A CO2-responsive composite of multiwall carbon nanotube (MWCNT) coated with polydopamine (PDA) and polydimethylamino-ethyl methacrylate (PDMAEMA) was prepared. The PDA was first self-polymerized on the surface of carbon nanotube. 2-bromoisobutyryl bromide (BiBB) was then immobilized by PDA and then initiated the ATRP of DMAEMA on the carbon nanotube surface. The resulting composite was characterized by Fourier-transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM). The CO2-responsive test was performed by bubbling CO2 into the mixture of MWCNT-PDA-PDMAEMA composite in water. A well-dispersed solution was obtained and the UV-Vis transmittance decreased dramatically. This is attributed to the reaction between PDMAEMA and CO2. The formation of ammonium bicarbonates on the surface of carbon nanotubes leads to the separation of nanotube bundles. This process can be reversed as the removal of CO2 by bubbling N2.

Massive quantities of spent coffee grounds (SCGs) are generated by users around the world. Different processes have been proposed for SCG valorization, including pyrolytic processes to achieve carbonaceous materials. Here, we report the preparation of activated carbons through pyrolytic processes carried out under different experimental conditions and in the presence of various porosity activators. Textural and chemical characterization of the obtained carbons have been achieved through Brunauer−Emmett−Teller (BET), ESEM, 13C solid state NMR, XPS, XRD, thermogravimetric and spectroscopic determinations. The aim of the paper is to relate these data to the preparation method, evaluating the correlation between the spectroscopic data and the physical and textural properties, also in comparison with the corresponding data obtained for three commercial activated carbons used in industrial adsorption processes. Some correlations have been observed between the Raman and XPS data.

Sensor faults frequently occur in wastewater treatment plant (WWTP) operation, leading to incomplete monitoring or poor control of the plant. Reliable operation of the WWTP considerably depends on the aeration control system, which is essentially assisted by the dissolved oxygen (DO) sensor. Results on the detection of different DO sensor faults, such as bias, drift, wrong gain, loss of accuracy, fixed value, or complete failure, were investigated based on Principal Components Analysis (PCA). The PCA was considered together with two statistical approaches, i.e., the Hotelling’s T2 and the Squared Prediction Error (SPE). Data used in the study were generated using the previously calibrated first-principle Activated Sludge Model no.1 for the Anaerobic-Anoxic-Oxic (A2O) reactors configuration. The equation-based model was complemented with control loops for DO concentration control in the aerobic reactor and nitrates concentration control in the anoxic reactor. The PCA data-driven model w... [more]

This study investigated the long-term effect of horizontal Ground-Source Heat Exchangers (GSHEs) on mitigating permafrost thaw settlement. In the conceptual system, a fan coil was used to chill the recirculating fluid in the linear High-Density Polyethylene (HDPE) ground loop system. A fully coupled thermo-hydro-mechanical finite element framework was employed to analyze multiphysics processes involved in the thaw settlement phenomenon. To investigate the sustainability of the system, a period of 50 years was simulated. Two operational modes were defined: one without and the other with HDPE. Different heat carrier velocities and inlet temperatures, and heat exchanger depths were examined to explore their effects on the thaw settlement rate. It was concluded that the proposed system can effectively alleviate the predicted permafrost thaw settlement over the study period. Moreover, the heat carrier temperature was found to have a prominent impact on the thaw settlement rate amongst other... [more]

With the rapid development of solar energy, the photovoltaic (PV) module fault detection plays an important role in knowing how to enhance the reliability of the solar photovoltaic system and knowing the fault type when a system problem occurs. Therefore, this paper proposed the hybrid algorithm of chaos synchronization detection method (CSDM) with convolutional neural network (CNN) for studying PV module fault detection. Four common PV module states were discussed, including the normal PV module, module breakage, module contact defectiveness and module bypass diode failure. First of all, the defects in 16 pieces of 20W monocrystalline silicon PV modules were preprocessed, and there were four pieces of each fault state. When the signal generator delivered high frequency voltage to the PV module, the original signal was measured and captured by the NI PXI-5105 high-speed data acquisition system (DAS) and was calculated by CSDM, to establish the chaos dynamic error map as the image featu... [more]

Advancements in production techniques in PCB manufacturing industries are still required as compared to silicon-ICs fabrications. One of the concerned areas in PCBs fabrication is the use of conventional methodologies for metallization. Most of the manufacturers are still using the traditional Copper (Cu) laminates on the base substrate and patterning the structures using lithography processes. As a result, significant amounts of metallic parts are etched away during any mass production process, causing unnecessary disposables leading to pollution. In this work, a new approach for Cu metallization is demonstrated with considerable step-reducing pattern-transfer mechanism. In the fabrication steps, a seed layer of covalent bonded metallization (CBM) chemistry on top of a dielectric epoxy resin is polymerized using actinic radiation intensity of a 375 nm UV laser source. The proposed method is capable of patterning any desirable geometries using the above-mentioned surface modification f... [more]

The aim of this study is to investigate the effects of a combination extract of Gardeniae Fructus and Perillae Folium (GP) on inflammatory reactions in lipopolysaccharide (LPS)-activated mouse macrophages RAW 264.7 cells. Multiplex cytokine assay, Fluo-4 calcium assay, Flow cytometry assay for phospho-P38 MAPK, and quantitative PCR were carried out. GP significantly reduced LPS-induced productions of macrophage inflammatory protein (MIP)-1α and monokine induced by gamma interferon (MIG) and release of intracellular calcium in LPS-activated RAW 264.7 cells. GP also significantly inhibited P38 MAPK phosphorylation and mRNA levels of Chop, Camk2a, Stat1, Stat3, Jak2, Fas, Nos2, and Ptgs2 in LPS-activated RAW 264.7 cells. Taken together, this study represents that GP exerts anti-inflammatory effects on LPS-activated RAW 264.7 cells via ER stress-induced CHOP pathway.

The effects of ultrasonic treatment (UT)-assisted transglutaminase (TGase) catalysis on the physicochemical properties of individual αs-casein (αs-CN), β-casein (β-CN), and κ-casein (κ-CN) were investigated. After 60 min of incubation at 30 °C, αs-CN, β-CN, and κ-CN were cross-linked with TGase (6.0 units/mL), and high molecular weight polymers (>200 kDa) were formed. The use of TGase in conjunction with UT (20 kHz, power of 400 W, and amplitude 20%) led to an increase in the rate of αs-CN, β-CN, and κ-CN polymerization compared to the individual casein that contained TGase but did not undergo UT. SDS-PAGE scrutiny showed that the intensities of αs-CN, β-CN, and κ-CN incubation with regard to TGase and UT at 30 °C for 60 min noticeably decreased to 5.66 ± 0.39, 3.97 ± 0.43, and 26.07 ± 1.18%, respectively (p < 0.05). Particle size analysis results indicated that the molecule size appropriation for the cross-linking of αs-CN, β-CN, and κ-CN ranged from 6000 to 10,000 nm after 60 min... [more]

Hydroquinone (HDQ) is a natural depigmenting agent, which is commonly used in skin-toning preparations. The safety and greenness of analytical methods of HDQ quantification were not considered in previous literature. Therefore, a highly sensitive and ecologically greener reversed-phase high-performance thin-layer chromatography (RP-HPTLC)-based assay was established for HDQ estimation in four different commercial whitening creams (CWCs). The binary ethanol−water (60:40, v·v−1) mixture was utilized as the green solvent system. The estimation of HDQ was carried out at 291 nm. The present RP-HPTLC-based assay was linear in the 20−2400 ng band−1 range. The present analytical method was highly sensitive based on the detection and quantification data. The other validation parameters, such as accuracy, precision, and robustness, were also suitable for the determination of HDQ. Maximum HDQ quantities were obtained in CWC A (1.23% w·w−1) followed by CWC C (0.81% w·w−1), CWC D (0.43% w·w−1), and... [more]

Kiln is a prime need in the ceramics industry, where energy loss is a major part which consumes about 60% production cost through thermal energy for different applications. Higher density of fired and tunnel kiln refractory material lowers the thermal diffusivity and the proper selection of fired material minimizes the energy loss along the kiln. In particular, this research analysed the results of a heat recovery system comprised of a metallic recuperator which gives around 8% energy savings in natural gas consumption. In this work, detailed power quality analysis of low-power factor motors of a tunnel kiln was carried out and a power factor improvement solution was suggested to save electrical energy with payback period of 0.8 y. The motor operating at a low-power factor consumes more reactive power which does not produce beneficial work. A low-power factor around 0.4 causes network power loss, increases in transformer loss and voltage drops. The solution with accumulative capacitanc... [more]

In addition to their nutritional and physiological role, proteins are recognized as the major compounds responsible for the rheological properties of food products and their stability during manufacture and storage. Furthermore, proteins have been shown to be source of bioactive peptides able to exert beneficial effects on human health. In recent years, scholarly interest has focused on the incorporation of high-quality proteins into the diet. This fact, together with the new trends of consumers directed to avoid the intake of animal proteins, has boosted the search for novel and sustainable protein sources and the development of suitable, cost-affordable, and environmentally friendly technologies to extract high concentrations of valuable proteins incorporated into food products and supplements. In this review, current data on emergent and promising methodologies applied for the extraction of proteins from natural sources are summarized. Moreover, the advantages and disadvantages of t... [more]

, genetic hybrids of Saccharomyces cerevisiae and the Saccharomyces eubayanus, is one of the most widely used lager yeasts in the brewing industry. In recent years, new strategies have been adopted and new lines of research have been outlined to create and expand the pool of lager brewing starters. The vineyard microbiome has received significant attention in the past few years due to many opportunities in terms of biotechnological applications in the winemaking processes. However, the characterization of S. cerevisiae strains isolated from winery environments as an approach to selecting starters for beer production has not been fully investigated, and little is currently available. Four wild cryotolerant S. cerevisiae strains isolated from vineyard environments were evaluated as potential starters for lager beer production at laboratory scale using a model beer wort (MBW). In all tests, the industrial lager brewing S. pastorianus Weihenstephan 34/70 was used as a reference strain. The... [more]

(1) Background: Re-emerging influenza threats continue to challenge medical and public health systems. Quercetin is a ubiquitous flavonoid found in food and is recognized to possess antioxidant, anti-inflammatory, antiviral, and anticancer activities. (2) Methods: To elucidate the targets and mechanisms underlying the action of quercetin as a therapeutic agent for influenza, network pharmacology and molecular docking were employed. Biological targets of quercetin and target genes associated with influenza were retrieved from public databases. Compound−disease target (C-D) networks were constructed, and targets were further analyzed using KEGG pathway analysis. Potent target genes were retrieved from the compound−disease−pathway (C-D-P) and protein−protein interaction (PPI) networks. The binding affinities between quercetin and the targets were identified using molecular docking. (3) Results: The pathway study revealed that quercetin-associated influenza targets were mainly involved in... [more]

Solar architecture is defined as a kind of building integrated photovoltaic (BIPV) in which the PV modules are deployed to passive solar concepts, to minimize the heating and cooling load, to upgrade the indoor environment, and to be adjustable for regional weather and to continuously succeed architectural culture. Solar architecture needs to consider the architectural culture and climate of the region through an ecological convergence. The ecological criteria lead to optimizing solar architecture through an ecological convergence of a passive intelligence and renewable energy system. The optimal angle of the bi-facial PV module as a shade is 23.5° considering the physical interaction and the traditional architecture in Korea according to the ecological criteria. The shading concept of the PV module reduces 27.5~34% of the building cooling load. Effective solar irradiance (ESR) is very important not only for PV efficiency but also for the system usage rate. This ESR should be controlle... [more]

Refinery planning optimization is a challenging problem as regards handling the nonconvex bilinearity, mainly due to pooling operations in processes such as crude oil distillation and product blending. This work investigated the performance of several representative piecewise linear (or piecewise affine) relaxation schemes (referred to as McCormick, bm, nf5, and nf6t) and de (which is a new approach proposed based on eigenvector decomposition) that mainly give rise to mixed-integer optimization programs to convexify a bilinear term using predetermined univariate partitioning for instances of uniform and non-uniform partition sizes. The computational results showed that applying these schemes improves the relaxation tightness compared to only applying convex and concave envelopes as estimators. Uniform partition sizes typically perform better in terms of relaxation solution quality and convergence behavior. It was also seen that there is a limit on the number of partitions that contribu... [more]

Biodiesel is one of the more recent green fuel products in the world. It can be produced from several raw materials such as straight vegetable oils, animal fats, tallow, and waste cooking oils, and blended with diesel. Properties of biodiesel are different compared to fossil diesel in terms of production methods and emission levels released after combustion in an internal combustion engine. Kuwait consumes a huge amount of energy which is almost 8% to meet the increasing demand for electricity and water. Moreover, the use of electricity in the production of biodiesel increases energy use and cost of production. Kuwait is receiving an amount of solar irradiation ranging from 2050 kWh/m2 to 2100 kWh/m2. The present study is concerned with the evaluation of the potential to use solar energy to produce biodiesel from sheep fat waste as a raw material. An experimental test rig was set up for a single cylinder diesel engine in the laboratory, where a solar power system was used to assist the... [more]

The heat transfer efficiency of a regenerative thermal oxidizer with three canisters used for volatile organic compounds treatment was studied using numerical simulation methods. A one-dimensional model that took into account the variation of physical parameters with temperature was built. The results show that the preheating temperature and outlet temperature tend to be stable as the operation time is increased. The heat transfer efficiency of equipment was mainly evaluated by heat recovery efficiency and energy recovery ratio under steady state conditions, which was affected by the inlet gas flow and temperature, valve switch time, combustion temperature, materials and porosity of the regenerative medium, and packing height. With the increase in packing cross-sectional area and packing height, the increase in heat transfer efficiency leads to an increase in equipment cost. Simultaneously, the shorter the valve switch time and the higher the density of the regenerative medium battery... [more]

In this study, the blade shape of the squirrel-cage fan system inside the range hood was optimized using the surrogate model to improve the maximum volume flow rate. The influence of computational fluid dynamics (CFD) noise was concerned. The regression Kriging model (RKM) was used as a surrogate model to reflect the relationship between the design parameters of the blade and the volume flow rate. The parallel filling criterion after re-interpolation was used to improve the optimization efficiency further and ensure global optimization. Through experimental verification, we found that the relative error between the volume flow rate of the optimal sample of RKM and the experiment was only 0.4%. Compared with the prototype, the maximum volume flow rate of the optimal sample of RKM was increased by 2.9%, and the efficiency under the corresponding working conditions was increased by 2%. RKM was used to predict the velocity field of the volute and impeller exit section to explore the feasib... [more]

In this paper, the analysis and discussion are presented for two prominent types of wireless charging, namely inductive power transfer (IPT) and capacitive power transfer (CPT). The paper presents a comparative analysis between CPT and IPT. A comparison between different geometries of plates used in CPT is performed and it is shown that rectangular-shaped plates have the best power transfer efficiency. The effect of foreign particles between the capacitor plates of a single-module as well as a double-module CPT system on capacitance and energy transfer density are also investigated in the paper. The case of ceramic coating on the capacitor plates and its effects on the capacitance and energy transfer density with varying thickness are analyzed and presented. Different naturally occurring particles such as water, sand and wet sand have been simulated between the capacitor plates of the CPT system and their respective impact on power transfer is analyzed and the simulation results are de... [more]

Quantitative determination of most economic valuable metals in waste is the first fundamental operation of evaluating the feasibility of recycling processes. Field-portable X-ray fluorescence spectrometers (FPXRFs) represent a more practical, efficient, and economic tool in determining the elemental composition of samples with respect to conventional analytical techniques, such as atomic absorption spectrometry (AAS) and inductively coupled plasma emission spectrometry (ICP). In this paper, quick and smart determination of gold content in printed circuit boards (PCBs) of waste mobile phones was studied. The aim of the research was to combine the practicality of FPXRFs with the reliability of quantitative spectrometry analysis and evaluate the error between the two techniques. Several samples (33) of PCBs were ground to a size below 0.5 mm, and then, the powders were analyzed by FPXRFs at different acquisition times with five replications for each sample. The same analyzed samples then... [more]

Integrated energy services will have multiple values and far-reaching significance in promoting energy transformation and serving “carbon peak and carbon neutralization”. In order to balance the supply and demand of power system in integrated energy, it is necessary to establish a scientific model for power load forecasting. Different algorithms for short-term electric load forecasting considering meteorological factors are presented in this paper. The correlation between electric load and meteorological factors is first analyzed. After the principal component analysis (PCA) of meteorological factors and autocorrelation analysis of the electric load, the daily load forecasting model is established by optimal support vector machine (OPT-SVM), Elman neural network (ENN), as well as their combinations through linear weighted average, geometric weighted average, and harmonic weighted average method, respectively. Based on the actual data of an industrial park of Nantong in China, the predi... [more]

Pyrolysis (thermal decomposition) is considered as the most important stage of a forest fire before direct forest fuel ignition. This process is accompanied by soot particle formation. Such particles have a negative impact on public health in the vicinity of forest fires. The purpose of this article was to investigate the heat and mass transfer process occurring in a typical forest fuel element (birch leaf). The pyrolysis and soot formation processes were taken into account, and various forest fire scenarios were considered. Computational experiments were carried out using the high-level programming language Delphi. Heat and mass transfer processes were described by nonlinear non-stationary differential heat conduction equations with corresponding initial and boundary conditions. The differential equations were solved by the finite difference method. Nonlinearity was resolved using a simple iteration. The main results of the research were (1) physical and mathematical models proposed f... [more]

This paper uses an ultrasonic vibration-integrated array electrode for 301 stainless steel micro-hole drilling. The influence of machining parameters such as ultrasonic vibration amplitude, working voltage, pulse-off time and electrode feed rate on different processing characteristics are discussed. The experimental results show that the ultrasonic-assisted electrode array vibrating generates a periodic pressure difference for the electrolyte. The periodic pressure difference forms a pumping effect and a cavitation effect. The two effects can effectively renew the electrolyte in the machining gap and discharge the reaction product, gas and reaction heat from the gap. Machining speed can be increased by over 500% when the ultrasonic amplitude increases from 0.94 μm to 2.87 μm. Micro-hole drilling with the optimum experimental parameter combination of ultrasonic amplitude 2.87 μm, working voltage 11 V, pulse-off time 50 μs and electrode feed rate 5 μm/s can result in a minimum average di... [more]

When a PIV flowmeter is used to measure a large flow of natural gas, the flow field fluctuation and particle distribution have a significant influence on the measurement accuracy and the particle injection mode plays a key role in the flow field fluctuation and particle distribution. To improve the measurement accuracy of PIV flowmeters, the method of filling tracer particles in single pipes, multiple pipes, and L pipes of a natural gas DN100 pipeline under high-pressure working conditions was compared and analyzed through numerical calculation and testing. The results show that the disturbance distance of filling particles in L pipes was the shortest, but the particle distribution area was small, whereas the flow metering error was large. By shortening the intersection distance between the L tube injection flow field and the main flow field, the problem that the particles failed to fill the test area was effectively solved, and the peak turbulence intensity at the intersection of the... [more]

Brazil’s large biofuels industry generates significant amounts of effluents, e.g., vinasse from bioethanol, that can effectively be used as substrate for production of biogas via Anaerobic Digestion (AD). The Oxidative Coupling of Methane (OCM) is the heterogeneous catalytic oxidation of methane into ethylene, which is a main building block for the chemical industry. This work investigates the potential and competitiveness of bio-ethylene production via OCM using biogas produced by biological anaerobiosis of vinasse as a feedstock. The proposed process can add incentive to treat of vinasse via AD and replace fossil ethylene, thus potentially reducing emissions of Greenhouse Gases (GHG). A process model is developed in Aspen Plus v10 software and used to design an economic Biogas-based Oxidative Coupling of Methane (Bio-OCM) process that consumes biogas and oxygen as educts and produces ethylene, ethane, and light off-gases as products. Operating conditions in the reaction section are o... [more]