LAPSE:2023.11332
Published Article

LAPSE:2023.11332
Fenton Reaction−Unique but Still Mysterious
February 27, 2023
Abstract
This study is devoted to the Fenton reaction, which, despite hundreds of reports in a number of scientific journals, provides opportunities for further investigation of its use as a method of advanced oxidation of organic macro- and micropollutants in its diverse variations and hybrid systems. It transpires that, for example, the choice of the concentrations and ratios of basic chemical substances, i.e., hydrogen peroxide and catalysts based on the Fe2+ ion or other transition metals in homogeneous and heterogeneous arrangements for reactions with various pollutants, is for now the result of the experimental determination of rather randomly selected quantities, requiring further optimizations. The research to date also shows the indispensability of the Fenton reaction related to environmental issues, as it represents the pillar of all advanced oxidation processes, regarding the idea of oxidative hydroxide radicals. This study tries to summarize not only the current knowledge of the Fenton process and identify its advantages, but also the problems that need to be solved. Based on these findings, we identified the necessary steps affecting its further development that need to be resolved and should be the focus of further research related to the Fenton process.
This study is devoted to the Fenton reaction, which, despite hundreds of reports in a number of scientific journals, provides opportunities for further investigation of its use as a method of advanced oxidation of organic macro- and micropollutants in its diverse variations and hybrid systems. It transpires that, for example, the choice of the concentrations and ratios of basic chemical substances, i.e., hydrogen peroxide and catalysts based on the Fe2+ ion or other transition metals in homogeneous and heterogeneous arrangements for reactions with various pollutants, is for now the result of the experimental determination of rather randomly selected quantities, requiring further optimizations. The research to date also shows the indispensability of the Fenton reaction related to environmental issues, as it represents the pillar of all advanced oxidation processes, regarding the idea of oxidative hydroxide radicals. This study tries to summarize not only the current knowledge of the Fenton process and identify its advantages, but also the problems that need to be solved. Based on these findings, we identified the necessary steps affecting its further development that need to be resolved and should be the focus of further research related to the Fenton process.
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Keywords
advanced oxidation processes, Fenton reaction, Fenton-like reactions, wastewater treatment
Subject
Suggested Citation
Kastanek F, Spacilova M, Krystynik P, Dlaskova M, Solcova O. Fenton Reaction−Unique but Still Mysterious. (2023). LAPSE:2023.11332
Author Affiliations
Kastanek F: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Spacilova M: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Krystynik P: Faculty of Environment, University of J. E. Purkyne in Usti nad Labem, Pasteurova 3632/15, 400 96 Usti nad Labem, Czech Republic [ORCID]
Dlaskova M: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Solcova O: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Spacilova M: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Krystynik P: Faculty of Environment, University of J. E. Purkyne in Usti nad Labem, Pasteurova 3632/15, 400 96 Usti nad Labem, Czech Republic [ORCID]
Dlaskova M: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Solcova O: Institute of Chemical Process Fundamentals of the Czech Academy of Sciences, Rozvojova 1/135, 165 00 Prague, Czech Republic [ORCID]
Journal Name
Processes
Volume
11
Issue
2
First Page
432
Year
2023
Publication Date
2023-02-01
ISSN
2227-9717
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Original Submission
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PII: pr11020432, Publication Type: Review
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LAPSE:2023.11332
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https://doi.org/10.3390/pr11020432
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Feb 27, 2023
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