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Showing records 25387 to 25411 of 43292. [First] Page: 1 1013 1014 1015 1016 1017 1018 1019 1020 1021 Last
25387. LAPSE:2023.13747
In Situ Growth of COF on PAN Nanofibers to Improve Proton Conductivity and Dimensional Stability in Proton Exchange Membranes
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: covalent organic frameworks, dimensional stability, electrospinning, fuel cell, nanofibers, perfluorosulfonic acid, polyacrylonitrile, proton exchange membranes
Perfluorosulfonic acid (PFSA) polymer is considered as a proton exchange membrane material with great potential. Nevertheless, excessive water absorption caused by abundant sulfonic acid groups makes PFSA have low dimensional stabilities. In order to improve the dimensional stability of PFSA membranes, nanofibers are introduced into PFSA membranes. However, because nanofibers lack proton conducting groups, it usually reduces the proton conductivities of PFSA membranes. It is a challenge to improve dimensional stabilities while maintaining high proton conductivities. Due to the structural designability, covalent organic frameworks (COFs) with proton conductive groups are chosen to improve the overall performance of PFSA membranes. Herein, COFs synthesized in situ on three-dimensional PAN nanofibers were introduced into PFSA to prepare PFSA@PAN/TpPa-SO3H sandwiched membranes. The PFSA@PAN/TpPa-SO3H-5 composite membrane exhibited outstanding proton conductivity, which reached 260.81 mS·cm... [more]
25388. LAPSE:2023.13746
Genetically Optimized Extended Kalman Filter for State of Health Estimation Based on Li-Ion Batteries Parameters
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: equivalent circuit model, genetic algorithm (GA), Kalman filter, lithium-ion battery, online parameters estimation, state of health (SOH)
The state of health (SOH) is among the most important parameters to be monitored in lithium-ion batteries (LIB) because it is used to know the residual functionality in any condition of aging. The paper focuses on the application of the extended Kalman filter (EKF) for the identification of the parameters of a cell model, which are required for the correct estimation of the SOH of the cell. This article proposes a methodology for tuning the covariance matrices of the EKF by using an optimization process based on genetic algorithms (GA). GAs are able to solve the minimization problems for the non-linear functions, and they are better than other optimization algorithms such as gradient descent to avoid the local minimum. To validate the proposed method, the cell parameters obtained from the EKF are compared with a reference model, in which the parameters have been determined with proven procedures. This comparison is carried out with different cells and in the whole range of the cell’s S... [more]
25389. LAPSE:2023.13745
Can the Relationship between Atmospheric Environmental Quality and Urban Industrial Structure Adjustment Achieve Green and Sustainable Development in China? A Case of Taiyuan City
March 1, 2023 (v1)
Subject: Environment
Keywords: atmospheric environmental quality, coupling coordination model, industrial structure, Taiyuan city, VAR model
Atmospheric environmental quality affects the high quality and sustainable development of the economy. The optimisation and upgrading of the industrial system are important to improve the operation efficiency of the economy and society. Firstly, this paper constructs the theoretical analysis framework of coupling and coordination between the atmospheric environment system and the industrial system and analyses the internal mechanism of the interaction and coordinated development of the two systems. Then, it puts forward the combination of the coupling coordination model and the VAR model (Vector autoregressive model) and presents the analysis and evaluation method of the relationship between them from the two perspectives of “static” and “dynamic”. Finally, the empirical study is conducted in Taiyuan, a resource-based city in China. The results show that: (1) The two systems in Taiyuan have an obvious interaction and develop in the direction of benign coupling. (2) The impact of the tw... [more]
25390. LAPSE:2023.13744
Sedimentary Characteristics of Lacustrine Beach-Bars and Their Formation in the Paleogene Weixinan Sag of Beibuwan Basin, Northern South China Sea
March 1, 2023 (v1)
Subject: Environment
Keywords: beach-bars, Beibuwan Basin, formation mechanism, sedimentary characteristics, Weixinan sag
Beach-bar reservoirs have been promising hydrocarbon-bearing exploration advances in the Beibuwan Basin, especially in the WZ12-2 area within the Weixinan sag. The sedimentary characteristics, distribution and formation mechanisms of beach-bar sand bodies in Mbr2 (Member 2) of the Paleogene Liushagang Fm. in the WZ12-2 area within the Weixinan sag were analyzed based on well-log, seismic and core data on thin section and heavy mineral data. Mbr2 in the WZ12-2 area comprises a third-order sequence, which consists of three systems tracts (lowstand systems tract, transgressive systems tract and a locally developed highstand systems tract). Thick beach-bar sand bodies are developed in the WZ12-2 area during the lowstand systems tract stage. The formation of sandy beach-bar sand bodies can be divided into five stages. By integrating lithology, mineral composition, sedimentary structures and geophysical characteristics, it can be concluded that the beach-bar sand bodies in the study area wer... [more]
25391. LAPSE:2023.13743
Advanced Control Techniques for Wind/Solar/Battery Systems
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: Batteries, photovoltaic source, pulse-width modulation, quasi-Z-source inverter, solar irradiance prediction, wind energy
This Editorial summarizes the papers of the Special Issue entitled ‘Advanced Control Techniques for Wind/Solar/Battery Systems’ published in Energies. The Special Issue includes four scientific articles published in 2021 and 2022 in the field of quasi-Z-Source inverter control, photovoltaic energy conversion, battery charge control, wind turbine speed control, and solar irradiance prediction. New scientific achievements with experimental verifications of the achieved results are presented in all articles.
25392. LAPSE:2023.13742
Layer-by-Layer Materials for the Fabrication of Devices with Electrochemical Applications
March 1, 2023 (v1)
Subject: Materials
Keywords: capacitors, electrochemistry, electrodes, Energy Storage, Layer-by-Layer, miniaturization, thin film
The construction of nanostructured materials for their application in electrochemical processes, e.g., energy storage and conversion, or sensing, has undergone a spectacular development over the last decades as a consequence of their unique properties in comparison to those of their bulk counterparts, e.g., large surface area and facilitated charge/mass transport pathways. This has driven strong research on the optimization of nanostructured materials for the fabrication of electrochemical devices, which demands techniques allowing the assembly of hybrid materials with well-controlled structures and properties. The Layer-by-Layer (LbL) method is well suited for fulfilling the requirements associated with the fabrication of devices for electrochemical applications, enabling the fabrication of nanomaterials with tunable properties that can be exploited as candidates for their application in fuel cells, batteries, electrochromic devices, solar cells, and sensors. This review provides an u... [more]
25393. LAPSE:2023.13741
Make Hay While the Sun Shines: Beneficiaries of Renewable Energy Promotion
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: enterprise survival, industrial transition, photovoltaics, Poland
One of the conditions behind the development of any company is its capability of meeting the constantly changing challenges posed by the surrounding environment. Photovoltaics in Poland has been a boom industry in recent years. On 1 April 2022, new changes in photovoltaics came into force. A very short transition time will bring about serious problems to companies dealing in the photovoltaics branch since it has had an exceptionally short time to sufficiently prepare for the changes. The article presents results of a questionnaire-based survey conducted among 394 companies dealing in fitting photovoltaic installations in Poland. The subjects were selected for participation according to the purposive sample principle. The aim of the article was to present and analyze the entrepreneurs’ opinions concerning prospects for development in the nearest year to come. The alterations to the system of support of prosumers, which entered into force on 1 April 2022, will limit the interest in photo... [more]
25394. LAPSE:2023.13740
Lean Burn Flame Kernel Characterization for Different Spark Plug Designs and Orientations in an Optical GDI Engine
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: flame kernel, lean burn, optically accessible engine, spark plug design
Lean burn spark ignition (SI) engines represent an effective solution for improving fuel economy and reducing exhaust emissions and can be implemented both in conventional and hybrid powertrains. On the other hand, lean operation increases cyclic variability with negative impact on power output, engine efficiency, roughness, and operating stability. Although this phenomenon has been widely investigated, the effects of flow field on the inception and development of flames in direct injection spark ignition (DISI) engines under lean burn conditions is not yet completely understood. In particular, the effect of spark plug geometry and electrode orientation with respect to tumble motion has been minimally investigated. For these reasons, two different spark-plug geometries (i.e., single- and double-ground electrode) and three different orientations (i.e., cross-, counter-, and uni-flow with respect to the direction of tumble motion) were investigated in an optically accessible DISI engine... [more]
25395. LAPSE:2023.13739
Renewable Energy, Urbanization, and CO2 Emissions: A Global Test
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: CO2 emissions, innovation, patents, Renewable and Sustainable Energy, urbanization
A fixed effects regression and two-step system generalized method of moments (GMM) is used to analyze secondary data from the World Bank, covering 163 countries over the period from 2000 to 2016. The study tests the relationship between renewable energy, urbanization, and CO2 emissions. The empirical results show that urbanization has an inverted U-shaped relationship with CO2 emissions, while renewable energy consumption mitigates CO2 emissions. If causal, a 1% increase in renewable energy use leads to a 1.2% decrease in CO2 emissions. The results also show that the GDP per capita has an inverted U-shaped relationship with CO2 emissions, confirming the environmental Kuznets curve (EKC). We also found that innovation, proxied by residents’ patents, has a non-linear effect on CO2 emissions. As a policy implication, developing countries should increase the share of renewable energy in their total energy use, and promote innovative activities by increasing government spending on R&D.
25396. LAPSE:2023.13738
Piezoelectric Energy Harvesting from Roadways under Open-Traffic Conditions: Analysis and Optimization with Scaling Law Method
March 1, 2023 (v1)
Subject: Optimization
Keywords: intelligent pavement, piezoelectric energy harvesting, scaling law method
Piezoelectric energy harvesting from roadways, which converts ambient vibration energy of roads into electric energy, has a wide range of potential applications in intelligent transportation systems. On-site open-traffic tests revealed that energy harvested by piezoelectric energy harvester (PEH) units embedded in roadways is far less than the value in laboratories, which may be because the parameters of traffic flow load (frequency, distribution, wave shape, etc.) and the road structure are significantly different from the pre-established conditions in laboratories or even on-site tests with only one vehicle passing. To address this issue, an analytical model for piezoelectric energy harvesting from roadways under open-traffic conditions was proposed to examine the mechanical response of the road structure and the electrical performance of the stack PEH units embedded in the road. The influence of all parameters in the energy-harvesting system was then obtained with the scaling law me... [more]
25397. LAPSE:2023.13737
Concept for Biomass and Organic Waste Refinery Plants Based on the Locally Available Organic Materials in Rural Areas of Poland
March 1, 2023 (v1)
Subject: Materials
Keywords: bioenergy, biofuel, biomass refinery, organic waste, rural area, valuable product
The importance of developing efficient and environmentally friendly means of biomass conversion into bioenergy, biofuels, and valuable products is currently high in Poland. Accordingly, herein, two new energy and biofuel units are proposed, namely, POLpec and POLbp, which are used as reference sources for comparing energy consumption and biofuel production in other countries or regions in the world. One POLpec equals 4400 PJ (195.1 Mtoe), reflecting the annual primary energy consumption of Poland in 2020. Meanwhile, one POLbp equals 42 PJ (1.0 Mtoe), referring to the annual production of biofuels in Poland in 2020. Additionally, a new import−export coefficient β is proposed in the current study, which indicates the relationship between the import and export of an energy carrier. More specifically, the potential of biomass and organic waste to be converted into energy, biofuels, and valuable products has been analysed for the rural areas of Poland. Results show that the annual biomass a... [more]
25398. LAPSE:2023.13736
Multi-Objective Optimal Scheduling of CHP Microgrid Considering Conditional Value-at-Risk
March 1, 2023 (v1)
Subject: Planning & Scheduling
Keywords: CHP microgrid, conditional value-at-risk, multi-objective optimal, sparrow search algorithm
A combined heating and power (CHP) microgrid has high flexibility and economy, but the output of renewable energy is uncertain. Meanwhile, excessive flexible load adjustment in the demand response process will increase user dissatisfaction. In order to solve the above problems, this paper quantifies uncertainty with the conditional value-at-risk (CVaR) of relative disturbance. Additionally, a multi-objective optimal scheduling model that takes into account both the operating economy and the demand-side power consumption satisfaction is established. In order to solve the multi-objective mixed-integer nonlinear programming problem well, we propose an improved sparrow search algorithm (ISSA), which solves the problem that the sparrow search algorithm (SSA) is prone to low accuracy, insufficient in population diversity and easy to be trapped in local optimum. Combined with the non-dominated solution ranking method, ISSA has the ability of multi-objective optimization. Finally, simulation o... [more]
25399. LAPSE:2023.13735
Study on the Environmental Efficiency of the Chinese Cement Industry Based on the Undesirable Output DEA Model
March 1, 2023 (v1)
Subject: Environment
Keywords: Chinese cement industry, DDF, efficiency loss, environmental efficiency
In recent decades, China’s cement production has been the highest in the world, but the extensive development model, which has been formed for a long time, has brought serious damage to the natural environment. In order to promote the transformation of the production mode of China’s cement industry, this paper adopts the nonparametric frontier method to analyze the environmental efficiency of China’s cement manufacturing industry using the input−output and pollutant emission data of China’s cement manufacturing industry from 2004 to 2016. The results show that the overall environmental efficiency of China’s cement industry is low, and there is still much room for improvement. Moreover, there are serious imbalances from very low to very high between different regions. Further investigation found that during the study period, strict environmental supervision brought an average compliance cost of CNY 23.41 billion to China’s cement manufacturing industry, but the overall environmental eff... [more]
25400. LAPSE:2023.13734
Machine Learning Short-Term Energy Consumption Forecasting for Microgrids in a Manufacturing Plant
March 1, 2023 (v1)
Subject: Energy Management
Keywords: energy consumption, LSTM, microgrids, short-term forecasting, smart grids
Energy production and supply are important challenges for civilisation. Renewable energy sources present an increased share of the energy supply. Under these circumstances, small-scale grids operating in small areas as fully functioning energy systems are becoming an interesting solution. One crucial element to the success of micro-grid structures is the accurate forecasting of energy consumption by large customers, such as factories. This study aimed to develop a universal forecasting tool for energy consumption by end-use consumers. The tool estimates energy use based on real energy-consumption data obtained from a factory or a production machine. This model allows the end-users to be equipped with an energy demand prediction, enabling them to participate more effectively in the smart grid energy market. A single, long short-term memory (LSTM)-layer-based artificial neural network model for short-term energy demand prediction was developed. The model was based on a manufacturing plan... [more]
25401. LAPSE:2023.13733
Valve Regulated Lead Acid Battery Evaluation under Peak Shaving and Frequency Regulation Duty Cycles
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: battery degradation, frequency regulation, grid energy storage, peak shaving, valve regulated lead acid battery
This work highlights the performance metrics and the fundamental degradation mechanisms of lead-acid battery technology and maps these mechanisms to generic duty cycles for peak shaving and frequency regulation grid services. Four valve regulated lead acid batteries have been tested for two peak shaving cycles at different discharge rates and two frequency regulation duty cycles at different SOC ranges. Reference performance and pulse resistance tests are done periodically to evaluate battery degradation over time. The results of the studies are expected to provide a valuable understanding of lead acid battery technology suitability for grid energy storage applications.
25402. LAPSE:2023.13732
Technical Development and Economic Evaluation of the Integration of Thermal Energy Storage in Steam Power Plants
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: coal-fired power plants, heat storage, power plant flexibilization, TES, thermal energy storage
Grid-compliant integration of renewable energies will in future require considerable increases in flexibility in the operation of conventional power plants. The integration of thermal energy storage systems (TES) into the power plant process can create considerable improvements, for example, in the speed of load change and partial load behavior. In the case of existing plants, there are thus good prospects of upgrading for more flexible operation, which promises improvements in the energy system that can be achieved in the relatively short term. The aim of this publication is, therefore, to identify integration options for TES in coal-fired power plants which would enable the desired high flexibility potentials and, at the same time, include cost-efficient solutions. By means of an iterative approach between future scenarios of the energy market, the power plant process, and the TES component, favored configurations were developed from a wide range of integration concepts. For this pur... [more]
25403. LAPSE:2023.13731
A Straightforward Approach to Site-Wide Assessment of Wind Turbine Tower Lifetime Extension Potential
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: damageequivalent loads, fatigue damage, lifetime extension, site assessment, wind farms, wind turbine tower
This contribution presents a novel methodology to evaluate the lifetime extension potential of wind turbines—taking towers as the key component that preserves onshore turbines’ structural integrity—as a consequence of the difference between design and site-specific loads. Specifically, attention is drawn to the site-specific wind direction distribution, which provides an additional source of lifetime extension potential. For this purpose, variants of closed-form solutions (based on the tower section’s normal stress) are developed to enable fatigue damage accumulation due to fore-aft and side-to-side bending moments at any point on the tower circumference without the need for further information on tower section geometry or material properties. Based on the degree of data availability, different scenarios are defined to estimate lifetime extension potential from the accurate tower’s normal stress and approximations using resultant bending moment, fore-aft bending moment, and finally, wi... [more]
25404. LAPSE:2023.13730
Oil-Immersed Power Transformer Condition Monitoring Methodologies: A Review
March 1, 2023 (v1)
Subject: Process Operations
Keywords: asset management, condition monitoring, oil-immersed power transformer, operational life estimation, transformer failure
A power transformer is one of the most critical and expensive assets in electric power systems. Failure of a power transformer would not only result in a downtime to the entire transmission and distribution networks but may also cause personnel and environmental hazards due to oil leak and fire. Hence, to enhance a transformer’s reliability and extend its lifespan, a cost-effective and reliable condition monitoring technique should be adopted from day one of its installation. This will help detect incipient faults, extend a transformer’s operational life, and avoid potential consequences. With the global trend to establish digital substation automation systems, transformer online condition monitoring has been given much attention by utilities and researchers alike. Several online and offline condition monitoring techniques have been recently proposed for oil-immersed power transformers. This paper is aimed at providing a state-of-the-art review for the various condition monitoring tech... [more]
25405. LAPSE:2023.13729
A 3D Transient CFD Simulation of a Multi-Tubular Reactor for Power to Gas Applications
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: biogas upgrading, CO2 methanation, Computational Fluid Dynamics, multi-tubular reactor, power to gas
A 3D stationary CFD study was conducted in our previous work, resulting in a novel reactor design methodology oriented to upgrading biogas through CO2 methanation. To enhance our design methodology incorporating relevant power to gas operational conditions, a novel transient 3D CFD modelling methodology is employed to simulate the effect of relevant dynamic disruptions on the behaviour of a tubular fixed bed reactor for biogas upgrading. Unlike 1D/2D models, this contribution implements a full 3D shell cooled methanation reactor considering real-world operational conditions. The reactor’s behaviour was analysed considering the hot-spot temperature and the outlet CH4 mole fraction as the main performance parameters. The reactor start-up and shutdown times were estimated at 330 s and 130 s, respectively. As expected, inlet feed and temperature disruptions prompted “wrong-way” behaviours. A 30 s H2 feed interruption gave rise to a transient low-temperature hot spot, which dissipated after... [more]
25406. LAPSE:2023.13728
Thermochemical Modeling of Metal Composition and Its Impact on the Molten Corium−Concrete Interaction: New Insights with Sensitivity Analysis
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: ablation depth, corium temperature, melt/corium metal content, molten corium–concrete interaction, water injection
The characterization of molten corium−concrete interaction (MCCI) has increasingly become a cause of concern because, in the case of a severe nuclear accident, the core could meltdown and release radiation into the environment. The objective of this study was to determine the thermochemical impact of metal content in the corium and analyze the effect of corium metal content on ablation depth, corium temperature, its viscosity and surface heat flux, and production of hydrogen, carbon monoxide, and carbon dioxide. The governing heat transfer equations were solved while considering the various thermochemical reactions in the existing numerical code in a comprehensive way. The developed MCCI model in CORQUENCH was validated against the data available in the literature. Our findings showed that the composition of corium, especially its metal content, has a noticeable effect on mitigating or aggravating the ablation depth and nuclear reactor integrity. We observed that during molten corium−c... [more]
25407. LAPSE:2023.13727
Nonlinear Hydraulic Vibration Modeling and Dynamic Analysis of Hydro-Turbine Generator Unit with Multiple Faults
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: high variability, hydraulic vibration, hydro-turbine generator unit, nonlinear dynamics
Hydraulic vibration is a critical factor affecting the stability and health of the hydro-turbine generator unit (HGU). This paper investigates the nonlinear dynamic characteristics of the HGU occurring from the hydraulic vibration. First, using the turbulence flow model, the lift and drag coefficients of the asymmetric airfoil blades are calculated at different Reynolds numbers and angles of attack. Based on the lift and drag coefficients of the asymmetric airfoil blade, a novel nonlinear mathematical model of asymmetric hydraulic forces is proposed for the asymmetric airfoil blade. Then, combining mechanic and electric asymmetric excitations, a coupled nonlinear mathematical model of the HGU is built using Lagrange equations. Moreover, the correctness of this model is verified. Finally, dynamic behaviors of the HGU changing with attack angle, deviation of the outlet blade angle, outlet guide vane angle, and Reynolds number are analyzed by bifurcation diagrams. It is found that increas... [more]
25408. LAPSE:2023.13726
Bioprocesses for the Biodiesel Production from Waste Oils and Valorization of Glycerol
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: biodiesel, bioprocesses, crude glycerol, purification, valorization, waste oils
The environmental context causes the use of renewable energy to increase, with the aim of finding alternatives to fossil-based products such as fuels. Biodiesel, an alternative to diesel, is now a well-developed solution, and its production from renewable resources makes it perfectly suitable in the environmental context. In addition, it is biodegradable, non-toxic and has low greenhouse gas emissions: reduced about 85% compared to diesel. However, the feedstock used to produce biodiesel competes with agriculture and the application of chemical reactions is not advantageous with a “green” process. Therefore, this review focuses only on bioprocesses currently taking an important place in the production of biodiesel and allow high yields, above 90%, and with very few produced impurities. In addition, the use of waste oils as feedstock, which now accounts for 10% of feedstocks used in the production of biodiesel, avoids competition with agriculture. To present a complete life-cycle of oil... [more]
25409. LAPSE:2023.13725
Data-Driven, Web-Based Parameter Identification for a Reduced-Order Model of the Chilean Power System
March 1, 2023 (v1)
Subject: System Identification
Keywords: data analytics, phasor measurement systems, power system scada
The current need for power-system control-room operational tools to increase real-time situational awareness has led to various proposals on data analytics algorithms to obtain operational information from SCADA and PMU power system networks. Most of the proposals are implemented in simulation, with reduced practical significance for system operators. This work proposes a web-based simple algorithm to identify the dynamic parameters of a reduced-order model of power system frequency dynamics that is implemented with industrial hardware on a PMU network in the Chilean power system. To demonstrate the applicability of the proposed tool, the algorithm is implemented in a web page with real-time monitoring of the frequency of the Chilean power system, so that utilities and academic institutions with access to PMU measurements can apply the proposed concepts regardless of the topology of the monitored system.
25410. LAPSE:2023.13724
Take the Right Seat: The Influence of Occupancy Schemes on Performance Indicators of Lighting in Open Plan Offices
March 1, 2023 (v1)
Subject: Planning & Scheduling
Keywords: artificial lighting, assignment problems, blossom algorithm, daily light dose, Energy Efficiency, Hungarian algorithm, occupancy schemes
Work processes and sociological structures can differ significantly between organizations. These organizational aspects determine user behavior, which in turn exerts considerable influence on the key performance indicators of artificial lighting systems. Accordingly, the use of generalized assumptions about user behavior in the building design phase can lead to large discrepancies between design and operation. In the following work, the possible influences of different occupancy schemes, an essential aspect of user behavior and shaped by the organization, on energy demand and workplace-related daylight dose are evaluated. For this purpose, calculations are made based on real measurement data of an open-plan office with zoned lighting. Multi-level calculation models are used to determine improved user distributions in the room to ensure optimization according to the desired target criteria. The results show that occupancy schemes have a significant impact on energy demand, contributing... [more]
25411. LAPSE:2023.13723
Pyrolysis Characteristics of Hailar Lignite in the Presence of Polyvinyl Chloride: Products Distribution and Chlorine Migration
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: chlorine migration, co-pyrolysis, low-rank coal, products distribution, PVC
This study investigated the effects of polyvinyl chloride (PVC) addition on low-rank coal’s pyrolysis characteristics, especially the products distribution and chlorine migration. Hailar lignite (HLE) with different industrial, pure, PVC-content additions were prepared (the mass percentage of PVC addition was from 5% to 25%), and the co-pyrolysis characteristics of HLE and PVC were performed on a fixed-bed reactor and thermogravimetric analyzer. The chars were characterized with X-ray diffraction (XRD), X-ray fluorescence (XRF), and Fourier-transform infrared (FT-IR) spectroscopy analysis. The gas and tar compositions were analyzed by using gas chromatography (GC) and a gas chromatography−mass spectrometry (GC−MS) system, respectively. The results indicate that the addition of PVC can increase the release amounts of CH4, C2H4, and C2H6, simultaneously reducing the release amount of CO2 and CO; the quality of pyrolysis tar was also improved, especially the alkane content in tar, which i... [more]
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