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Records with Type: Published Article
12898. LAPSE:2023.26237
Forecasting Electricity Prices Using Deep Neural Networks: A Robust Hyper-Parameter Selection Scheme
April 3, 2023 (v1)
Subject: Energy Management
Keywords: artificial neural network, deep learning, electricity price forecasting, hyper-parameter optimization, Machine Learning.
Deep neural networks are rapidly gaining popularity. However, their application requires setting multiple hyper-parameters, and the performance relies strongly on this choice. We address this issue and propose a robust ex-ante hyper-parameter selection procedure for the day-ahead electricity price forecasting that, when used jointly with a tested forecast averaging scheme, yields high performance throughout three-year long out-of-sample test periods in two distinct markets. Being based on a grid search with models evaluated on long samples, the methodology mitigates the noise induced by local optimization. Forecast averaging across calibration window lengths and hyper-parameter sets allows the proposed methodology to outperform a parameter-rich least absolute shrinkage and selection operator (LASSO)-estimated model and a deep neural network (DNN) with non-optimized hyper-parameters in terms of the mean absolute forecast error.
12899. LAPSE:2023.26236
Energy, Environmental, and Economic Analyses of Geothermal Polygeneration System Using Dynamic Simulations
April 3, 2023 (v1)
Subject: Environment
Keywords: energy district, geothermal energy, geothermal energy community, heating and cooling network, ORC, polygeneration system.
This paper presents a thermodynamic, economic, and environmental analysis of a renewable polygeneration system connected to a district heating and cooling network. The system, fed by geothermal energy, provides thermal energy for heating and cooling, and domestic hot water for a residential district located in the metropolitan city of Naples (South of Italy). The produced electricity is partly used for auxiliaries of the thermal district and partly sold to the power grid. A calibration control strategy was implemented by considering manufacturer data matching the appropriate operating temperature levels in each component. The cooling and thermal demands of the connected users were calculated using suitable building dynamic simulation models. An energy network dedicated to heating and cooling loads was designed and simulated by considering the variable ground temperature throughout the year, as well as the accurate heat transfer coefficients and pressure losses of the network pipes. The... [more]
12900. LAPSE:2023.26235
Optimal Monazite Concentration Processes for the Extraction of Uranium and Thorium Fuel Material
April 3, 2023 (v1)
Subject: Materials
Keywords: autoclave leaching, Extraction, flow chart, monazite, radium, rare earth elements, separation, thorium, uranium.
The optimal conditions for the nitric acid dissolution of precipitates of hydroxides and hydrated oxides of rare-earth elements, uranium, and thorium obtained after autoclave alkaline opening of samples of monazite concentrate have been determined. The distribution of radioactive impurities between the solid phase and the solution in the processes of alkaline opening, dephosphorization, and acid dissolution of the pulp was studied. Two options are proposed for the extraction of uranium and thorium in the presence of rare earth elements, followed by separation of the components using tributyl phosphate of various contents in the carbon diluent.
12901. LAPSE:2023.26234
Operating and Investment Models for Energy Storage Systems
April 3, 2023 (v1)
Subject: Planning & Scheduling
Keywords: electricity markets, energy storage systems, mathematical modelling, power system operation, power system planning.
In the context of climate changes and the rapid growth of energy consumption, intermittent renewable energy sources (RES) are being predominantly installed in power systems. It has been largely elucidated that challenges that RES present to the system can be mitigated with energy storage systems (ESS). However, besides providing flexibility to intermittent RES, ESS have other sources of revenue, such as price arbitrage in the markets, balancing services, and reducing the cost of electricity procurement to end consumers. In order to operate the ESS in the most profitable way, it is often necessary to make optimal siting and sizing decisions, and to determine optimal ways for the ESS to participate in a variety of energy and ancillary service markets. As a result, many publications on ESS models with various goals and operating environments are available. This paper aims at presenting the results of these papers in a structured way. A standard ESS model is first outlined, and that is fol... [more]
12902. LAPSE:2023.26233
Integration of Municipal Air-Conditioning, Power, and Gas Supplies Using an LNG Cold Exergy-Assisted Kalina Cycle System
April 3, 2023 (v1)
Subject: Environment
Keywords: district cooling, economic, environmental, Kalina, liquefied natural gas (LNG) regasification, power.
A Kalina cycle-based integration concept of municipal air-conditioning, electricity and gas is investigated thermodynamically, economically, and environmentally to reduce the carbon intensity of these supplies, with attention to hot climatic conditions. The proposed poly-generation system is driven by low-grade renewable or surplus heat, and utilizes waste exergy from liquefied natural gas vaporization for refrigeration and power augmentation. At nominal conditions (130 °C driving heat), approximately 561 and 151 kJ of refrigeration and useful power per kg of liquefied natural gas regasified are generated by the proposed system, respectively, at effective first-law and exergetic efficiencies of 33% and 35%, respectively. The Kalina sub-system condenser cryogenic heat rejection condition is found to triple the system useful electrical output compared with high ambient temperature condenser heat sinking conditions. Per million ton per annum of liquefied natural gas vaporization capacity,... [more]
12903. LAPSE:2023.26232
Modelling of Distributed Resource Aggregation for the Provision of Ancillary Services
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: aggregation, ancillary services, distributed energy resources, Optimization, power system operation.
Nowadays, ancillary services (ASs) are usually provided by large power generating units located in transmission networks, while smaller assets connected to distribution systems remain passive. It is expected that active distribution systems will start to play an important role due to numerous issues related to power system operation caused mainly by developing renewable generation and restrictions imposed on conventional power generating units by climate policies. The future development of the power system management will also lead to the establishment of new market agents such as distributed resource aggregators (DRAs). The article presents the concept of the DRA as part of an active distribution system enabling small resources to participate in wholesale markets, provide ASs and indicates the functions of the DRA coordinator in the modern power system. The proposed method of the DRA structure modelling with the use of the mixed-integer linear programming (MILP) is aimed at evaluating... [more]
12904. LAPSE:2023.26231
Energy Inputs in Motor-Manual Release Cutting of Broadleaved Forests: Results of Twelve Options
April 3, 2023 (v1)
Subject: Process Operations
Keywords: balance, Energy, forestry, input, motor-manual, operations, release cutting.
Lignocellulosic biomass is used in various industries and its procurement involves a set of operations that are mainly done using equipment powered by internal combustion engines. The sustainability of forest operations may be characterized by balancing their energy inputs with those typically embodied in their outputted products. Forest tending operations are problematic because most of them cannot output marketable products while the data on their energy inputs are important for the forest management. Six of the most commonly used brushcutters equipped successively with discs and knives were tested to provide part of the data needed to run an energy analysis and to be able to characterize the energy inputs in release cutting operations by implementing the Gross Energy Requirements method. Fuel burning was found to have the greatest contribution (83−92%) in the total energy inputs (0.8−1.2 GJ/ha) of the studied operations and it was highly dependent on the efficiency of operations. Mo... [more]
12905. LAPSE:2023.26230
Evaluation of the Administrative Phase-Out of Coal Power Plants on the Italian Electricity Market
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: coal phase-out, decarbonisation, electricity price, generation adequacy, Italy, optimization model and simulation, price analysis.
Although decarbonisation is one of the most important macro-trends of this century, electricity generation from coal power plants is still broadly common. The main goal of this study is to evaluate the impact of a premature coal power plants phase-out on the Italian day-ahead electricity market. For this purpose, two electricity price forecasts, related to different scenarios between 2019 and 2030, and two different hypotheses for the creation of electricity spot price, were compared. The results from the different scenarios show that coal power plants phase-out determines a small variation in electricity price when bid-up is not considered; instead, when operators’ bid-up is included in the study, the price variation becomes relevant.
12906. LAPSE:2023.26229
Improving Prediction Accuracy Concerning the Thermal Environment of a Data Center by Using Design of Experiments
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: air-conditioning, air-management metrics, computational fluid dynamics (CFD), data center, design of experiments (DOE), energy conservation, prediction accuracy.
In data centers, heating, ventilation, and air-conditioning (HVAC) consumes 30−40% of total energy consumption. Of that portion, 26% is attributed to fan power, the ventilation efficiency of which should thus be improved. As an alternative method for experimentations, computational fluid dynamics (CFD) is used. In this study, “parameter tuning”—which aims to improve the prediction accuracy of CFD simulation—is implemented by using the method known as “design of experiments”. Moreover, it is attempted to improve the thermal environment by using a CFD model after parameter tuning. As a result of the parameter tuning, the difference between the result of experimental-measurement results and simulation results for average inlet temperature of information-technology equipment (ITE) installed in the ventilation room of a test data center was within 0.2 °C at maximum. After tuning, the CFD model was used to verify the effect of advanced insulation such as raised-floor fixed panels and show th... [more]
12907. LAPSE:2023.26228
DC Bus Voltage Control of Grid-Side Converter in Permanent Magnet Synchronous Generator Based on Improved Second-Order Linear Active Disturbance Rejection Control
April 3, 2023 (v1)
Subject: Other
Keywords: correction link, DC bus voltage, frequency domain analysis, grid-side converter, linear active disturbance rejection control, reduced-order linear expansion state observer.
In the permanent magnet synchronous generator (PMSG), the DC bus voltage fluctuates up and down under the influence of the load and power grid, which greatly affects the safe and reliable work of PMSG. In order to suppress the wide range fluctuation of DC bus voltage under disturbance and enhance its anti-disturbance performance, an optimized DC bus voltage control strategy is proposed by using the improved linear active disturbance rejection control (LADRC) in the voltage outer loop. By considering factors, such as load disturbance and grid voltage mutation as the total disturbance of the system, the improved reduced-order linear expansion state observer (RLSEO) is used to estimate and compensate the total disturbance, which greatly improves the stability of DC bus voltage. Firstly, the mathematical model of grid-side converter is established. On this basis, the LADRC control based on RLESO is designed, which reduces the phase lag of the linear extended state observer (LESO) and enhan... [more]
12908. LAPSE:2023.26227
Frequency Analysis of Solar PV Power to Enable Optimal Building Load Control
April 3, 2023 (v1)
Subject: Process Control
Keywords: boxplot, energy storage systems, Fourier transform, Model Predictive Control, Solar Photovoltaic, spectral analysis, thermostatically controlled loads.
In this paper, we present a flexibility estimation mechanism for buildings’ thermostatically controlled loads (TCLs) to enable the distribution level consumption of the majority of solar photovoltaic (PV) generation by local building TCLs. The local consumption of PV generation provides several advantages to the grid operation as well as the consumers, such as reducing the stress on the distribution network, minimizing voltage fluctuations and two-way power flows in the distribution network, and reducing the required battery storage capacity for PV integration. This would result in increasing the solar PV generation penetration levels. The aims of this study are twofold. First, spectral (frequency) analyses of solar PV power generation together with the power consumption of multiple building TCLs (such as heating, ventilation, and air conditioning (HVAC) systems, water heaters, and refrigerators) are performed. These analyses define the bandwidth over which these TCLs can operate and a... [more]
12909. LAPSE:2023.26226
Defrosting Performance Improvement of Air-Source Heat Pump Combined Refrigerant Direct-Condensation Radiant Floor Heating System with Phase Change Material
April 3, 2023 (v1)
Subject: Materials
Keywords: ASHP system, CPCM, defrosting, indoor thermal comfort, refrigerant direct-condensation radiant floor heating.
Traditional defrosting methods applied to solve frosting problems of air-source heat pumps operating in cold periods may reduce heat capacity of the system and decrease indoor thermal comfort. In order to improve the performance of air-source heat pump (ASHP) and maintain indoor temperature in defrosting conditions, an air-source heat pump combined with a refrigerant direct-condensation radiant floor heating system with phase change material is proposed and evaluated in this study. Two radiant floor heating terminals with and without composite phase change material modules were compared through experiments. A composite phase change material based on dodecanoic acid-tetradecanol-hexadecanol mixture and expanded graphite was investigated for this application. Experimental results indicate that both heat fluxes of two comparing terminals are higher than 70 W/m2 in heating condition. At the same time, the floor surface temperature, indoor air temperature, and heating capacity of the termin... [more]
12910. LAPSE:2023.26225
Gas-Wetting Alteration by Fluorochemicals and Its Application for Enhancing Gas Recovery in Gas-Condensate Reservoirs: A Review
April 3, 2023 (v1)
Subject: Other
Keywords: flow behavior, fluorochemical, gas-wetting alteration, liquid-blocking effect, morphology.
Gas-wetting alteration is a versatile and effective approach for alleviating liquid-blockage that occurs when the wellbore pressure of a gas-condensate reservoir drops below the dew point. Fluorochemicals are of growing interest in gas-wetting alteration because of their high density of fluorine groups and thermal stability, which can change the reservoir wettability into more favorable conditions for liquids. This review aims to integrate the overlapping research between the current knowledge in organic chemistry and enhanced oil and gas recovery. The difference between wettability alteration and gas-wetting alteration is illustrated, and the methods used to evaluate gas-wetting are summarized. Recent advances in the applications of fluorochemicals for gas-wetting alteration are highlighted. The mechanisms of self-assembling adsorption layers formed by fluorochemicals with different surface morphologies are also reviewed. The factors that affect the gas-wetting performance of fluoroch... [more]
12911. LAPSE:2023.26224
Multi Usage Applications of Li-Ion Battery Storage in a Large Photovoltaic Plant: A Practical Experience
April 3, 2023 (v1)
Subject: Energy Systems
Keywords: battery storage, intraday market, peak-shaving, photovoltaic power plant, power control, smart grid.
The number of large energy storage units installed in the power system has increased over the last few years. This fact remains closely linked to the increase in the share of renewable energy in electricity generation. This is necessary to maintain the stability of the grid, which is becoming increasingly difficult to maintain due to the growing number of renewable energy sources (RES). Energy production from these sources is difficult to estimate, and possible unplanned shortages and surpluses in production are the cause of voltage and frequency fluctuations, which is an undesirable state. Consequently, the use of energy storage not only contributes to the regulation of grid operation but can also, under appropriate conditions, constitute an additional load if too much energy is generated by RES, or the source when the generation from RES is insufficient. The main contributions of this paper are as follows: A presentation of practical results achieved by implementing two optimal contr... [more]
12912. LAPSE:2023.26223
Studies on Dynamic Properties of Ultracapacitors Using Infinite r−C Chain Equivalent Circuit and Reverse Fourier Transform
April 3, 2023 (v1)
Subject: Energy Systems
Keywords: equivalent circuit, Fourier transform, internal resistance, ultracapacitor.
The specific power storage capabilities of double-layer ultracapacitors are receiving significant attention from engineers and scientific researchers. Nevertheless, their dynamic behavior should be studied to improve the performance and for efficient applications in electrical devices. This article presents an infinite resistor−capacitor (r−C) chain-based mathematical model for the analysis of double layer ultracapacitors. The internal resistance and capacitance were measured for repetitive charging and discharging cycles. The magnitudes of internal resistance and capacitance showed approximately ±10% changes for charge-discharge processes. Electrochemical impedance spectroscopy investigations revealed that the impedance of a double-layer ultracapacitor does not change significantly in the temperature range of (−30 °C to +30 °C) and voltage range of (0.3376−2.736 V). The analysis of impedance data using the proposed mathematical model showed good agreement between the experimental and... [more]
12913. LAPSE:2023.26222
Experimental Investigations of Forward and Reverse Combustion for Increasing Oil Recovery of a Real Oil Field
April 3, 2023 (v1)
Subject: Energy Systems
Keywords: carbonate reservoir, enhanced oil recovery, forward combustion, high-pressure combustion tube, reverse combustion.
The work presented herein is devoted to a unique set of forward and reverse combustion tube (CT) experiments to access the suitability and potential of the in situ combustion (ISC) method for the light oil carbonate reservoir. One forward and one reverse combustion tube tests were carried out using the high-pressure combustion tube (HPCT) experimental setup. However, during reverse combustion, the front moved in the opposite direction to the airflow. The results obtained from experiments such as fuel/air requirements, H/C ratio, and recovery efficiency are crucial for further validation of the numerical model. A quantitative assessment of the potential for the combustion was carried out. The oil recovery of forward combustion was as high as 91.4% of the initial oil in place, while that for the reverse combustion test demonstrated a 43% recovery. In the given conditions, forward combustion demonstrated significantly higher efficiency. However, the stabilized combustion front propagation... [more]
12914. LAPSE:2023.26221
Enhancement in Combustion, Performance, and Emission Characteristics of a Diesel Engine Fueled with Ce-ZnO Nanoparticle Additive Added to Soybean Biodiesel Blends
April 3, 2023 (v1)
Subject: Energy Systems
Keywords: cerium-zinc oxide nanoparticle additives, engine performance, nanoparticle combustion, soybean biodiesel.
This study considered the impacts of diesel−soybean biodiesel blends mixed with 3% cerium coated zinc oxide (Ce-ZnO) nanoparticles on the performance, emission, and combustion characteristics of a single cylinder diesel engine. The fuel blends were prepared using 25% soybean biodiesel in diesel (SBME25). Ce-ZnO nanoparticle additives were blended with SBME25 at 25, 50, and 75 ppm using the ultrasonication process with a surfactant (Span 80) at 2 vol.% to enhance the stability of the blend. A variable compression ratio engine operated at a 19.5:1 compression ratio (CR) using these blends resulted in an improvement in overall engine characteristics. With 50 ppm Ce-ZnO nanoparticle additive in SBME25 (SBME25Ce-ZnO50), the brake thermal efficiency (BTE) and heat release rate (HRR) increased by 20.66% and 18.1%, respectively; brake specific fuel consumption (BSFC) by 21.81%; and the CO, smoke, and hydrocarbon (HC) decreased by 30%, 18.7%, and 21.5%, respectively, compared to SBME25 fuel ope... [more]
12915. LAPSE:2023.26220
SiC-MOSFET and Si-IGBT-Based dc-dc Interleaved Converters for EV Chargers: Approach for Efficiency Comparison with Minimum Switching Losses Based on Complete Parasitic Modeling
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: electric vehicle (EV), fast charging, interleaved dc–dc converter, Si devices, SiC devices.
Widespread dissemination of electric mobility is highly dependent on the power converters, storage systems and renewable energy sources. The efficiency and reliability, combined with the emerging and innovative technologies, are crucial when speaking of power converters. In this paper the interleaved dc−dc topology has been considered for EV charging, due to its improved reliability. The efficiency comparison of the SiC-MOSFET and Si-IGBT-based converters has been done on wide range of switching frequency and output inductances. The interleaved converters were considered with the optimal switching parameters resulting from the analysis done on a detailed parasitic circuit model, ensuring minimum losses and maintaining the safe operating area. The analysis included the comparison of different inductors, and for the selected ones the complete system efficiency and cost were conducted. The results indicate the benefits when SiC-MOSFETs are applied to the interleaved dc−dc topology for wid... [more]
12916. LAPSE:2023.26219
Cement Integrity Loss due to Interfacial Debonding and Radial Cracking during CO2 Injection
April 3, 2023 (v1)
Subject: Process Control
Keywords: cement integrity, CO2 injection, energy release rate, interfacial debonding, radial cracking.
Cement provides zonal isolation and mechanical support, and its integrity is critical to the safety and efficiency of the CO2 injection process for geologic carbon storage. This work focuses on interfacial debonding at wellbore interfaces and radial cracking in cement during CO2 injection. It adopts the definition of the energy release rate (ERR) to characterize the propagation of cracks. Based on the finite element method, the proposed model estimates the ERRs of both types of cracks with practical wellbore configurations and injection parameters. Further parametric studies reveal the effects of cement’s mechanical and thermal properties and the crack geometry on crack propagation. Simulation results show that the ERRs of interfacial and radial cracks would surpass 100 J/m2 with typical cement properties. The cement’s thermal expansion coefficient is the most influential factor on the ERR, followed by its Young’s modulus, Poisson’s ratio, and thermal conductivity. The initial sizes an... [more]
12917. LAPSE:2023.26218
An Improvement of Output Power in Doubly Salient Permanent Magnet Generator Using Pole Configuration Adjustment
April 3, 2023 (v1)
Subject: Other
Keywords: brushless machines, doubly salient permanent magnet machines, permanent magnet generator, permanent magnet synchronous machines, rotating machines.
The doubly salient permanent magnet (DSPM) machines are very attractive for low-speed power generation. In this work, we propose a design technique to improve the output power of the DSPM generator by an adjustment of pole configuration. The number of stator and rotor poles, split ratio, as well as the stator pole arc of the generator, were proposedly adjusted and optimized. The output characteristics of the generator including the magnetic flux linkage, electromotive force, harmonic, cogging torque, electromagnetic torque, output voltage and output power were analyzed through finite element analysis. The symmetrical magnetic field distribution of all generators was firstly verified. Then, the results indicated that this particular generator was optimized at 18 stator poles and 12 rotor poles, while the split ratio and the stator pole arc should be set as 0.78 and 6.15 degrees, respectively. The proposed optimal generator could provide a significant improvement in the output voltage an... [more]
12918. LAPSE:2023.26217
Nonlinear Optimization of Turbine Conjugate Heat Transfer with Iterative Machine Learning and Training Sample Replacement
April 3, 2023 (v1)
Subject: Energy Systems
Keywords: conjugate thermal analysis, heat transfer, Machine Learning, Optimization, thermal design, turbine cooling.
A simple yet effective optimization technique is developed to solve nonlinear conjugate heat transfer. The proposed Nonlinear Optimization with Replacement Strategy (NORS) is a mutation of several existing optimization processes. With the improvements of 3D metal printing of turbine components, it is feasible to have film holes with unconventional diameters, as these holes are created while printing the component. This paper seeks to optimize each film hole diameter at the leading edge of a turbine vane to satisfy several optimum thermal design objectives with given design constraints. The design technique developed uses linear regression-based machine learning model and further optimizes with strategic improvement of the training dataset. Optimization needs cost and benefit criteria are used to base its decision of success, and cost is minimized with maximum benefit within given constraints. This study minimizes the coolant flow (cost) while satisfying the constraints on average metal... [more]
12919. LAPSE:2023.26216
Smart Control Strategies for Primary Frequency Regulation through Electric Vehicles: A Battery Degradation Perspective
April 3, 2023 (v1)
Subject: Energy Systems
Keywords: electric vehicle batteries (EVBs), electric vehicles (EVs), frequency droop control (FDC), vehicle-to-grid (V2G).
Nowadays, due to the decreasing use of traditional generators in favor of renewable energy sources, power grids are facing a reduction of system inertia and primary frequency regulation capability. Such an issue is exacerbated by the continuously increasing number of electric vehicles (EVs), which results in enforcing novel approaches in the grid operations management. However, from being an issue, the increase of EVs may turn to be a solution to several power system challenges. In this context, a crucial role is played by the so-called vehicle-to-grid (V2G) mode of operation, which has the potential to provide ancillary services to the power grid, such as peak clipping, load shifting, and frequency regulation. More in detail, EVs have recently started to be effectively used for one of the most traditional frequency regulation approaches: the so-called frequency droop control (FDC). This is a primary frequency regulation, currently obtained by adjusting the active power of generators i... [more]
12920. LAPSE:2023.26215
On-Line Diagnosis and Fault State Classification Method of Photovoltaic Plant
April 3, 2023 (v1)
Subject: Process Operations
Keywords: health index, Machine Learning, on-line diagnosis, operation and maintenance, photovoltaic plant, reliability.
This paper presents an on-line diagnosis method for large photovoltaic (PV) power plants by using a machine learning algorithm. Most renewable energy output power is decreased due to the lack of management tools and the skills of maintenance engineers. Additionally, many photovoltaic power plants have a long down-time due to the absence of a monitoring system and their distance from the city. The IEC 61724-1 standard is a Performance Ratio (PR) index that evaluates the PV power plant performance and reliability. However, the PR index has a low recognition rate of the fault state in conditions of low irradiation and bad weather. This paper presents a weather-corrected index, linear regression method, temperature correction equation, estimation error matrix, clearness index and proposed variable index, as well as a one-class Support Vector Machine (SVM) method and a kernel technique to classify the fault state and anomaly output power of PV plants.
12921. LAPSE:2023.26214
Influence of Slag Cement on the Permeability of Concrete for Biological Shielding Structures
April 3, 2023 (v1)
Subject: Materials
Keywords: carbonation, chloride permeability, magnetite, microstructure, MIP, mix design, Portland cement, radiation shielding concrete, slag cement.
Durability of concrete designed for radiation shielding structures is an important issue in nuclear power plant safety. An investigation of the permeability of concrete containing heavyweight aggregates and water-bearing aggregates was performed with respect to gaseous and liquid media. Mix design was developed using Portland and slag cement, crushed magnetite and serpentine aggregate. The use of slag cement in concrete containing magnetite and serpentine aggregates resulted in the substantial improvement of the compressive strength in comparison with Portland cement concrete. The application of slag cement was found to reduce the chloride ingress, regardless of the special aggregate use. The coefficient of chloride migration was within the range 5 ÷ 8 × 10−12 m2/s and 17 ÷ 25 × 10−12 m2/s for slag cement concrete and Portland cement concrete, respectively. At the same time, the carbonation depth was increased twice for slag cement concrete in comparison to Portland cement concrete. Ho... [more]
12922. LAPSE:2023.26213
Water-Induced Corrosion Damage of Carbon Steel in Sulfolane
April 3, 2023 (v1)
Subject: Materials
Keywords: AISI 1010 steel, corrosion resistance, fractal dimension, Kelvin probe, sulfolane.
Sulfolane in contact with water and oxygen forms acidic (by-) products that are major factors in accelerating the corrosion of carbon/stainless steel. In consequence, water-induced corrosion damage can be a serious problem in industrial systems. Hence, the determination of the corrosion resistance of AISI 1010 steel immersed in sulfolane containing 0 to 6 vol.% water was the principal objective of the study. Evaluation of the corrosion resistance of steel electrodes was performed using a potentiodynamic technique and scanning Kelvin probe microscopy. It was observed that the corrosion products layer that formed on the surface of AISI 1010 steel partially protects it against corrosion in sulfolane with a water concentration in the range from 1 vol.% to 4 vol.%. Interestingly, amounts of water above 4 vol.% cause a break-down of the corrosion products layer and deteriorate the corrosion resistance of AISI 1010 steel as well. Moreover, the relationship between the fractal dimension, corro... [more]
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