Crude oil is one of the major pollutants present. Its extraction and processing generate processing waters contaminated by hydrocarbons which are harmful to both human health and the flora and fauna that come into contact with it. Hydrocarbon contamination can involve soil and water, and several technologies are used for recovery. The most used techniques for the recovery of spilt oil involve chemical-physical methods that can remove most of the pollutants. Among these, must consider the bioremediation by microorganisms, mostly bacterial capable of degrading many of the toxic compounds contained within the petroleum. Microalgae participate in bioremediation indirectly, supporting the growth of degrading bacteria, and directly acting on contaminants. Their direct contribution is based on the activation of various mechanisms ranging from the production of enzymes capable of degrading hydrocarbons, such as lipoxygenases, to the attack through the liberation of free radicals. The following... [more]

This article presents an ultramodern modelling algorithm for predicting the remnant cellulose life cycle for oil-submerged power transformers based on the adaptive neuro-fuzzy interference system (ANFIS). The polymer characteristics, degree of polymerization (DP), and 2-furaldehyde (2FAL) of 100 power transformers were measured and collated, which were apportioned into 70 training databanks and 30 as testing datasets. The remnant cellulose life cycle of the transformer was predicted using the proposed ANFIS model characterized by polymer characteristics, DP and 2FAL as inputs. The proposed approach returns 98.23% training and 99.86% testing reliability. The proposed model was applied to 10 transformer case studies in predicting their remnant cellulose life cycle. To corroborate the proposed ANFIS, a comparative study was carried out by employing existing approaches in predicting the remnant life cycle of the case studies, and significant error margins were observed. At large, the resul... [more]

With the characteristics of low fracturing pressure, little damage to the reservoirs, and assuming the role of carbon storage, supercritical carbon dioxide (SC-CO2) fracturing is suitable for the development of unconventional oil and gas resources. Based on the tensile failure mechanism of rocks, this paper establishes a thermal-fluid-solid coupling initiation pressure model for SC-CO2 fracturing. Using this model, the changes in formation temperature and pore pressure near a wellbore caused by invasion of CO2 into the formation are analyzed, as well as the impact of these changes on the tangential stress of reservoir rocks. The field data of SC-CO2 fracturing in a sandstone gas well are used to validate the reliability of the model. The results show that SC-CO2 fracturing can significantly reduce the initiation pressure, which decreases with the increase in fracturing fluid injection rate. The minimum value of tangential stress is located at the well wall, and the direction of tangent... [more]

This research paper presents novel condensed CNN architecture for the recognition of multispectral images, which has been developed to address the lack of attention paid to neural network designs for multispectral and hyperspectral photography in comparison to RGB photographs. The proposed architecture is able to recognize 10-band multispectral images and has fewer parameters than popular deep designs, such as ResNet and DenseNet, thanks to recent advancements in more efficient smaller CNNs. The proposed architecture is trained from scratch, and it outperforms a comparable network that was trained on RGB images in terms of accuracy and efficiency. The study also demonstrates the use of a Bayesian variant of CNN architecture to show that a network able to process multispectral information greatly reduces the uncertainty associated with class predictions in comparison to standard RGB images. The results of the study are demonstrated by comparing the accuracy of the network’s predictions... [more]

In this paper, a multi-objective collaborative optimization (MOCO) strategy is proposed for making decisions on a distillation column group. Firstly, based on data preprocessing, the operating modes of the tower group are determined by use of the fuzzy C-means clustering method. Secondly, based on the proposed concept of a collaborative variable, the discrete state-space model of the main towers are constructed by the subspace identification method. Then, a MOCO optimization model is designed for the ethylene plant. Finally, NSGA-III is used to solve the optimization problem. An analysis of a Pareto-optimal frontier and population is carried out. To illustrate the superiority of the proposed strategy, the results are compared with historical data and the appealing operation area is finally obtained.

Friction stir welding is a material processing technique used to combine dissimilar and similar materials. Ultimate tensile strength (UTS) is one of the most common objectives of welding, especially friction stir welding (FSW). Typically, destructive testing is utilized to measure the UTS of a welded seam. Testing for the UTS of a weld seam typically involves cutting the specimen and utilizing a machine capable of testing for UTS. In this study, an ensemble deep learning model was developed to classify the UTS of the FSW weld seam. Consequently, the model could classify the quality of the weld seam in relation to its UTS using only an image of the weld seam. Five distinct convolutional neural networks (CNNs) were employed to form the heterogeneous ensemble deep learning model in the proposed model. In addition, image segmentation, image augmentation, and an efficient decision fusion approach were implemented in the proposed model. To test the model, 1664 pictures of weld seams were cre... [more]

The effects of the adhesive thickness and overlap of a polyurethane adhesive have been studied by using different substrate configurations. Single lap joint (SLJ) specimens have been tested with homologous substrates, carbon fibre-reinforced plastics and painted metal substrates. Furthermore, a configuration with dissimilar substrates has been included in the experimental campaign. Both types of these adhesive and substrates are used in the automotive industry. The bonding procedure has been carried out without a surface treatment in order to quantify the shear strength and stiffness when surface treatments are not used on the substrates, reproducing typical mass production conditions. Three different ageing cycles have been used to evaluate the effects on SLJ specimens. A finite element model that uses cohesive modelling has been built and optimised to assess the differences between the different adopted SLJ configurations.

This study is devoted to the Fenton reaction, which, despite hundreds of reports in a number of scientific journals, provides opportunities for further investigation of its use as a method of advanced oxidation of organic macro- and micropollutants in its diverse variations and hybrid systems. It transpires that, for example, the choice of the concentrations and ratios of basic chemical substances, i.e., hydrogen peroxide and catalysts based on the Fe2+ ion or other transition metals in homogeneous and heterogeneous arrangements for reactions with various pollutants, is for now the result of the experimental determination of rather randomly selected quantities, requiring further optimizations. The research to date also shows the indispensability of the Fenton reaction related to environmental issues, as it represents the pillar of all advanced oxidation processes, regarding the idea of oxidative hydroxide radicals. This study tries to summarize not only the current knowledge of the Fen... [more]

Celecoxib, a cyclooxygenase-2 inhibitor (COX-2), is attracting considerable interest owing to its potential anticancer activity. The repurposing strategy of this drug, however, requires preclinical assessment involving the use of increasingly improved analytical methods. In this work, a rapid, accurate, precise, and sensitive reversed-phase high-performance liquid chromatography (RP-HPLC) method was developed for the quantification of celecoxib in five mouse matrices (plasma, brain, spleen, liver, and kidney). Chromatographic separation was achieved within 8 min on a reversed-phase C18 column at 35 °C using a mixture of acetonitrile and 2% (v/v) acetic acid (50:50) as mobile phase, at a flow rate of 0.6 mL/min. Celecoxib and curcumin, as the internal standard, were analyzed at 425 nm and 250 nm, respectively. Linearity was observed (r2 ≥ 0.996) in the concentration ranges selected for celecoxib. Overall precision was below 14.9%, and accuracy was between −14.9% and 13.2%. The acceptanc... [more]

This article presents the preliminary results on the drying process in a fountain dryer designed and adapted to drying waist sawdust and/or chips of various morphology and moisture content. In terms of drying technology, it is important to reduce the demand for heat and electricity. The phenomena occurring during the drying of sawdust in a fountain dryer were analyzed. Modifications of a typical fountain dryer were proposed in order to dry the chips, to obtain appropriate moisture and quality suitable for the process of their further granulation for the production of pellets. The test stand and the most important properties of the fountain dryer were described and discussed. Such characteristic aims of the device, i.e., efficiency, combustion, air and exhaust gas flow measurements, among others, were presented. The characteristics of the sawdust drying curves as a function of temperature were also determined. Computer simulations of heat exchange, air, and exhaust gas flow velocities w... [more]

Trichlorosilane (SiHCl3) is an important raw material for preparing solar cells and semiconductor chips in the Siemens method. Since the boiling points of SiHCl3 and methyldichlorosilane (CH3SiHCl2) are close to each other, it is difficult to remove CH3SiHCl2 from the raw material to obtain high-purity products by traditional distillation methods. Therefore, we propose an efficient catalytic approach to convert CH3SiHCl2 to methyltrichlorosilane (CH3SiCl3) with an anion-exchange resin as the catalyst and tetrachlorosilane (SiCl4) as the Cl donor in a continuous-flow fixed bed reactor. Seven anion-exchange resins, including D201, D301, D303, 201 × 7, D301F, D315 and D380 were evaluated. The results showed that D301 resin had the best performance. Reaction conditions such as reaction temperature, reactant molar ratio and catalyst stability were investigated. The maximum conversion of CH3SiHCl2 was 60% at an optimum reaction temperature of 150 °C, n(CH3SiHCl2):n(SiCl4) = 1:3 and a liquid... [more]

The surface subsidence caused by underground mining is a spatiotemporal process. The impact of mining on surface structures (houses, highways, railways, dikes, etc.) and structures in rock strata (shafts, roadways, chambers, etc.) is a dynamic process. It is necessary to study the dynamic movement law of the surface and overlying strata in the mining process of the working face to predict the extent of the impact of mining on the aforementioned structures. It provides a reference for pre-reinforcement and post-mining treatment. This paper studies the variation of surface dynamic movement based on the survey line above the working face of Peigou Coal Mine. The numerical simulation model of the overlying strata dynamic movement is established to study the dynamic movement law of rock strata with different depths, and the fitting function of surface and overlying strata dynamic movement is determined. Finally, the subsidence velocity prediction function of the major section of the surface... [more]

In this paper, a new hybrid MpGA-CS is elaborated between multi-population genetic algorithm (MpGA) and cuckoo search (CS) metaheuristic. Developed MpGA-CS has been adapted and tested consequently for modelling of bacteria and yeast fermentation processes (FP), due to their great impact on different industrial areas. In parallel, classic MpGA, classic CS, and a new hybrid MpGA-CS have been separately applied for parameter identification of E. coli and S. cerevisiae FP models. For completeness, the newly elaborated MpGA-CS has been compared with two additional nature-inspired algorithms; namely, artificial bee colony algorithm (ABC) and water cycle algorithm (WCA). The comparison has been carried out based on numerical and statistical tests, such as ANOVA, Friedman, and Wilcoxon tests. The obtained results show that the hybrid metaheuristic MpGA-CS, presented herein for the first time, has been distinguished as the most reliable among the investigated algorithms to further save computat... [more]

The exactitude of petroleum fluid molecular weight correlations affects significantly the precision of petroleum engineering calculations and can make process design and trouble-shooting inaccurate. Some of the methods in the literature to predict petroleum fluid molecular weight are used in commercial software process simulators. According to statements made in the literature, the correlations of Lee−Kesler and Twu are the most used in petroleum engineering, and the other methods do not exhibit any significant advantages over the Lee−Kesler and Twu correlations. In order to verify which of the proposed in the literature correlations are the most appropriate for petroleum fluids with molecular weight variation between 70 and 1685 g/mol, 430 data points for boiling point, specific gravity, and molecular weight of petroleum fluids and individual hydrocarbons were extracted from 17 literature sources. Besides the existing correlations in the literature, two different techniques, nonlinear... [more]

Coal mine noise affects human physiology, psychology, and behavior. It causes errors at work and increases accidents. In this study, we built a coal mine noise simulation experiment system. The system not only included an experimental environment simulation system and a physiological indicator test system, but it also added a miners’ working simulation system. This paper aimed to study the effect of different short-term (25 min) noise levels (60 dB, 70 dB, 80 dB, 90 dB, and 100 dB) on human physiology (skin conductivity and heart rate). Critical analysis showed that the stronger the noise intensity is, the shorter the contact time it takes for physiological indicators to present significant changes, and by setting different noises and measuring the skin conductivity and heart rate of human body, it was concluded that the noise level should be reduced to 90 dB to reduce accidents of miners.

With the combustor burning hydrogen, as well as the strongly coupled fuel and cooling system, the configuration of a hydrogen-fueled aero engine is more complex than that of a conventional aero engine. The performance, and especially the dynamic behavior of a hydrogen-fueled aero engine, need to be fully understood for engine system design and optimization. In this paper, both the transient modeling and performance analysis of hydrogen-fueled engines are presented. Firstly, the models specific to the hydrogen-fueled engine components and systems, including the hydrogen-fueled combustor, the steam injection system, a simplified model for a quick NOx emission assessment, and the heat exchangers, are developed and then integrated to a conventional engine models. The simulations with both Simulink and Speedgoat-based hardware in the loop system are carried out. Secondly, the performance analysis is performed for a typical turbofan engine configuration, CF6, and for the two hydrogen-fueled... [more]

Multi-crop plants (fibrous hemp, maize, and faba bean) can potentially be an alternative to wood biomass pellets, but there is no detailed knowledge to support the suitability of this biomass for solid biofuel production. The aim of this study is to analyze and justify the suitability of multi-crop plant biomass for the production of biofuel pellets and to assess the environmental impact of burning them. This paper presents studies of physical-mechanical, thermal, and chemical characteristics of biofuel pellets from multi-crop plants and emissions during their combustion under laboratory conditions. The main parameters of the produced pellets were determined according to international standards, which are detailed in the methodology part. The length of the produced pellets ranged from 17.6 to 26.6 mm, and the diameter was about 6 mm. The density of wet pellets varied from 1077.67 to 1249.78 kg m−3. The amount of ash in the pellets varied from 5.75% to 8.02%. Determined lower calorific... [more]

Autoclaved aerated concrete is an excellent thermal insulation wall material, but with a large amount of waste. This paper describes the high-temperature activation and rehydration activity of waste cement−lime−sand autoclaved aerated concrete (SAAC) and discusses the high-temperature phase transition of SAAC. SAAC calcined at 750 °C was confirmed to be a metastable and amorphous state, which could hydrolyze Ca2+ ions with reactivity in water. The conductivity curve demonstrates that the concentration of ions in the suspension decreases rapidly at 150−250 min, and the hydration reaction turns dominant at this time. The hydration heat curve also displays a hydration exothermic peak at 2.5 h. In addition, the conductivity measurement of suspension and the exothermic measurement of hydration reaction proves that SAAC calcined at 750 °C has a hydration activity and can rehydrate with SiO2 in the system. The rehydration activity was verified by replacing 30% cement in the standard test bloc... [more]

Forty-eight crude oils with variations in specific gravity (0.782 ≤ SG ≤ 1.002), sulphur content (0.03 ≤ S ≤ 5.6 wt.%), saturate content (23.5 ≤ Sat. ≤ 92.9 wt.%), asphaltene content (0.1 ≤ As ≤ 22.2 wt.%), and vacuum residue content (1.4 ≤ VR ≤ 60.7 wt.%) were characterized with HTSD, TBP, and SARA analyses. A modified SARA analysis of petroleum that allows for the attainment of a mass balance ≥97 wt.% for light crude oils was proposed, a procedure for the simulation of petroleum TBP curves from HTSD data using nonlinear regression and Riazi’s distribution model was developed, and a new correlation to predict petroleum saturate content from specific gravity and pour point with an average absolute deviation of 2.5 wt.%, maximum absolute deviation of 6.6 wt.%, and bias of 0.01 wt.% was developed. Intercriteria analysis was employed to evaluate the presence of statistically meaningful relations between the different petroleum properties and to evaluate the extent of similarity between th... [more]

Uranium aerosols are released from uranium-containing materials in high-temperature environments caused by nuclear accidents or other processes. Research on the generation characteristics of uranium aerosols under such conditions is an important part of nuclear-safety analysis. In this experiment, the similarity between metal cerium aerosols and uranium material aerosols was evaluated from the aspects of particle size distribution and source term. Combined with the experiment data, the effect of air flow rate and sampling time is discussed. The calculation result of the air release fraction (ARF) is 6.07 × 10−3−4.8 × 10−2, and the respirable fraction (RF) is 0.810−0.978, respectively, showing that the size distribution of particles and ARF of the cerium aerosol are different from the results of the uranium aerosols in the literature, while the RF is similar to the results obtained by using the uranium−niobium alloy in the literature.

Cereal products are regarded as important protein providers, though they could feature poor nutritional quality due to their occasional imbalanced amino acid content. Cereal proteins are low in cysteine or tryptophan, and rich in methionine; however, while their combination with legume proteins makes them nutritionally more comprehensive, such a possibility must be addressed by the cereal processing industry. However, the incorporation of legume protein concentrates and isolates might also influence the functionality and bioavailability of some cereal constituents. Therefore, the objective of the present review is to gain insights into the effects of cereal products incorporated with legume protein isolates/concentrates, knowing that both the cereals and the protein extracts/isolates are complex structural matrices, and besides the final products acceptability they should efficiently promote the health condition of consumers. The combination of legume proteins with cereals will bring a... [more]

Lithium is a vital raw material used for a wide range of applications, such as the fabrication of glass, ceramics, pharmaceuticals, and batteries for electric cars. The accelerating electrification transition and the global commitment to decarbonization have caused an increasing demand for lithium. The current supply derived from brines and hard rock ores is not enough to meet the global demand unless alternate resources and efficient techniques to recover this valuable metal are implemented. In the past few decades, several approaches have been studied to extract lithium from aqueous resources. Among those studied, chemical precipitation is considered the most efficient technology for the extraction of metals from wastewater. This paper outlines the current technology, its challenges, and its environmental impacts. Moreover, it reviews alternative approaches to recover lithium via chemical precipitation, and systematically studies the effects of different operating conditions on the l... [more]

To ensure the ecological security of the basin, data on the heavy metal content in the sediments of the Weihe River Basin were collected to analyze the spatial distribution characteristics of heavy metals based on descriptive statistics and geostatistics. The geoaccumulation index and potential ecological risk assessment were conducted, and the number of pollution sources and the contribution rate were determined by combining correlation analysis, principal component analysis, and APCS-MLR. The results showed that the mean values of As, Pb, Zn, Ni, Cr, Hg, Cu, and Cd were 15.42, 27.27, 88.05, 31.05, 75, 0.13, 29.47, and 1.05 mg·kg−1, respectively. Igeo is in the order of Cd > Hg > As > Cu > Pb > Zn > Cr > Ni. Cd had the highest potential ecological risk factor, followed by Hg with a critical risk proportion of 12.6%. The traceability analysis showed that the heavy metals come from mixed, industrial, and agricultural sources, among which Pb, Zn, Ni, Cr, and Cu are affected by soil-formi... [more]

Quality control is considered a critical aspect of plastic materials in the injection molding process. Two types of deformations occur during the injection molding process, namely, volumetric shrinkage and warpage. This study aims to optimize the warpage of the polyethylene terephthalate preform (PET) used for the packing of carbonated drinks. PET warpage results in an uneven distribution of material over the wall surface of the preform and causes variation in wall thickness. During the filling operation of carbonated drinks, the preforms are subjected to high pressure at the points where the wall thickness is at a minimum, which induces a high-stress concentration. Under high pressure, the preforms are ruptured at the points where the warpage is at a maximum (stress concentration area), causing wastage of the beverage as well as the preform. In this study, the Taguchi method and analysis of variance (ANOVA) are used to determine the most significant parameters to induce warpage during... [more]

Anaerobic digestion allows for the proper management of agro-waste, including manure. Currently, more than 18,000 anaerobic digestion plants are under operation in EU, 80% of which are employed in the rural context. Tariff schemes for power generation from biogas produced during anaerobic digestion of agricultural feedstocks in Germany, Italy and Austria are coming to an end and new approaches are needed to exploit the existing infrastructures. Digesters in the rural context can be implemented and modified to be transformed into sustainable multi-feedstock and multi-purpose biorefineries for the production of energy, nutrients, proteins, bio-chemicals such as carboxylic acids, polyesters and proteins. This paper describes how the transition of agricultural anaerobic digesters into multi-products biorefineries can be achieved and what are the potential benefits originating from the application of a pilot scale platform able to treat cow manure and other crop residues while producing vol... [more]