Mass transfer phenomena in polymeric electrolyte membrane fuel cells (PEMFC) electrodes has already been analyzed in terms of the interactions between diffusive and forced flows. It was demonstrated that the whole phenomenon could be summarized by expressing the Sherwood number as a function of the Peclet number. The dependence of Sherwood number on Peclet one Sh(Pe) function, which was initially deduced by determining three different flow regimes, has now been given a more accurate description. A comparison between the approximate and the accurate results for a reference condition of diluted reactant and limit current has shown that the former are useful for rapid, preliminary calculations. However, a more precise and reliable estimation of the Sherwood number is worth attention, as it provides a detailed description of the electrochemical kinetics and allows a reliable comparison of the various geometrical arrangements used for the distribution of the reactants.

We present a thermo-economic analysis of an Organic Rankine Cycle (ORC) for waste heat recovery. A case study for a heat source temperature of 150 °C and a subcritical, saturated cycle is performed. As working fluids R245fa, isobutane, isopentane, and the mixture of isobutane and isopentane are considered. The minimal temperature difference in the evaporator and the condenser, as well as the mixture composition are chosen as variables in order to identify the most suitable working fluid in combination with optimal process parameters under thermo-economic criteria. In general, the results show that cost-effective systems have a high minimal temperature difference ΔTPP,C at the pinch-point of the condenser and a low minimal temperature difference ΔTPP,E at the pinch-point of the evaporator. Choosing isobutane as the working fluid leads to the lowest costs per unit exergy with 52.0 €/GJ (ΔTPP,E = 1.2 K; ΔTPP,C = 14 K). Considering the major components of the ORC, specific costs range betw... [more]

As drivers of climate action, cities are taking measures to reduce greenhouse gas (GHG) emissions, which if left unabated pose a challenge to meeting long-term climate targets. The economics of climate action needs to be at the forefront of climate dialogue to prioritize investments among competing mitigation measures. A marginal abatement cost (MAC) curve is an effective visualization of climate action that initiates a technical and economic discussion of the cost-effectiveness and abatement potential of such actions among local leaders, policy makers, and climate experts. More commonly demonstrated for countries, MAC curves need to be developed for cities because of their heterogeneity, which vary in their urban activities, energy supply, infrastructure stock, and commuting patterns. The methodology for constructing bottom-up MAC curves for cities is presented for technologies that offer fuel switching and/or energy efficiencies, while considering technology lifetimes, city-specific... [more]

The rapid development of modern society has resulted in an increased demand for energy, mainly from fossil fuels. The use of this source of energy has led to the accumulation of carbon dioxide (CO₂) in the atmosphere. In this context, microalgae culturing may be an effective solution to reduce the CO₂ concentration in the atmosphere, since these microorganisms can capture CO₂ and, simultaneously, produce bioenergy. This work consists of a techno-economic assessment of a microalgal production facility integrated in a petrochemical complex, in which established infrastructure allows efficient material and energy transport. Seven different scenarios were considered regarding photosynthetic, lipids extraction and anaerobic digestion efficiencies. This analysis has demonstrated six economically viable scenarios able to: (i) reduce CO₂ emissions from a thermoelectric power plant; (ii) treat domestic wastewaters (which were used as culture medium); and (iii) produce lipids and electrical and... [more]

A ground-coupled heat pump (GCHP) system used to provide the space heating for an office room is a renewable, high performance technology. This paper discusses vapour compression-based HP systems, briefly describing the thermodynamic cycle calculations, as well as the coefficient of performance (COP) and CO₂ emissions of a HP with an electro-compressor and compares different heating systems in terms of energy consumption, thermal comfort and environmental impact. It is focused on an experimental study performed to test the energy efficiency of the radiator or radiant floor heating system for an office room connected to a GCHP. The main performance parameters (COP and CO₂ emissions) are obtained for one month of operation of the GCHP system, and a comparative analysis of these parameters is presented. Additionally, two numerical simulation models of useful thermal energy and the system COP in heating mode are developed using the Transient Systems Simulation (TRNSYS) software. Finally, t... [more]

Nanoscale FeS₂ was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS₂@C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS₂ batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS₂@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS₂) and that of uncoated FeS₂ was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS₂ were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS₂ batteries.

Natural gas hydrate accumulations were confirmed in the Dongsha Area of the South China Sea by the Guangzhou Marine Geological Survey 2 (GMGS2) scientific drilling expedition in 2013. The drilling sites of GMGS2-01, -04, -05, -07, -08, -09, -11, -12, and -16 verified the existence of a hydrate-bearing layer. In this work gas production behavior was evaluated at GMGS2-8 by numerical simulation. The hydrate reservoir in the GMGS2-8 was characterized by dual hydrate layers and a massive hydrate layer. A single vertical well was considered as the well configuration, and depressurization was employed as the dissociation method. Analyses of gas production sensitivity to the production pressure, the thermal conductivity, and the intrinsic permeability were investigated as well. Simulation results indicated that the total gas production from the reference case is approximately 7.3 × 10⁷ ST m³ in 30 years. The average gas production rate in 30 years is 6.7 × 10³ ST m³/day, which is much higher... [more]

This paper describes the reduced capacity of the inrush current suppressor using a matrix converter (MC) in a large-capacity wind power generation system (WPGS) with two squirrel-cage induction machines (SCIMs). These SCIMs are switched over depending on the wind speed. The input side of the MC is connected to the source in parallel. The output side of the MC is connected in series with the SCIM through matching transformers. The modulation method of the MC used is direct duty ratio pulse width modulation. The reference output voltage of the MC is decided by multiplying the SCIM current with the variable control gain. Therefore, the MC performs as resistors for the inrush current. Digital computer simulation is implemented to confirm the validity and practicability of the proposed inrush current suppressor using PSCAD/EMTDC (power system computer-aided design/electromagnetic transients including DC). Furthermore, the equivalent resistance of the MC is decided by the relationship betwee... [more]

Electric load forecasting is an important issue for a power utility, associated with the management of daily operations such as energy transfer scheduling, unit commitment, and load dispatch. Inspired by strong non-linear learning capability of support vector regression (SVR), this paper presents an SVR model hybridized with the differential empirical mode decomposition (DEMD) method and quantum particle swarm optimization algorithm (QPSO) for electric load forecasting. The DEMD method is employed to decompose the electric load to several detail parts associated with high frequencies (intrinsic mode function—IMF) and an approximate part associated with low frequencies. Hybridized with quantum theory to enhance particle searching performance, the so-called QPSO is used to optimize the parameters of SVR. The electric load data of the New South Wales (Sydney, Australia) market and the New York Independent System Operator (NYISO, New York, USA) are used for comparing the forecasting perfor... [more]

Currently, most hybrid electric vehicles (HEVs) equipped with automated mechanical transmission (AMT) are implemented with the conventional two-parameter gear shift schedule based on engineering experience. However, this approach cannot take full advantage of hybrid drives. In other words, the powertrain of an HEV is not able to work at the best fuel-economy points during the whole driving profile. To solve this problem, an optimization method of gear shift schedule for HEVs is proposed based on Dynamic Programming (DP) and a corresponding solving algorithm is also put forward. A gear shift schedule that can be employed in real-vehicle is extracted from the obtained optimal gear shift points by DP approach and is optimized based on analysis of the engineering experience in a typical Chinese urban driving cycle. Compared with the conventional two-parameter gear shift schedule in both simulation and real vehicle experiments, the extracted gear shift schedule is proved to clearly improve... [more]

The electricity sector is undergoing an evolution that demands the development of a network model with a high level of intelligence, known as a Smart Grid. One of the factors accelerating these changes is the development and implementation of renewable energy. In particular, increased photovoltaic generation can affect the network’s stability. One line of action is to provide inverters with a management capacity that enables them to act upon the grid in order to compensate for these problems. This paper describes the design and development of a prototype embedded system able to integrate with a photovoltaic inverter and provide it with multifunctional ability in order to analyze power quality and operate with protection. The most important subsystems of this prototype are described, indicating their operating fundamentals. This prototype has been tested with class A protocols according to IEC 61000-4-30 and IEC 62586-2. Tests have also been carried out to validate the response time in... [more]

Current offshore wind farms (OWFs) design processes are based on a sequential approach which does not guarantee system optimality because it oversimplifies the problem by discarding important interdependencies between design aspects. This article presents a framework to integrate, automate and optimize the design of OWF layouts and the respective electrical infrastructures. The proposed framework optimizes simultaneously different goals (e.g., annual energy delivered and investment cost) which leads to efficient trade-offs during the design phase, e.g., reduction of wake losses vs collection system length. Furthermore, the proposed framework is independent of economic assumptions, meaning that no a priori values such as the interest rate or energy price, are needed. The proposed framework was applied to the Dutch Borssele areas I and II. A wide range of OWF layouts were obtained through the optimization framework. OWFs with similar energy production and investment cost as layouts desig... [more]

A standalone DC microgrid integrated with distributed renewable energy sources, energy storage devices and loads is analyzed. To mitigate the interaction among distributed power modules, this paper describes a modeling and control design procedure for the distributed converters. The system configuration and steady-state analysis of the standalone DC microgrid under study are discussed first. The dynamic models of the distributed converters are then developed from two aspects corresponding to their two operating modes, device-regulating mode and bus-regulating mode. Average current mode control and linear compensators are designed accordingly for each operating mode. The stability of the designed system is analyzed at last. The operation and control design of the system are verified by simulation results.

The conversion efficiency of thin-film silicon solar cells needs to be improved to be competitive with respect to other technologies. For a more efficient use of light across the solar spectrum, multi-junction architectures are being considered. Light-management considerations are also crucial in order to maximize light absorption in the active regions with a minimum of parasitic optical losses in the supportive layers. Intrinsic and doped silicon oxide alloys can be advantageously applied within thin-film Si solar cells for these purposes. Intrinsic a-SiOx:H films have been fabricated and characterized as a promising wide gap absorber for application in triple-junction solar cells. Single-junction test devices with open circuit voltage up to 950 mV and ~1 V have been demonstrated, in case of rough and flat front electrodes, respectively. Doped silicon oxide alloys with mixed-phase structure have been developed, characterized by considerably lower absorption and refractive index with r... [more]

This paper presents an actuator control unit (ACU) with a 450-J embedded energy storage backup to face safety critical mechatronic applications. The idea is to ensure full operation of electric actuators, even in the case of battery failure, by using supercapacitors as a local energy tank. Thanks to integrated switching converter circuitry, the supercapacitors provide the required voltage and current levels for the required time to guarantee actuator operation until the system enters into safety mode. Experimental results are presented for a target application related to the control of servomotors for a robotized prosthetic arm. Mechatronic devices for rehabilitation or assisted living of injured and/or elderly people are available today. In most cases, they are battery powered with lithium-based cells, providing high energy density and low weight, but at the expense of a reduced robustness compared to lead-acid- or nickel-based battery cells. The ACU of this work ensures full operatio... [more]

The efficient operation of a passive solar house requires an efficient ventilation system to prevent the loss of energy and provide the required ventilation rates. This paper proposes the use of “breathing architectural members” (BAMs) as passive natural ventilation devices to achieve much improved ventilation and insulation performance compared to mechanical ventilation. Considering the importance of evaluating the ventilation and insulation performances of the members, we also propose numerical models for predicting the heat and air movements afforded by the members. The numerical model was validated by comparison with experimental results. The effectiveness of the BAMs was also verified by installation in houses located in an area with warm climate. For this purpose, chamber experiments were performed using samples of the BAMs, as well as numerical simulations to assess natural ventilation and heat load. The main findings of the study are as follows: (1) the one-dimensional chamber... [more]

Energy-efficient building performance requires sophisticated control systems that are based on realistic occupant behaviour models. To provide robust data for the development of these models, research studies in real-world settings are needed. Yet, such studies are challenging and necessitate careful design in terms of data collection methods and procedures. This paper describes and critiques the design of a mixed methods approach for occupant behaviour research. It reviews the methodology developed for a longitudinal study in a real-world office environment where occupants’ experience with a novel facade technology (electrochromic glazing) was investigated. The methodology integrates objective physical measurements, observational data and self-reported experience data. Using data from one day of the study, this paper illustrates how the different sources can be combined in order to derive an in-depth understanding of the interplay between external daylight conditions, characteristics... [more]

The evaluation of the thermodynamic performance of the mutual transformation of different kinds of exergy linked to the intensive thermodynamic parameters of the flow inside the ejector of a refrigeration system is undertaken. Two thermodynamic metrics, exergy produced and exergy consumed, are introduced to assess these transformations. Their calculation is based on the evaluation of the transiting exergy within different ejector sections taking into account the temperature, pressure and velocity variations. The analysis based on these metrics has allowed pinpointing the most important factors affecting the ejector’s performance. A new result, namely the temperature rise in the sub-environmental region of the mixing section is detected as an important factor responsible for the ejector’s thermodynamic irreversibility. The overall exergy efficiency of the ejector as well as the efficiencies of its sections are evaluated based on the proposed thermodynamic metrics.

The broad diffusion of renewable energy-based technologies has introduced several open issues in the design and operation of smart grids (SGs) when distributed generators (DGs) inject a large amount of power into the grid. In this paper, a theoretical investigation on active and reactive power data is performed for one active line characterized by several photovoltaic (PV) plants with a great amount of injectable power and two passive lines, one of them having a small peak power PV plant and the other one having no PV power. The frequencies calculated via the empirical mode decomposition (EMD) method based on the Hilbert-Huang transform (HHT) are compared to the ones obtained via the fast Fourier transform (FFT) and the wavelet transform (WT), showing a wider spectrum of significant modes mainly due to the non-periodical behavior of the power signals. The results obtained according to the HHT-EMD analysis are corroborated by the calculation of three new indices that are computed starti... [more]

Distributed renewable electricity generators facilitate decarbonising the electricity network, and the smart grid allows higher renewable penetration while improving efficiency. Smart grid scenarios often emphasise localised control, balancing small renewable generation with consumer electricity demand. This research investigates the applicability of proposed decentralised smart grid scenarios utilising a mixed strategy: quantitative analysis of PV adoption data and qualitative policy analysis focusing on policy design, apparent drivers for adoption of the deviation of observed data from the feed-in tariff impact assessment predictions. Analysis reveals that areas of similar installed PV capacity are clustered, indicating a strong dependence on local conditions for PV adoption. Analysing time series of PV adoption finds that it fits neither neo-classical predictions, nor diffusion of innovation S-curves of adoption cleanly. This suggests the influence of external factors on the decisio... [more]

This study describes the performance evaluation of an energy management system, based on electricity consumption, for a Gen 6 Thin Film Transistor Liquid Crystal Display (TFT-LCD) panel plant. Of the various production lines and facility systems, the array system and the compressed dry air consumed the most electricity of 21.8% and 19.8%, respectively, while the public utility used only 1.6% of the total electricity. The baseline electricity consumptions were correlated well (R² ≥ 0.77) to the monthly average wet-bulb temperatures of ambient air and the panel yield rates, which were determined by the product yield over the equipment available time index. After implementing the energy saving projects, the energy conservation performance was determined using a three-parameter change-point regression model incorporated with the panel yield rates. The post-retrofit monthly savings of the total electricity consumption for the panel manufacture were 5.35%⁻10.36%, with the efficiency of the e... [more]

The pulse-based charging method for battery cells has been recognized as a fast and efficient way to overcome the shortcoming of a slow charging time in distributed battery cells, which is regarded as a connection of cells such as the Internet of Things (IoT). The pulse frequency for controlling the battery charge duration is dynamically controlled within a certain range in order to inject the maximum charge current into the battery cells. The optimal frequency is determined in order to minimize battery impedance. The adaptation of the proposed pulse duty and frequency decreases the concentration of the polarization by sensing the runtime characteristics of battery cells so that it guarantees a certain level of safety in charging the distributed battery cells within the operating temperature range of 5⁻45 °C. The sensed terminal voltage and temperature of battery cells are dynamically monitored while the battery is charging so as to adjust the frequency and duty of the proposed chargin... [more]

With its large capacity, the total urban rail transit energy consumption is very high; thus, energy saving operations are quite meaningful. The effective use of regenerative braking energy is the mainstream method for improving the efficiency of energy saving. This paper examines the optimization of train dwell time and builds a multiple train operation model for energy conservation of a power supply system. By changing the dwell time, the braking energy can be absorbed and utilized by other traction trains as efficiently as possible. The application of genetic algorithms is proposed for the optimization, based on the current schedule. Next, to validate the correctness and effectiveness of the optimization, a real case is studied. Actual data from the Beijing subway Yizhuang Line are employed to perform the simulation, and the results indicate that the optimization method of the dwell time is effective.

The quest for single-stage deposition of CuInGaSe₂ (CIGS) is an open race to replace very effective but capital intensive thin film solar cell manufacturing processes like multiple-stage coevaporation or sputtering combined with high pressure selenisation treatments. In this paper the most recent achievements of Low Temperature Pulsed Electron Deposition (LTPED), a novel single stage deposition process by which CIGS can be deposited at 250 °C, are presented and discussed. We show that selenium loss during the film deposition is not a problem with LTPED as good crystalline films are formed very close to the melting temperature of selenium. The mechanism of formation of good ohmic contacts between CIGS and Mo in the absence of any MoSe₂ transition layers is also illustrated, followed by a brief summary of the measured characteristics of test solar cells grown by LTPED. The 17% efficiency target achieved by lab-scale CIGS devices without bandgap modulation, antireflection coating or K-dop... [more]

Logging residues, which refer to the unused portions of trees cut during logging, are important sources of biomass for the emerging biofuel industry and are critical feedstocks for the first-type biofuel facilities (e.g., corn-ethanol facilities). Logging residues are under-utilized sources of biomass for energetic purposes. To support the scaling-up of the bioenergy industry, it is essential to design cost-effective biofuel supply chains that not only minimize costs, but also consider the biomass quality characteristics. The biomass quality is heavily dependent upon the moisture and the ash contents. Ignoring the biomass quality characteristics and its intrinsic costs may yield substantial economic losses that will only be discovered after operations at a biorefinery have begun. This paper proposes a novel bioenergy supply chain network design model that minimizes operational costs and includes the biomass quality-related costs. The proposed model is unique in the sense that it suppor... [more]