digital surface model, which has a strong impact on solar resource assessments. We found that 3D city models... [more]

In order to weaken the influence of external groundwater on in situ pyrolysis exploitation, the flow characteristics of groundwater were studied according to the oil shale reservoir characteristics of Qingshankou Formation in Songliao Basin, China. In addition, the parameters of marginal gas flooding for water-stopping were optimized. Taking a one-to-one pattern and a five-spot pattern as examples, the characteristics of groundwater flow under the in situ process were studied. Under the one-to-one pattern, the external groundwater flows into the production well from the low-pressure side, and the water yield was basically stable at 1000 kg/d. In the five-spot pattern, the groundwater can flow into the production wells directly from the windward side, and the water yield of the production well on the leeward side mainly comes from the desaturated zone; the water yield of each production well remains at a high level. By setting water-stopping wells around the production well and keeping... [more]

Battery energy storage systems (BESSs) play a critical role in eliminating uncertainties associated with renewable energy generation, to maintain stability and improve flexibility of power networks. In this paper, a BESS is used to provide energy arbitrage (EA) and frequency regulation (FR) services simultaneously to maximize its total revenue within the physical constraints. The EA and FR actions are taken at different timescales. The multitimescale problem is formulated as two nested Markov decision process (MDP) submodels. The problem is a complex decision-making problem with enormous high-dimensional data and uncertainty (e.g., the price of the electricity). Therefore, a novel co-optimization scheme is proposed to handle the multitimescale problem, and also coordinate EA and FR services. A triplet deep deterministic policy gradient with exploration noise decay (TDD−ND) approach is used to obtain the optimal policy at each timescale. Simulations are conducted with real-time electric... [more]

We demonstrated the efficient coupling of BiFeO3 (BFO) ferroelectric material within the carbon−sulfur (C-S) composite cathode, where polysulfides are trapped in BFO mesh, reducing the polysulfide shuttle impact, and thus resulting in an improved cyclic performance and an increase in capacity in Li-S batteries. Here, the built-in internal field due to BFO enhances polysulfide trapping. The observation of a difference in the diffusion behavior of polysulfides in BFO-coupled composites suggests more efficient trapping in BFO-modified C-S electrodes compared to pristine C-S composite cathodes. The X-ray diffraction results of BFO−C-S composite cathodes show an orthorhombic structure, while Raman spectra substantiate efficient coupling of BFO in C-S composites, in agreement with SEM images, showing the interconnected network of submicron-size sulfur composites. Two plateaus were observed at 1.75 V and 2.1 V in the charge/discharge characteristics of BFO−C-S composite cathodes. The observed... [more]