Ratios of equilibrium solubilities rarely exceed two-fold for polymorph pairs. A model has been developed based on two intrinsic properties of polymorph pairs, namely the ratio of equilibrium solubilities of the individual pairs (C*me/C*st) and the ratio of interfacial energies (γst/γme) and one applied experimental condition, namely the supersaturation identifies which one of a pair of polymorphs nucleates first. A domain diagram has been developed, which identifies the point where the critical free energy of nucleation for the polymorph pair are identical. Essentially, for a system supersaturated with respect to both polymorphs, the model identifies that low supersaturation with respect to the stable polymorph (Sst) leads to an extremely small supersaturation with respect to the metastable polymorph (Sme), radically driving up the critical free energy with respect to the metastable polymorph. Generally, high supersaturations sometimes much higher than the upper limit of the metastabl... [more]

A mathematical modeling of glucose−water separation through a reverse osmosis (RO) membrane was developed to research the membrane’s performance during the mass transfer process. The model was developed by coupling the concentration−polarization (CP) model, which uses one-dimensional flow assumption, with the irreversible thermodynamic Spiegler−Kedem model. A nonlinear parameter estimation technique was used to determine the model parameters Lp (hydraulic permeability constant), σ (reflection coefficient), and Bs (solute transport coefficient). Experimental data were obtained from the treatment of a pre-treated glucose solution using a laboratory-scale RO system, and studies on the validation of the model using experimental results are presented. The calculated results are consistent with the experimental data. The proposed model describes the RO membrane concentration process and deduces the expression of k (mass transfer coefficient in the CP layer). The verification shows that the e... [more]

This paper presents a pioneering study on numerical modeling of load bearing characteristics of the jacket foundation pile for offshore wind turbines on the west coast of Taiwan. Because Taiwan is located in an earthquake prone area, there is significant interest in improving the prediction of the behavior of wind turbine jacket foundations subjected to seismic loading. Investigation of the bearing capacity of the jacket foundation pile for the offshore wind farm using effective stress analysis, with consideration of pore pressure generation and soil/liquid coupled analysis, was conducted. A new procedure to evaluate the design of offshore wind turbine foundation piles in the sand and clay inter-layered soil was also proposed. Static and dynamic analyses of bearing capacity of the jacket foundation pile were conducted. Results obtained demonstrate that the design process for the jacket foundation pile proposed in this study can properly reflect the interaction behavior of the foundatio... [more]

Machine tool is the basic manufacturing equipment in today’s mechanical manufacturing industry. A considerable amount of energy and carbon emission are consumed in machining processes, the realization of sustainable manufacturing of machine tools have become an urgent problem to be solved in the field of industry and academia. Therefore, five types of machine tools were selected for the typical machining processes (turning, milling, planning, grinding and drilling). Then the model of the energy efficiency, carbon efficiency and green degree model were established in this paper which considers the theory and experiment with the resource, energy and emission modeling method. The head frame spindle and head frame box were selected to verify the feasibility and practicability of the proposed model, based on the orthogonal experiment case of the key machining process. In addition, the influence rules of machining parameters were explored and the energy efficiency and green degree of the mac... [more]

Gas hydrate blockage in pipelines during offshore production becomes a major problem with increasing water depth. In this work, a series of experiments on gas hydrate formation in a flow loop was performed with low flow rates of 0.33, 0.66, and 0.88 m/s; the effects of the initial subcooling, flow rate, pressure, and morphology were investigated for methane hydrate formation in the flow loop. The results indicate that the differential pressure drop (ΔP) across two ends of the horizontal straight pipe increases with increasing hydrate concentration at the early stage of gas hydrate formation. When the flow rates of hydrate fluid are low, the higher the subcooling is, the faster the transition of the hydrates macrostructures. Gas hydrates can agglomerate, and sludge hydrates appear at subcoolings of 6.5 and 8.5 °C. The difference between the ΔP values at different flow rates is small, and there is no obvious influence of the flow rates on ΔP. Three hydrate macrostructures were observed:... [more]

The flashing phenomenon is relevant to nuclear safety analysis, for example by a loss of coolant accident and safety release scenarios. It has been studied intensively by means of experiments and simulations with system codes, but computational fluid dynamics (CFD) simulation is still at the embryonic stage. Rapid increasing computer speed makes it possible to apply the CFD technology in such complex flow situations. Nevertheless, a thorough evaluation on the limitations and restrictions is still missing, which is however indispensable for reliable application, as well as further development. In the present work, the commonly-used two-fluid model with different mono-disperse assumptions is used to simulate various flashing scenarios. With the help of available experimental data, the results are evaluated, and the limitations are discussed. A poly-disperse method is found necessary for a reliable prediction of mean bubble size and phase distribution. The first attempts to trace the evol... [more]

Global solar radiation is generally measured on a horizontal surface, whereas the maximum amount of incident solar radiation is measured on an inclined surface. Over the last decade, a number of models were proposed for predicting solar radiation on inclined surfaces. These models have various scopes; applicability to specific surfaces, the requirement for special measuring equipment, or limitations in scope. To find the most suitable model for a given location the hourly outputs predicted by available models are compared with the field measurements of the given location. The main objective of this study is to review on the estimation of the most accurate model or models for estimating solar radiation components for a selected location, by testing various models available in the literature. To increase the amount of incident solar radiation on photovoltaic (PV) panels, the PV panels are mounted on tilted surfaces. This article also provides an up-to-date status of different optimum til... [more]

In the field of domestic refrigeration, it is important to look for methods that can be used to simulate, and, thus, improve the thermal behavior of the fresh food compartment. In this sense, this study proposes some methods to model the thermal behavior of this compartment when the shelves’ positions are changed. Temperature measurements at specific locations in this compartment were obtained. Several shelf position combinations were performed to use three 2D interpolation methods in order to simulate the temperature mean and the temperature variance. The methods used were: Lagrange’s interpolation, cubic spline interpolation and bilinear interpolation. Two validation points were chosen to verify the proposed methods. By comparing the experimental results with the computer simulations, it was possible to conclude that the method of Lagrange’s interpolation provided values that were not close to the real measured values. On the other hand, it was observed that the method of bilinear in... [more]

We have investigated the effects of the rotating blades of an upwind-type three-blade horizontal-axis wind turbine (HAWT) on the basic characteristics of aerodynamic forces acting on its tower by conducting improved delayed detached-eddy simulations (DESs). Three tip-speed ratios were considered for the operating conditions of the HAWT: λ = 3 (low), λ = 6 (optimum), and λ = 10 (high). The diversion of the flow approaching the tower by the rotating blades and the low-pressure region that formed downwind of the blades significantly affected the aerodynamic forces acting on the tower. For example, the azimuth angle around the tower at which the pressure reached a maximum at each height shifted significantly in the direction of the movement of the blade passing the tower because of the diversion of the flow by the blades. Fluctuations in the lift force of the tower were significantly larger than those in its drag force because of the low-pressure region downwind of the blades.

This article presents a novel mixed-thermoelastohydrodynamic (TEHD) model for the lateral lubricating interfaces which exist between floating lateral bushings and gears in external gear machines (EGMs). The proposed model integrates the influence of surface asperities along with the fluid structure and thermal interaction in the interface, especially in the regions of very low film thicknesses by following a stochastic approach in modelling the mixed lubrication regime. Furthermore, the current work includes validation of the predictions of the mixed-TEHD model against experimentally measured leakages from the lateral gap and compares the performance of this model with a previously developed full film TEHD model for the lateral gaps in EGMs.

Small and micro hydropower systems represent an attractive solution for generating electricity at low cost and with low environmental impact. The pump-as-turbine (PAT) approach has promise in this application due to its low purchase and maintenance costs. In this paper, a new method to predict the inverse characteristic of industrial centrifugal pumps is presented. This method is based on results of simulations performed with commercial three-dimensional Computational Fluid Dynamics (CFD) software. Model results have been first validated in pumping mode using data supplied by pump manufacturers. Then, the results have been compared to experimental data for a pump running in reverse. Experimentation has been performed on a dedicated test bench installed in the Department of Civil Construction and Environmental Engineering of the University of Naples Federico II. Three different pumps, with different specific speeds, have been analyzed. Using the model results, the inverse characteristic... [more]

Numerical simulations were performed to investigate pressure fluctuations in the S-shaped region of a pump-turbine model. Analyses focused on pressure fluctuations in the draft tube and in the gap between the guide vanes and runner. Calculations were made under six different operating conditions with a constant guide vane opening, and the best efficiency point, runaway point, and low-discharge point in the turbine brake zone were determined. The simulated results were compared with experimental measurements. In the draft tube, a twin vortex rope was observed. In the gap between the guide vanes and runner, a low frequency component was captured at both the runaway and low-discharge points in the turbine brake zone, which rotated at 65% of the runner frequency. This low frequency component was induced by the rotating stall phenomenon. At the runaway point, a single stall cell was found in the gap between the guide vanes and runner, while at the low-discharge point, four stall cells were... [more]

A computational efficient battery pack model with thermal consideration is essential for simulation prototyping before real-time embedded implementation. The proposed model provides a coupled equivalent circuit and convective thermal model to determine the state-of-charge (SOC) and temperature of the LiFePO₄ battery working in a real environment. A cell balancing strategy applied to the proposed temperature-dependent battery model balanced the SOC of each cell to increase the lifespan of the battery. The simulation outputs are validated by a set of independent experimental data at a different temperature to ensure the model validity and reliability. The results show a root mean square (RMS) error of 1.5609 × 10−5 for the terminal voltage and the comparison between the simulation and experiment at various temperatures (from 5 °C to 45 °C) shows a maximum RMS error of 7.2078 × 10−5.

In this study, a three dimensional (3D) modeling has been built for a lithium ion battery pack using the field synergy principle to obtain a better thermal distribution. In the model, the thermal behavior of the battery pack was studied by reducing the maximum temperature, improving the temperature uniformity and considering the difference between the maximum and maximum temperature of the battery pack. The method is further verified by simulation results based on different environmental temperatures and discharge rates. The thermal behavior model demonstrates that the design and cooling policy of the battery pack is crucial for optimizing the air-outlet patterns of electric vehicle power cabins.

Numerous analytical studies for power augmentation systems can be found in the literature with the goal to improve the performance of wind turbines by increasing the energy density of the air at the rotor. All methods to date are only concerned with the effects of a diffuser as the power augmentation, and this work extends the semi-empirical shrouded wind turbine model introduced first by Foreman to incorporate a converging-diverging nozzle into the system. The analysis is based on assumptions and approximations of the conservation laws to calculate optimal power coefficients and power extraction, as well as augmentation ratios. It is revealed that the power enhancement is proportional to the mass stream rise produced by the nozzle diffuser-augmented wind turbine (NDAWT). Such mass flow rise can only be accomplished through two essential principles: the increase in the area ratios and/or by reducing the negative back pressure at the exit. The thrust coefficient for optimal power produc... [more]

Mixing phenomena in metallurgical steel ladles by bottom gas injection involves three phases namely, liquid molten steel, liquid slag and gaseous argon. In order to numerically solve this three-phase fluid flow system, a new approach is proposed which considers the physical nature of the gas being a dispersed phase in the liquid, while the two liquids namely, molten steel and slag are continuous phases initially separated by a sharp interface. The model was developed with the combination of two algorithms namely, IPSA (inter phase slip algorithm) where the gas bubbles are given a Eulerian approach since are considered as an interpenetrating phase in the two liquids and VOF (volume of fluid) in which the liquid is divided into two separate liquids but depending on the physical properties of each liquid they are assigned a mass fraction of each liquid. This implies that both the liquid phases (steel and slag) and the gas phase (argon) were solved for the mass balance. The Navier−Stokes c... [more]

This paper describes a mathematical model for the convection, diffusion, and balance phenomena for predicting the depletion curves, i.e., variations in the timed surface-active molecule concentration for fractionation processes in bubbles and foam column, operated in semi-batch. The model was applied for the purification of the surfactin solution and the results were compared with experimental data. Gibbs adsorption curves were obtained for the biosurfactant at different temperatures, and then adjusted with estimated parameters, according to the Langmuir adsorption model. The gas bubble sizes were optically determined. The isotherm adsorption parameters and bubble average diameter are crucial for the attainment of the depletion curves, generated by the model described. The results demonstrate that the process is most effective when operating a column with reduced gas flow and low initial concentration. A top product with two or thirty times greater concentration than the initial one wa... [more]

The thermodynamic approach for the description of multiphase open phase processes is developed based on van der Waals equation in the metrics of Gibbs and incomplete Gibbs potentials. Examples of thermodynamic modeling of the multiphase and multicomponent A3B5 systems (In-Ga-As-Sb and In-P-As-Sb) and Na+, K+, Mg2+, Ca2+//Cl−, SO42−-H2O water−salt system are presented. Topological isomorphism of different type phase diagrams is demonstrated.

The petroleum coke gasification integrated gasification combined cycle power plant (petcoke-IGCC) is a promising avenue for disposal of the ever-growing amount of stockpiled petroleum coke. In this work, we present a novel techno-economic and life cycle assessment of the process operated with carbon capture and sequestration. The proposed petcoke-to-electricity plant is designed and simulated in Aspen Plus v10. The proposed power plant was compared against coal integrated gasification combined cycle (coal-IGCC) and supercritical pulverized coal power plants operated with carbon capture and sequestration. The results showed that although the efficiency of the coal-IGCC plant is higher than the petcoke-IGCC plant, the higher energy density of the petcoke and lower resource costs were such that the levelized cost of electricity of petcoke-IGCC was lower than coal-IGCC. Furthermore, the feed flow rate of petcoke to the petcoke-IGCC process is approximately 15% lower than the coal feed rate... [more]

In this article, electrical characteristics of a high-power inductively-coupled plasma (ICP) torch operating at 3 MHz are determined by direct measurement of radio-frequency (RF) current and voltage together with energy balance in the system. The variation of impedance with two parameters, namely the input power and the sheath gas flow rate for a 50 kW ICP is studied. The ICP torch system is operated at near atmospheric pressure with argon as plasma gas. It is observed that the plasma resistance increases with an increase in the RF-power. Further, the torch inductance decreases with an increase in the RF-power. In addition, plasma resistance and torch inductance decrease with an increase in the sheath gas flow rate. The oscillator efficiency of the ICP system ranges from 40% to 80% with the variation of the Direct current (DC) powers. ICP has also been numerically simulated using Computational Fluid Dynamics (CFD) to predict the impedance profile. A good agreement was found between the... [more]

Computational Fluid Dynamics (CFD) tools are used to investigate fluid flow and scalar mixing in micromixers where low molecular diffusivities yield advection dominant transport. In these applications, achieving a numerical solution is challenging. Numerical procedures used to overcome these difficulties may cause misevaluation of the mixing process. Evaluation of the mixing performance of these devices without appropriate analysis of the contribution of numerical diffusion yields over estimation of mixing performance. In this study, two- and four-inlet swirl-generating micromixers are examined for different mesh density, flow and molecular diffusivity scenarios. It is shown that mesh densities need to be high enough to reveal numerical diffusion errors in scalar transport simulations. Two-inlet micromixer design was found to produce higher numerical diffusion. In both micromixer configurations, when cell Peclet numbers were around 50 and 100 for Reynolds numbers 240 and 120, the numer... [more]

Groundwater contamination previously occurred at a broad range of locations in present-day China. There are thousands of kinds of contaminants which can be divided into soluble and insoluble categories in groundwater. In recent years, the non-aqueous phase liquid (NAPL) pollution that belongs to the multi-phase seepage flow phenomenon has become an increasingly prominent topic due to the challenge brought by groundwater purification and its treatment. Migrating with seepage flow and moving into the potable water sources, these contaminants directly endanger people’s health. Therefore, it is necessary to research how these contaminants not only migrate, but also are then accordingly remedied. First, as an analysis means, an effective numerical method is necessary to be built. A three-dimensional finite element method program for analyzing two-phase flow in porous media, which can be applied to the immiscible contaminant transport problem in subsurface flow has been developed in this pap... [more]

The application of the hole cleaning device in downhole is a new technology that can improve the problem of cuttings accumulation in the annulus and improve the hole cleaning effect of the wellbore during drilling. In this paper, the Reynolds Averaged Navier⁻Stokes model, together with the Realizable k-ε turbulence model, are used to perform transient simulations. The effects of rotational speed, blade shape, and helical angle on the initial swirl intensity and its decay behavior along the flow direction are studied. The swirl number, the initial swirl intensity, the decay rate, the tangential velocity distribution, and the variation of pressure are analyzed. The results indicate that the swirl number of the swirl flow exponentially decays along the flow direction. The straight blade and V-shaped blade have different swirl flow induction mechanisms. Under specific drilling parameters, the critical helical angle is determined for both types of blades. When the selection of the helical a... [more]

As debris flow is one of the most destructive natural disasters in many parts of the world, the assessment and management of future debris flows with proper forecasting methods are crucial for the safety of life and property. So increasing attention has been paid to the forecasting methods on debris flows. A debris flow forecasting method based on the rainfall-unstable soil coupling mechanism (R-USCM) is presented in the current study. This method is based on the debris flow formation mechanism. The density of sediment is introduced as an evaluation index to determine the susceptibility of debris flow occurrence. The forecasting method includes two phases: (1) rainfall and soil coupling and (2) runoff and unstable soil coupling. Scoops3D, a three-dimensional (3D) model for analyzing slope stability, was introduced into the debris flow forecasting method. In order to test the forecasting accuracy of this method, Jiaohe County was selected as a research area, and the serious debris flow... [more]

Recent in vitro experiments have demonstrated the ability of the pathogen Clostridium difficile and commensal gut bacteria to form biofilms on surfaces, and biofilm development in vivo is likely. Various studies have reported that 3%⁻15% of healthy adults are asymptomatically colonized with C. difficile, with commensal species providing resistance against C. difficile pathogenic colonization. C. difficile infection (CDI) is observed at a higher rate in immunocompromised patients previously treated with broad spectrum antibiotics that disrupt the commensal microbiota and reduce competition for available nutrients, resulting in imbalance among commensal species and dysbiosis conducive to C. difficile propagation. To investigate the metabolic interactions of C. difficile with commensal species from the three dominant phyla in the human gut, we developed a multispecies biofilm model by combining genome-scale metabolic reconstructions of C. difficile, Bacteroides thetaiotaomicron from the p... [more]