Modern observations and geological records suggest that anthropogenic ocean warming could destabilise marine methane hydrate, resulting in methane release from the seafloor to the ocean-atmosphere, and potentially triggering a positive feedback on global temperature. On the decadal to millennial timescales over which hydrate-sourced methane release is hypothesized to occur, several processes consuming methane below and above the seafloor have the potential to slow, reduce or even prevent such release. Yet, the modulating effect of these processes on seafloor methane emissions remains poorly quantified, and the full impact of benthic methane consumption on ocean carbon chemistry is still to be explored. In this review, we document the dynamic interplay between hydrate thermodynamics, benthic transport and biogeochemical reaction processes, that ultimately determines the impact of hydrate destabilisation on seafloor methane emissions and the ocean carbon cycle. Then, we provide an overvi... [more]

Consolidation with European social, economic and environmental programmes in the framework of Ukraine’s integration into the European energy space has become extremely important given the growing threats to energy security and should become the basis for greening regional and national innovation systems in the context of decarbonisation, the minimisation of carbon emissions and the transition to alternative energy sources. The comparison of the regions of the country by the level of enterprise innovation and the extrapolation of these results to the share of such enterprises in the total number of industrial entities in the regions helped identify their lack of correlation and emphasised the lack of stable dependence between industrial development and innovation activity. The methodology of the article includes a number of general scientific, special and interdisciplinary methods that allowed the screening of areas for the most favourable economic development, taking into account the s... [more]

Passive infrared optical gas imaging (IOGI) is sensitive to toxic or greenhouse gases of interest, offers non-invasive remote sensing, and provides the capability for spatially resolved measurements. It has been broadly applied to emission detection, localization, and visualization; however, emission quantification is a long-standing challenge for passive IOGI. In order to facilitate the development of quantitative IOGI, in this review, we summarize theoretical findings suggesting that a single pixel value does not provide sufficient information for quantification and then we proceed to collect, organize, and summarize effective and potential methods that can support IOGI to quantify column density, concentration, and emission rate. Along the way, we highlight the potential of the strong coupling of artificial intelligence (AI) with quantitative IOGI in all aspects, which substantially enhances the feasibility, performance, and agility of quantitative IOGI, and alleviates its heavy rel... [more]

In order to study the strong electromagnetic pulse effect of critically vulnerable equipment in power systems and evaluate the survivability under high-altitude electromagnetic pulses, it is necessary to study the characteristics of the transient response of metal oxide arresters to the high-altitude electromagnetic pulse by experiment. In this paper, an experimental platform for high-altitude electromagnetic pulse conduction current injection for a typical 10 kV metal oxide arrester was set up, and the key parameters such as peak value of overshoot voltage, peak value of residual voltage, action voltage and response time were obtained by the experiment. The results show that: the action voltage of this type of metal oxide arrester is 3.53 times higher than that of its rated voltage; the peak value of overshoot voltage is 2.19 times that of the peak value of residual voltage under lightning impulse current; the peak value of residual voltage is 1.57 times that under lightning impulse;... [more]

In this paper, an attempt is undertaken to identify the acoustic signature of railway vehicles travelling at 200 km/h. In the framework of conducted experimental research, test fields were determined, measurement apparatus was selected and a methodology for making measurements was specified, including the assessment of noise emission on curved and straight track for electric multiple units of Alstom type ETR610-series ED250, the so-called Pendolino. The measurements were made with the use of an acoustic camera and a 4 × 2 microphone array, including four equipped measurement points and two microphones located at the level of the head of the rail and at a height of 4 m above this level. As a result of the conducted experimental research, the dominant noise sources were identified and amplitude−frequency characteristics for these sources were determined by dividing the spectrum into one-third octave bands in the range from 20 Hz to 20 kHz. The paper also considers issues related to the v... [more]

A vessel of a laboratory setup for hosting molten alkali carbonate immersion experiments was recently decommissioned after about 4000 h discontinuous operation at 800 °C. In this article, we want to describe the long-term damage of the vessel caused by evaporated alkali carbonate species in a carbon dioxide gas environment. The vessel is made of alloy 253MA and coated by an aluminum powder pack diffusion process. The degree of material loss and internal degradation did not correlate with the temperature profile across the vessel but rather with the vicinity to the gas and salt evaporation source. One millimeter of the vessel’s initial 5 mm wall thickness was completely consumed at the strongest attacked location plus another 800 µm of internal attack beneath the metal−oxide interface.

The Jizhong depression contains several geothermal reservoirs that are characterized by localized low-velocity anomalies. In this article, full-waveform inversion (FWI) is used to characterize these anomalies and determine their extent. This is a challenging problem because the reservoirs are quite small and the available data have usable frequencies only down to 5 Hz. An accurate-enough starting model is carefully built by using an iterative travel time tomography method combined with a cycle-skipping assessment method to begin the inversion at 5 Hz. A multiscale Laplace−Fourier-domain FWI with a layer-stripping approach is implemented on the starting model by gradually increasing the maximum offset. The result of overlapping the recovered velocity model on the migrated seismic profile shows a good correlation between the two results. The recovered model is assessed by ray tracing, synthetic seismogram modeling, checkerboard testing and comparisons with nearby borehole data. These tes... [more]

The Huainan Coalfield is a typical multi-coal seam coalfield. In order to systematically investigate the distribution, occurrence, and integration of arsenic (As) in Shanxi coal, 26 coal samples and three rock samples were collected in the No. 1 coal seam of Huainan coalfield. The minerals, major element oxides, and As were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), polarized light microscopy, X-ray fluorescence spectroscopy (XRF) and inductively coupled plasma-mass spectrometry (ICP-MS). The results indicated that the coals of Shanxi Formation were characterized by very low ash yields and low total sulfur contents. The identified minerals by XRD in the studied coals are dominated by kaolinite, quartz, calcite, and a lesser amount of pyrite. The As content ranges from 10.33 mg/kg to 95.03 mg/kg, with an average of 44.74 mg/kg. Compared with world coals, the studied coals have higher contents of As, which are characterized by enrichment. Based on statistica... [more]

The emission of carbon dioxide and other greenhouse gases through electricity consumption by firms is one of the significant drivers of climate change. The performance of a firm’s environmental programme is to a large extent dependent on employee behaviour. Drawing on the Theory of Planned Behaviour (TPB), the study tested a theoretical model that incorporates benefits and leadership as antecedents of attitude towards electricity saving by the employees of small firms in the hospitality sector. The effects of five benefits (intrinsic, extrinsic, organisational, social, and environmental) and two leadership factors (leadership behaviour and leadership support) were examined. Investigating the antecedents of TPB constructs can help in understanding the process through which the constructs are associated with intention. In addition, the moderating effect of green psychological climate in the relationship between intention and electricity saving behaviour was examined. The study used the q... [more]

The Vestnesa Ridge, located off the west Svalbard margin, is a >60 km long ridge consisting of fine-grained sediments that host a deep-marine gas hydrate and associated seepage system. Geological and geophysical observations indicate the predominance of vertical fluid expulsion through fractures with pockmarks expressed on the seafloor along the entire ridge. However, despite the apparent evidence for an extended free gas zone (FGZ) below the base of the gas hydrate stability zone (BGHSZ), present-day seafloor seepage has been confirmed only on the eastern half of the sedimentary ridge. In this study, we combine the relationships between aqueous phase pressure, capillary pressure, sediment clay fraction, porosity, and total stress to simulate how much gas is required to open preexisting fractures from the BGHSZ towards the seafloor. Data from four specific sites with different lithology and pressure regime along the ridge are used to constrain the simulations. Results demonstrate that... [more]

The analysis of the implementation effect of the supply-side reform (SSR) in the industrial sector of China’s provinces and the reasons behind them are of great significance for China to formulate relevant policies in the future. However, this work has not yet been carried out. Industrial development performance is closely related to energy and environmental efficiency (EEE), and the effect of the SSR implementation is directly reflected in EEE. This study fills this gap by analyzing the EEE of 30 provinces in China from 2012 to 2017 using data envelopment analysis and Malmquist index methods. The results show that the positive effect of China’s implementation of SSR has emerged. This positive effect is mainly reflected in the implementation of measures such as reducing overcapacity, which has promoted the technological innovation of enterprises. However, the low management level and resource-allocation efficiency hinder the further improvement of the implementation effect of the SSR,... [more]

In order to achieve the European Union’s climate and energy goals, investments are required, mainly in the areas of energy efficiency, renewable energy sources and infrastructure. Buildings are responsible for almost half of total energy consumption, and nearly 80% of them are energy and ecologically inefficient. The policy of European countries is increasingly more focused on facilities with the highest potential in the areas of energy and matter saving and the possibly circular economy. The aim of the work was to assess the environmental loads occurring in the life cycle of an existing retail and service building. The analysis was performed using the Life Cycle Assessment (LCA) method. By using the IMPACT 2002+ model, it has become possible to assess the impact of the life cycle of the studied facility on human health, environmental quality, climate change and raw material resources. The highest level of negative consequences in the above-mentioned areas was recorded for the life cyc... [more]

Because generating electricity significantly contributes to global greenhouse gas emissions, meeting the 2015 Paris Agreement and 2021 Glasgow Climate Pact requires rapidly transitioning to zero or low-emissions electricity grids. Though the installation of renewables-based generators—predominantly wind and solar-based systems—is accelerating worldwide, electrical energy storage systems, such as pumped storage hydropower, are needed to balance their weather-dependent output. The authors of this paper are the first to examine the status and potential for pumped storage hydropower development in 24 Pacific Rim economies (the 21 member economies of the Asia Pacific Economic Cooperation plus Cambodia, Lao PDR, and Myanmar). We show that there is 195 times the pumped storage hydropower potential in the 24 target economies as would be required to support 100% renewables-based electricity grids. Further to the electrical energy storage potential, we show that pumped storage hydropower is a lo... [more]

Considering increasingly ambitious pledges by countries and various forms of pressure from current international constellations, society, investors, and clients further up the supply chain, the question for companies is not so much whether to take decarbonisation action, but what action and by when. However, determining an ideal mix of measures to apply ‘decarbonisation efficiency’ requires more than knowledge of technically feasible measures and how to combine them to achieve the most economic outcome: In this paper, working in a ‘backcasting’ manner, the author describes seven aspects which heavily influence the composition of an ‘ideal mix’ that executive leadership needs to take a (strategic) position on. Contrary to previous studies, these aspects consider underlying motivations and span across (socio-)economic, technical, regulatory, strategic, corporate culture, and environmental factors and further underline the necessity of clarity of definitions. How these decisions influence... [more]

Building system operation faces the challenge of reducing energy use and implementing a demand response, which can be defined as a temporary modification in energy loads affecting dynamic energy price and reliability information. The heating, ventilation, and air-conditioning (HVAC) system in buildings provides an opportunity for implementing demand response strategies due to the thermal inertia in building zones. However, an HVAC-based demand response is not a prevalent strategy in actual facility management due to the lack of understanding among building operators of their facilities and occupants. Herein, we focus on developing a better understanding of the occupant side by obtaining a reliable prediction of occupants’ thermal satisfaction. We evaluate the prediction performance of a probabilistic model provided in our previous paper using a case study with a subset of the ASHRAE Global Thermal Comfort Database II. The influence of a better prediction of thermal satisfaction on the... [more]

Total-factor energy efficiency (TFEE) is widely used to measure energy efficiency under the data envelopment analysis (DEA) framework, but the efficiencies obtained from DEA are structurally biased upward, and thus TFEE tends to overestimate energy efficiency. This research thus applies the bootstrapped DEA approach to correct the bias of TFEE. Using a dataset consisting of 30 provinces of China in the period 2016−2019, the bootstrapped-based test supports technology with variable returns to scale. The biased-corrected TFEE also indicates that energy consumption on average can be scaled down by 42.36%, rather than the biased value of 19.4%. The bootstrapped clustering partitions provinces into three groups: Cluster 1, with Guizhou as the representative medoid, includes half of the superior coastal provinces in terms of actual energy consumption and TFEE and half of the competitive inland provinces, whereas Cluster 3 outperforms Cluster 2 in terms of TFEE, but the actual energy consumpt... [more]

Circular economy (CE) strategy is crucial in developing towards sustainable growth. It was created to promote resource utilization and the elimination of waste production. This article aimed to study the possibilities of using the CE framework in wastewater bioremediation and energy recovery using hydroponic tanks. The integration of phytoremediation with bioenergy, construction and lifespan of hydroponic tanks in phytoremediation of wastewater, selection of aquatic plants and the expected challenges in the implementation of CE in phytoremediation of wastewater were discussed. The plant-based biomass harvested and the relative growth rate (RGR) of the selected plants from the phytoremediation process was evaluated. The findings obtained indicated that the selected plants tripled in weight after 14 days cultivation period at different retention times. E. crassipes recorded the highest growth with 2.5 ± 0.03 g g−1 d−1, followed by S. molesta with 1.33 ± 0.05 g g−1 d−1 and then P. stratio... [more]

Recently, due to the corrosion problem in the petroleum industry and the usage of commercial corrosion inhibitors, which, when released untreated into the environment, are considered to be environmentally unfriendly, green corrosion inhibitors are being researched. In this paper, the results of dandelion-root-extract testing as a green corrosion inhibitor for carbon steel in simulated brine solution saturated with carbon dioxide (CO2) are shown. The extract’s inhibition efficiency in static and flow conditions was determined by using potentiodynamic polarization with Tafel extrapolation and electrochemical-impedance-spectroscopy methods. In static conditions, the extract was tested at different concentrations. A maximum inhibition efficiency of 98.37% in static conditions at an extract concentration of 12 mL/L and 82.80% in flow conditions at a concentration of 14 mL/L was achieved. Additionally, for the most efficient dandelion-root-extract concentration (12 mL/L), the biodegradabilit... [more]

Typically, reinforced concrete and brick masonry construction is the most common construction system of the majority of the southern European residential building stock. However, the lightweight steel framing (LSF) construction system has been progressively assuming a relevant position in the residential sector. Since LSF is not the traditional construction system, the indoor thermal environment of these buildings has not been widely studied and discussed considering the southern European climate context. The low thermal inertia of this construction system is commonly pointed to as a possible weakness in warmer climates. The present work aims to address this research gap by evaluating and comparing the LSF and masonry construction systems in terms of the indoor thermal environment focusing on the level of thermal inertia. The considered methodology lies in a long-term experimental campaign based on the construction and monitoring of two identical experimental test cells, differing only... [more]

Worldwide, around 998 million tons of agricultural waste are generated yearly, including livestock wastes, which create several critical environmental issues if not properly treated. In this study, a Geographical Information System (GIS)-based model to locate and quantify both the yearly amount of livestock waste, i.e., sheep wool, and the territorial distribution of sheep farms, was carried out and applied within the selected study area. The aim was to identify those territorial areas most suitable for localizing new shared wool collection centers to sustainably manage the reuse of this waste as potential green building material. Data related to both sheep farms and sheep number and the related sheep shared wool (SSW) yearly production were acquired and applied in GIS. By GIS-based model results, two collection centers have been identified within the provinces of Agrigento and Enna. Then, to develop a sustainable reuse in terms of reducing environmental impact due to the SSW logistics... [more]

The aim of the paper is to analyze how regulatory design and its framework’s topics, other than macroeconomic factors, might impact green innovation by taking into consideration a brand-new renewable source of energy that is becoming more and more important in recent years: hydrogen and fuel cell patenting activities. Such activities have been used as a proxy for green technological change in a panel data of 52 countries over a 6-year period. A series of sectorial, energy regulation, and macroeconomic variables were tested to assess their impact on that technological frontier of green energy transition policy. As might have been expected, the empirical analysis carried out with the model that was prefigured confirms significant evidence of lock-in effects on fossil fuel policies. The model confirms, however, another evidence: countries already investing in renewables might be willing to invest in hydrogen projects. A sort of reinforcement to the further development of green sustainable... [more]

Green intellectual capital (GIC) is a distinctive intangible asset that may assist organizations in pursuing sustainable development strategies. In Polish organizations, interest in this new concept is low. Analysis of the literature showed a lack of research regarding the implementation of GIC practices or their impacts on the sustainable development of organizations in Polish enterprises. In order to fill the detected research gap, the study covered 150 randomly selected Polish enterprises. The purpose of the research was to determine the impact of activities fostering GIC on the environmental development of companies in Poland and to identify major practices supporting GIC development. In addition, the author attempted to establish a correlation between the impact of individual practices oriented at GIC formation and their practical implementations in the analyzed enterprises. The first stage of the analysis focused on identification of activities leading to the accumulation of GIC... [more]

In today’s social, economic, and political reality, it cannot be overlooked that the energy self-sufficiency of municipalities not only optimizes the lives of the inhabitants of the municipality but also, in a broader perspective, the services provided by the municipality. The sustainable development of a municipality will therefore depend on its degree of self-reliance and self-sufficiency. Economic and technological considerations are not sufficient for the municipality to achieve optimal energy independence without normative conditions. The current (2021/2022) trends in electricity prices and in the development of national and international policies and strategies for electricity generation from renewable energy sources also make the change in the energy market structure toward distributed generation. The main objective of this paper is a theoretical analysis of the legal solutions in force in Poland that allow building energy self-sufficiency in municipalities and their adequacy to... [more]

Green transformation at the beginning of the 21st century occupies the top positions in modern society’s sustainability transition research and policy debates due to its multiple propositions of various innovations, addressing the still unsolved issues of rapidly on-going societal and technological changes. Rooting from the general climate change concerns, recently, sustainability transformation has become a special focus in the EU, which is facing new and very concrete demands—to elucidate the evidence-based pathways towards the green transformation with European Green Deal and European Climate Law targets ahead. The main aim of this research is to disclose the pathway towards the green transformation in Lithuania in one of the fast-growing research fields of circular bioeconomy—biogas production from manure and waste. To reach this aim, a hybrid methodology approach was used. Analysis and synthesis of scientific literature, document analysis and structuring, stakeholder mapping, inte... [more]

This article approaches the optimal solution of energy sustainability based on the use of artificial intelligence (AI). The application of renewable energy sources (RES) and unit commitment (UC) is the basic idea of this concept. Therefore, a new approach to solving the UC problem is introduced. The proposed method has a simple procedure to obtain the popular solutions in an acceptable time interval, by creating a basic model of the schedule of the state of energy units RES. It is obvious that individual consumer units, of an operational nature, take hourly performance values by performing economic evaluations on them in the sense of cost optimization. This is conducted through an artificial intelligence (AI) algorithm by optimizing the dedicated cost function, simulated by annealing. Despite the acceptable solution obtained from these two steps, another shift is proposed, called the TDD process in a given consumer area. This process in the application of AI in the system of selection... [more]