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Showing records 9251 to 9275 of 9568. [First] Page: 367 368 369 370 371 372 373 374 375 Last
Efficiency Improvement of Photovoltaic Panels: A Novel Integration Approach with Cooling Tower
Emad Abdelsalam, Hamza Alnawafah, Fares Almomani, Aya Mousa, Mohammad Jamjoum, Malek Alkasrawi
February 22, 2023 (v1)
Keywords: co-cooling, cooling tower, downdraft system, efficiency, photovoltaic, PV cooling
Overheating of photovoltaic (PV) panels decreases their efficiency and lifetime, and subsequently increases the levelized cost of energy (LCOE). Passive PV cooling would enhance the PV operational stability and durability. The cooling tower (CT) technology offers an attractive approach for zero-cost capability. In this work, we developed and customized a CT specific for passive PV cooling. Since the dense downdrafted cooled air gained high velocity, a turbine was installed at the bottom of the CT for power production. At the height’s ambient temperature, the CT cooled the air from 50 °C down to 30 °C. The cooled air at 30 °C has enough capacity to cool the PV panels. This cooling capacity improved the average annual efficiency of the PV panels by 6.83%. The design specifications of the CT have the highest performance, with the maximum radius of PV area of panels that can be cooled at 50 m. Furthermore, the current design could operate during the night for power production with minimum... [more]
Testing and Modeling of Vehicle Li-Ion Battery Module with Prismatic Cells under Abuse Conditions
Krishna Prasath Logakannan, Feng Zhu, David Sypeck, Sida Xu, Jie Deng, Sangyeon Kim
February 22, 2023 (v1)
Keywords: FE model, Li-ion batteries, module, penetration, safety
The damage behavior of Li-ion vehicle battery modules with prismatic cells has been investigated through mechanical experiments and numerical simulations. The modules were subjected to quasi-static indentation using a V-shaped stainless-steel wedge along three orthogonal directions. One higher speed test was also performed. Force and voltage were measured as a function of displacement to monitor damage during loading. A detailed finite element (FE) model was developed to simulate force-displacement with very good comparison to experimental results. Based on the FE model, energy absorption contributions of four major component groups were analyzed along with detailed effects of enclosure weld defects. Analysis indicates the steel parts absorbed significant amounts of energy irrespective of indentation direction. The welds connecting the side plates were the weak link in the protective structure. Increasing the thickness of the steel plates could help absorb more energy.
Forecasting the Monash Microgrid for the IEEE-CIS Technical Challenge
Richard Bean
February 22, 2023 (v1)
Keywords: random forests, Renewable and Sustainable Energy, solar forecasting, time-series forecasting
Effective operation of a microgrid depends critically on accurate forecasting of its components. Recently, internet forecasting competitions have been used to determine the best methods for energy forecasting, with some competitions having a special focus on microgrids and COVID-19 energy-use forecasting. This paper describes forecasting for the IEEE Computational Intelligence Society 3rd Technical Challenge, which required predicting solar and building loads of a microgrid system at Monash University for the month of November 2020. The forecast achieved the lowest error rate in the competition. We review the literature on recent energy forecasting competitions and metrics and explain how the solution drew from top-ranked solutions in previous energy forecasting competitions such as the Global Energy Forecasting Competition series. The techniques can be reapplied in other forecasting endeavours, while approaches to some of the time-series forecasting are more ad hoc and specific to the... [more]
A Post-Mortem Study Case of a Dynamically Aged Commercial NMC Cell
Md Sazzad Hosen, Poonam Yadav, Joeri Van Mierlo, Maitane Berecibar
February 22, 2023 (v1)
Keywords: aging mechanism, battery aging, EDS analysis, post-mortem, real-life cycling, SEM analysis
Lithium-ion batteries are currently the pioneers of green transition in the transportation sector. The nickel-manganese-cobalt (NMC) technology, in particular, has the largest market share in electric vehicles (EVs), offering high specific energy, optimized power performance, and lifetime. The aging of different lithium-ion battery technologies has been a major research topic in the last decade, either to study the degradation behavior, identify the associated aging mechanisms, or to develop health prediction models. However, the lab-scale standard test protocols are mostly utilized for aging characterization, which was deemed not useful since batteries are supposed to age dynamically in real life, leading to aging heterogeneity. In this research, a commercial NMC variation (4-4-2) was aged with a pragmatic standard-drive profile to study aging behavior. The characterized measurable parameters were statistically investigated before performing an autopsy on the aged battery. Harvested s... [more]
CO2 Emissions from Renewable and Non-Renewable Electricity Generation Sources in the G7 Countries: Static and Dynamic Panel Assessment
Liton Chandra Voumik, Md. Azharul Islam, Samrat Ray, Nora Yusma Mohamed Yusop, Abdul Rahim Ridzuan
February 22, 2023 (v1)
Keywords: climate change, CO2 emissions, electricity production sources, energy consumption, G7
The threat of global warming has increased due to industrialization, urbanization, population expansion, and changes in lifestyle among the Group of Seven(G7) Carbon dioxide emissions (CO2) directly affect how much electricity can be generated from various sources. This research aims to identify environmental hazards associated with various energy sources. Analyzing the impact of various energy sources on CO2 emissions from electricity and heat production using data from the G7. The data is analyzed using quantile regression (QR), generalized method of moments (GMM), random effects (RE), and fixed effects (FE). Our results indicate a substantial positive impact on CO2 emissions regardless of the technology used to generate coal and gas power. Coal-fired power plants have a larger impact on the environment than other sources of emissions. Also, all coal and gas coefficients are significant in FE, RE, GMM, and QR. Oil coefficients have a negative impact on environmental degradation and a... [more]
Fractional-Order PID Controller (FOPID)-Based Iterative Learning Control for a Nonlinear Boiler System
Ahmed Zubair Jan, Krzysztof Kedzia, Muhammad Jamshed Abbass
February 22, 2023 (v1)
Keywords: boiler turbine unit, coordinated control, iterative learning control, optimization of energy efficiency, throttle pressure control
For the boiler-turbine unit in power systems, a coordinated control structure plays a crucial role in maintaining the balance in supply and demand of energy, reducing pollutant emissions and optimizing energy efficiency. The matching requirements of the turbine and boiler, the wide range of load changes, and the cooperative operation of many devices in the power system pose many challenges to designing a coordinated control system for the boiler turbine system, thus making the control design a difficult task. In this paper, iterative learning control (ILC) is used to maintain the throttle pressure and megawatt output power of a boiler turbine at the desired set points by controlling the hybrid pattern design structure. Simulation results show that the proposed approach can maintain the desired set points, and the desired response can also be obtained faster by using the proposed approach compared to the ones available in the literature.
Study on the Rotation Effect on the Modal Performance of Wind Turbine Blades
Yewen Chen, Shuni Zhou, Chang Cai, Weilong Wang, Yuheng Hao, Teng Zhou, Xinbao Wang, Qingan Li
February 22, 2023 (v1)
Keywords: dynamic stiffening, modal analysis, spin softening, wind turbine blades
With the large-scale development of wind turbines, large flexible blades bear heavier loads. In the actual rotating work of blades, the coupling of structural deformation and motion produces a dynamic stiffening effect and spin softening effect, which affects the dynamic characteristics of blades. In this study, the finite element method is used to model the NREL 5MW blade, and the dynamic stiffening and spin softening effects are investigated using the modal analysis. The influence of rotating effects on the blade’s natural frequency is revealed. It is concluded that the effect of dynamic stiffening is more significant than that of spin softening, and the comprehensive result of the two effects is not simply the superposition of them but presents obvious nonlinearity.
Hybrid Propulsion Efficiency Increment through Exhaust Energy Recovery—Part 1: Radial Turbine Modelling and Design
Emiliano Pipitone, Salvatore Caltabellotta, Antonino Sferlazza, Maurizio Cirrincione
February 22, 2023 (v1)
Keywords: compound engine, exhaust energy recovery, exhaust gas turbine, hybrid vehicle
The efficiency of Hybrid Electric Vehicles (HEVs) may be substantially increased if the energy of the exhaust gases, which do not complete the expansion inside the cylinder of the internal combustion engine, is efficiently recovered by means of a properly designed turbogenerator and employed for vehicle propulsion; previous studies, carried out by the same authors of this work, showed a potential hybrid vehicle fuel efficiency increment up to 15% by employing a 20 kW turbine on a 100 HP rated power thermal unit. The innovative thermal unit here proposed is composed of a supercharged engine endowed with a properly designed turbogenerator, which comprises two fundamental elements: an exhaust gas turbine expressly designed and optimized for the application, and a suitable electric generator necessary to convert the recovered energy into electric energy, which can be stored in the on-board energy storage system of the vehicle. In these two parts, the realistic efficiency of the innovative... [more]
Numerical and Experimental Study on an Anti-Oscillation Device for the DeepCwind Floating Semi-Submersible Turbine Platform
Wei Wang, Sheming Fan, Yunxiang You, Cheng Zhao, Liqun Xu, Guibiao Wang
February 22, 2023 (v1)
Keywords: anti-oscillation device, DeepCwind floating wind turbine platform, hydrodynamic analysis, surge and heave reduction
The DeepCwind floating wind turbine platform has become one of the most successful structures for accommercial floating wind farms, and the stability of it is crucial for survivability. Hence, this paper studies an anti-oscillation device with the purpose of reducing the heave and surge effects of the platform. The influence of various chamfered perforations at different sizes of the anti-heave device on the floating platform was further studied by numerical and experimental methods. Furthermore, through an analysis of the surge and heave of the pedestal with anti-heave devices with different chamfered perforations under different wave heights and wave periods, the effects on the hydrodynamic performance of the pedestal were studied. Physical experiments were conducted on a pedestal with anti-heave devices with chamfered perforations under the working conditions of different wave heights and wave periods to verify the reliability of the numerical simulation. The results show that the a... [more]
Impact of Investments and R&D Costs in Renewable Energy Technologies on Companies’ Profitability Indicators: Assessment and Forecast
Olha Prokopenko, Tetiana Kurbatova, Marina Khalilova, Anastasiia Zerkal, Gunnar Prause, Jacek Binda, Temur Berdiyorov, Yuriy Klapkiv, Sabina Sanetra-Półgrabi, Igor Komarnitskyi
February 22, 2023 (v1)
Keywords: depreciation and amortisation, earnings before interest, earnings before interest and taxes, investments, net income, Renewable and Sustainable Energy, research and development, return on investments, taxes
Renewable energy technologies play a crucial role in solving global energy and environmental issues, and the pace of the energy transition directly depends on improving their efficiency. Presently, the development and implementation of renewable energy systems are ensured mainly through state funding, the possibilities of which are limited. The potential of attracting private investments depends directly on their impact on companies’ profitability indicators, and the uncertainty regarding the return on investments is one of the main barriers affecting investors’ decision-making. Based on a vector autoregressive model for analysing the stationary time series, the paper explores the impact of long-term investments and research and development costs in renewable energy technologies on the financial performance of ten of the largest companies operating in this field. The study’s results showed that investments and spending on research and development positively affect such companies’ profi... [more]
Exergy and Exergy-Economic Approach to Evaluate Hybrid Renewable Energy Systems in Buildings
Sonja Kallio, Monica Siroux
February 22, 2023 (v1)
Keywords: costing method, efficiency, Exergy, hybrid renewable energy systems, micro-grid
Hybrid renewable energy systems (HRES) combine two or more renewable energy systems and are an interesting solution for decentralized renewable energy generation. The exergy and exergo-economic approach have proven to be useful methods to analyze hybrid renewable energy systems. The aim of this paper is to present a review of exergy and exergy-economic approaches to evaluate hybrid renewable energy systems in buildings. In the first part of the paper, the methodology of the exergy and exergo-economic analysis is introduced as well as the main performance indicators. The influence of the reference environment is analyzed, and results show that the selection of the reference environment has a high impact on the results of the exergy analysis. In the last part of the paper, different literature studies based on exergy and exergo-economic analysis applied to the photovoltaic-thermal collectors, fuel-fired micro-cogeneration systems and hybrid renewable energy systems are reviewed. It is sh... [more]
Progress of Coupled Heat Transfer Mechanisms of Regenerative Cooling System in a Scramjet
Ni He, Chaoyang Liu, Yu Pan, Jian Liu
February 22, 2023 (v1)
Keywords: coupled heat transfer, pyrolysis, regenerative cooling, scramjet
The feasibility of regenerative cooling technology in scramjet engines has been verified, while the heat transfer behavior involved in the process needs further study. This paper expounds on the necessity of coupled heat-transfer analysis and summarizes its research progress. The results show that the effect of pyrolysis on heat transfer in the cooling channel depends on the heat flux and coking rate, and the coupling relationship between combustion and heat transfer is closely related to the fuel flow rate. Therefore, we confirm that regulating the cooling channel layout according to the real heat-flux distribution, suppressing coking, and accurately controlling the fuel flow rate can contribute to accomplishing the optimal collaborative design of cooling performance and combustion performance. Finally, a conjugate thermal analysis model can be used to evaluate the performance of various thermal protection systems.
Pyrolysis of RDF and Catalytic Decomposition of the Produced Tar in a Char Bed Secondary Reactor as an Efficient Source of Syngas
Bogusław Kusz, Dariusz Kardaś, Łukasz Heda, Bartosz Trawiński
February 22, 2023 (v1)
Keywords: catalyst, cracking, municipal solid waste, pyrolysis, residence time
One of the technical limitations of refuse-derived fuel (RDF) pyrolysis is the high content of tar in its gas products. In order to resolve this problem, a two-stage RDF pyrolysis with a catalyst based on char from RDF pyrolysis is proposed. This paper presents the results of municipal waste pyrolysis beginning in an oven heated to 480 °C and ending with catalytic tar cracking carried out in the temperature range from 800 to 1000 °C. Thermal and catalytic pyrolysis with a char catalyst containing a minimum of 6% Fe resulted in increases in the CO and H2 contents in gas products and decreases in CO2 and CH4. At 1000 °C, the mass ratio of gaseous products to liquids was greater than 6. The residence time of the gases in the catalytic zone was about 3−5 s. The reactor was a good source of hydrogen and carbon monoxide.
Detailed Analysis of Exergy Destruction of All Basic Types of Heat Exchangers
Martina Rauch, Saša Mudrinić, Antun Galović
February 22, 2023 (v1)
Keywords: dimensionless analytical solution, local and total exergy destruction, recuperators
Dimensionless expressions of exergy destruction, normalized to ambient temperature and heat capacity of the weaker stream, for all basic types of recuperators are derived. The analytical expressions for maximum exergy destruction were calculated using the GNU Octave software for all recuperators, namely parallel-flow and counter-flow recuperators, and all forms of cross-flow heat exchangers, namely without mixing of streams, only mixing the streamlines of the weaker stream, only mixing the streamlines of the stronger stream and mixing the weaker and stronger streams. For parallel-flow and counter-flow recuperators, as well as for their special cases, expressions for local and total exergy destruction are given. It is shown that the maximum exergy destruction, as a local extreme, is the same for all recuperators for mutually equal values of the quantities π3 (ratio of the heat capacity of the weaker stream to the heat capacity of the stronger stream) and πT (ratio of the inlet temperatu... [more]
Catalytic Transformation of Biomass-Derived Glucose by One-Pot Method into Levulinic Acid over Na-BEA Zeolite
Natalia Sobuś, Izabela Czekaj
February 22, 2023 (v1)
Keywords: biomass conversion, glucose, H2SO4, levulinic acid, Na-BEA, zeolites
This article presents the results of the conversion of biomass-based glucose to levulinic acid (LA) with the use of Na-BEA commercial zeolite catalyst. For this purpose, synthetic zeolite BEA was used as a matrix. The glucose conversion process with the participation of Na-BEA zeolite allowed the following acids to be obtained: levulinic acid, lactic acid, pyruvic acid and formic acid. The highest yield of levulinic acid was achieved when processed for 1−5 h at 200−250 °C with 0.1 g and 0.6 g of Na-BEA catalyst. We also compare the one-pot heterogeneous process with similar homogeneous process using H2SO4 as catalyst.
Fundamental Study on Hydrogen Low-NOx Combustion Using Exhaust Gas Self-Recirculation
Kenta Kikuchi, Tsukasa Hori, Fumiteru Akamatsu
February 22, 2023 (v1)
Keywords: burner, exhaust gas self-recirculation, Hydrogen, NOx
Hydrogen is expected to be a next-generation energy source that does not emit carbon dioxide, but when used as a fuel, the issue is the increase in the amount of NOx that is caused by the increase in flame temperature. In this study, we experimentally investigated NOx emissions rate when hydrogen was burned in a hydrocarbon gas burner, which is used in a wide temperature range. As a result of the experiments, the amount of NOx when burning hydrogen in a nozzle mixed burner was twice as high as when burning city gas. However, by increasing the flow velocity of the combustion air, the amount of NOx could be reduced. In addition, by reducing the number of combustion air nozzles rather than decreasing the diameter of the air nozzles, a larger recirculation flow could be formed into the furnace, and the amount of NOx could be reduced by up to 51%. Furthermore, the amount of exhaust gas recirculation was estimated from the reduction rate of NOx, and the validity was confirmed by the relation... [more]
Effects of Different Ethanol/Diesel Blending Ratios on Combustion and Emission Characteristics of a Medium-Speed Diesel Engine
Zhiqiang Wang, Lijun Li
February 22, 2023 (v1)
Keywords: combustion and emission characteristics, CONVERGE, diesel engine, ethanol/diesel blended fuel
In order to better evaluate the effects of ethanol/diesel blends on engine combustion and emission characteristics, we developed an engine cylinder model using the software CONVERGE combined with the program CHEMKIN. The model was validated experimentally. A modified chemical kinetic mechanism was used to calculate the combustion process of diesel fuel and ethanol for the diesel engine, including 154 reactions and 68 species. Furthermore, the influence of different ethanol proportions on diesel engine combustion and emission characteristics, including power, brake specific fuel consumption, brake thermal efficiency, cylinder pressure, cylinder temperature, nitrogen oxide (NOx), carbon monoxide (CO), and soot emissions, was also investigated. Our results showed that cylinder pressure and temperature increased with increased ethanol content. When the ethanol content increased to 20% at 100% load, the cylinder pressure increased by 0.46%, and the thermal efficiency increased by 3.63%. How... [more]
Optimization Analysis of Locomotive Diesel Engine Intake System Based on Matlab-Simulink and GT-Power
Feng Jiang, Wentong Cao, Xueyou Tan, Jie Hu, Junming Zhou, Zedan Tan
February 22, 2023 (v1)
Keywords: emission, locomotive diesel engine, optimizer model method, performance
In this paper, based on the coupling calculation of Simulink software and GT-Power software, an Optimizer model method was proposed for a 16V265H diesel engine to study the effects of different ratios of biodiesel (B0, B10, and B20) on the performance of a 16V265H diesel engine at 1000 rpm and 75% load. Firstly, the four parameters of diesel engine power, BSFC, soot emission, and NOx emission were taken as the result variables of the optimization model. Taking the intake and exhaust timing of the diesel engine as the independent variable of the optimization model, the maximum power, minimum BSFC, and minimum diesel engine emission were studied and analyzed. Finally, the performance parameters were comprehensively analyzed to determine the best intake and exhaust valve timing. Moreover, based on the model optimization, the diesel engine’s BSFC and power performance were compared, and the optimal intake timing scheme for the diesel engine with different biodiesel ratios at 75% operating... [more]
Biomass-Derived Carbon/Sulfur Composite Cathodes with Multiwalled Carbon Nanotube Coatings for Li-S Batteries
Lina Han, Zemin Li, Yang Feng, Lijiang Wang, Bowen Li, Zijie Lei, Wenyan Wang, Weiwei Huang
February 22, 2023 (v1)
Keywords: Li-S batteries, multiwalled carbon nanotube coating, ramie carbon, shuttle effect
Lithium sulfur (Li-S) batteries stand out among many new batteries for their high energy density. However, the intermediate charge−discharge product dissolves easily into the electrolyte to produce a shuttle effect, which is a key factor limiting the rapid development of Li-S batteries. Among the various materials used to solve the challenges related to pure sulfur cathodes, biomass derived carbon materials are getting wider research attention. In this work, we report on the fabrication of cathode materials for Li-S batteries based on composites of sulfur and biomass-derived porous ramie carbon (RC), which are coated with multiwalled carbon nanotubes (MWCNTs). RC can not only adsorb polysulfide in its pores, but also provide conductive channels. At the same time, the MWCNTs coating further reduces the dissolution of polysulfides into the electrolyte and weakens the shuttle effect. The sulfur loading rate of RC is 66.3 wt.%. As a result, the initial discharge capacity of the battery is... [more]
Research on the Approximate Calculation Method of the Fundamental Frequency and Its Characteristics on a Tensioned String Bridge
Guangwei Zhou, Changzhao Qian, Changping Chen
February 22, 2023 (v1)
Keywords: approximation calculation, bridge engineering, fundamental frequency, Rayleigh method, tensioned string bridge
As a new type of composite bridge, the dynamic structural characteristics of a tensioned string bridge need to be deeply studied. In this paper, based on the structural characteristics of a tensioned string bridge, the Rayleigh method is used to derive formulas for calculating the frequencies of vertical, antisymmetric and lateral bending vibrations. The characteristics of the vertical and lateral bending vibration frequencies are summarized. The fundamental frequencies of the antisymmetric vertical bending and lateral bending of the tensioned string bridge are the same as that of the single-span beam under the corresponding constraint conditions. The shape and physical characteristics of the main cable have no effect on the frequency. The vertical bending symmetrical vibration frequency of the tensioned string bridge is greater than the corresponding symmetrical vibration frequency of the simply supported beam. The shape and physical characteristics of the main cable have a greater im... [more]
Effects of Water Removal from Palm Oil Reactant by Electrolysis on the Fuel Properties of Biodiesel
Cherng-Yuan Lin, Lei Ma
February 22, 2023 (v1)
Keywords: electrode structure, molecular sieve, palm-oil biodiesel, transesterification, water removal
Biodiesel, which is composed of mono-alkyl esters of long carbon-chained fatty acids, is used as an alternative fuel to petro-diesel. The water content of the reactant mixture of feedstock oil influences the extent of transesterification and thus the fuel characteristics. Lower water content in feedstock oil is generally suggested for successful transesterification. This experimental study removed water from the reactant mixture of feedstock palm oil and methanol during transesterification using various systems composed of either electrodes or molecular sieves with rotary vibration. The effect of input electrical energy, number of electrodes, vibration modes, and operating time on the amount of water removed from the reactant mixture and the fuel properties of the final biodiesel product were analyzed and compared with those achieved using molecular sieves. The results show that the biodiesel—after water was removed during transesterification—appeared to have increased kinematic viscos... [more]
An Analytical Elastic Solution for Right-Angle Trapezoidal Opening in Steeply Inclined Coal Seam
Wankui Bu, Hui Xu, Ming Ji
February 22, 2023 (v1)
Keywords: conformal mapping, deformation analysis, plane elasticity, right-angle trapezoidal opening, steeply inclined coal seam
In the process of underground mining, steeply inclined rocks or coal seams are often encountered, forming the openings of right-angle trapezoid. According to the geological conditions of a mining project in China, an analytical elastic solution of stress and displacement around right-angle trapezoidal opening in a homogeneous, isotropic, and linear elastic geomaterial is presented, which is based on the evaluation of the conformal mapping representation by an appropriate numerical calculation and the complex potential functions. The different results from other shaped openings are shown as follows. In a right-angle trapezoidal opening, the maximum displacements of roof falling occur on the low side, while the most horizontal displacements on the low side are around the roof and the most horizontal displacements on the high side are around the middle of the high side in this opening. These results are also compared with the numerical calculations in FLAC software, illustrating that the... [more]
Assessment of Wind Energy Resources in Jordan Using Different Optimization Techniques
Bashar Al-Mhairat, Ayman Al-Quraan
February 22, 2023 (v1)
Keywords: Gamma approach, power density, power–speed curve, probability distribution function, Rayleigh approach, Weibull approach, wind energy, wind turbine
Wind energy has become one of the world’s most renewable energy sources in recent years. It is regarded as a clean energy source because it produces no greenhouse gas emissions. The assessment of wind energy resources is an important step in the development of any wind energy conversion system (WECS). As a result, this article examines the wind energy potential of nine Jordanian wind locations: Queen Alia Airport, Civil Amman Airport, King Hussein Airport, Irbid, Mafraq, Ma’an, Ghor Al Safi, Safawi, and Irwaished. The available wind speed data were implemented using three statistical distribution models, Weibull, Rayleigh, and Gamma distributions, and one traditional estimation method, the Maximum Likelihood Method (MLM). Three optimization techniques were used to assign parameters to each distribution model: Particle Swarm Optimization (PSO), Grey Wolf Optimizer (GWO), and Whale Optimization Algorithm (WOA). To determine the optimal distribution model, the performance of these distrib... [more]
Impact of Silica Additions on the Phase Composition and Electrical Transport Properties of Ruddlesden-Popper La2NiO4+δ Mixed Conducting Ceramics
Kiryl Zakharchuk, Aleksandr Bamburov, Eugene N. Naumovich, Miguel A. Vieira, Aleksey A. Yaremchenko
February 22, 2023 (v1)
Keywords: apatite, electrical conductivity, electrode polarization, lanthanum nickelate, lanthanum silicate, oxygen permeability, Ruddlesden-Popper phase, solid electrolyte, solid oxide fuel cell
The present work explores the possibility of incorporation of silicon into the crystal structure of Ruddlesden-Popper La2NiO4+δ mixed conducting ceramics with the aim to improve the chemical compatibility with lanthanum silicate-based solid electrolytes. Ceramics with the nominal composition La2Ni1−ySiO4+δ (y = 0, 0.02 and 0.05) were prepared by the glycine nitrate combustion technique and sintered at 1450 °C. While minor changes in the lattice parameters of the tetragonal K2NiF4-type lattice may suggest incorporation of a small fraction of Si into the Ni sublattice, combined XRD and SEM/EDS studies indicate that this fraction is very limited (≪2 at.%, if any). Instead, additions of silica result in segregation of apatite-type La10−xSi6O26+δ and La2O3 secondary phases as confirmed experimentally and supported by the static lattice simulations. Both total electrical conductivity and oxygen-ionic transport in La2NiO4+δ ceramics are suppressed by silica additions. The preferential reactiv... [more]
Effect of Pre-Injection on Combustion and Emission Characteristics of a Diesel Engine Fueled with Diesel/Methanol/n-Butanol Blended Fuel
Zhiqiang Wang, Lijun Li
February 22, 2023 (v1)
Keywords: combustion and emission characteristics, diesel engine, diesel/methanol/n-butanol blended fuel, pre-injection
In this study, the combustion and emission characteristics of a diesel/methanol/n-butanol blended fuel engine with different pre-injection timings and pre-injection mass ratios were investigated by a computational fluid dynamics (CFD) model. The CFD model was verified by the measured results and coupled with a simplified chemical kinetics mechanism. Firstly, the corresponding three-dimensional CFD model was established by CONVERGE software and the CHEKMIN program, and a chemical kinetic mechanism containing 359 reactions and 77 species was developed. Secondly, the combustion and emission characteristics of the diesel engine with different diesel/methanol/n-butanol blended fuels were analyzed and discussed. The results showed that increases in the pre-injection timing and the pre-injection mass ratio could increase cylinder pressure and cylinder temperature and decrease soot, HC, and CO emissions. At 100% load, the maximum cylinder pressures at the start of pre-injection timing from −15... [more]
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