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A Review of the Relation between Household Indoor Temperature and Health Outcomes
Fátima Lima, Paula Ferreira, Vítor Leal.
March 27, 2023 (v1)
Subject: Environment
Keywords: buildings, elderly, fuel poverty, health, indoor environment, indoor temperature.
This paper provides a review of research that addresses the relationship between indoor temperatures and health outcomes, taking into consideration studies that focus heat or cold exposure within the household context. It aims to extend previous research by considering both indoor temperatures from existing housing, and empirical studies that focus on energy efficiency measures and subsequent health impacts. To achieve this aim, a literature review was undertaken, combining engineering and health databases. The review established that, overall, inadequate indoor temperatures are associated with poor health status, whereas energy efficiency measures have been associated to improved indoor temperatures and occupant’s health namely regarding cardiovascular, respiratory and mental health disorders. These health conditions are among the most prevalent non-communicable diseases (NCD). The review also highlighted the need for more empirical studies with an extended timeframe to deal with clim... [more]
Thermal-Aware Virtual Machine Allocation for Heterogeneous Cloud Data Centers
Abbas Akbari, Ahmad Khonsari, Seyed Mohammad Ghoreyshi.
March 27, 2023 (v1)
Subject: Optimization
Keywords: Cloud computing, energy-efficiency, heterogeneous data center, thermal-aware, Virtual Machine.
In recent years, a large and growing body of literature has addressed the energy-efficient resource management problem in data centers. Due to the fact that cooling costs still remain the major portion of the total data center energy cost, thermal-aware resource management techniques have been employed to make additional energy savings. In this paper, we formulate the problem of minimizing the total energy consumption of a heterogeneous data center (MITEC) as a non-linear integer optimization problem. We consider both computing and cooling energy consumption and provide a thermal-aware Virtual Machine (VM) allocation heuristic based on the genetic algorithm. Experimental results show that, using the proposed formulation, up to 30 % energy saving is achieved compared to thermal-aware greedy algorithms and power-aware VM allocation heuristics.
Effect of FSI Based Ionic Liquid on High Voltage Li-Ion Batteries
Wenlin Zhang, Yongqi Zhao, Yu Huo.
March 27, 2023 (v1)
Keywords: capacity retention, FSI based ionic liquids, high-voltage Li-ion battery, LiNi0.5Mn1.5O4/Li.
In this manuscript, a functionalized ionic liquid 1-cyanoethyl-2-methyl-3-allylimidazolium bis (trifluoromethanesulfonimide) salt (CEMAImTFSI) was synthesized and explored as an electrolyte component to improve the oxidation resistance of the electrolyte in high-voltage lithium-ion batteries. Based on the calculation by Gaussian 09, CEMAImTFSI has a higher highest occupied molecular orbital (HOMO) value than the organic solvents ethylene carbonate (EC) and dimethyl carbonate (DMC), suggesting that CEMAImTFSI is more susceptible to oxidation than EC and DMC. Moreover, a low Li+ binding energy value of −3.71 eV and the lower lowest unoccupied molecular orbital (LUMO) enable CEMAImTFSI to migrate easily to the surface of the LiNi0.5Mn1.5O4 cathode and participate in the formation of the SEI (solid electrolyte interphase) film, protecting the electrode materials. Electrochemical studies showed that the LiNi0.5Mn1.5O4/Li cell with 1.0 mol/L LiPF6-EC/DMC/10 vol% has the best cycling stabilit... [more]
Effects of Decentral Heat Pump Operation on Electricity Storage Requirements in Germany
Simon Hilpert.
March 27, 2023 (v1)
Keywords: 100% renewable energy systems, electricity storage, energy system modelling, flexibility options, heat pump, open science, sector coupling, thermal energy storage.
Several studies show that heat pumps need to play a major role for space heating and hot water supply in highly decarbonised energy systems. The degree of elasticity of this additional electricity demand can have a significant impact on the electricity system. This paper investigates the effect of decentral heat pump flexibilisation through thermal energy storage units on electricity storage investment. The analysis is carried using an open source model for the German electricity system based on the Open Energy Modelling Framework (oemof). Results highlight the importance of flexible heat pump operation in 100% renewable energy systems and relate well to findings of other existing studies. Flexibilisation of heat pumps in the German energy system can reduce the need for electricity storage units significantly. While no impact was found for systems with a share below 80% renewable energy, investment in short term storage units is reduced by up to 42−62% in systems with shares of more th... [more]
Novel Time Method of Identification of Fractional Model Parameters of Supercapacitor
Miroslaw Lewandowski, Marek Orzylowski.
March 27, 2023 (v1)
Keywords: energy storage system, fractional model, identification, supercapacitor.
Accurate dynamic models of supercapacitors (SCs) are a basis for the design, control and exploitation of the hybrid energy storage systems for electric vehicles. This paper concerns a fractional model of SC impedance, based on the Cole−Cole equation describing relaxation in electric double layer. This article provides a new method of identifying the parameters of fractional order model of SC impedance, performed without disconnecting the SC module from the energy storage system. The test drive for this purpose needs only the respect a few simple recommendations. The article presents the conditions of the mentioned test drive that will ensure the frequency spectra of the recorded signals lying in the bandwidth necessary for the correct identification of the model parameters. These parameters are determined by means of the Nelder−Mead simplex optimization method. The results of the identification described by the time method coincide with those obtained in the frequency domain. It has be... [more]
The Influence of Fe on the Structure and Hydrogen Sorption Properties of Ti-V-Based Metal Hydrides
Magnus M. Nygård, Magnus H. Sørby, Arne A. Grimenes, Bjørn C. Hauback.
March 27, 2023 (v1)
Keywords: activation energy for hydrogen desorption, hydrogen storage, in situ synchrotron radiation powder X-ray diffraction, metal hydrides.
Ti-V-based metal hydrides have decent overall performance as hydrogen storage materials, but V is expensive and it is therefore tempting to replace it by less expensive ferrovanadium containing about 20% Fe. In the present work we have investigated how Fe influences the structure and hydrogen storage properties of (Ti0.7V0.3)1−zFez alloys with e r r o r t y p e c e z ∈ { 0 , 0.03, 0.06, 0.1, 0.2, 0.3} using synchrotron radiation powder X-ray diffraction, thermogravimetric analysis, differential scanning calorimetry and manometric measurements performed in a Sieverts apparatus. The alloys form body-centered cubic (bcc) crystal structures for all considered values of z, and the addition of Fe causes the unit cell to contract. When exposed to hydrogen gas, the bcc alloys form face-centered cubic (fcc) hydrides if e r r o r t y p e c e z ≤ 0 . 1 while other hydrogen-containing phases are formed for higher Fe-contents. The hydrogen capacities of... [more]
Optimal Control for Hydraulic Cylinder Tracking Displacement of Wave Energy Experimental Platform
Wei Zhang, Shizhen Li, Yanjun Liu, Detang Li, Qin He.
March 27, 2023 (v1)
Keywords: control strategy, experimental platform, hydraulic transmission system, Lyapunov criterion.
The wave energy converter captures the wave power by buoy’s heaving motion, transfers it by hydraulic system, and converts it into the electric power by generator. The hydraulic conversion system plays an important role that can realize the effective regulation of the output power. In order to develop the working characteristics of the hydraulic transmission system, a new wave energy experimental platform was devised. The platform adopts the matching design mode of the driving oil cylinder and the driven oil cylinder. The active hydraulic cylinder and the clump weight can simulate the movement of the oscillating float under certain sea conditions, and the driven oil cylinder realizes the conversion and the output of wave energy. In order to improve the operation accuracy of the active hydraulic cylinder, the control strategy of the active hydraulic cylinder was studied. An adaptive sliding mode control strategy based on the back-stepping method was proposed to overcome the influence of... [more]
Performance and Design Optimization of Two-Mirror Composite Concentrating PV Systems
Guihua Li, Yamei Yu, Runsheng Tang.
March 27, 2023 (v1)
Subject: Optimization
Keywords: design optimization, mathematical model, optical and photovoltaic performance, two-mirror composite solar concentrator.
The reflectors of a linear solar concentrator investigated in this work consisted of two plane mirrors (2MCC), and they were designed in such a way that made all radiation within the acceptance angle (θa) arrive on flat-plate absorber, after less than two reflections. To investigate the performance of an east−west aligned 2MCC-based photovoltaic (PV) system (2MCPV), a mathematical procedure was suggested based on the three-dimensional radiation transfer and was validated by the ray-tracing analysis. Analysis indicated that the performance of 2MCPV was dependent on the geometry of 2MCC, the reflectivity of mirrors (ρ), and solar resources in a site, thus, given θa, an optimal geometry of 2MCC for maximizing the annual collectible radiation (ACR) and annual electricity generation (AEG) of 2MCPV in a site could be respectively found through iterative calculations. Calculation results showed that when the ρ was high, the optimal design of 2MCC for maximizing its geometric concentration (Cg... [more]
Effect of Multi-Factor Coupling on the Movement Characteristics of the Hydraulic Variable Valve Actuation
Zhaohui Jin, Wei Hong, Tian You, Yan Su, Xiaoping Li, Fangxi Xie.
March 27, 2023 (v1)
Keywords: combustion engine, hydraulic pressure fluctuation, multi-factor coupling, orthogonal design, Taguchi method, variable valve actuation.
Studies show that the valve lift (VL) of the cam-driven hydraulic variable valve actuation (VVA) can be continuously adjusted in the range of 0−8.2 mm by controlling the opening of the throttling valve. In the present study, an orthogonal experiment with interaction was designed to analyze the effect of multi-factor coupling on the VL, valve-seating velocity (VSV), and pressure fluctuation in the valve piston cavity. In order to reduce the pressure fluctuation, the Taguchi method was applied to find the optimal combination of the key parameters including the diameter of the piston, the spring preload of the valve-seating buffer mechanism (VSBM), the spring preload of the valve, and the valve piston mass. The correctness of the VVA simulation model is verified through experiments. Moreover, the pressure fluctuation is analyzed through a numerical simulation. The obtained results showed that as long as the VSV is less than 0.5 m·s−1, the pressure fluctuations in hydraulic VVA can be redu... [more]
Framing in Renewable Energy Policies: A Glossary
Maarten Wolsink.
March 27, 2023 (v1)
Subject: Energy Policy
Keywords: centralized power, common goods, community energy, coproduction, demand response, distributed generation, intermittency, microgrids, P2P, prosumer, virtual power plants.
The transformation of a power supply, a social-technical system suffering from a heavy lock-ins, requires structural adaptations which are extremely complex. All actors in social acceptance processes have either strong vested interests in the current system or are challenging these. In strategies developed by those actors, so-called ‘frames’ play a key role. These are biased problem definitions and mental shortcuts, tools to affect the course of decision-making processes. Examples are “clean coal”, “smart grid”, “base-load”, or “decentralized”. Framing is fundamental to political processes, including those of decision making on renewables. This review presents a glossary of significant frames used in social acceptance processes of renewables’ innovation in power supply systems. The identified frames are classified and presented with, in each entry, one significant frame discussed and analyzed in relation to its most associated frames. Overall, the contrast comes to the fore between the... [more]
Models for Short-Term Wind Power Forecasting Based on Improved Artificial Neural Network Using Particle Swarm Optimization and Genetic Algorithms
Dinh Thanh Viet, Vo Van Phuong, Minh Quan Duong, Quoc Tuan Tran.
March 27, 2023 (v1)
Keywords: Genetic Algorithm, neural network, Particle Swarm Optimization, Renewable and Sustainable Energy, wind power forecasting.
As sources of conventional energy are alarmingly being depleted, leveraging renewable energy sources, especially wind power, has been increasingly important in the electricity market to meet growing global demands for energy. However, the uncertainty in weather factors can cause large errors in wind power forecasts, raising the cost of power reservation in the power system and significantly impacting ancillary services in the electricity market. In pursuance of a higher accuracy level in wind power forecasting, this paper proposes a double-optimization approach to developing a tool for forecasting wind power generation output in the short term, using two novel models that combine an artificial neural network with the particle swarm optimization algorithm and genetic algorithm. In these models, a first particle swarm optimization algorithm is used to adjust the neural network parameters to improve accuracy. Next, the genetic algorithm or another particle swarm optimization is applied to... [more]
Computer Simulation as a Tool for Managing the Technical Development of Methods for Diagnosing the Technical Condition of a Vehicle
Karol Tucki, Andrzej Wasiak, Olga Orynycz, Remigiusz Mruk.
March 27, 2023 (v1)
Keywords: computer simulation, diagnosis of vehicle’s technical condition, management of technological progress, technical condition of a vehicle.
Introduced by the Civil Code, the rules of road safety are introducing continuously increasingly strict requirements on motor vehicles. These requirements relate to various aspects of the technical condition of vehicles, both those that determine traffic safety and those that affect the vehicle’s environmental impact. The law requires regular diagnosis of the technical condition of vehicles in service. Diagnostic tests conducted in the form of road tests or the tests performed in workshop conditions allow to determine the symptoms of dysfunctions of the tested vehicle, not always clearly defining the causes and location of damage. The purpose of the work is the design the simulation of a station for of vehicle dynamics tests up to 3.5 t using simulation programs OpenModelica and SciLab. A simulation of the work of the stand for testing the dynamics of vehicles in the form of a chassis dynamometer was achieved. The program enables the simulation of tests: NEDC (New European Drive Cycle)... [more]
Heating Performance Characteristics of an Electric Vehicle Heat Pump Air Conditioning System Based on Exergy Analysis
Xingwang Tang, Qin Guo, Ming Li, Mingzhe Jiang.
March 27, 2023 (v1)
Keywords: battery electric vehicle, efficiency, exergy analysis, heat pump.
In this paper, a heat pump air conditioning system (HPACS) with refrigerant R134a based on the functional requirements of battery electric vehicle is designed and tested. Experiments were conducted to evaluate the effects of different ambient temperature, air flow rate of internal condenser, expansion valve (EXV) opening and compressor speed. The results demonstrate that air flow rate of internal condenser, EXV opening and compressor speed have important impact on heating capacity, compressor power consumption and coefficient of performance (COP) under several ambient temperatures. To verify the HPACS can also provide the heating capacity required by the battery electric vehicle cabin in cold climate, the system was also tested under a −5 °C ambient temperature, it was found that the heating capacity is 3.6 kW and the COP is 3.2, demonstrating that the system has high energy efficiency. In addition, heating process analysis of the HPACS under lower temperature is studied by exergy prin... [more]
Life Cycle Assessment of Electric Vehicle Batteries: An Overview of Recent Literature
Andrea Temporelli, Maria Leonor Carvalho, Pierpaolo Girardi.
March 27, 2023 (v1)
Subject: Environment
Keywords: battery electric vehicles, environmental impacts, life cycle assessment, review.
In electric and hybrid vehicles Life Cycle Assessments (LCAs), batteries play a central role and are in the spotlight of scientific community and public opinion. Automotive batteries constitute, together with the powertrain, the main differences between electric vehicles and internal combustion engine vehicles. For this reason, many decision makers and researchers wondered whether energy and environmental impacts from batteries production, can exceed the benefits generated during the vehicle’s use phase. In this framework, the purpose of the present literature review is to understand how large and variable the main impacts are due to automotive batteries’ life cycle, with particular attention to climate change impacts, and to support researchers with some methodological suggestions in the field of automotive batteries’ LCA. The results show that there is high variability in environmental impact assessment; CO2eq emissions per kWh of battery capacity range from 50 to 313 g CO2eq/kWh. Ne... [more]
The Sensitivity of an Electro-Thermal Photovoltaic DC−DC Converter Model to the Temperature Dependence of the Electrical Variables for Reliability Analyses
Wieland Van De Sande, Simon Ravyts, Omid Alavi, Philippe Nivelle, Johan Driesen, Michaël Daenen.
March 27, 2023 (v1)
Keywords: DC/DC converter, photovoltaic, plastic energy dissipation, sensitivity, temperature dependence.
The operational expenditures of solar energy are gaining attention because of the continuous decrease of the capital expenditures. This creates a demand for more reliable systems to further decrease the costs. Increased reliability is often ensured by iterative use of design for reliability. The number of iterations that can take place strongly depends on the computational efficiency of this methodology. The main research objective is to quantify the influence of the temperature dependence of the electrical variables used in the electro-thermal model on the reliability and the computation time. The influence on the reliability is evaluated by using a 2-D finite elements method model of the MOSFET and calculating the plastic energy dissipation density in the die-attach and the bond wire. The trade-off between computation time of the electro-thermal model in PLECS (4.3, Plexim, Zurich, Switzerland) and generated plastic energy accuracy obtained in COMSOL (5.3, COMSOL Inc., Burlington, MA... [more]
Identification of Energy Efficiency Trends in the Context of the Development of Industry 4.0 Using the Polish Steel Sector as an Example
Radosław Wolniak, Sebastian Saniuk, Sandra Grabowska, Bożena Gajdzik.
March 27, 2023 (v1)
Subject: Energy Policy
Keywords: Energy Efficiency, Industry 4.0, investment policy in the steel sector.
The steel sector is crucial for the national economy of Poland and the global economy. In response to the challenges of the global steel market and the need to increase the sector’s competitiveness, a number of actions have been taken to increase the energy efficiency of steel production. Based on the synthesis of the literature and our own research, we describe the issues related to energy efficiency and the Industry 4.0 concept. The main aim of this paper is to identify energy efficiency trends in enterprises, especially those that focus on increasing the energy efficiency of production processes, and to make recommendations for investment policy for the Polish steel sector in the era of Industry 4.0. To achieve our goals and answer the research question, we used data from 2000−2019 for the Polish steel industry. The calculations and models in this paper were made by using Gretl software. Using direct research, an econometric model was built that verified the hypothesis regarding the... [more]
Calculating the Interface Flow Limits for the Expanded Use of High-Voltage Direct Current in Power Systems
Sangwook Han.
March 27, 2023 (v1)
Keywords: contingency list, DC tap control, FV analysis, FV margin, HVDC, interface lines, interface power flow, power system operation.
Although loads are increasingly becoming concentrated in metropolitan areas, power generation has decreased in metropolitan areas and increased in nonmetropolitan areas; hence, power transmission must occur through interface lines. To achieve this, additional transmission lines must be secured because the existing interface lines have reached their large-scale power transmission limits. The Korea Electric Power Corporation has installed many high-voltage direct current lines, thereby impacting the determination of interface power flow limits. These serve as the basis for system operations. However, knowledge of operating high-voltage direct current lines as a simple transmission line in a single power system is lacking. The effects of high-voltage direct current and its related parameters for interface flow limit analysis remain unclear. Furthermore, whether high-voltage direct current should be included in the selection of the interface lines that serve as the basis for interface flow... [more]
An Improved Solution for Reactive Power Dispatch Problem Using Diversity-Enhanced Particle Swarm Optimization
Mini Vishnu, Sunil Kumar T. K..
March 27, 2023 (v1)
Subject: Optimization
Keywords: diversity-enhanced particle swarm optimization, mixed-integer discrete continuous (MIDC) problem, reactive power dispatch, static synchronous compensator (STATCOM).
Well-structured reactive power policies and dispatch are major concerns of operation and control technicians of any power system. Obtaining a suitable reactive power dispatch for any given load condition of the system is a prime duty of the system operator. It reduces loss of active power occurring during transmission by regulating reactive power control variables, thus boosting the voltage profile, enhancing the system security and power transfer capability, thereby attaining an improvement in overall system operation. The reactive power dispatch (RPD) problem being a mixed-integer discrete continuous (MIDC) problem demands the solution to contain all these variable types. This paper proposes a methodology to achieve an optimal and practically feasible solution to the RPD problem through the diversity-enhanced particle swarm optimization (DEPSO) technique. The suggested method is characterized by the calculation of the diversity of each particle from its mean position after every iter... [more]
Fault Detection Algorithm for Wind Turbines’ Pitch Actuator Systems
Gisela Pujol-Vazquez, Leonardo Acho, José Gibergans-Báguena.
March 27, 2023 (v1)
Keywords: Fault Detection, interval observer, pitch actuator, wind turbines.
A fault detection innovation to wind turbines’ pitch actuators is an important subject to guarantee the efficiency wind energy conversion and long lifetime operation of these rotatory machines. Therefore, a recent and effective fault detection algorithm is conceived to detect faults on wind turbine pitch actuators. This approach is based on the interval observer framework theory that has proved to be an efficient tool to measure dynamic uncertainties in dynamical systems. It is evident that almost any fault in any actuator may affect its historical-time behavior. Hence, and properly conceptualized, a fault detection system can be successfully designed based on interval observer dynamics. This is precisely our main contribution. Additionally, we realize a numerical analysis to evaluate the performance of our approach by using a dynamic model of a pitch actuator device with faults. The numerical experiments support our main contribution.
Combined Duval Pentagons: A Simplified Approach
Luiz Cheim, Michel Duval, Saad Haider.
March 27, 2023 (v1)
Keywords: combined pentagons, DGA, Duval pentagons, fault classification, transformer.
The paper describes a newly proposed combination of the two existing Duval Pentagons method utilized for the identification of mineral oil-insulated transformers. The aim of the combination is to facilitate automatic fault identification through computer programs, and at the same time, apply the full capability of both original Pentagons, now reduced to a single geometry. The thorough classification of a given fault (say, of the electrical or thermal kind), employing individual Pentagons 1 and 2, as originally defined, involves a complex geometrical problem that requires the build-up of a convoluted geometry (a regular Pentagon whose axes represent each of five possible combustible gases) to be constructed using computer language code and programming, followed by the logical localization of the geometrical centroid of an irregular pentagon, formed by the partial contribution of individual combustibles, inside two similar structures (Pentagons 1 and 2) that, nonetheless, have different... [more]
Influence of Hydrothermal Pretreatment Temperature on the Hydration Properties and Direct Carbonation Efficiency of Al-Rich Ladle Furnace Refining Slag
Yi Huang, Guo Xiong.
March 27, 2023 (v1)
Subject: Materials
Keywords: CO2 uptake, hydration products, hydrothermal pretreatment, LF slag, temperature.
The influence of hydrothermal pretreatment temperature on the hydration products and carbonation efficiency of Al-rich LF slag was investigated. The results showed that the carbonation efficiency was strongly dependent on the morphology of hydration products and the hydration extent of the raw slag. Hydrothermal pretreatment at 20 °C or 80 °C favored the formation of flake-shaped products with a higher specific surface area and therefore resulted in a higher CO2 uptake of 20 °C and 80 °C-pretreated slags (13.66 wt% and 10.82 wt%, respectively). However, hydrothermal pretreatment at 40 °C, 60 °C or 100 °C led to the rhombohedral-shaped calcite layer surrounding the unreacted core of the raw slag and the formation of fewer flake-shaped products, resulting in a lower CO2 uptake of 40 °C, 60 °C and 100 °C-pretreated slags (9.21 wt%, 9.83 wt%, and 6.84 wt%, respectively).
Anaerobic Acidogenic Fermentation of Cellobiose by Immobilized Cells: Prediction of Organic Acids Production by Response Surface Methodology
Panagiota Tsafrakidou, Konstantina Tsigkou, Argyro Bekatorou, Maria Kanellaki, Athanasios A. Koutinas.
March 27, 2023 (v1)
Keywords: anaerobic acidogenesis, cellobiose, immobilized cells, organic acids, predictive model, γ-alumina.
Response surface methodology was used to derive a prediction model for organic acids production by anaerobic acidogenic fermentation of cellobiose, using a mixed culture immobilized on γ-alumina. Three parameters (substrate concentration, temperature, and initial pH) were evaluated. In order to determine the limits of the parameters, preliminary experiments at 37 °C were conducted using substrates of various cellobiose concentrations and pH values. Cellobiose was used as a model sugar for subsequent experiments with lignocellulosic biomass. The culture was well adapted to cellobiose by successive subculturing at 37 °C in synthetic media (with 100:5:1 COD:N:P ratio). The experimental data of successive batch fermentations were fitted into a polynomial model for the total organic acids concentration in order to derive a predictive model that could be utilized as a tool to predict fermentation results when lignocellulosic biomass is used as a substrate. The quadratic effect of temperature... [more]
An Insight into the Separation of 1,2-Propanediol, Ethylene Glycol, Acetol and Glycerol from an Aqueous Solution by Adsorption on Activated Carbon
Jorge Fortea, Lucía García, Joaquín Ruiz, Miriam Oliva, Jesús Arauzo.
March 27, 2023 (v1)
Keywords: 1,2-propanediol, acetol, activated carbon, Adsorption, ethylene glycol, glycerol.
Glycerol conversion processes such as aqueous phase reforming and hydrogenolysis generate value-added compounds highly diluted in water. Because distillation is a high energy demand separation step, adsorption could be an attractive alternative to recover these chemicals. Adsorption isotherms of 1,2-propanediol, acetol, ethylene glycol and glycerol onto activated carbon were determined by batch adsorption experiments. These isotherms were fitted slightly better to the Freundlich equation than to the Langmuir equation. Acetol is the compound with the highest adsorption at concentrations smaller than 1 M. Properties of the adsorbate such as the −OH group number, chain length, molecular size and dipole moment, besides characteristics of the adsorbent such as the surface area, oxygen and ash content, are considered to explain the observed results. Moreover, adsorption experiments were performed with mixtures of compounds and it was determined that the molar amount adsorbed is less than pre... [more]
Dependence of Viscosity and Diffusion on β-Cyclodextrin and Chloroquine Diphosphate Interactions
Lenka Musilová, Aleš Mráček, Eduarda F. G. Azevedo, M. Melia Rodrigo, Artur J. M. Valente, Miguel A. Esteso, Ana C. F. Ribeiro.
March 27, 2023 (v1)
Subject: Materials
Keywords: chloroquine diphosphate, diffusion, drugs, solutions, transport properties.
Mutual diffusion coefficients of chloroquine diphosphate (CDP) in aqueous solutions both without and with β-cyclodextrin (β-CD) were measured at concentrations from (0.0000 to 0.0100) mol dm−3 and 298.15 K, using the Taylor dispersion technique. Ternary mutual diffusion coefficients (Dik) measured by the same technique are reported for aqueous CDP + β-CD solutions at 298.15 K. The presence of β CD led to relevant changes in the diffusion process, as showed by nonzero values of the cross-diffusion coefficients, D12 and D21. β-CD concentration gradients produced significant co-current coupled flows of CDP. In addition, the effects of β-CD on the transport of CDP are assessed by comparing the binary diffusion coefficient of aqueous CDP solutions with the main diffusion coefficient (D11) measured for ternary {CDP(1) + β-CD(2)} solutions. These observations are supported by viscosity analysis. All data allow to have a better interpretation on the effect of cyclodextrin on the transport beha... [more]
Special Issue “Advances in Postharvest Process Systems”
Daniel I. Onwude, Guangnan Chen.
March 27, 2023 (v1)
The world population is predicted to increase from the present 7 [...]
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