Biological methanation is the production of CH4 from CO2 and H2. While this approach to carbon capture utilization have been widely researched in the recent years, there is a gap in the technology. The gap is towards the flexibility in biomethanation, utilizing biological trickling filters (BTF). With the current intermittent energy system, electricity is not a given surplus energy which will interfere with a continuous operation of biomethanation and will result in periods of operational downtime. This study investigated the effect of temperature and H2 supply during downtimes, to optimize the time needed to regain initial performance. Short (6 h), medium (24 h) and long (72 h) downtimes were investigated with combinations of three different temperatures and three different flow rates. The results from these 27 experiments showed that with the optimized parameters, it would take 60 min to reach 98.4% CH4 in the product gas for a short downtime, whereas longer downtimes needed 180 min... [more]

Diode-based HVDC link technology is considered an alternative to reduce the cost and complexity of offshore HVDC platforms. When this technology is used, the AC grid of the wind farm must be created artificially. This paper proposes an advanced frequency control method that permits forming an AC grid voltage system to connect offshore wind turbines to a diode-based HVDC link rectifier. The proposed algorithm can be easily implemented in the wind farm’s overall Power Plant Controller (PPC) without any change in the commercial wind turbine firmware. All wind turbines receive reactive power targets from the PPC to maintain the frequency and amplitude of the offshore AC line, delivering the maximum active power generated by the wind. A novel black start method is proposed to establish the wind farm’s local AC grid voltage system. The control method has been implemented and proved in an experimental setting. The black start has been successfully verified, and the frequency control algorithm... [more]

Greenhouse gases (GHG) concentration (CO2, CH4, and NOx mainly) in the Earth’s atmosphere has dramatically increased since 1960; in particular, the atmospheric CO2 levels have increased from 320 ppm to 412 ppm from 1960 to 2019 [...]

EAF steelmaking based on renewable electricity allows for low-CO2 steel production. However, the increased integration of volatile renewable energies into the energy system requires the provision of flexibility options. In view of the substantial oxygen consumption in the steel mill, flexible on-site generation and storage holds a significant potential for demand-side management. The utilization of by-product oxygen from an electrolysis plant not only contributes to load flexibility but also generates a climate-neutral fuel. In the present study, different process layouts are developed based on state-of-the-art technologies. The proposed supply systems for oxygen, hydrogen, and synthetic natural gas are subjected to design and operational optimization and assessed with respect to the overall demand-side flexibility, carbon dioxide emission reduction, and economic viability.

Marine energy resources could be crucial in meeting the increased demand for clean electricity. To enable the use of marine energy resources, developing efficient and durable offshore electrical systems is vital. Currently, there are no large-scale commercial projects with marine energy resources, and the question of how to design such electrical systems is still not settled. A natural starting point in investigating this is to draw on experiences and research from offshore wind power. This article reviews different collection grid topologies and key components for AC and DC grid structures. The review covers aspects such as the type of components, operation and estimated costs of commercially available components. A DC collection grid can be especially suitable for offshore marine energy resources, since the transmission losses are expected to be lower, and the electrical components could possibly be made smaller. Therefore, five DC collection grid topologies are proposed and qualitat... [more]

Renewable energy is predicted to play a crucial role in the energy sector as transitioning from fossil fuels to biofuels is key to achieving carbon neutrality. The comprehensive utilization of livestock manure and crop residues as a viable source of biofuels can play a significant role in Ghana’s future energy system. This current study aims to examine and predict the biofuel potential in Ghana from animal manure and crop residues. The biogas-biomethane potential of animal manure is determined using anaerobic digestion technology, whereas crop residues’ bioethanol potential is assessed using computational and analytical approaches. The findings demonstrate that animal manure biogas potential is 237.72 normal million cubic meters (NMm3). The highest manure-biogas potential per animal is from cattle (27.15 Nm3) and pigs (18.15 Nm3), while the least contribution is from chickens (1.80 Nm3). In addition, the annual bioethanol production is 3.74 gigaliters (GL), and residues from maize (0.8... [more]

The integration of distributed generation systems, including intermittent solar photovoltaic (PV) and wind, has a significant impact on the power system [...]

Nowadays, power converters with reduced cost, compact size and high efficiency are evolving to overcome the emergent challenges of renewable energy integrations. In this context, there is an increased demand for well-designed power converters in renewable energy applications to reduce energy utilization and handle a variety of loads. This paper proposes a center-tapped bridge cascaded series-resonant LC dual active bridge (DAB) converter for DC-DC conversion. The low part count of the proposed converter enables a high-power density design with reduced cost. The proposed converter offers reduced conduction losses as the reverse current is eliminated by adopting current blocking characteristics. Reverse current blocking also enables zero voltage switching (ZVS) and zero current switching (ZCS) over a wide operating range. Therefore, using a simple fixed frequency modulation (FFM) scheme offers a wide operating range compared to a conventional DAB converter. A thorough comparison of the p... [more]

Cathode precursors of lithium-NMC 811 were synthesized by the coprecipitation method using two different nickel sources, namely mixed nickel−cobalt hydroxide precipitate (MHP) and nickel sulfate. The characteristics of the synthesized precursors were compared with the characteristics of the commercial NMC 811 cathode precursor obtained from the international market. The XRD analyses identified that the diffraction peaks of the three precursor materials were in close agreement to that of Li0.05Ni0.75Co0.1Mn0.1O2, with the figure(s) of merit (FoM) of 0.81, 0.88, and 0.9, respectively, for the synthesized precursor that used MHP as the source of nickel (SM-LNMCO-811), nickel sulfate as the source of nickel (SX-LNMCO-811), and the commercial precursor (K-NMC-811). The elemental analysis of the synthesized precursors revealed the Ni:Mn:Co mol ratios of 0.8:0.08:0.12 and 0.76:0.11:0.13 for SM-LNMCO-811 and SX-LNMCO-811, respectively. The SEM analysis revealed that SX-LNMCO-811 and K-NMC-811... [more]

The construction of new wastewater treatment plants and the modernization of existing ones lead to the expansion of sewage networks, resulting in a sharp increase in the volume of municipal sewage sludge, which translates into a global problem of sludge management. The solution to this problem could be the recovery of energy from sewage sludge in the cement industry to exploit its energy potential. The aim of the present study was to examine the results of laboratory research on the production of alternative fuels based on municipal sewage sludge, plastic waste from end-of-life vehicles, and wood waste (sawdust) from carpentry enterprises. The tests were carried out for waste mixtures designated as PAZO I, PAZO II, PAZO III, and PAZO IV fuels, differing in the percentage of waste used and the type of plastic waste. The following parameters were evaluated in fuels: water content, ash content, sulfur content, and calorific value. Water content of the obtained fuels ranged from 17.1% to 1... [more]

Despite the many different methods for creating modified heat transfer surfaces to increase critical heat fluxes and heat transfer coefficients at pool boiling of various liquids at given reduced pressures, active research is currently underway to find optimal surface morphology and geometric parameters of structures for practical application. In this work, we used the method of microarc oxidation (MAO) to obtain coatings with different microstructures on the surface of duralumin heaters. In the present work, we studied the effect of MAO coatings on heat transfer, critical heat flux, and evaporation dynamics during liquid nitrogen boiling under conditions of steady-state heat release at pressures of 0.1, 0.05, and 0.017 MPa. It was shown that the modification of heaters led to a 50−60% increase in heat transfer coefficients as compared to the smooth one under the atmospheric pressure. Based on the data of high-speed video filming of boiling, it was shown that the main mechanism of inte... [more]

Oil shale constitutes an important proportion of unconventional resources, and its efficient exploitation helps alleviate the Chinese oil shortage situation. Nowadays, microwave heating is a promising method for in situ development of oil shale. However, the corresponding numerical simulation lacks in guiding the retorting optimization under microwave heating. A novel pseudo three-dimensional model, considering electromagnetics, temperature field, and chemical reactions coupling was developed and implemented to investigate oil shale reservoirs’ retorting performance under microwave heating based on the finite element method (FEM). The effects of microwave power, antenna number, and antenna position were analyzed creatively to optimize the microwave heating parameters. Numerical results showed high microwave power increased the maximum reservoir temperature quickly near the heating well, but the thermal conductivity of oil shale dominated the temperature of distal formation. For a typic... [more]

Wind turbines (WTs) are exposed to a dynamic/cyclic load environment, and are subjected to 1P/3P loads under operational conditions. Recent studies introduced the Sommerfeld Effect to explain the dynamic response amplification induced by 1P/3P loads. This study establishes a theoretical model to analyze the resonance of WTs under 1P/3P loads. Sensitiveness analysis was conducted for parameters b, c, S, F, and T to explore their influence on the dynamic response. The resonance phenomenon induced by 1P/3P frequency passing the natural frequency is discussed. The results show that there is no Sommerfeld Effect in soft−stiff WTs. Only if the imbalance reaches a much higher value (19200 kg·m in this study) should the Sommerfeld Effect be considered for soft WTs; otherwise, it can be ignored. The 3P resonance appeared when the 3P frequency approached the natural frequency, but it was not the Sommerfeld Effect.

As an emerging foundation structure for offshore wind turbines, bucket foundations with superior bearing capacities and efficient construction procedures have attracted significant attention in China. Thick-walled bucket foundations with concrete skirts can effectively reduce the cost and prevent the buckling problem of steel skirts during construction, transportation, and installation. However, great challenges are encountered during the sinking process, and the accurate calculation of sinking resistance is a critical process. Static-pressure tests of thin-walled and thick-walled models in sand were performed to measure the penetration resistance and soil pressure at the sidewalls and ends. The horizontal-soil-pressure coefficients of different models were calculated, and the end and skin-friction coefficients in the cone-penetration test method are recommended. The drag-reduction effects of the anti-drag ring and pressure-pull-out loading method were examined, and the drag-reduction... [more]

Converting municipal solid waste (MSW) into valuable feedstocks, such as refuse-derived fuel (RDF), is a sustainable method according to the concept of waste management hierarchy. A heterogeneous composition with a good calorific value and lower emissions allows RDF to be used for energy recovery purposes. We have earlier analyzed the generation and thermochemical characteristics of the MSW produced in Kazakhstan. This work aims to study the combustion characteristics in terms of emissions and ash composition to evaluate the possibility of RDF co-firing with Ekibastuz coal. In particular, RDF is blended with high ash bituminous coal (Ekibastuz coal) and co-fired in the laboratory scale bubbling fluidized bed reactor (BFB) at a bed temperature of 850 °C. The co-firing tests of RDF to coal samples were conducted under various proportions to analyze flue gas compositions. Experiments were carried in the presence of bed material (sand), and the fuel particles were fed in batch mode into th... [more]

Raw Jojoba oil was used in a direct-injection diesel engine without any engine modifications and compared with both diesel fuel and 50/50 raw Jojoba/diesel. The measured parameters included the rheological properties measured in the range of shear rate from 100 to 500 1/s. Distillation data were presented for raw Jojoba oil compared to diesel. The parameters included exhaust gas analysis, block vibration, sound noise, and the combustion pressure and its rise rate. Averaged pressure-crank angle, vibration, and its frequency spectrum and sound level were presented. Data also included brake power, specific fuel consumption, and exhaust temperatures for all fuels used. For Jojoba oil, the engine did not exhibit low power output or specific fuel consumption. Exhaust temperatures, smoke opacity, and NOx emissions were lower than diesel case. Noise for Jojoba was higher than diesel case. The engine block vibration was concentrated towards the low frequency range.

Shale reservoirs are characterized by extremely low porosity and permeability, poor connectivity, and high content of clay minerals. This leads to the reservoir being vulnerable to imbibition damage caused by foaming agent solutions during foam drainage gas recovery. It results in the decrease of reservoir permeability and the reduction of gas well production and ultimate recovery. Therefore, as the most commonly used foam drainage gas production, it is particularly important. This study is structured as follows. First, we analyze and evaluate the characteristics of shale reservoirs within the target area, and that of mineral composition and microscopic pore throat structures. Second, we study foaming agent types and two types are selected to be applied in subsequent sensitivity tests. Simultaneously, the nuclear magnetic resonance (NMR) method was used to study the microscopic characteristics of reservoir damage and imbibition damage of shale, caused by the impact of foaming agent sol... [more]

In order to exploit a fast-growing Paulownia hardwood as an energy crop, a xylose-enriched hydrolysate was obtained in this work to increase the ethanol concentration using the hemicellulosic fraction, besides the already widely studied cellulosic fraction. For that, Paulownia elongata x fortunei was submitted to autohydrolysis treatment (210 °C or S0 of 4.08) for the xylan solubilization, mainly as xylooligosaccharides. Afterwards, sequential stages of acid hydrolysis, concentration, and detoxification were evaluated to obtain fermentable sugars. Thus, detoxified and non-detoxified hydrolysates (diluted or not) were fermented for ethanol production using a natural xylose-consuming yeast, Scheffersomyces stipitis CECT 1922, and an industrial Saccharomyces cerevisiae MEC1133 strain, metabolic engineered strain with the xylose reductase/xylitol dehydrogenase pathway. Results from fermentation assays showed that the engineered S. cerevisiae strain produced up to 14.2 g/L of ethanol (corre... [more]

Diesel fuel mixtures with high concentrations of biodiesel have been investigated to analyze the technical feasibility of their use in diesel cycle engines regarding thermal and oxidative properties. The results of combined techniques of oxidative stability, high Pressurized Differential Scanning Calorimetry (P-DSC), Calculated Cetane Index (CCI), and calorific power were used to verify the effect of the thermal-oxidative stability as a function of the percentage of biodiesel in the mixtures. The obtained results evidenced that the thermal and oxidative stability decreased with the addition of biodiesel from 50 to 5% v/v. Low stability fuels require rapid use as the oxidation compounds degrade the product and impair vehicle performance, as well as lead to corrosion and clogging problems in various mechanical systems.

Synthetic fuel production via gasification of residual biomass streams from the pulp and paper industry can be an opportunity for the mills to enable improved resource utilization and at the same time reduce the production of excess heat. This paper summarizes initial oxygen-blown gasification experiments with two bark residues from a European pulp and paper mill, i.e., a softwood bark and a hardwood bark. The gasification process was characterized by measuring syngas yields and process efficiency to find optimum operating conditions. In addition, impurities in the syngas and ash behavior were characterized. Maximum yields of CO and H2 were obtained from softwood bark and amounted to approximately 29 and 15 mol/kg fuel, respectively. Optimum cold gas efficiency was achieved at an oxygen stoichiometric ratio of λ = 0.40 and was approximately 76% and 70% for softwood bark and hardwood bark, respectively. Increased λ had a reducing effect on pollutants in the syngas, e.g., higher hydrocar... [more]

H2 production through dry reforming of methane (DRM) is a hot topic amidst growing environmental and atom-economy concerns. Loading Ni-based reducible mixed oxide systems onto a thermally stable support is a reliable approach for obtaining catalysts of good dispersion and high stability. Herein, NiO was dispersed over MOx-modified-γ-Al2O3 (M = Ti, Mo, Si, or W; x = 2 or 3) through incipient wetness impregnation followed by calcination. The obtained catalyst systems were characterized by infrared, ultraviolet−visible, and X-ray photoelectron spectroscopies, and H2 temperature-programmed reduction. The mentioned synthetic procedure afforded the proper nucleation of different NiO-containing mixed oxides and/or interacting-NiO species. With different modifiers, the interaction of NiO with the γ-Al2O3 support was found to change, the Ni2+ environment was reformed exclusively, and the tendency of NiO species to undergo reduction was modified greatly. Catalyst systems 5Ni3MAl (M = Si, W) comp... [more]

Developing simple and effective chemistry able to convert industrial waste streams into valuable chemicals is a primary contributor to sustainable development. Working in the context of biodiesel production, we found that plain bisulfate on silica (SSANa, 3.0 mmol/g) proved to be an optimal catalyst to convert glycerol into solketal. With the assistance of a proper anhydrification technique, isolated yields of 96% were achieved working in mild conditions, on 100 g scale.

When Saccharomyces cerevisiae undergoes heat stress it stimulates several changes that are necessary for its survival, notably in carbon metabolism. Notable changes include increase in trehalose production and glycolytic flux. The increase in glycolytic flux has been postulated to be due to the regulatory effects in upper glycolysis, but this has not been confirmed. Additionally, trehalose is a useful industrial compound for its protective properties. A model of trehalose metabolism in S. cerevisiae was constructed using Convenient Modeller, a software that uses a combination of convenience kinetics and a genetic algorithm. The model was parameterized with quantitative omics under standard conditions and validated using data collected under heat stress conditions. The completed model was used to show that feedforward activation of pyruvate kinase by fructose 1,6-bisphosphate during heat stress contributes to the increase in metabolic flux. We were also able to demonstrate in silico tha... [more]

The constant increase in greenhouse gases in the environment is forcing people to look for different ways to reduce such pollution. One of these ways is the use of biodiesel for road transport. Conventional biodiesel production involves the catalytic triglyceride transesterification process. When using homogeneous two-stage catalysis, it is difficult to purify the resulting product from the by-products formed, and the catalysts cannot be reused. In the case of heterogeneous catalysis, the process costs are increased due to separation and regeneration of the catalysts. To solve these problems of catalytic synthesis, a noncatalytic process has been recently studied that which takes place under supercritical conditions for an alcohol or other acyl receptor. In such biodiesel production, fatty feedstocks and alcohols are used as raw materials, with the synthesis taking place at supercritical conditions for alcohol, i.e., high temperature and pressure, thus making the process quite simple.... [more]

In the past decades, carbon dioxide (CO2) emissions have become an important issue for many researchers and policy makers. The focus of scientists and experts in the area is mainly on lowering the CO2 emission levels. In this article, panel data is analyzed with an econometric model, to estimate the impact of renewable energy, biofuels, bioenergy efficiency, population, and urbanization level on CO2 emissions in European Union (EU) countries. Our results underline the fact that urbanization level has a negative impact on increasing CO2 emissions, while biofuels, bioenergy production, and renewable energy consumption have positive and direct impacts on reducing CO2 emissions. Moreover, population growth and urbanization level are negatively correlated with CO2 emission levels. The authors’ findings suggest that the public policies at the national level must encourage the consumption of renewable energy and biofuels in the EU, while population and urbanization level should come along wit... [more]