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Records with Type: Published Article
19490. LAPSE:2023.19644
Short-Term Deterministic Solar Irradiance Forecasting Considering a Heuristics-Based, Operational Approach
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: fuzzy logic, heuristics, Markov chains, Renewable and Sustainable Energy, solar energy, solar power forecasting
Solar energy is an economic and clean power source subject to natural variability, while energy storage might attenuate it, ultimately, effective and operationally feasible forecasting techniques for energy management are needed for better grid integration. This work presents a novel deterministic forecast method considering: irradiance pattern classification, Markov chains, fuzzy logic and an operational approach. The method developed was applied in a rolling manner for six years to a target location with no prior data to assess performance and its changes as new local data becomes available. Clearness index, diffuse fraction and irradiance hourly forecasts are analyzed on a yearly basis but also for 20 day types, and compared against smart persistence. Results show the proposed method outperforms smart persistence by ~10% for clearness index and diffuse fraction on the base case, but there are significant differences across the 20 day types analyzed, reaching up to +60% for clear day... [more]
19491. LAPSE:2023.19643
A Critical Review of Experimental Investigations about Convective Heat Transfer Characteristics of Nanofluids under Turbulent and Laminar Regimes with a Focus on the Experimental Setup
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: convective heat transfer, experimental investigation, nanofluids
In this study, several experimental investigations on the effects of nanofluids on the convective heat transfer coefficient in laminar and turbulent conditions were analyzed. The aim of this work is to provide an overview of the thermal performance achieved with the use of nanofluids in various experimental systems. This review covers both forced and natural convection phenomena, with a focus on the different experimental setups used to carry out the experimental campaigns. When possible, a comparison was performed between different experimental campaigns to provide an analysis of the possible common points and differences. A significant increase in the convective heat transfer coefficient was found by using nanofluids instead of traditional heat transfer fluids, in general, even with big data dispersion from one case to another that depended on boundary conditions and the particular experimental setup. In particular, a general trend shows that once a critic value of the Reynolds numbe... [more]
19492. LAPSE:2023.19642
Experimental Analysis of the R744/R404A Cascade Refrigeration System with Internal Heat Exchanger. Part 1: Coefficient of Performance Characteristics
March 9, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: cascade refrigeration system (CRS), coefficient of performance (COP), efficiency, internal heat exchanger (IHE), multilinear regression analysis, R404A refrigerant, R744 refrigerant
This study evaluates the performance of an R744/R404A cascade refrigeration system (CRS) with internal heat exchangers (IHE) in supermarkets. R744 is used as the refrigerant in a low-temperature cycle, and R404A is used as the refrigerant in a high-temperature cycle. In previous studies, there are many studies including theoretical performance analysis of the CRS. However, experimental studies on the CRS are lacking, and experimental research on the R744/R404A system with an IHE is scarce. Therefore, this study provides basic data for optimal refrigeration system design by experimentally evaluating the results of modifying various parameters. The operating parameters considered in this study include subcooling and superheating, condensing and evaporating temperature, cascade evaporation temperature, and IHE efficiency in the R744 low- and R404A high-temperature cycle. The main results are summarized as follows: (1) By applying the results of this study, energy efficiency is achieved by... [more]
19493. LAPSE:2023.19641
Ammonium Chloride (NH4Cl)—Ammonia (NH3): Sorption Characteristics for Heat Pump Applications
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: Adsorption, ammonia, desorption, heat, heat pump, resorption, thermochemical
In a resorption heat pump, the adsorption and desorption reaction of ammonium chloride (NH4Cl) with ammonia (NH3) is of interest as a Low Temperature Salt (LTS). Reviewing previously published NH4Cl-NH3 equilibrium lines, ammonium chloride appears to offer useable working temperatures (50−70 °C) in the 10−15 bar pressure range during the adsorption reaction, and provides beneficial working conditions for the desorption reaction, when compared with alternative LTS candidates at atmospheric pressure. The NH4Cl-NH3 adsorption and desorption reactions, using a NH4Cl composite salt, have been evaluated under dynamic ‘real-world’ conditions in a Large Temperature Jump (LTJ) experimental testing rig; although there are concerns with mass transfer characteristics, the salt exhibits no hysteresis between the adsorption and desorption reactions, contrary to previous literature. The experimentally obtained equilibrium line values for the reaction enthalpy and entropy are 29,835 J/mol and 207 J/(m... [more]
19494. LAPSE:2023.19640
Multi-Criteria Optimization of Energy-Efficient Cementitious Sandwich Panels Building Systems Using Genetic Algorithm
March 9, 2023 (v1)
Subject: Modelling and Simulations
Keywords: 3D sandwich panels, composite action, construction, energy-efficient buildings, Genetic Algorithm, multi-criteria optimization, numerical simulation
This paper presents results of a study that focuses on developing a genetic algorithm (GA) for multi-criteria optimization of orthotropic, energy-efficient cementitious composite sandwich panels (CSP). The current design concept of all commercially produced CSP systems is based on the assumption that such panels are treated as doubly reinforced sections without the consideration of the three-dimensional truss contribution of the orthotropic panel system. This leads to uneconomical design and underestimating both the strength and stiffness of such system. In this study, two of the most common types of commercially produced sandwich were evaluated both numerically and experimentally and results were used as basis for developing a genetic algorithm optimization process using numerical modeling simulations. In order to develop a sandwich panel with high structural performance, design optimization techniques are needed to achieve higher composite action, while maintaining the favorable feat... [more]
19495. LAPSE:2023.19639
Energy Consumption Model of Aerial Urban Logistic Infrastructures
March 9, 2023 (v1)
Subject: Optimization
Keywords: city logistics, distribution systems, energy optimization, Unmanned Aerial Vehicles
In the last decade, logistic systems based on small aerial vehicles (drones) have become attractive for urban delivery operations as a sustainable alternative to ground vehicles because they are not affected by the congestion of the road network, thus allowing for faster and more reliable services. Aerial logistic systems, however, require a substantially different approach to operations management and need specifically designed supportive infrastructures. While the research on urban aerial delivery mostly focuses on the optimization vehicle operations, the appropriate design of supportive infrastructures is seldom considered. This paper focuses on the energy efficiency of aerial logistic systems, and proposes a new original methodology to obtain a realistic estimate of the overall energy consumed by a swarm of drones employed for urban delivery, taking into account the extension of the area served and its specific features. The methodology proposed offers relevant information for the... [more]
19496. LAPSE:2023.19638
Identification of Critical Components in the Complex Technical Infrastructure of the Large Hadron Collider Using Relief Feature Ranking and Support Vector Machines
March 9, 2023 (v1)
Subject: System Identification
Keywords: CERN, classification, complex technical infrastructure, critical components, feature ranking, filter methods, functional logic, Large Hadron Collider, Relief technique, support vectors machines
This work proposes a data-driven methodology for identifying critical components in Complex Technical Infrastructures (CTIs), for which the functional logic and/or the system structure functions are not known due the CTI’s complexity and evolving nature. The methodology uses large amounts of CTI monitoring data acquired over long periods of time and under different operating conditions. The critical components are identified as those for which the condition monitoring signals permit the optimal classification of the CTI functioning or failed state. The methodology includes two stages: in the first stage, a feature selection filter method based on the Relief technique is used to rank the monitoring signals according to their importance with respect to the CTI functioning or failed state; the second stage identifies the subset of signals among those highlighted by the Relief technique that are most informative with respect to the CTI state. This identification is performed on the basis o... [more]
19497. LAPSE:2023.19637
Criteria, Indicators, and Factors of the Sustainable Energy-Saving Economic Development: The Case of Natural Gas Consumption
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: energy consumption, Energy Efficiency, energy saving, energy-saving economic development, Natural Gas, Sustainability
To solve the contradiction between achieving long-term economic growth and reducing the consumption of certain types of resources, the concept of sustainable resource saving economic development must be put into practice. The purpose of this research is to establish criteria, develop indicators, and identify factors of the sustainable energy-saving economic development, as well as to test the developed theoretical provisions using the example of natural gas consumption by different countries. To achieve this goal, various methods were used, including economic and mathematical modeling, time series analysis, factor analysis, regression analysis, and so on. The criteria were formalized, according to which a certain type of economic development can be attributed to energy saving both at the level of the state economy as a whole and at the level of individual industries and enterprises. It was established that the formalized criteria of the sustainable energy-saving economic development ha... [more]
19498. LAPSE:2023.19636
Sizing and Management of an Energy System for a Metropolitan Station with Storage and Related District Energy Community
March 9, 2023 (v1)
Subject: Process Control
Keywords: energy community, energy management, optimal control, optimal sizing
Future renewable energy communities will reshape the paradigm in which we design and control efficient power systems at the district level. In this manner, the focus will be fundamentally shifted towards sustainable related concepts such as self-consumption, self-sufficiency and net energy exchanged with the grid. In this context, the paper presents a novel approach for optimally designing and controlling the photovoltaic plant and energy storage systems for a metro station in order to increase collective self-consumption and self-sufficiency at the district level. The methodology considers a community of several households connected to a subway station and focuses on the interaction between energy sources and consumers. Furthermore, the optimal solution is determined by using a Mixed Integer Linear Programming Approach, and the impact of different configurations on the overall district benefit is investigated by using several simulation scenarios. The work presents a detailed case stu... [more]
19499. LAPSE:2023.19635
Discontinuous Current Mode Modeling and Zero Current Switching of Flyback Converter
March 9, 2023 (v1)
Subject: Modelling and Simulations
Keywords: discontinuous current mode, flyback, GaN HEMT
The flyback converters are widely used in low power applications. The switch typically requires 600 V breakdown voltage in order to perform large step-down voltage. Thus, slight variation on the switch control can either permanently damage the switch or decrease the efficiency of the power conversion. In order to achieve higher power efficiency, the previous literature suggested operating the flyback converter in the discontinuous current mode (DCM). It is then required to understand the critical conditions of the DCM through analyzing the dynamic behavior and discontinuous current mechanism. This paper started from the current waveform analyses, proceeded to the derivation of zero current switching (ZCS) formulation, and finally reached the necessary conditions for the DCM. The entire DCM operation was divided into three phases that subsequently affect the result of the zero voltage switching (ZVS) and then to the ZCS. The experiment shows a power efficiency of over 96% when the outpu... [more]
19500. LAPSE:2023.19634
Experimental and Numerical Study on the Sooting Behaviors of Furanic Biofuels in Laminar Counterflow Diffusion Flames
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: 2,5-dimethylfuran, counterflow flames, furans fuel, light extinction, soot formation
Furanic biofuels have received increasing research interest over recent years, due to their potential in reducing greenhouse gas emissions and mitigating the production of harmful pollutants. Nevertheless, the heterocyclic structure in furans make them readily to produce soot, which requires an in-depth understanding. In this study, the sooting characteristic of several typical furanic biofuels, i.e., furan, 2-methylfuran (MF), and 2,5-dimethylfuran (DMF), were investigated in laminar counterflow flames. Combined laser-based soot measurements with numerical analysis were performed. Special focus was put on understanding how the fuel structure of furans could affect soot formation. The results show that furan has the lowest soot volume fraction, followed by DMF, while MF has the largest value. Kinetic analyses revealed that the decomposition of MF produces high amounts of C3 species, which are efficient benzene precursors. This may be the reason for the enhanced formation of polycyclic... [more]
19501. LAPSE:2023.19633
Design of a Hybrid Energy System with Energy Storage for Standalone DC Microgrid Application
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: battery energy storage system (BESS), DC/DC converters, maximum power point tracking (MPPT), solar photovoltaic (PV), wind turbine coupled to permanent magnet synchronous generator (WT-PMSG)
This paper presents microgrid-distributed energy resources (DERs) for a rural standalone system. It is made up of a solar photovoltaic (solar PV) system, battery energy storage system (BESS), and a wind turbine coupled to a permanent magnet synchronous generator (WT-PMSG). The DERs are controlled by maximum power point tracking (MPPT)-based proportional integral (PI) controllers for both maximum power tracking and error feedback compensation. The MPPT uses the perturb and observe (P&O) algorithm for tracking the maximum power point of the DERs. The PI gains are tuned using the Ziegler−Nichols method. The developed system was built and simulated in MATLAB/Simulink under two conditions—constant load, and step-load changes. The controllers enabled the BESS to charge even during conditions of varying load and other environmental factors such as change of irradiance and wind speed. The reference was tracked extremely well by the output voltage of the DC microgrid. This is useful research fo... [more]
19502. LAPSE:2023.19632
The Environmental Aspect in the Concept of Corporate Social Responsibility in the Energy Industry and Sustainable Development of the Economy
March 9, 2023 (v1)
Subject: Environment
Keywords: corporate social responsibility, CSR reporting, energy industry, environment in CSR, ISO standards, supply chain management and CSR, sustainable development
Sustainable development is now an important direction for the further development of all economies in the world. It is important to balance economic development with the impact on the environment and our planet. Another direction in the development of management sciences is the emergence of the concept of Corporate Social Responsibility, which considers this impact in three key aspects—economic, environmental and social—in terms of microeconomics. This concept gives companies specific guidelines and tools that minimize their negative impact on the environment. Reducing the negative impact of companies influences the environment and this is what is mainly associated with them. However, companies should also pay attention to internal consistency and caring for employees. Company practices such as the exploitation of people, including children, and injustice in the workplace are some of the factors that can be observed in less developed countries. The article focuses on the presentation o... [more]
19503. LAPSE:2023.19631
Impact of Quadrature Booster on Power-System State Estimation in Polar Coordinates
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: phase shifter, power system, quadrature booster, state estimation
The paper concerns the estimation of the state of a power system in which there is a phase shifter called a quadrature booster. The aim of the paper is a comparative analysis of two different cases including the quadrature booster in the state estimation. In the first case, the quadrature booster is represented by a model consisting of two real voltage sources, one in series with a power line and the other in a shunt branch. In the second case, in the power system model, the real branch with the quadrature booster is represented as off at the end where the considered quadrature booster is actually installed. The state estimation is assumed to be carried out in the polar coordinate system. The properties of the state estimation are characterized by: the number of iterations in the calculation process, the index of conditioning of the matrix of coefficients in the equations to be solved (cond(G)), and ratio Je/Jm, which is a measure of the accuracy of the estimation. Using IEEE 14-bus te... [more]
19504. LAPSE:2023.19630
Evaporator Frosting in Refrigerating Appliances: Fundamentals and Applications
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: appliance, defrost, frost, heat exchanger, refrigeration
Modern refrigerators are equipped with fan-supplied evaporators often tailor-made to mitigate the impacts of frost accretion, not only in terms of frost blocking, which depletes the cooling capacity and therefore the refrigerator coefficient of performance (COP), but also to allow optimal defrosting, thereby avoiding the undesired consequences of condensate retention and additional thermal loads. Evaporator design for frosting conditions can be done either empirically through trial-and-error approaches or using simulation models suitable to predict the distribution of the frost mass along the finned coil. Albeit the former is mandatory for robustness verification prior to product approval, it has been advocated that the latter speeds up the design process and reduces the costs of the engineering undertaking. Therefore, this article is aimed at summarizing the required foundations for the design of efficient evaporators and defrosting systems with minimized performance impacts due to fr... [more]
19505. LAPSE:2023.19629
Critical Review of Intelligent Battery Systems: Challenges, Implementation, and Potential for Electric Vehicles
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: advanced monitoring, battery management system, electric vehicle, intelligent battery system, reconfigurable battery, smart battery
This review provides an overview of new strategies to address the current challenges of automotive battery systems: Intelligent Battery Systems. They have the potential to make battery systems more performant and future-proof for coming generations of electric vehicles. The essential features of Intelligent Battery Systems are the accurate and robust determination of cell individual states and the ability to control the current of each cell by reconfiguration. They enable high-level functions like fault diagnostics, multi-objective balancing strategies, multilevel inverters, and hybrid energy storage systems. State of the art and recent advances in these topics are compiled and critically discussed in this article. A comprising, critical discussion of the implementation aspects of Intelligent Battery Systems complements the review. We touch on sensing, battery topologies and management, switching elements, communication architecture, and impact on the single-cell. This review contribut... [more]
19506. LAPSE:2023.19628
Exploring Sustainable Aspects Regarding the Food Supply Chain, Agri-Food Quality Standards, and Global Trade: An Empirical Study among Experts from the European Union and the United States
March 9, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: agri-food industry, European Green Deal, farm to fork strategy, food safety, German chambers of commerce abroad, global supply chains, quality management, quality standards, sustainable trade, Transatlantic Trade and Investment Partnership (TTIP)
Sustainability is increasingly a priority in the policies of the European Union, especially in the Common Agricultural Policy. This paper focuses on Sustainable Development Goals, the European Green Deal, and the Farm to Fork Strategy in an attempt to establish a relationship with the European Union’s trade policy. Three selected components of the agri-food sector—the food supply chain, agri-food quality standards, and global trade—are examined in relation to defined sustainability aspects. The aim is to understand the interrelationship between the three components with specific regard to sustainability, to highlight their high complexity and current relevance, to contribute to systematic analysis in this area, and to present current progress. This qualitative−explorative study is empirically supported by a survey of market experts, and the Transatlantic Trade and Investment Partnership between the European Union and the United States is used as an example. The results show the complex... [more]
19507. LAPSE:2023.19627
Addressing European Ocean Energy Challenge: The DTOceanPlus Structured Innovation Tool for Concept Creation and Selection
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: DTOceanPlus, FMEA, fundamental relationships, innovation, ocean energy, quality function deployment, structured innovation tool, theory of inventive problem solving
The whole energy system requires renewables that scale and produce reliable, valuable energy at an acceptable cost. The key to increasing the deployment of ocean energy is bringing down development and operating costs. This paper proposes a structured approach to innovation in ocean energy systems that would spur innovation and expand the market for ocean energy. This approach can be used by a wide range of stakeholders—including technology and project developers and investors—when considering creating or improving designs. The Structured Innovation design tool within the DTOceanPlus suite is one of a kind beyond the current state-of-the-art. It enables the adaptation and integration of systematic problem-solving tools based on quality function deployment (QFD), the theory of inventive thinking (TRIZ), and the failure modes and effects analysis (FMEA) methodologies for the ocean energy sector. In obtaining and assessing innovative concepts, the integration of TRIZ into QFD enables the... [more]
19508. LAPSE:2023.19626
Advanced Metering Infrastructure—Towards a Reliable Network
March 9, 2023 (v1)
Subject: System Identification
Keywords: AMI, KDE, reliability, SAIDI, SAIFI, smart grid
In order to ensure continuous energy supply, Distribution System Operators (DSOs) have to monitor and analyze the condition of the power grid, especially checking for random events, such as breakdowns or other disturbances. Still, relatively little information is available on the operation of the Low Voltage (LV) grid. This can be improved thanks to digital tools, offering online processing of data, which ultimately increases effectiveness of the power grid. Among those tools, the use of the Advanced Metering Infrastructure (AMI) is especially conducive for improving reliability. AMI is one of the elements of the system Supervisory Control and Data Acquisition (SCADA) for the LV grid. Exact knowledge of the reliability conditions of a power grid is also indispensable for optimizing investment. AMI is also key in providing operational capacity for carrying out energy balance in virtual power plants (VPPs). This paper deals with methodology of identification and location of faults in the... [more]
19509. LAPSE:2023.19625
Strengthening Gender Justice in a Just Transition: A Research Agenda Based on a Systematic Map of Gender in Coal Transitions
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: coal phase-out, gender, just transition, research agenda, systematic map, women
For climate change mitigation, a rapid phase-out of fossil fuels such as coal is necessary. This has far-reaching gender-specific consequences. This paper presents a systematic map of the literature that examines the impact of historical coal phase-out processes on women and their role in these processes. The search process consisted of screening over 3100 abstracts and reading 247 full-text studies. The analysis of the 73 publications ultimately included in the systematic map shows that past coal phase-outs meant both opportunities (e.g., increased labour market participation) as well as burdens for women (e.g., double burden of job and household). It becomes clear that agency within coal transitions was also gendered. For example, it was difficult for women to gain access to union structures, which led them to organise themselves into grassroots movements. Our research shows that policies aiming for a just sustainability transition should always be explicitly gender-responsive. Howev... [more]
19510. LAPSE:2023.19624
Experimental Analysis of Nucleation Triggering in a Thermal Energy Storage Based on Xylitol Used in a Portable Solar Box Cooker
March 9, 2023 (v1)
Subject: Materials
Keywords: cooling phase, heating phase, nucleation triggering, phase change material, sugar alcohol, supercooling, thermal energy storage
Sugar alcohols have interesting thermodynamic properties that make them good options as heat storage materials (HSMs) to be used in solar cookers. Among sugar alcohols, xylitol is affected by severe supercooling that can significantly alter its usefulness in thermal energy storage (TES) systems. To overcome the supercooling issue, in this work the thermal behavior of a xylitol-based TES installed in a portable solar box cooker was investigated experimentally. The solar cooker has a 4.08 concentration ratio and the TES is a double-pot system filled with 2.5 kg of commercial-grade xylitol. The TES includes a manual mixing device that can be used to trigger the nucleation of xylitol. The effectiveness of the TES system with and without triggering was assessed through several outdoor tests, divided into heating and cooling phases, using silicone oil as absorbing media. It was found that the average load cooling time, in the temperature range of the test fluid from 110 to 80 °C, increased b... [more]
19511. LAPSE:2023.19623
Possibilities of Upgrading Warsaw Existing Residential Area to Status of Positive Energy Districts
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: district heating, positive energy districts, renewable energy resources, residential buildings
This paper analyses possibilities of refurbishment of Warsaw’s residential buildings towards standards of the Positive Energy District. The annual final energy consumption in the city in 2019 for the district heating was 8668 GWh, gas (pipelines) was 5300 GWh, electricity from the grid was 7500 GWh, while the emission of the carbon dioxide was 5.62 × 109 kg. The city consists of 18 districts, which are heterogeneous in terms of typology and structure of buildings. The great variety of buildings can be seen, for example, by the annual final energy demand for space heating and hot water preparation per unit of room area. This annual index ranges from over 400 kWh/m2 in historic buildings to 60 kWh/m2 in modern buildings. A reduction in the consumption of non-renewable energy sources and carbon dioxide emissions can be achieved by improving the energy standard of residential buildings and by using renewable energy sources: solar energy, geothermal energy and biogas. The potential barriers... [more]
19512. LAPSE:2023.19622
A Survey on FOPID Controllers for LFO Damping in Power Systems Using Synchronous Generators, FACTS Devices and Inverter-Based Power Plants
March 9, 2023 (v1)
Subject: Process Control
Keywords: FACTS, fractional-order proportional–integral–derivative (FOPID) controller, inverter-based power plant (IBPP), low-frequency oscillation (LFO), power oscillation damping controller (PODC), synchronous generator (SG)
In recent decades, various types of control techniques have been proposed for use in power systems. Among them, the use of a proportional−integral−derivative (PID) controller is widely recognized as an effective technique. The generalized type of this controller is the fractional-order PID (FOPID) controller. This type of controller provides a wider range of stability area due to the fractional orders of integrals and derivatives. These types of controllers have been significantly considered as a new approach in power engineering that can enhance the operation and stability of power systems. This paper represents a comprehensive overview of the FOPID controller and its applications in modern power systems for enhancing low-frequency oscillation (LFO) damping. In addition, the performance of this type of controller has been evaluated in a benchmark test system. It can be a driver for the development of FOPID controller applications in modern power systems. Investigation of different pie... [more]
19513. LAPSE:2023.19621
Evaporative Cooling Integrated with Solid Desiccant Systems: A Review
March 9, 2023 (v1)
Subject: Energy Systems
Keywords: air conditioning, direct evaporative cooling, indirect evaporative cooling, solar energy, solid desiccant
Evaporative cooling technology (ECT) has been deemed as an alternative to the conventional vapor-compression air conditioning system for dry climates in recent years due to its simple structure and low operating cost. Generally speaking, the ECT includes two types of different technologies, direct evaporative cooling (DEC) and indirect evaporative cooling (IEC). Both technologies can theoretically reduce the air temperature to the wet-bulb temperature of outdoor air. The major difference between these two technologies is that DEC will introduce extra moisture to the supply air while IEC will not. The enhanced IEC, Maisotsenko-cycle (M-cyle) IEC, can even bring down the air temperature to the dew point temperature. The ECT integrated with solid desiccant systems, i.e., solid desiccant-assisted evaporative cooling technologies (SDECT), could make the technology applicable to a wider range of weather conditions, e.g., weather with high humidity. In this paper, the recent development of va... [more]
19514. LAPSE:2023.19620
Synthesis and Characterization of ZnO from Thermal Decomposition of Precipitated Zinc Oxalate Dihydrate as an Anode Material of Li-Ion Batteries
March 9, 2023 (v1)
Subject: Materials
Keywords: anode, Li-ion battery, precipitation, sintering, ZnO
Zinc oxide (ZnO) is one of the most promising materials applied in Li-ion batteries. In this research, ZnO was synthesized by the thermal decomposition of zinc oxalate dihydrate. This precursor was obtained from the precipitation process of zinc sulfate with oxalic acid. In-depth studies were carried out on the effect of various heating temperatures of zinc oxalate dihydrate precursors on ZnO synthesis. The as-prepared materials were characterized by XRD, SEM, and FTIR. Based on the XRD analysis, the presence of the ZnO-wurtzite phase can be confirmed in samples heated at temperatures above 400 °C. Meanwhile, SEM-EDX results showed that the ZnO particles have a micron size. Cells with ZnO samples as anodes have low columbic efficiency. In contrast, cells with ZnO/Graphite composite anodes have a relatively large capacity compared to pure graphite anodes. Overall, based on the consideration of the characterization results and electrochemical performance, the optimal sintering temperatur... [more]
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