The reuse of wastewater has been observed as a viable option to cope with increasing water stress in Africa. The present case studies evaluated the optimization of the process of phycoremediation as an alternative low-cost green treatment technology in two municipality wastewater treatment pond systems that make up the largest number of domestic sewage treatment systems on the African continent. A consortium of specific microalgae (Chlorella vulgaris and Chlorella protothecoides) was used to improve the treatment capacity of domestic wastewater at two operational municipality wastewater pond systems under different environmental conditions in South Africa. Pre- and post-phycoremediation optimization through mass inoculation of a consortium of microalgae, over a period of one year under different environmental conditions, were compared. It was evident that the higher reduction of total phosphates (74.4%) in the effluent, after treatment with a consortium of microalgae at the Motetema po... [more]

Among the innovative technologies utilized for the treatment of contaminated soils, the use of green surfactants appears to be a biocompatible, efficient, and attractive alternative, since the cleaning processes that normally use synthetic surfactants as additives cause other problems due to toxicity and the accumulation of by-products. Three green surfactants, i.e., two biobased (biobased 1 and biobased 2) surfactants produced by chemical synthesis and a microbial surfactant produced from the yeast Starmerella bombicola ATCC 22214, were used as soil remediation agents and compared to a synthetic surfactant (Tween 80). The three surfactants were tested for their ability to emulsify, disperse, and remove different hydrophobic contaminants. The biosurfactant, which was able to reduce the water surface tension to 32.30 mN/m at a critical micelle concentration of 0.65 g/L, was then used to prepare a commercial formulation that showed lower toxicity to the tested environmental bioindicators... [more]

The issue of oily wastewater treatment has become a worldwide challenge due to increasing industrial oily wastewater and frequent oil spill accidents. As an integral part of practical sewage treatment, pretreatment is conducted to remove inorganic particles, floating oil, and some emulsified oil, and to pave the way for post-treatment. Here, we report a facile fabricated, hydrostable, and rapid underwater-formed superoleophobic copper mesh with polydopamine (PDA) coating for efficient oily wastewater pre-treatment. Unlike with traditional technologies, using the interface phenomenon to solve the problem of oil/water mixture separation provided a new approach for the low energy input pretreatment process. The PDA coating formed by the in situ Fenton method not only rapidly constructs a protection layer for the etched hierarchical micro-size particles on mesh and results in enhanced hydrophilicity, but also exhibits high uniformity and enhanced stability in acid/alkali medium. Benefiting... [more]

Volatile organic compounds (VOCs) are intermittently emitted at high concentrations (tens of thousands of ppmv) from small-scale laundry shops in urban areas, affecting the urban atmospheric environment. In this study, we suggested integrating VOC treatment processes incorporating condensation and adsorption in series to remove VOCs released from small-scale laundry dryers (laundry weighing less than 30 kg). We designed two different processes depending on regeneration modes for adsorber beds; an open-circuit flow process and a closed-loop flow process in regeneration mode. Our VOC treatment processes enable sustainable operation via the regeneration of adsorbers on a regular basis. Before applying the VOC treatment processes, average concentration of total volatile organic compounds (TVOCs) was 4099 ppmv (12,000 ppmv of the peak concentration) during the drying operation. After applying our closed-loop flow process, TVOC concentration decreased to 58 ppmv, leading to 98.5% removal eff... [more]

With the increase in industrialization and urbanization, water pollution has become increasingly serious, and wastewater treatment has become a common step in preventing this. For a greater understanding of the sustainability of different wastewater treatment systems, two processes, Anaerobic Baffled Reactor + Anaerobic-Anoxic-Oxic and Anaerobic Baffled Reactor + Cyclic Activated Sludge System, were selected, and their sustainability was evaluated based on three indicators, namely emergy yield ratio, environmental load rate, and emergy sustainability development index, according to emergy theory. The results show that the emergy yield ratio and environmental load rate of the ABR + CASS process were lower than those of the ABR + A2/O process, and the emergy sustainability development index of the ABR + CASS process was higher than that of the ABR + A2/O process, showing better sustainability. The research methods and findings of this study play an important role for decision makers in s... [more]

The stable quality of circulating water ensures the long-term stable operation of various processes in petrochemical production and achieves energy savings and emission reduction while reducing environmental pollution and yielding economic benefits to petrochemical enterprises. However, traditional circulating water quality evaluation and modeling for corrosion rate prediction suffer from adaptability and accuracy problems. To address these problems, the water quality analysis data of the circulating water in the field were subjected to data preprocessing and water quality index calculation to perform feature engineering, followed by modeling using a machine learning method that integrates the adaptive immune genetic algorithm and random forest (RF) algorithm and can intelligently select the water quality parameters to be used as the input variables for the RF modeling. Finally, the method was validated using an industrial example, and the results indicate that the method is capable of... [more]

Kiln is a prime need in the ceramics industry, where energy loss is a major part which consumes about 60% production cost through thermal energy for different applications. Higher density of fired and tunnel kiln refractory material lowers the thermal diffusivity and the proper selection of fired material minimizes the energy loss along the kiln. In particular, this research analysed the results of a heat recovery system comprised of a metallic recuperator which gives around 8% energy savings in natural gas consumption. In this work, detailed power quality analysis of low-power factor motors of a tunnel kiln was carried out and a power factor improvement solution was suggested to save electrical energy with payback period of 0.8 y. The motor operating at a low-power factor consumes more reactive power which does not produce beneficial work. A low-power factor around 0.4 causes network power loss, increases in transformer loss and voltage drops. The solution with accumulative capacitanc... [more]

, genetic hybrids of Saccharomyces cerevisiae and the Saccharomyces eubayanus, is one of the most widely used lager yeasts in the brewing industry. In recent years, new strategies have been adopted and new lines of research have been outlined to create and expand the pool of lager brewing starters. The vineyard microbiome has received significant attention in the past few years due to many opportunities in terms of biotechnological applications in the winemaking processes. However, the characterization of S. cerevisiae strains isolated from winery environments as an approach to selecting starters for beer production has not been fully investigated, and little is currently available. Four wild cryotolerant S. cerevisiae strains isolated from vineyard environments were evaluated as potential starters for lager beer production at laboratory scale using a model beer wort (MBW). In all tests, the industrial lager brewing S. pastorianus Weihenstephan 34/70 was used as a reference strain. The... [more]

This study presents a current status and future trends of innovative and environmentally sustainable technological solutions for the post-harvest food supply chain and the food industry, in terms of ecological packaging, active, and/or intelligent packaging. All these concerns are currently highlighted due to the strong increase in the purchase/sale of products on online platforms, as well as the requirements for stricter food security and safety. Thus, this study aims to increase the global awareness of agro-industrial micro, small, and medium size enterprises for the adoption of innovative food solutions though industry digitalization (Industry 4.0), associated logistics and circular economy, with a concern for cybersecurity and products information, communication and shelf-life extension. The adoption of these guidelines will certainly foster along the complete food chain (from producer to consumer, with all intermediary parties) the awareness on environmentally sustainable technolo... [more]

Hot-melt pressure-sensitive adhesive (HMPSA) is an environmentally benign adhesive which is typically processed without solvent in industries. However, casting solution method is commonly used for experimental purposes in the lab for convenience. Therefore, seven types of solvent with different polarities, including toluene as the most commonly used solvent, were investigated in this work to study the feasibilities. Quick bond strength and holding power were tested with different types of solvents and different adhesive weight percent in the prepared solutions. Through viscosity measurement, thermal analysis, and compositional analysis, the correlation between the chosen solvents and adhesive performance was further explored. It was found that the differences in the obtained bond strength of HMPSA treated with a variety of solvents were due to physical reasons instead of chemical reactions, and a solvent with similar polarity to toluene (e.g., tetrachloride, octane) should be considere... [more]

Polycyclic aromatic hydrocarbons (PAHs) are reportedly toxic, ubiquitous and organic compounds that can persist in the environment and are released largely due to the incomplete combustion of fossil fuel. There is a range of microorganisms that are capable of degrading low molecular weight PAHs, such as naphthalene; however, fewer were reported to degrade higher molecular weight PAHs. Bacillus spp. has shown to be effective in neutralizing polluted streams containing hydrocarbons. Following the growing regulatory requirement to meet the PAH specification upon disposal of contaminated soil, the following study aimed to identify potential Bacillus strains that could effectively remediate low and high molecular weight PAHs from the soil. Six potential hydrocarbon-degrading strains were formulated into two prototypes and tested for the ability to remove PAHs from industry-contaminated soil. Following the dosing of each respective soil system with prototypes 1 and 2, the samples were analyz... [more]

The pollutants emission during the process of municipal solid waste management (MSWM) is of great concern due to its hazardous effect on the environment and living organisms. An assessment of the air quality of MSWM sites was made after having 16 repetitive visits at solid waste disposal sites and transfer stations of Lahore during wet and dry seasons. Pollution parameters such as fine particulate matter (PM2.5) and greenhouse gases (GHG) were measured along with meteorological parameters. PM2.5 measurement was made by using particle counter Dylos and TSI’s Dust Trak. Both of these instruments were positioned simultaneously at the source site and downwind (50 m). CH4 and meteorological parameters were measured by Aeroqual 500 series, while the Extech CO220 monitor was used to measure CO2 concentration. An assessment of air quality showed the levels of their mean values as CH4 and CO2 ranged between 1.5−13.7 ppm and 443.4−515.7 ppm, respectively. The PM2.5 ranged between 127.1 and 307.1... [more]

The paper discusses issues related to the sectors of biofuels for transport. Development directions of those sectors and factors limiting the growth rate thereof are analysed. At present, researchers’ attention is increasingly focused on development of the alternative fuels sector. Moreover, issues related to waste used in the sector of alternative fuels are now among the leading undertakings of environmental engineering. The authors have analysed the potential of biofuels sectors in Poland taking into account the EU’s legislative requirements. The paper contains a discussion of the sector of esters, liquid biofuels, sector of lignocellulose, sector of liquid bio-hydrocarbons and, additionally, pays attention to the sector of electromobility as one of the most attractive and prospective sectors in terms of emission reduction.

This work presents an advanced reactor selection strategy that combines elements of a knowledge-based expert system to reduce the number of feasible reactor configurations with elaborated and automatised process simulations to identify reactor performance parameters. Special focus was given to identify optimal catalyst loadings and favourable conditions for each configuration to enable a fair comparison. The workflow was exemplarily illustrated for the Ru/C-catalysed hydrogenation of arabinose and galactose to the corresponding sugar alcohols. The simulations were performed by using pseudo-2D reactor models implemented in Aspen Custom Modeler® and automatised by using the MS-Excel interface and VBA. The minichannel packings, namely wall-coated minichannel reactor (MCWR), minichannel reactor packed with catalytic particles (MCPR), and minichannel reactor packed with a catalytic open-celled foam (MCFR), outperform the conventional and miniaturised trickle-bed reactors (TBR and MTBR) in t... [more]

With the growing interests in non-aqueous media for diversified applications, ionic liquids (ILs) are frequently considered as green solvents. While the environmental, health, and safety assessments of the commercially developed ILs and their ‘greenness’ status are in debate, research focus is shifting towards the application of halide-free ILs for diversified applications. To clarify the situation on their greenness, and to understand if they really possess safe characteristics, we performed an initial assessment of 193 halide free ionic liquids composed of four groups of cations (imidazolium, pyridinium, pyrrodilinium, piperidinum) and 5 groups of anions (acetate, propionate, butyrate, alkanesulfonates, alkylsulfates). The ‘Technique for Order of Preference by Similarity to Ideal Solutions’ (TOPSIS), a multi-criteria decision analysis (MCDA) tool that allows ranking many alternatives is applied by carrying out the assessment against 14 criteria that includes hazard statements, precau... [more]

The link between different plastic waste pollutants and their impact on the natural aquatic environment and food chain remains a constant and growing issue. Bisphenol A (BPA), a known endocrine disruptor produced in large quantities primarily in the industry of polycarbonate plastics, can accumulate in vegetal and animal tissue, thus magnifying through trophic levels. In this study we exposed viable specimens of the aquatic plant Lemna minor under controlled conditions to 50, 100 and 200 ppm BPA levels in order to partially observe the toxic effects of BPA. Colonies ceased to form during the exposure and chlorosis was present especially in the 100 ppm group. Interestingly enough, a high density formation of non-fermenting bacteria as well as coliforms was also observed in the BPA exposed cultures but not in the control groups. The levels of Malondialdehyde (MDA) in the vegetal tissue indicated cellular insults and severe damage, results that were correlated with the HPLC BPA determined... [more]

Phosphorus, as one of the main pollutants in municipal sewage, has received increasing attention recently. Phosphorus recovery also increases the sustainable development of municipal wastewater. Since algae have the ability to effectively redirect nutrients, including phosphorus, from municipal sewage to algae biomass, municipal sewage treatments involving microalgae have piqued the interest of many researchers. The phosphorus removal depends on the potential of the microalgae to absorb, preserve, or degrade phosphorus in municipal wastewater. It is, therefore, of great interest to study the mechanisms underlying the absorption, storage, and degradation of phosphorus by microalgae to ensure the viability of this phosphorus removal process in wastewater. The objectives of this review were to summarize phosphorus metabolism in microalgae, examine key external and internal factors impacting phosphorous removal by microalgae from wastewater, and examine the status of phosphorous-metabolism... [more]

Electrochemical advanced oxidation processes (EAOP®) are promising technologies for the decentralized treatment of water and will be important elements in achieving a circular economy. To overcome the drawback of the high operational expenses of EAOP® systems, two novel reactors based on a next-generation boron-doped diamond (BDD) anode and a stainless steel cathode or a hydrogen-peroxide-generating gas diffusion electrode (GDE) are presented. This reactor design ensures the long-term stability of BDD anodes. The application potential of the novel reactors is evaluated with artificial wastewater containing phenol (COD of 2000 mg L−1); the reactors are compared to each other and to ozone and peroxone systems. The investigations show that the BDD anode can be optimized for a service life of up to 18 years, reducing the costs for EAOP® significantly. The process comparison shows a degradation efficiency for the BDD−GDE system of up to 135% in comparison to the BDD−stainless steel electrod... [more]

Applications of dual-evaporator refrigeration systems have recently gained much attention both in academia and industry due to their multiple benefits. In this study, a comprehensive thermodynamic and economic analysis is conducted to evaluate the potential of using several environmentally friendly refrigerant couples and identifies the most suitable one yielding the best economic results. To achieve this goal, a detailed parametric study is conducted, and an optimization process is performed using a particle swarm optimization (PSO) approach to minimize the unit production cost of cooling (UPCC) of the cascade refrigeration system. The results showed that among all selected 18 refrigerant pairs and for all ranges of examined operating parameters, the R170-R161 pair and R1150-R1234yf pair are identified as the best and worst pairs, respectively, from both thermodynamic and economic viewpoints. The results also confirm that R170-R161 pair has an improvement over R717-R744, used as a typ... [more]

Sulfate-reducing bacteria (SRB) are a heterogeneous group of anaerobic microorganisms that play an important role in producing hydrogen sulfide not only in the natural environment, but also in the gastrointestinal tract and oral cavity of animals and humans. The present review was written with the inclusion of 110 references including the time period from 1951 to 2021. The following databases were evaluated: Web of Science, Scopus and Google Scholar. The articles chosen to be included in the review were written mainly in the English and Czech languages. The molecular mechanisms of microbial cryoprotection differ depending on the environment where microorganisms were initially isolated. It was observed that the viability of microorganisms after cryopreservation is dependent on a number of factors, primarily colony age, amount of inoculum, cell size or rate of cooling, and their molecular inventory. Therefore, this paper is devoted to assessing the performance and suitability of various... [more]

Biofuels have many environmental and practical benefits as a transportation fuel. They are among the best alternatives to fossil fuels- thanks to their capacity for negative carbon emissions, which is vital for archiving the global ambition of a net-zero economy. However, conventional biofuel production takes place on inland sites and relies on freshwater and edible crops (or land suitable for edible crop production), which has led to the food versus fuel debate. It also suffers technical and economical barriers owing to the energy balance and the cost of production compared with fossil fuels. Establishing a coastal integrated marine biorefinery (CIMB) system for the simultaneous production of biofuels, high-value chemicals, and other co-products could be the ultimate solution. The proposed system is based on coastal sites and relies entirely on marine resources including seawater, marine biomass (seaweed), and marine microorganisms (marine yeasts and marine microalgae). The system doe... [more]

Over recent years, the food industry has striven to reduce waste, mostly because of rising awareness of the detrimental environmental impacts of food waste. While the edible oils market (mostly represented by soybean oil) is forecasted to reach 632 million tons by 2022, there is increasing interest to produce non-soybean, plant-based oils including, but not limited to, coconut, flaxseed and hemp seed. Expeller pressing and organic solvent extractions are common methods for oil extraction in the food industry. However, these two methods come with some concerns, such as lower yields for expeller pressing and environmental concerns for organic solvents. Meanwhile, supercritical CO2 and enzyme-assisted extractions are recognized as green alternatives, but their practicality and economic feasibility are questioned. Finding the right balance between oil extraction and phytochemical yields and environmental and economic impacts is challenging. This review explores the advantages and disadvant... [more]

The aim of the work was to purify model textile wastewater (MTW) using a two-stage membrane filtration process comprising nanofiltration (NF) and reverse osmosis (RO). For this purpose, a nanofiltration membrane TFC-SR3 (KOCH) and reverse osmosis membrane AG (GE Osmonics) were used. Each model wastewater contained a selected surfactant. The greatest decrease in flux in the initial phase of the process occurred for the detergents based on fatty-acid condensation products. An evident decrease in performance was observed with polysiloxane-based surfactants. No fouling effect and high flux values were observed for the wastewater containing a nonionic surfactant based on fatty alcohol ethoxylates. During RO, a significantly higher flux and lower resistance were observed for the feed that originally contained the anionic agent. For the MTW containing the nonionic surfactant, the conductivity reduction ranged from 84% to 92% depending on the concentrate ratio at the consecutive stages of RO.... [more]

The chitosan−EDTA modified magnetic biochar (E−CMBC) was successfully used as a novel adsorbent to remove heavy metals. The adsorption behaviour and mechanisms of E−CMBC to Cd2+, Cu2+ and Ni2+ were performed in single and binary system in aqueous solutions. In single−metal system, the adsorption process of Cd2+, Cu2+ and Ni2+ on E−CMBC fitted well with the Avrami fractional−order kinetics model and the Langmuir isotherm model. The measured maximum adsorption capacities were 61.08 mg g−1, 48.36 mg g−1 and 41.17 mg g−1 for Cd2+, Cu2+ and Ni2+, respectively. In binary−metal system, coexisting ions have obvious competitive adsorption behaviour on E−CMBC when the concentration of heavy meal beyond 20 mg L−1. The maximum adsorption capacities of the heavy metals were found to be lower than that in single−metal system. The order of the competitive adsorption ability was Cu2+ > Ni2+ > Cd2+. Interestingly, in Cd2+−Cu2+ system the earlier adsorbed Cd2+ could be completely replaced by Cu2+ from t... [more]

The adsorption of sodium dihydrogen phosphate (NaH2PO4) onto X- and Y-type faujasite zeolites was computationally studied using the Density Functional Theory (DFT) method. The structures were modeled using the Materials Studio software. The Si/Al ratios for the X- and Y-type zeolite models were 1.2 and 2.5, respectively. The central pore of the zeolite provided a more favorable coordination for adsorbing NaH2PO4. Full molecular optimization and adsorption energy calculations were performed using the VASP code. The adsorption was more effective on zeolite Y, with an adsorption energy of 161 kJ/mol, compared to the zeolite X system, with an adsorption energy of 31.64 kJ/mol. This calculated value for X-type faujasite was found in the interval of the adsorption energy of H2PO4− on hydrated Fe oxide (94.4 kJ/mol) and modified polyether sulfone (22.5 kJ/mol), and the calculated adsorption energy of the molecule on Y-type faujasite coincides with the reported value for this adsorbate on Mg/C... [more]