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Records with Type: Published Article
20743. LAPSE:2023.18391
Comparison Study on High Force Density Linear Motors for Compressor Application
March 8, 2023 (v1)
Subject: Modelling and Simulations
Keywords: dual-stator, linear compressor, permanent magnet motor, ring-type magnet
This paper presents the modular topologies of the dual-stator dual-winding permanent magnet (PM) linear motors for linear compressors used in the electrified transportation application. Compared to the conventional PM linear motor in compressor, the proposed modular model is designed with the same volume but a higher thrust force density and a further higher air pressure in air cylinder, which are competitive in the compressor industry. The proposed compact PM linear motors are constructed with tubular windings in both inner and outer stators, as well as the ring-type magnet in mover. Simulation results of motor characteristics are compared by three-dimensional finite element method (3D FEM). Finally, the prototypes of the proposed PM linear motors are manufactured and tested for the linear compressor application.
20744. LAPSE:2023.18390
Pressure Swing-Based Reactive Distillation and Dividing Wall Column for Improving Manufacture of Propylene Glycol Monomethyl Ether Acetate
March 8, 2023 (v1)
Subject: Optimization
Keywords: dividing-wall column, Optimization, pressure swing, Process Intensification, propylene glycol monomethyl ether acetate, Reactive Distillation
Propylene glycol monomethyl ether acetate (PGMEA) is a commonly used solvent in the rapidly developing semiconductor industry. Ultra-high purity PGMEA is required for this ultra-precision industry and to satisfy the current strict waste management regulations. The traditional PGMEA production process consumes considerable energy and has a high production cost. In this study, a novel heat integrated and intensified design, which applies a dividing wall column, reactive distillation, and pressure swing techniques, was proposed for improving the energy efficiency and reducing the cost of PGMEA production. Heat integration was applied to maximize the heat recovery of the process. All processes were simulated using the commercial simulator Aspen Plus V11. The economic and environmental parameters of the process alternative were assessed for a fair comparison with the conventional process. The results showed that heat integration of the optimal pressure swing-based reactive distillation and... [more]
20745. LAPSE:2023.18389
Investigation of Water Composition on Formation Damage and Related Energy Recovery from Geothermal Reservoirs: Geochemical and Geomechanics Insights
March 8, 2023 (v1)
Subject: Energy Systems
Keywords: carbonate geothermal reservoirs, energy recovery, formation damage, geochemical and geomechanics insights, water composition
The main challenge in extracting geothermal energy is to overcome issues relating to geothermal reservoirs such as the formation damage and formation fracturing. The objective of this study is to develop an integrated framework that considers the geochemical and geomechanics aspects of a reservoir and characterizes various formation damages such as impairment of formation porosity and permeability, hydraulic fracturing, lowering of formation breakdown pressure, and the associated heat recovery. In this research study, various shallow, deep and high temperature geothermal reservoirs with different formation water compositions were simulated to predict the severity/challenges during water injection in hot geothermal reservoirs. The developed model solves various geochemical reactions and processes that take place during water injection in geothermal reservoirs. The results obtained were then used to investigate the geomechanics aspect of cold-water injection. Our findings presented that... [more]
20746. LAPSE:2023.18388
Phase Change Materials (PCMs) Based in Paraffin/Synthetic Saponite Used as Heat Storage Composites
March 8, 2023 (v1)
Subject: Materials
Keywords: clay, one-pot synthetic organophilic saponite, phase change materials
Synthetic saponites were successfully used to prepare phase change materials (PCMs) based on paraffin/synthetic saponite. Paraffin/synthetic saponites PCMs were prepared by a solution intercalation process. The PCMs were characterized by powder X-ray diffraction, FT-IR spectroscopy, thermal analyses and nitrogen adsorption. The thermal properties and the stability of PCMs were measured by DSC analysis and from heating−cooling curves. The results showed that the prepared PCMs have a higher heating rate and a lower cooling speed than paraffin because the heat storage was improved with the synthetic saponite. A one-pot synthesis method for obtaining PCM has been successfully developed in this work. The material thus obtained had better results for heat storage applications.
20747. LAPSE:2023.18387
Study on the Positioning Accuracy of GNSS/INS Systems Supported by DGPS and RTK Receivers for Hydrographic Surveys
March 8, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: Differential Global Positioning System (DGPS), Global Navigation Satellite System (GNSS), hydrographic surveys, Inertial Navigation System (INS), International Hydrographic Organization (IHO), positioning accuracy, positioning availability, Real Time Kinematic (RTK)
Hydrographic surveys, in accordance with the International Hydrographic Organization (IHO) S-44 standard, can be carried out in the following five orders: Exclusive, Special, 1a, 1b and 2, for which minimum accuracy requirements for the applied positioning system have been set out. They are as follows, respectively: 1, 2, 5, 5 and 20 m, with a confidence level of 95% in two-dimensional space. The Global Navigation Satellite System (GNSS) network solutions (accuracy: 2−3 cm (p = 0.95)) and the Differential Global Positioning System (DGPS) (accuracy: 1−2 m (p = 0.95)) are now commonly used positioning methods in hydrography. Due to the fact that a new order of hydrographic surveys has appeared in the IHO S-44 standard from 2020—Exclusive, looking at the current positioning accuracy of the DGPS system, it is not known whether it can be used in it. The aim of this article is to determine the usefulness of GNSS/Inertial Navigation Systems (INS) for hydrographic surveys. During the research,... [more]
20748. LAPSE:2023.18386
A Highly Accurate NILM: With an Electro-Spectral Space That Best Fits Algorithm’s National Deployment Requirements
March 8, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: DSO—distributed system operator, E-V—electric vehicle, GMM—Gaussian mixture model, HGL—harmonic generating load (inspired from current’s physical components theory), KDE—kernel density estimation, KNN—K-nearest neighbor, NILM—nonintrusive load monitoring, NIS—network information system, P-V—photo-voltaic, PCA—principal component analysis, RNN—recurrent neural network, SGD—stochastic gradient descent
The central problems of some of the existing Non-Intrusive Load Monitoring (NILM) algorithms are indicated as: (1) higher required electrical device identification accuracy; (2) the fact that they enable training over a larger device count; and (3) their ability to be trained faster, limiting them from usage in industrial premises and external grids due to their sensitivity to various device types found in residential premises. The algorithm accuracy is higher compared to previous work and is capable of training over at least thirteen electrical devices collaboratively, a number that could be much higher if such a dataset is generated. The algorithm trains the data around 1.8×108 faster due to a higher sampling rate. These improvements potentially enable the algorithm to be suitable for future “grids and industrial premises load identification” systems. The algorithm builds on new principles: an electro-spectral features preprocessor, a faster waveform sampling sensor, a shorter requir... [more]
20749. LAPSE:2023.18385
Socioemotional Wealth (SEW) of Family Firms and CEO Behavioral Biases in the Implementation of Sustainable Development Goals (SDGs)
March 8, 2023 (v1)
Subject: Environment
Keywords: family firm, financial strategy, managerial overconfidence, Sustainable Development Goals (SDGs), sustainable entrepreneurship
Agreed upon by the UN member states, Agenda 2030 assumes joint action for long-term sustainable development. These actions are focused on the implementation of 17 Sustainable Development Goals (SDGs), where actions are assumed to lead to the suppression of negative externalities of human activity. It is stressed that the objectives of sustainable development can only be achieved through deep institutional changes in most dimensions of the economy, including the entrepreneurship dimension. Entrepreneurship plays a pivotal role in the sustainable transformation of the community, as the related activities of companies are the source of the desired structural changes. Entrepreneurial projects make the biggest contribution to the objectives of sustainable development through research and development, investment in new technologies, and innovation. The biggest threat to sustainable entrepreneurship is firms’ aggressive corporate financial strategy, which most often results from CEO overconfi... [more]
20750. LAPSE:2023.18384
The Impact of Corporate Governance on the Capital Structure of Companies from the Energy Industry. The Case of Poland
March 8, 2023 (v1)
Subject: Energy Management
Keywords: capital structure, CEO personal characteristics, corporate governance, emerging markets, energy sector, financial reporting, Poland, theories of capital structure
The energy sector is expected to face fundamental challenges in the near future. On the one hand, it is experiencing a rapidly increasing demand for energy. At the same time, it is subject to the pressure of the climate policy due to environmental issues. For the same reason, the energy sector is forced to undertake costly investments to transform production from black to green energy. The issue of financing has become one of the key problems of the energy sector, especially in those countries in which energy production traditionally is based on fossil fuels, i.e., coal. The paper aims to investigate the impact of corporate governance on the capital structure of companies from the energy industry. We use three proxies of corporate governance quality: institutional investors, the board size, and state ownership and investigate their impact on capital structure. Our findings suggest that the latter two negatively impact debt levels. In our model, we control for financial factors and CEO... [more]
20751. LAPSE:2023.18383
Experimental Evaluation of 3D Tortuosity of Long Laboratory Spark Trajectory for Sphere-Sphere and Sphere-Plane Discharges under Lightning and Switching Impulse Voltages
March 8, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: discharge channel, electrical discharge in air, lightning impulse, long laboratory spark, spark tortuosity, spark trajectory, switching impulse
Evaluation of attractive areas of high- and ultra-high voltage power transmission lines to direct lightning strokes is based on modeling of propagating progress of the lightning leader approaching the transmission line. The aim of the modeling is to determine the effectiveness of lightning protection for a given line design. The statistical models are currently being developed to extend the conventional deterministic models by embracing the randomness of the discharge channel in space and hence to reproduce the statistical distribution of the striking points. These models require experimental data for understanding of the lightning leader development process and to validate the model across the measurement data. This paper reports on the measured trajectories of discharge channels of long laboratory sparks in various high voltage laboratory arrangements. The sparks were initiated by switching and lightning impulses with peak values ranging from 1200 kV to 3364 kV of positive and negati... [more]
20752. LAPSE:2023.18382
Energy and Environmental Effects of Human Habits in Residential Buildings Due to COVID-19 Outbreak Scenarios in a Dwelling near Rome
March 8, 2023 (v1)
Subject: Environment
Keywords: building consumption, building simulation, COVID-19, hourly calculation method, human habits effects, HVAC, occupancy profile, UNI EN ISO 52016
The COVID-19 pandemic and resulting containment measures have shown that energy consumption in buildings is linked to several factors, such as living habits, occupancy profiles, and heating ventilation and air conditioning (HVAC) systems. This paper addresses the influences of such factors on energy consumption in a residential building, analysing different scenarios (pre-COVID-19, lockdown, post-COVID-19), in terms of discomfort and energy needs, through the new hourly calculation method (UNI EN ISO 52016). Energy and environmental effects were studied in a real case study near Rome by varying occupancy profiles, lighting and appliance schedules, and HVAC systems. Results show that, during the heating period, the lockdown scenario led to the lowest hours of discomfort (−29% on average), but the highest in the cooling period (up to +154%, +28% on average). The same scenario led to reasonable reduction of energy needs for heating (−14%), but also highlighted a significant increase (+60%... [more]
20753. LAPSE:2023.18381
A Method to Analyze the Performance of Geocooling Systems with Borehole Heat Exchangers. Results in a Monitored Residential Building in Southern Alps
March 8, 2023 (v1)
Subject: Energy Systems
Keywords: borehole heat exchangers, geocooling, geothermal energy, radiant underfloor systems, residential space cooling
Geothermal heat is an increasingly adopted source for satisfying all thermal purposes in buildings by reversible heat pumps (HP). However, for residential buildings located in moderate climates, geocooling, that implies the use of geothermal source for cooling buildings without the operation of HP, is an efficient alternative for space cooling not yet explored enough. Geocooling allows two main benefits: to cool the buildings by high energy efficiencies improving summer comfort; to recharge the ground if space heating is provided by HP exploiting the geothermal source (GSHP). In these cases, geocooling allows to avoid the decreasing of the performances of the GSHP for space heating over the years. To explore these issues, a method has been developed and tested on a real case: a new residential building in Lugano (southern Switzerland) coupled with 13 borehole heat exchangers. The system provides space heating in winter by a GSHP and space cooling in summer by geocooling. During a 40 mo... [more]
20754. LAPSE:2023.18380
Recyclables Collection Route Balancing Problem with Heterogeneous Fleet
March 8, 2023 (v1)
Subject: Optimization
Keywords: crew rostering problem, e-mobility, electric garbage trucks, electric vehicle, mix integer programming, Optimization, solid waste collection, solid waste management, vehicle routing problem
Nowadays, robust and efficient solid waste collection is crucial to motivate citizens to participate in the circular economy by sorting recyclable solid waste. Vocational vehicles, including garbage trucks, contribute significantly to CO2 emissions; therefore, it is strongly recommended, and in the European Union it is mandatory, to replace conventional-fuel-based garbage trucks with electric ones. For providing sustainable and energy-efficient solid waste collection with a heterogeneous fleet, in-depth mathematical computations are needed to support solving complex decision-making problems, including crew rostering and vehicle routing, because the distance and capacity of electric garbage trucks differ from conventional-fuel-based ones. However, the literature on solid waste collection using electric garbage trucks is still relatively scarce. The main contribution of this paper is developing an optimization problem for balancing travel distance assigned to each garbage truck of a hete... [more]
20755. LAPSE:2023.18379
Thermal Performance of Integrated Direct Contact and Vacuum Membrane Distillation Units
March 8, 2023 (v1)
Subject: Energy Systems
Keywords: direct contact membrane distillation (DCMD), integrated MD units, thermal performance, vacuum membrane distillation (VMD), water recovery factor
An integrated membrane distillation (MD) flowsheet, consisting of direct contact membrane distillation (DCMD) and vacuum membrane distillation (VMD) units, was proposed and analysed in terms of thermal performance and water recovery factor, for the first time. The same lab-scale membrane module (40 cm2) was used for carrying out experiments of DCMD and VMD at fixed feed operating conditions (deionised water at 230 L/h and ~40 °C) while working at the permeate side with deionised water at 18 °C and with a vacuum of 20 mbar for the DCMD and the VMD configuration, respectively. Based on experimental data obtained on the single modules, calculations of the permeate production, the specific thermal energy consumption (STEC) and the gained output ratio (GOR) were carried out for both single and integrated units. Moreover, the calculations were also made for a flow sheet consisting of two DCMD units in series, representing the “traditional” way in which more units of the same MD configuration... [more]
20756. LAPSE:2023.18378
Reliability Assessment of Aircraft Commutators
March 8, 2023 (v1)
Subject: Modelling and Simulations
Keywords: aircraft, commutator device, differential equations, Fokker–Planck equation, starter-generator
The article describes the method of predicting the reliability and durability of an aircraft commutator, which is a primary source of electric energy in helicopters. Tests were conducted for 10 starter-generators. From this research it follows that the technical condition of brushes and bearings has a significant impact on the reliability of starter-generators. The reliability of starter-generators was determined based on the method consisting of two stages that was adopted: the first stage involved determining the density function of changes in diagnostic parameter depending on the operating time, but the second stage included the assessment of the reliability of bearings of the starter-generator taking into account the real flight profile. The first stage of the adopted method consisted of defining the dynamic model of changing the length of the starter-generator’s brush, which became the probabilistic model. Subsequently, based on differential equations, Fokker−Planck partial differ... [more]
20757. LAPSE:2023.18377
Real-Time Data Acquisition and Processing System for MHz Repetition Rate Image Sensors
March 8, 2023 (v1)
Subject: Process Design
Keywords: 1D image acquisition, GOTTHARD, KALYPSO, linear camera, MicroTCA, optical spectrometer
An electro-optic detector is one of the diagnostic setups used in particle accelerators. It employs an electro-optic crystal to encode the longitudinal beam charge profile in the spectrum of a light pulse. The charge distribution is then reconstructed using data captured by a fast spectrometer. The measurement repetition rate should match or exceed the machine bunching frequency, which is often in the range of several MHz. A high-speed optical line detector (HOLD) is a linear camera designed for easy integration with scientific experiments. The use of modern FPGA circuits helps in the efficient collection and processing of data. The solution is based on Xilinx 7-Series FPGA circuits and implements a custom latency-optimized architecture utilizing the AXI4 family of interfaces. HOLD is one of the fastest line cameras in the world. Thanks to its hardware architecture and a powerful KALYPSO sensor from KIT, it outperforms the fastest comparable commercial devices.
20758. LAPSE:2023.18376
Formation of a Fast Charge Transfer Channel in Quasi-2D Perovskite Solar Cells through External Electric Field Modulation
March 8, 2023 (v1)
Subject: Energy Systems
Keywords: electric field modulation, ions, quasi-2D perovskite
Quasi-2D perovskites solar cells exhibit excellent environmental stability, but relatively low photovoltaic properties, compared with 3D perovskites solar cells. However, charge transport and extraction in quasi-2D perovskite solar cells are still limited by the inevitable quantum well effect, resulting in low power conversion efficiency (PCE). To date, most efforts concentrate on crystal orientation and favorable alignment during materials and films processing. In this paper, we demonstrated that the quasi-2D perovskite [(BA)2(MA)3Pb4I13 (n = 4)] solar cells show an optimized device performance through forming a fast charge transfer channel among 2D quantum wells through external electric field modulation, with appropriate modulation bias and time after the device has been fabricated. Essentially, ions will move directionally due to local polarization in quasi-2D perovskite solar cells under the action of electric field modulation. More importantly, the mobile ions function as a dopan... [more]
20759. LAPSE:2023.18375
The Influence of Investors’ Mood on the Stock Prices: Evidence from Energy Firms in Warsaw Stock Exchange, Poland
March 8, 2023 (v1)
Subject: Energy Management
Keywords: causality, emotions, energy market, mood, stock market, weather
The subject of this publication is an analysis of the sentiment of stock exchange investors in terms of making investment decisions in the energy sector of the Polish stock exchange. The investment mood is considered in the context of the possible impact of weather factors on investment decisions. Possible effects are verified in relation to the rates of return and the volume of trading of energy sector entities. The analysis is carried out both in terms of co-integration analyses as well as in econometric terms, in the cross-section of classic OLS models or causality analysis using VAR vector autoregression models. The main purpose of the issues discussed is the problem of indicating (illustrating) the presence or absence of mutual relations between weather factors and the stock market in terms of the methods considered.
20760. LAPSE:2023.18374
Exploring the Political Discursive Lock-Ins on Sustainable Aviation in Sweden
March 8, 2023 (v1)
Subject: Energy Policy
Keywords: aviation, discourse, electrified aviation, emission, industry, lock-in, policy, Sustainability
This article analyses the political discourse about governing the future of the aviation industry in Sweden and how a polarized and entrenched discursive path dependency around aviation makes it difficult to invest into aviation’s possible futures as a sustainable transport. We find three different politically merged frames in the political discussion about governing the road to sustainable aviation: (1) Neoliberal sustainable aviation, (2) Green Keynesian sustainable aviation and (3) National environmentalists’ aviation. We can see a discrepancy between two merged frames that believe sustainable aviation will be possible with more or less government support and steering (Neoliberal sustainable aviation and Green Keynesian sustainable aviation) whereas the third merged frame (National environmentalists’ aviation) argues that aviation is bound to be environmentally inferior to trains and, therefore, all focus should go to the later. We can see that there is not just a path dependency in... [more]
20761. LAPSE:2023.18373
Thermal Performance of Cemented Paste Backfill Body Considering Its Slurry Sedimentary Characteristics in Underground Backfill Stopes
March 8, 2023 (v1)
Subject: Energy Systems
Keywords: backfilled stope, CPB, heat transfer, sedimentary characteristic, thermophysical property
The combined mine backfill−geothermal (CMBG) system can be used to effectively extract geothermal energy by installing a heat exchange tube (HET) in the underground backfilled stopes of mines, which can be used as the heat supply for buildings in mines and the surrounding areas. The efficient performance of this system strongly depends on the thermal exchange process between the HET and its surrounding cemented paste backfill body (CPB). In this study, a validated simulation model is established to investigate the heat exchange performance of CPB, in which the nonuniformly distributed thermal properties in CPB are fully considered. The results indicate that the increase in the porosity has a negative effect on the heat exchange performance of CPB. With the increase in the porosity, the decreased rate of the conductive heat transfer in CPB could be up to approximately 18%. In conditions with seepage flow, the heat transfer capacity of CPB could be effectively improved. Generally, a high... [more]
20762. LAPSE:2023.18372
Functional Materials for Waste-to-Energy Processes in Supercritical Water
March 8, 2023 (v1)
Subject: Materials
Keywords: metal catalysts, metal oxides catalysts, supercritical water, supercritical water gasification, supercritical water oxidation, waste treatment
In response to increasing energy demand, various types of organic wastes, including industrial and municipal wastewaters, or biomass wastes, are considered reliable energy sources. Wastes are now treated in supercritical water (SCW) for non-fossil fuel production and energy recovery. Considering that SCW technologies are green and energetically effective, to implement them on a large scale is a worldwide interest. However, issues related to the stability and functionality of materials used in the harsh conditions of SCW reactors still need to be addressed. Here we present an overview on materials used in the SCW technologies for energy harvesting from wastes. There are catalysts based on metals or metal oxides, and we discuss on these materials’ efficiency and selectivity in SCW conditions. We focus on processes relevant to the waste-to-energy field, such as supercritical water gasification (SCWG) and supercritical water oxidation (SCWO). We discuss the results reported, mainly in the... [more]
20763. LAPSE:2023.18371
Identification of Grid Impedance by Broadband Signals in Power Systems with High Harmonics
March 8, 2023 (v1)
Subject: System Identification
Keywords: broadband signals, harmonic disturbances, impedance-based stability, power electronics, pseudo random binary sequence, small-signal stability, spectral leakage
Grid impedance is an important parameter and is used to perform impedance-based stability analysis for the operation of grid-connected systems, such as power electronics-interfaced solar, wind and other distributed power generation systems. The identification of grid impedance with the help of broadband signals is a popular method, but its robustness depends strongly on the harmonic disturbances caused by non-linear loads or power electronics. This paper provides an in-depth analysis of how harmonics affect the identification of grid impedance while using broadband measurements. Furthermore, a compensation method is proposed to remove the disturbing influences of harmonics on broadband impedance identification. This method is based on exploiting the properties of the used maximum-length binary sequence (MLBS). To explain the methodology of the proposed method, the design basis for the excitation signal is discussed in detail. The analysis from simulations and a real measurement in an i... [more]
20764. LAPSE:2023.18370
Reliability Enhancement of Power IGBTs under Short-Circuit Fault Condition Using Short-Circuit Current Limiting-Based Technique
March 8, 2023 (v1)
Subject: Process Control
Keywords: IGBTs, protection, reliability, short circuit fault
Like the widely-used semiconductor switch, Insulated Gate Bipolar Transistors (IGBTs) are subject to many failures and degradation in power electronic converters. In Short Circuit Fault (SCF), as the most reported failures in IGBTs, drastic, sudden temperature rise, and peak SCF current are widespread failures owing to a relatively long delay of the protection subsystem. This paper proposes a protection strategy to limit the junction temperature rise by limiting the SCF current by adding a small value resistor in the IGBT emitter. Second, it reduces the SCF current to a value much less than the saturated current. With the proposed control approach, sudden temperature rise during SCF is controlled, preventing significant failure in IGBTs. The extension of the permissible SCF time is achieved even for the cases with temporary arcs. A simple control loop activates in the SCF condition and does not create slow transients for the IGBT. The results of this paper are validated through simulat... [more]
20765. LAPSE:2023.18369
An Economic Model to Assess Profitable Scenarios of EAF-Based Steelmaking Plants under Uncertain Conditions
March 8, 2023 (v1)
Subject: Environment
Keywords: direct reduction, economic evaluation, electric arc furnace, environmental cost, steel plant, steelmaking process
The steelmaking processes are considered extremely energy-intensive and carbon-dependent processes. In 2018, it was estimated that the emissions from global steel production represented 7−9% of direct emissions generated by fossil fuels. It was estimated that a specific emissions value of 1.8 tCO2 per ton of steel was produced due to the carbon-dependent nature of the traditional blast furnace and basic oxygen furnace (BF-BOF) route. Therefore, it is necessary to find an alternative solution to the BF-BOF route for steel production to counteract this negative trend, resulting in being sustainable from an environmental and economic point of view. To this concern, the objective of this work consists of developing a total cost function to assess the economic convenience of steelmaking processes considering the variability of specific market conditions (i.e., iron ore price, scraps price, energy cost, etc.). To this purpose, a direct reduction (DR) process fueled with natural gas (NG) to f... [more]
20766. LAPSE:2023.18368
Lifecycle Assessment of a Non-Phase-Transition Drying Pyrolysis and Mass Conversion Technology
March 8, 2023 (v1)
Subject: Environment
Keywords: Biomass, carbon emission, lifecycle assessment, straw
A lifecycle model was established to explore the efficiency, economy, and greenhouse gas emissions of a non-phase-transition drying pyrolysis and mass conversion technology, based on the principle of lifecycle assessment. The evaluation scope included straw collection and transportation, drying and crushing, biomass pyrolysis, charcoal processing, and waste heat utilization. The results show that the energy output/input ratio for non-phase-transition drying pyrolysis was 20.43, and the energy efficiency was high. The pure profit from treating wet straw was USD 45.32 per ton, the profit margin of sales was 52.11%, and the economic benefit was high. The equivalent emission of CO2 was 34.10 g·MJ−1, demonstrating high environmental benefits. Therefore, non-phase-transition drying pyrolysis and mass conversion technology is a potential biomass utilization technology with energy, economic, and ecological benefits.
20767. LAPSE:2023.18367
Fabrication of High-Performance Flexible Supercapacitor Electrodes with Poly(3,4-ethylenedioxythiophene) (PEDOT) Grown on Carbon-Deposited Polyurethane Sponge
March 8, 2023 (v1)
Subject: Materials
Keywords: carbon material deposited sponge, poly(3,4-ethylenedioxythiophene), supercapacitor, vapor-phase polymerization
Composite porous supercapacitor electrodes were prepared by growing poly(3,4-ethylenedioxythiophene) (PEDOT) on graphite nanoplatelet- or graphene nanoplatelet-deposited open-cell polyurethane (PU) sponges via a vapor phase polymerization (VPP) method. The resulting composite supercapacitor electrodes exhibited great capacitive performance, with PEDOT acting as both the conductive binder and the active material. The chemical composition was characterized by Raman spectroscopy and the surface morphology was characterized by scanning electron microscopy (SEM). Cyclic voltammetry (CV), charge-discharge (CD) tests and electrochemical impedance spectroscopy were utilized to study the electrical performance of the composite electrodes produced in symmetrically configured supercapacitor cells. The carbon material deposited on PU substrates and the polymerization temperature of PEDOT affected significantly the PEDOT morphology and the electrical properties of the resulting composite sponges. T... [more]
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