To manage the imbalance between energy supply and demand in various energy systems such as energy storage and energy conversion, “phase change materials” are presented as promising options for these applications. To overcome the long-standing disadvantages of PCMs, for instance, small values of thermal conductivity, liquid leakage, separation of phase, and the problem of supercooling, advanced phase change composites (PCCs) manufactured by chemical modifications or the incorporation of functional additives are essential to overcome these disadvantages and promote the large-scale application of PCMs. Herein, we discuss a complete assessment of the recent development and crucial topics concerning PCCs, with a brief description of PCC preparation using different techniques, enhancing PCCs thermal conductivity approaches, and their applications. The various techniques of elaboration of PCCs used can be illustrated as polymerization, encapsulation, and hybrid confinement. Phase change mater... [more]

The current interest in thermal energy storage is connected with increasing the efficiency of conventional fuel-dependent systems by storing the waste heat in low consumption periods, as well as with harvesting renewable energy sources with intermittent character. Many of the studies are directed towards compact solutions requiring less space than the commonly used hot water tanks. This is especially important for small capacity thermal systems in buildings, in family houses or small communities. There are many examples of thermal energy storage (TES) in the literature using the latent heat of phase change, but only a few are commercially available. There are no distinct generally accepted requirements for such TES systems. The present work fills that gap on the basis of the state of the art in the field. It reviews the most prospective designs among the available compact latent heat storage (LHS) systems in residential applications for hot water, heating and cooling and the methods fo... [more]

Reservoir simulation for unconventional reservoirs requires proper history matching (HM) to quantify the uncertainties of fracture properties and proper modeling methods to address complex fracture geometry. An integrated method, namely embedded discrete fracture model−artificial intelligence−automatic HM (EDFM−AI−AHM), was used to automatically generate HM solutions for a multistage hydraulic fracturing well in the Wolfcamp Formation. Thirteen scenarios with different combinations of matrix and fracture parameters as variables or fixed inputs were designed to generate 1300 reservoir simulations via EDFM−AI−AHM, from which 358 HM solutions were retained to reproduce production history and quantify the uncertainties of matrix and hydraulic fracture properties. The best HM solution was used for production forecasting and carbon dioxide (CO2)-enhanced oil recovery (EOR) strategy optimization. The results of the production forecast for primary recovery indicated that the drainage area for... [more]

Functional materials, in the combination of lignocelluloses, known as natural fibers, with oxide materials, can result in cultivating functional properties such as flexibility, relativity good electrical conduction, good electrical charge storage capacity, and tunable electric permittivity. This study presents the morphological, dielectric, and impedance properties of lignocellulose−lead oxide (LC/PbO2) composite sheets electrodeposited with silver metallic nanoparticles for various time spans. The uncoated samples show a rather simple behavior where the impedance data fit well to the two-system model with different relaxation times. On the other side, the impedance spectra of the electrodeposited sample have varying features, which mainly depend upon the deposition thickness of the Ag particles. The common feature is the drift of conductive species, as seen from the straight-line behavior in the Nyquist plots, which were fitted using a Warburg element in the equivalent circuit model.

The rising technology of green hydrogen supply systems is expected to be on the horizon. Hydrogen is a clean and renewable energy source with the highest energy content by weight among the fuels and contains about six times more energy than ammonia. Meanwhile, ammonia is the most popular substance as a green hydrogen carrier because it does not carry carbon, and the total hydrogen content of ammonia is higher than other fuels and is thus suitable to convert to hydrogen. There are several pathways for hydrogen production. The considered aspects herein include hydrogen production technologies, pathways based on the raw material and energy sources, and different scales. Hydrogen can be produced from ammonia through several technologies, such as electrochemical, photocatalytic and thermochemical processes, that can be used at production plants and fueling stations, taking into consideration the conversion efficiency, reactors, catalysts and their related economics. The commercial process i... [more]

Supercapacitors (SCs) are recognized by high power densities and significantly higher cyclic stability compared to batteries. However, the energy density in SCs should be improved for better applications and commercialization. This could be achieved by developing materials characterized by such porous structures as metal-organic frameworks (MOFs) and metal chalcogenides in the electrodes’ materials. Herein, the recent advances in MOF derived from metal sulfides and selenides as electrode materials for SCs are reviewed and discussed. Strategies such as adopting core-shell structures, carbon-coating, and doping, which are used to promote the electrochemical performances of these MOF-based materials, are presented. Additionally, the progress in developing S-doped MOF-derived catalysts for the oxidation-reduction reaction (ORR) in the cathode of fuel cells is also reviewed. In addition, the challenges and future research trends are summarized in this minireview.

Due to the success of oil and gas production, turbidites have become exploratory targets over the past 40 years in the rift and passive margin basins in the North and South Atlantic. The turbiditic reservoirs in rift and passive margin settings of Atlantic sedimentary basins located in Brazil (Campos Basin) and Portugal (Lusitanian Basin) represent potential economic units for the hydrocarbon exploration. However, despite being considered analogous reservoirs, these units present distinct potentials for the accumulation of hydrocarbons. In this context, the work presented discusses the results obtained from the analysis of static (source rock, reservoir rock, seal and trap) and dynamic elements (migration, tectonic, diagenetic and thermal processes) of both studied petroleum systems, using geological, seismic, well, geochemical and petrographic data. The developed methodology of multiscalar characterization of the two petroleum systems was successful, leading to a specific classificati... [more]

High-voltage transmission technology has advanced quickly with the overall development and increased use of renewable energy. More demands on the insulating system are made when high-voltage power systems evolve. One of the significant factors is the sharp rise in population density, which led to the high demand for electricity. Right-of-way infringement is a problem that frequently occurs these days. Transmission is done over a rated capacity; as a result, the transmission line heats up, the insulation ages, and the electric field becomes distorted. The insulating system is prone to fail too soon when the operating voltage inverses or when there is a significant temperature differential. Environmentally friendly insulating materials have received much attention recently. A synergistic optimisation of heat resistance properties, mechanical properties, and dielectric properties must be accomplished before these materials can be used in high-voltage transmission systems. They must also w... [more]

A case study on the melting performance of a shell-and-tube phase change material (PCM) thermal energy storage unit with a novel rectangular fin configuration is conducted in this paper. Paraffin wax and circulated water are employed as the PCM and heat transfer fluid (HTF), respectively. It can be observed that the melting performance could be significantly improved by using rectangular fins. Melting photographs demonstrate that the melting of the PCM is firstly dominated by heat conduction; then, the melting rate is improved further due to natural convection. Moreover, the results illustrate that the influence of the inlet HTF temperature on the melting performance is significantly greater than that of the inlet HTF flow rate. The liquid fraction of paraffin wax in the PCM unit with a higher inlet HTF temperature is always higher than that with a lower inlet HTF temperature at the same time. The total charging time is reduced by 62.38% and the average charging rate is increased by 16... [more]

In the bottom ash (BA) of municipal solid waste incineration, the content of iron and aluminum is relatively high. The efficiency of eddy current extraction of non-ferrous metals (including aluminium) routinely used in incineration plants is limited. The determination of the form of occurrence of aluminium or aluminium-rich components in BA is important in terms of its recovery or utilisation. BA from a newly built incineration plant in Poland was analysed using chemical analysis, X-ray diffraction, optical microscopy, and scanning electron microscopy with chemical microanalysis. Samples of water-quenched BA were analysed. For comparison, a non-quenched sample (collected above a water tank) was analysed. The obtained results indicate that aluminium-rich components in BA are present in both the melt phase and quench phase. In the melt phase (glassy material), the content of aluminium is low (usually below 2 wt%). Aluminium-rich components present in glass, inherited after aluminium prod... [more]

Due to there is no better way to exploit depleted gas reservoirs, and hydrogen can generate from natural gas combustion. In this paper, the possibility of in-situ hydrogen generation in air injected gas reservoirs was determined through pseudo dynamic experiments. The study indicated that higher temperature and steam/methane ratio can generate more hydrogen, and the temperature should not be lower than 600 °C within gas reservoirs. The debris has positive catalysis for hydrogen generation. The maximum mole fraction of hydrogen was 26.63% at 600 °C.

The equilibrium concentration space of the Ag−In−Te system in the part AgInTe2−Te−In2Te3 was studied through the modified solid-state electromotive force (EMF) method by dividing In2Te3−In2Te5−Ag3In97Te147 (I), In2Te5−Te−Ag3In97Te147 (II), Ag3In97Te147−Te−AgIn5Te8 (III), AgIn5Te8−Te−AgIn3Te5 (IV), and AgIn3Te5−Te−AgInTe2 (V), into separate phase regions at T ≤ 500 K. The formation of a thermodynamically stable combination of the binary and ternary phases in the (I)−(V) phase regions from a metastable phase mixture of substances was carried out at T ≤ 500 K in the R(Ag+) part of the positive electrode (PE) of the galvanic cells (GCs) of the structure: (−) C |∙| Ag |∙| SE |∙| R(Ag+) |∙| PE |∙| C (+), where C is the graphite (inert electrode), SE is the solid-state electrolyte (Ag3GeS3Br glass), and Ag is the left (negative) electrode. The Ag+ ions in the R(Ag+) region functioned as small nucleation centers for the formation of the stable phases. The spatial position of the (I)−(V) phase... [more]

A novel hammer-impact-driven power generator that uses a buzzer-type piezoelectric energy converter (BPEC) for wind-power-generator applications was designed, and the dynamic motions and output characteristics were analyzed. As the active material, Sm0.025-Pb0.9625[(Mg1/3Nb2/3)0.71Ti0.29]O3 (Sm-PMN-PT)ceramic was used; this material has a high piezoelectric charge constant of 1100 pC/N and an electromechanical coupling factor of 58%. A rotational impeller triggered an impact between one end of the bar-type hammer, and, thereby, impact energy transferred to the BPECs. The manufactured power generator was tested from 50 RPM to 250 RPM, using the handmade evaluation system; it was able to operate with small impact force and greatly improved output performance as rotation speed increased. The maximum output of the generator was 10.4 W at a load resistance of 500 Ω and rotation speed of 250 RPM. For improvement of the output characteristics, the generators were arranged such that they could... [more]

A potential method of storing and transporting hydrogen safely in a cost-effective and practical way involves the utilization of molecules that contain hydrogen in their structure such as ammonia. Because of its high hydrogen content and carbon-free molecular structure, as well as the maturity of related technology (easy liquefaction), ammonia has gained attention as a “hydrogen carrier” for the generation of energy. Unfortunately, hydrogen production from ammonia requires an efficient catalyst to achieve high conversion at low reaction temperatures. Recently, very attractive results have been obtained with low-surface-area materials. This review paper is focused on summarizing and comparing recent advances in novel, economic and active catalysts for this reaction, paying particular attention to materials with low surface area such as silicon carbide (SiC) and perovskites (ABO3 structure). The effects of the supports, the active phase and the addition of promoters in such low-porosity... [more]

Gasification is a promising thermochemical technology used to convert waste materials into energy with the introduction of low amounts of an oxidant agent, therefore producing an environmental impact that is lower when compared to incineration and landfilling. Moreover, gasification allows a sustainable management of wastes and reduces the use of fossil fuels responsible for the increment of greenhouse gases. This work aimed to perform gasification tests with solid recovered fuels (SRF) containing organic fractions mainly retrieved from construction and demolition wastes to assess the potential for energy conversion. Tests were conducted in a pilot-scale downdraft gasifier (maximum feedstock input of 22 kg/h) at c.a. 800 °C, using SRF samples containing different proportions of polymeric wastes ranging between 0 and 20 wt %. Gas and chars obtained as by-products were analysed to evaluate their properties and to establish valid pathways for their valorisation. The addition of polymeric... [more]

In recent years, the rapid consumption of fossil fuels has brought about the energy crisis and excess CO2 emission, causing a series of environmental problems. Photocatalytic CO2 reduction technology can realize CO2 emission reduction and fuel regeneration, which alleviates the energy crisis and environmental problems. As the most widely used LDH material in commercial application, MgAl-layered double hydroxide (MgAl-LDH) already dominates large-scale production lines and has the potential to be popularized in CO2 photoreduction. The adjustable component, excellent CO2 adsorption performance, and unique layer structure of MgAl-LDH bring specific advantages in CO2 photoreduction. This review briefly introduces the theory and reaction process of CO2 photocatalytic reduction, and summarizes the features and drawbacks of MgAl-LDH. The modification strategies to overcome the drawbacks and improve photocatalytic activity for MgAl-LDH are elaborated in detail and the development perspectives... [more]

The paper reports on research focused on the use of largely available carbonaceous materials, such as graphite, carbon black and chars, as thermoelectric materials for micro-generation at high temperature. The key feature is the possibility to ignite the thermoelectric device to self-sustain electric generation. The results of the tests performed with such materials, under both cold and hot conditions, showed that a significant change of the electromotive force, with absolute increase up to three orders of magnitude, occurred under hot conditions with flame irradiation, achieving measured values of electromotive force up to 55 mV, in the best case. Monoliths based on biomass chars and covered with a layer of gunpowder gave rise to similar variation of the Seebeck coefficient, as the case of the flame exposed samples. This result confirms the basic idea of the investigation and the possibility of generating an electrical peak in a self-sufficient combustion thermoelectric device with po... [more]

Seeking effective energy technology has become a herculean task in today’s world. Sodium-ion batteries play a vital role in the present energy tech market due to their entrancing electrochemical properties and this work is a breakthrough for developing sodium-ion batteries. As per recent reports, the preparation of anode materials seems to be very tedious in the realm of sodium-ion batteries. To remedy these issues, this work enlightens the preparation of hard carbon (HC) derived from coconut sheath (CS) by a pyrolysis process with different activating agents (KOH, NaOH, ZnCl2) and employed as an anode material for Sodium-ion batteries (SIBs). The prepared anode material was characterized for its thermal, structural, functional, morphological, and electrochemical properties. Additionally, the surface area and pore diameter of the as-prepared anode material was studied by nitrogen adsorption and desorption isotherm methods. The coconut sheath-derived hard carbon (CSHC) anode material de... [more]

The Opole Power Plant is part of the PGE group (Polish Energy Group), the largest power company in Poland. It produces electricity from coal combustion, which means that ESG (environmental, social and corporate governance) policy should be one of the power plant’s strategic priorities. The article focuses on evaluating the ESG activities implemented by the power plant and their relation to the standards set at the corporation. The article’s primary hypothesis is that ESG activities are a significant element of the power plant’s strategy, with most of them determined by policies undertaken at the level of the PGE Group as a whole. The secondary hypotheses assume that trade union representatives attach greater importance (than management) to the social elements of ESG (H2) and that individual management representatives rate higher regarding the importance of those ESG areas for which they are personally responsible (H3). The research method used in the article consists of interviews cond... [more]

In this paper, an analysis of electromagnetic−mechanical characteristics according to the shaft materials of a permanent magnet synchronous motor was performed. In general, the shaft of an electric motor rotating at high speed uses various materials, considering the mechanical rigidity and electromagnetic characteristics. However, because the material of the shaft has a significant influence on the electromagnetic performance according to the characteristics of the non-magnetic and magnetic materials, electromagnetic characteristics analysis was performed according to the material of the shaft. In addition, because the machine rotating at a high speed entails mechanical problems owing to the centrifugal force, the mechanical stability was secured through critical speed characteristic analysis according to each material after performing the von Mises stress analysis of the permanent magnet and sleeve.

Due to the unclear seepage mechanism for shale oil, it is hard to establish a reasonable mathematical model to describe the flowing law. In this study, a real shale pore structure was reconstructed with CT scanning and a numerical model of fluid flowing in the real shale pore is developed with COMSOL, based on the boundary slip at the micro-nano pore scale to study the causes of nonlinear seepage. A two-fluid model is employed to establish a simple mathematical model to describe the relationship between the flow rate and the pressure gradient using the effective slip length to account for the influence of pore structure and true slip, and the established model is verified with experimental data coming from Jiyang shale oil. The results indicated that the pore structure greatly affected the shape of the seepage curve. With the increase in displacement pressure, the percentage of fluid involved in the flow increased until it became stable, showing a changing trend from nonlinearity to li... [more]

In this study, the impact of NaOH on the hydrothermal oxidation of guaiacol was investigated. It was found that NaOH significantly accelerated the production of formic acid and acetic acid with H2O2 or CuO as the oxidant. With the strong oxidant, H2O2, the highest acetic acid yield (15.73%) and formic acid (5.64%) were obtained at 300 °C for 90 s with NaOH 1.0 mol·L−1 and a 100% H2O2 oxygen supply. In comparison, with CuO as the oxidant, the highest values of acetic acid (13.42%) and formic acid (4.21%) were acquired at 250 °C for 6 h with NaOH 1.0 mol·L−1. Formic acid and acetic acid were generated through the oxidation of intermediates, such as levulinic acid, fumaric acid, maleic acid, etc. These results demonstrated that NaOH catalytic hydrothermal oxidation has potential for the production of value-added chemicals from biomass materials. When CuO is used as the oxidant, this process could also be used as a green method for copper smelting along with the utilization of lignin bioma... [more]

This communication discusses the energy, exergy, and economic feasibility of novel heat storage based on a single-slope solar still coupled with a solar air heater (SAH). The analysis was conducted on three different solar stills, i.e., a single-slope solar still (SSSS), single-slope solar still with latent heat storage, and a single-slope solar still with latent heat storage coupled with a solar air heater. The performance evaluation of all types of solar still has been compared to evaluate the best-performing solar still. Paraffin wax as a phase change material (PCM) has been used at the bottom of the solar still to provide proper thermal storage. The experiments were conducted on different depths, i.e., 3 cm, 6 cm, 9 cm, 12 cm, and 15 cm. The efficiency of a single-slope solar still with PCM and SAH was 65.58% higher than a conventional solar still. The average exergy efficiency of a single-slope solar still with latent heat storage coupled with a solar air heater is 83.19% higher t... [more]

The accident-tolerant fuel concept involves replacing the conventional cladding system (zirconium) with a new material or coating that has specific thermomechanical properties. The aim of this study is to evaluate the neutronics performance of a chromium coating concept and design solutions. A Zircaloy−uranium fuel system (Zr−U) is currently used as a standard fuel system in pressurized water reactors around the world. This investigation presents the benefits of utilizing an alternative cladding material such as chromium coating and the effects on the thermal neutron parameters of the way in which the chromium coating is introduced in the reactor fuel. Among these significant benefits is an increase in the reactor fuel’s thermal conductivity, which improves reactor safety. Two types of fuel-cladding systems were investigated: Zircaloy−uranium (Zr−U) and Zircaloy−chromium (Zr−Cr−U) coating fuel systems. Neutronics analysis evaluations were performed for the selected fuel assemblies and... [more]

Alternating current (AC) copper losses in motors increase with carrier frequency of the pulse width modulation (PWM) and are further increased by leakage flux of the permanent magnet. Therefore, AC copper losses increase with motor speed. Conventional techniques for reducing AC copper losses tend to increase other losses. In this paper, AC copper loss was reduced by wrapping a magnetic tape made of a magnetic composite material around the winding. This method controlled the flux path through the winding. Magnetic composite materials are mixtures of magnetic powders and liquid resins whose magnetic properties can be manipulated by changing the combination and other factors. When Fe−Si−Al magnetic tape was wrapped around the winding, the AC copper loss was reduced by 40%. The loss was further reduced by optimizing the magnetic properties of the magnetic composite material. The AC copper loss was maximally reduced when the specific permeability was 100 and the saturation flux density was... [more]