Based on the contribution of elements and chemical bonds, the UNICAC (Universal Quasi-Chemical elements and chemical bonds Activity Coefficient) method was proposed to estimate the activity coefficients of nonelectrolyte liquid mixtures. The UNICAC method defined 10 elements and 33 chemical bonds as contribution groups. The calculation of activity coefficients was divided into the combination term and the residual term. The combination term represents molecular size differences, and the residual term describes the interaction between molecules. The interaction energy parameters of 43 groups were regressed simultaneously with the experimental data of the vapor−liquid equilibrium of 1085 binary systems. According to the molecular structural information of compounds, the UNICAC method can accurately predict the activity coefficients of nonelectrolyte liquid mixtures. The vapor−liquid equilibrium of 16 groups of the binary system, which were not included in the parameters regress, was pred... [more]

Herein we demonstrate a novel plating bath, free from cyanide, to plate a highly adherent nanocrystalline copper-silver (ncCuAg) coating on a stainless-steel substrate and its application as an antimicrobial coating. The microstructures, such as the grain size, texture, microstrain, and the crystalline preferential orientation of CuAg deposits, are systematically investigated by X-ray diffraction analysis. The range of 13.4−16.6 nm was discovered to be the crystallite size determined from the X-ray peak broadening (Scherrer’s formula). Both HRTEM, FESEM-EDS, XPS, and mapping analysis revealed that the ncCuAg coatings are composed of both Ag and Cu atoms. Electrochemical processes occurring during CuAg co-deposition were investigated by using linear sweep voltammetry (LSV), cyclic voltammetry (CV), and anodic linear stripping voltammetry (ALSV). Additionally, the coatings made of ncCuAg produced by these baths work well as antibacterial agents against gram-positive (Staphylococcus) and... [more]

In the development of high temperature sour gas reservoirs, gas−liquid sulfur two phase percolations exist, which have a significant impact on the gas permeability and gas well productivity. There are currently few reports on experimental studies on gas−liquid sulfur relative permeability. This study improves the experimental equipment and process, and it proposes an experimental method for measuring the gas−liquid sulfur relative permeability curve. Several typical core samples from a sour gas reservoir in Sichuan Basin, China were selected for experimental study, and the gas−liquid sulfur relative permeability under high temperature and high pressure (HTHP) was measured. The results show that, first, the critical flowing saturation of liquid sulfur was 40%, and the gas−liquid sulfur co-flow zone was narrow. With the increase in the liquid sulfur saturation, the gas relative permeability decreased rapidly. Second, the better the physical properties of the core, the greater the damage... [more]

In order to study temperature distributions under different influencing factors and evaluate the cooling performance of the turbocharger bearing casing, water-cooling system experiments regarding the turbocharger bearing casing are carried out, and an improved fuzzy analytic hierarchy process (FAHP) evaluation method for evaluating its design performance is proposed firstly. Then, the effects of various factors such as cooling-water inlet flow velocity, cooling-water inlet temperature, cooling-water pressure and exhaust temperature on the cooling performance of the bearing casing are investigated according to the experimental results. Finally, the design performance of the water-cooling system in the turbocharger bearing casing is evaluated based on the FAHP evaluation method. The results show that the turbocharger bearing casing temperature and the temperature drop rate show a decreasing trend with the increase of inlet cooling-water velocity, but that the temperature and temperature... [more]

In this paper, a characterization method for a lithium iron phosphate (LFP) pouch cell is presented and evaluated, using a method that applies to hybrid current pulses called hybrid power pulse characterization (HPPC). The purpose of the study is to validate the developed mathematical model capable of offering good results for virtualization of the cell with extrapolation capability for the entire battery. This type of characterization was tested before but on cells with low capacity where relatively small currents were applied. Here, the model is intended to be used for the development of electrical mobility applications, such as electric vehicles (EV) and electric vehicle supply equipment (EVSE), where high capacity and currents are required through the cell. The comparison between the real and simulated cell was made with two sets of results obtained from HPPC and using the FTP-72 speed profile by emulating real current conditions, where both show that the method is reliable under t... [more]

Understanding the physics of flow instabilities is important for processes in a wide range of engineering applications. Flow instabilities occur at the interfaces between moving fluids. Potential fluctuations are generated at the interfaces between two moving fluids based on the relationship of continuity. Theoretical analysis demonstrated that, in flow instabilities, potential fluctuation exhibits a potential oscillatory wave surface concurrently in the temporal and spatial dimensions. Potential fluctuations already internally exist in flow before flow instabilities begin to develop; these potential fluctuations greatly affect the formation of interpenetrating structures after forces act on the interfaces. Experimental studies supported the theoretical study: Experiments visualizing condensation flows using refrigerant in one smooth tube and one three-dimensional enhanced tube were conducted to show the development of potential fluctuation in spatial dimensions, and an experiment with... [more]

Energy need is predicted to increase by 48% in the next 30 years. Global warming resulting from the continuously increasing atmospheric CO2 concentration is becoming a serious and pressing issue that needs to be controlled. CO2 capture and storage/use (CCS/CCU) provide a promising route to mitigate the environmental consequences of CO2 emission from fossil fuel combustion. In recent years, hollow fiber membrane contactors are regarded as an advanced technique with several competitive advantages over conventional technologies such as easy scale-up, independent control of flow rates, more operational flexibility, absence of flooding and foaming as well as high interfacial area per unit volume. However, many factors such as the membrane material selection, proper choice of solvent, and membrane module design are critical to success. In this regard, this paper aims at covering all areas related to hollow fiber membranes, including membrane material, membrane modification, membrane surface... [more]

In the future, ammonia is expected to become a carbon-free fuel for internal combustion engines. However, the flammability of ammonia is poorer compared to conventional fuels such as gasoline and diesel fuel. Pre-chamber jet ignition may be an effective way to ensure stable ignition and enhance the combustion of ammonia. In this paper, the effects of pre-chamber geometric parameters, including volume and orifice diameter, on the jet ignition and combustion processes were studied using visualization methods, combined with pressure acquisition. The results showed that ignition energy increased and the jet duration was prolonged with the increase in pre-chamber volume, resulting in a higher maximum pressure and pressure rise rate in the main chamber. The jet characteristics of a larger volume pre-chamber exhibited higher stability when the ambient parameters were changed. The smaller volume pre-chamber showed the superiority of a shorter flame propagation distance inside the pre-chamber,... [more]

Magnesium and its alloys are widely used in many areas because of their light weight, excellent dimensional stability, and high strength-to-weight ratio. However, the material exhibits poor wear and corrosion resistance, which limits its use. Plasma electrolytic oxidation (PEO) is an effective surface modification method for producing ceramic oxide layers on Mg and their alloys. The influence of the additions of sodium tetrafluoroborate (NaBF4) and sodium fluoride (NaF) into alkaline-silicate electrolyte on the properties of the conversion layers formed in the magnesium AZ91D alloy has been investigated. Surface morphology and chemical composition were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The anticorrosive properties of the layers were evaluated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization (PDP) methods in simulated body fluid (SBF). The presence of NaBF4 or NaF in the electrolyte increases the... [more]

The aim of this study is to investigate the impact of time and temperature of the heat pump drying process of soursop slices at different levels on moisture content and total polyphenol content (TPC). Twelve types of classical kinetic models have been used in this work to describe the suitability of experimental data with models. The conformity is assessed based on statistical values (e.g., coefficient of determination (R2), Chi−square value (X2), etc.). The loss of moisture in the material is described in accordance with Fick’s diffusion law. Value of moisture rate (MR), and effective moisture diffusivities (Deff) have been identified. Experimental results show that MR value depends on the time and drying temperature, Deff increases when increasing the drying temperature from 20−50 °C with values of 1.24 × 10−9, 1.85 × 10−8, 7.69 × 10−8, and 5.54 × 10−7 m/s2. The Singh et al. model is the best option to describe the moisture of the sliced soursop drying process at 30 °C (R2 = 0.97815)... [more]

Advanced measurement technology on boundary layer transition is an effective means to study the flow mechanism and the performance of the cascade. In this research, to investigate the boundary layer transition of transonic VKI-RG turbine cascade, a noncontact measurement technique named temperature-sensitive paint (TSP) that is capable of quantitatively measuring the surface temperature of a model is used. Under the conditions of outlet Mach number (Ma2) = 0.4, 1.03, and 1.2, the transitional location of a cascade is accurately measured by TSP technique. Moreover, a numerical study on the transitional location of a planar cascade was conducted with the conditions of Mach number (Ma) and attack angle (α). The numerical results show that the transitional location moved forward with the increase in Ma2 and α at Ma2 < 1; otherwise, the transitional location moved backward with increasing Ma2 (Ma2 > 1). Lastly, a strong adverse pressure gradient was formed behind the shock wave, which led t... [more]

With the increasing attention to light oil, the catalytic cracking process of heavy oil is being vigorously developed. The silicon hydroxyl groups on the surface of mesoporous silica materials can be used as weak acid centers to preliminarily crack heavy oil macromolecules. Herein, a strategy of introducing titanium into a silica skeleton for modification is proposed to increase active sites, as well as improve the hydrothermal stability. After titanium modification, the mesoporous silica material has more weak acid sites, and shows better ability in deep cracking heavy oil. Notably, when the content of titanium doping is 2%, the CT(2) catalyst exhibited the best high-temperature hydrothermal stability, which can be used as a suitable heavy oil catalytic cracking catalyst. This kind of titanium-modified mesoporous silica material shows great application prospects in heavy oil catalytic cracking, which may provide a novel idea for subsequent development.

Although the lubrication systems for internal combustion engines have been designed to prevent engine wear and friction, their configuration does not contemplate the maximum use of each load of lubricant; because of this limitation, lubricant consumption is currently an environmental and economic problem. In this work, the performance of lubrication systems to form the tribological film that prevents wear is simulated and optimized, through the mass balance of the lubricant precursors contained in the oil and the implementation of optimal control techniques. Optimization results indicate that regulating the flow of lubricant passing through the engine prevents excessive degradation of lubricant precursors, maximizing the life of each lube oil charge, giving the possibility to increase the sustainability of internal combustion engines.

Inside the pump-turbine, energy is irreversibly lost due to turbulent pulsations in the high Reynolds number zone and actions of viscous forces close to the wall. The conventional differential pressure method cannot obtain specific details of the hydraulic loss within the machine’s flow passages; on the other hand, the entropy production method can provide accurate information on the location of irreversible losses and the spatial distribution of energy dissipation. Therefore, based on the entropy production theory, this study investigates the composition and distribution of hydraulic losses under different flow conditions for a prototype pump-turbine in pump mode. Study results indicated that total hydraulic losses significantly decreased, then slowly increased with an increase in flow rate. The entropy production rate caused by turbulence dissipation (EPTD), direct dissipation (EPDD), and wall shear stress (EPWS) displayed the same variation patterns as that of total hydraulic losses... [more]

Coaxial borehole heat exchangers provide a practical method for geothermal energy extraction, but heat transfer efficiency is low. In order to address this problem, three coaxial borehole heat exchangers with vortex generators, based on the enhanced heat transfer theory, are proposed in this paper. The author compared and analyzed the heat transfer performance of three coaxial borehole heat exchangers with vortex generators and those of traditional structures, which explains why the new heat exchanger’s heat transfer mechanism is enhanced. The results demonstrated that the vortex generator can enhance the fluid flow’s turbulent kinetic energy in the coaxial heat exchanger. This generator can also improve the mixing characteristics of the fluid flow and heat transfer. The resultant increase in the inlet flow velocity can decrease the friction coefficient f, increase the Nusselt number and strengthen the coaxial sleeve. As a result, the heat exchange performance of the tubular heat excha... [more]

The petrochemical industry is traditionally a high energy consumption industry, thus energy saving in this industry is of great significance in terms of trying to achieve the national goal of “carbon-peak and carbon neutrality” in China. Diesel is one of the main products of petrochemical enterprises. The energy consumption of a diesel hydrotreating (HDT) unit is relatively high due to the high reaction temperature and pressure of HDT reactors. In order to further explore the energy consumption of diesel HDT units under different operating conditions, this paper establishes a full-process simulation based on the kinetics of hydrodesulfurization, hydrodenitrogenation, and aromatics saturation, in Aspen Plus to discuss the effect of different operating conditions on the electricity, steam, and fuel gas consumptions. The results show that with the increase of reaction temperature or reaction pressure, the sulfur content in diesel oil decreases, but the consumption of related utilities and... [more]

The reaction process, mechanism, and kinetics of the decarbonation of coal-series kaolinite (CSK) were investigated using the thermal analysis (TG)−infrared spectrum analysis (IR) coupling method. A pilot test was performed using a suspended calcination system. Further, the carbon content, phase composition, whiteness, oil-absorbed value, and micromorphology of calcined kaolin were characterized. Results showed that the decarburization reaction of CSK was a two-step reaction that mainly occurred in the ranges of 593 °C−836 °C. The mechanism of the decarburization reaction was a phase-boundary reaction (unreacted-core shrinking model) with an activation energy of 214.56 kJ/mol. Calcination at 900 °C or 950 °C for ~3.3 s in a suspension reactor resulted in the decarburization rate of CSK becoming >99.9%. The whiteness of calcined kaolin was mainly positively associated with the decarburization rate, and increasing the calcination temperature aided in increasing the whiteness. The oil-abs... [more]

Solvothermal treatment using glycerol effectively removes chlorine from polyvinyl chloride (PVC). Additive-free PVC was dechlorinated by treatment with glycerol in an autoclave at 200−240 °C. Liquid glycerol was coexistent with a red powder after the reaction at 200 °C. At reaction temperatures of 220 and 240 °C, the liquid glycerol disappeared, and carbonization proceeded to form a black powder. In this reaction, the glycerol was directly converted into glycidol. Epichlorohydrin was also produced from the glycerol via 1,3-dichloro-2-propanol as an intermediate. The PVC was converted into the polyethylene oxide structure, following the generation of the polyene structure by zip-elimination. Finally, the converted PVC was resinified by an epoxidation reaction with the glycidol and epichlorohydrin. Thus, glycerol acted as a useful reaction medium for this reaction system. The analysis of the decomposition ratio and dechlorination yield showed that the PVC was converted into solid product... [more]

Compared with land wells, the production environment and reservoir depth of offshore oil and gas wells are more complex and shallower. Further, HPHT production fluid there will produce strong temperature and pressure disturbance that affects the wellbore, which easily generates wellbore safety problems, such as wellhead growth and leakage caused by the incompatible deformation of casing and cement sheath. Therefore, obtaining an accurate wellbore temperature and pressure field is the key to implementing a wellbore safety assessment. Based on the gas−liquid two-phase separated method, this paper established an improved calculation model of wellbore temperature and pressure field for offshore HPHT wells. This model also takes into account the heat transfer environment characteristics of “formation-seawater-air” and the influence of well structure. Compared with the measured data of the case well, the error of temperature and pressure calculation results of the improved model are only 0.8... [more]

In this study, flue gas heat recovery potential was determined by using the flue gas measurements from boilers of buildings with solid fuel-fired district and central heating systems in Balikesir, Turkey. Potential flue gas heat recovery potential in terms of energy savings were examined. The potential of heating the preheated water and combustion air supplied to the boiler was analyzed. Thus, the efficiency of the heating system was increased, and energy savings were achieved by providing fuel savings. In order to reduce the flue gas temperature in solid fuel-fired boilers, the acidification temperature, fuel properties and excess air coefficient should be known. Below the acidification temperature, corrosion and other adverse effects may occur in the flue and in the heat exchanger. In this study, acidification temperature and fuel and combustion characteristics of coal were taken into account. Generally, seven types of coal are used for heating purposes in Balikesir province. Thus, f... [more]

A four-stage condensers in series system was adopted to solve the problems of insufficient condensation of high-temperature pyrolysis steam and difficulty in the classification and recovery of pyrolysis oil, where the internal fluids conducted countercurrent convection heat exchange. A steady-state physical and mathematical model of a single condenser was established to clarify the discipline of heat transfer between the internal fluids. Meanwhile, the model of pyrolysis steam coupled multi-stage condensers was proposed with the help of the model compound firstly. A numerical simulation was carried out and the results showed that when the number of condensers in series was four, the heat transfer process of the system reached saturation, and the heat exchange of the cold and hot fluids was completely realized, and it was of little significance to continue to connect more condensers in series for the condensation of pyrolysis steam. To quickly condense the hot fluid, the key was to incr... [more]

The burner-type regeneration diesel particulate filter is one of the most widely used diesel particulate filters. Using AVL FIRE, a 3D model of a burner-type regeneration diesel particulate filter (DPF) was established, and simulation analyses were carried out. The effects of the exhaust parameters (temperature, exhaust mass flow rate, and soot load) and the structural parameters (channel density, inlet/outlet channel ratio, and the length−diameter ratio) on soot distribution (soot mass concentration and soot thickness) were analyzed. The results show that the soot distribution characteristics of regenerative DPF with a burner are as follows: the soot mass concentration first rapidly rises to the maximum value and then rapidly decreases to a low value, and the dust thickness gradually increases with the increase in location. With the increase in exhaust mass flow rate and soot load, soot mass concentration and soot thickness increase. With the increase in temperature, the mass concentr... [more]

The bottom-hole pressure of hydraulic fracturing in ductile reservoirs is much higher than that of the hydraulic fracturing simulation, and the fracture toughness inferred from the field data is 1−3 orders of magnitude higher than that measured in the laboratory. The rock apparent fracture toughness increases with the increase in the confining pressure. Excluding the influence of the fluid viscosity and the fluid lag on the apparent fracture toughness, the fracture process zone (FPZ) at the fracture tip can explain the orders of magnitude of difference in the apparent fracture toughness between the laboratory and the field. The fracture tip is passivated by plastic deformation, forming a wide and short hydraulic fracture. However, the size of the FPZ obtained in the laboratory is in the order of centimeters to decimeters, while an FPZ of 10 m magnitude is speculated in the field. The FPZ size is affected by the rock property, grain size, pore fluid, temperature, loading rate, and loadi... [more]

A series of numerical simulations were performed to study the discharge coefficient based on the geometric parameters of a stepped labyrinth seal that sealed the secondary flow path of a gas turbine. In contrast with straight-through seals, stepped labyrinth seals introduce additional geometrical parameters related to the steps. In this study, three shape variables were observed: step height (SH), position, and cavity width (CW). The sensitivity to the leakage flow of the shape variable in the stepped labyrinth seal was analyzed. The mechanism for improving the sealing performance of stepped labyrinth seals was investigated. The results indicated that the stepped labyrinth seal exhibited up to 17.9% higher leakage-suppression performance than the straight labyrinth seal. Seals with large discharge coefficients had a large vena contracta upstream of each tooth structure and a rapidly accelerated axial velocity in the radial direction. We could observe that the discharge coefficient chan... [more]

The purpose of this study is to review the Lean tool application and its utilisation in medical device design and the new product introduction process to establish the benefits and best practices for its integration with existing new product introduction processes. A review of the literature on the current state of medical device New Product Introduction (NPI) processes is completed along with a comprehensive review of the literature on the history and development of Lean NPI. The review indicates that Lean can be combined with the predominant NPI execution tools, Stage-Gate and Concurrent Engineering within the medical device industry to achieve a best-in-class continuous improvement methodology within the NPI process. This integration eliminates waste, focusses on customer value, and ultimately reduces cost and lead time to market. This review highlights for the first time the main challenges and issues with Lean in the medical device sector NPI processes, identifying possible future... [more]