Lithium-ion capacitors (LICs) are a novel and promising form of energy storage device that combines the electrode materials of lithium-ion batteries with supercapacitors. They have the potential to deliver high energy density, power density, and long cycle life concurrently. Due to the good electrochemical performance of lithiated manganese-based materials in LICs, they have received extensive attention in recent years. The latest advancements in lithiated manganese-based materials as electrode materials in lithium-ion capacitors are presented here, including LiMnPO4, LiMn2O4, and Li2MnSiO4. These electrode materials have a lot of potential as high-performance energy storage materials. Apart from capacitive-type electrodes, lithiated manganese-based materials are also used in the creation of LIC battery-type electrodes. The LICs based on lithiated manganese-based electrode materials demonstrated energy density, power density, and cycle life, which are relatively comparable with various... [more]

This paper presents a novel methodology for the calculation of angular indexes of an electrical system from stationary analysis, using load flow and nose curves (P−V) in each of the buses of the system to perform control actions and preserve or improve voltage stability. The control actions are proposed considering a novel method based on the concepts of the cutset angle (CA) and center of angle (COA). The target is a fast estimation of voltage-stability margins through an appropriate angular characterization of the whole system and for each load bus with a complete network and N-1 contingency criteria. The most significant enhancement is that the angular characterization is based on the COA, which is related to the angular dynamics of the system, and indirectly reflects the inertia and the respective angles of the generator rotor, as well as the impact on the angular equivalent-system model. Simulations showed that the COA is an important index to determine the location of occurrence... [more]

The mass production of cost-effective, large area, defect-free and high crystal quality graphene sheets with a high yield is a challenging task. In order to investigate the mechanisms involved, we report on the synthesis of graphene sheets by a homemade atmospheric pressure thermal plasma jet system, which is a single-step and less time-consuming technique. The samples were prepared by using pure Ar gas and a mixture of Ar and N2. The microstructure of the synthesized graphene sheets was characterized with the help of Raman spectroscopy, field emission scanning electron microscopy (FE-SEM) and Fourier transform infrared (FTIR) spectroscopy. The appearance of G and 2D peaks in the Raman spectrum confirmed the formation of graphene. Moreover, we observed that the addition of nitrogen increased the production of the graphene sheets but compromised the quality of those graphene sheets by increasing their structural defects. The morphology of the synthesized samples studied via FE-SEM image... [more]

Wheat straw is a renewable agricultural by-product that is currently underutilized in the production of bioenergy and bioproducts due to its high ash content, as well as high transport costs due to its low volumetric energy density. The thermogravimetric analysis of this material produces derivative curves with a single broad peak, making it difficult to identify the three conventional pseudo-components (cellulose, hemicellulose, and lignin), which is resolved using the second derivative to determine inflection points. Model-fitting methods and isoconversional methods were applied to determine the degradation kinetics of wheat straw at two different particle sizes, as well as that of a reference feedstock (beech wood), and the obtained values were used to divide the degradation curves to be compared to the experimental data. Seven different pyrolysis reaction networks from the literature were given a similar treatment to determine which provides the best estimation of the actual pyroly... [more]

Conventional construction materials which rely on a fossil-based, nonrenewable extractive economy are typically associated with an entrenched linear economic approach to production. Current research indicates the clear interrelationships between the production and use of construction materials and anthropogenic climate change. This paper investigates the potential for emerging high-performance biobased construction materials, produced sustainably and/or using waste byproducts, to enable a more environmentally sustainable approach to the built environment. Life-cycle assessment (LCA) is employed to compare three wall assemblies using local biobased materials in Montreal (Canada), Nairobi (Kenya), and Accra (Ghana) vs. a traditional construction using gypsum boards and rockwool insulation. Global warming potential, nonrenewable cumulative energy demand, acidification potential, eutrophication potential, and freshwater consumption (FWC) are considered. Scenarios include options for design... [more]

In thermal conversion utilization, nitrogen-rich biomass such as waste wood-based panels will release a large amount of NO into the atmosphere, causing serious harm to the surroundings. By means of co-pyrolysis, N in waste wood-based panels can be fixed in chars instead of discharging into the atmosphere in the form of volatile matter, which can reduce NO emission and lay a foundation for the preparation of nitrogen-rich carbon materials with high added value. As the most commonly used adhesive in the production of wood-based panels, urea-formaldehyde resin adhesive (UF) is the main nitrogen source in waste wood-based panels. Therefore, the purpose of this paper is to explore the effects of glucose, ethyl maltol and 2,5-dimethyl-4-hydroxy-3(2H)-furanone (DMHF) on nitrogen migration and conversion during UF pyrolysis by adjusting the different proportions of model compounds and UF. Thermogravimetric analysis showed that ethyl maltol and DMHF had lower thermal stability and the pyrolysis... [more]

To save and better deploy waste heat, the use of a mobilized heat storage system (MHSS) with phase change enhancement means is developed. In this paper, three kinds of gradient structures (positive gradient, negative gradient, and non-gradient) are designed in the MHSS system. The uniform porosity is 94% in the non-gradient structure, and the gradient porosities are 86%, 93%, and 98% in the gradient structure, respectively. Numerical models are developed to explore the contribution of the graded metal foam structure to the heat storage and release process. An economic analysis and comparison of MHSS systems with different heat transfer models are carried out. The results show that the positive gradient case can promote the thermal cycle of the melting and solidification process, while the negative gradient case inhibits the thermal cycle. The positive gradient case can reduce the melting time by 9.7% and the solidification time by 4.4%, while the negative gradient can prolong the melti... [more]

In the current study, the performance of the npn solar cell (SC) microstructure is improved by inspecting some modifications to provide possible paths for fabrication techniques of the structure. The npn microstructure is simulated by applying a process simulator by starting with a heavily doped p-type substrate which could be based on low-cost Si wafers. After etching deep notches through the substrate and forming the emitter by n-type diffusion, an aluminum layer is deposited to form the emitter electrode with about 0.1 µm thickness; thereby, the notches are partially filled. This nearly-open-notches microstructure, using thin metal instead of filling the notch completely with Al, gives an efficiency of 15.3%, which is higher than the conventional structure by 0.8%. Moreover, as antireflection coating (ARC) techniques play a crucial role in decreasing the front surface reflectivity, we apply different ARC schemes to inspect their influence on the optical performance. The influence of... [more]

Aiming at the shortcomings of the current rock-breaking technology, a new type of high-energy expansion agent for energetic materials based on combustion-to-detonation was developed. By characterizing the basic physical and chemical properties of the high-energy expansion agent (HEEA) such as morphology, particle size distribution, and pyrolysis characteristics, the work performance of different types of high-energy expansion agents was analyzed in combination with the energy characteristics. The results showed that the relationship between the expansion work done by the gas to the outside world was WHEEA-I > WHEEA-II > WHEEA-III under the same quality of HEEA combustion. The damage effect of high-temperature and high-pressure gas cracking specimens generated by deflagration of HEEA was obvious, having the rule that the disturbance damage of rock caused by low heat and high gas specific volume was smaller, and the damage degree of rock caused by high heat and low gas specific volume wa... [more]

An original multifractal algorithm is proposed for calculating the fractal characteristics of the cluster texture of biopolymer-inorganic (BIN) composites from microphotographic images (MPIs) of their texture, which allows one to determine the quantitative dependence of the mechanical properties of biopolymer−inorganic composites on the characteristics of their cluster texture. As a result of the studies conducted on the MPI texture of the “chitosan-silicon dioxide” BIN composites using a multifractal algorithm, it was found that such important indicators as strength and plasticity can be quantitatively described using generalized fractal pixel dimensions of MPI samples of the BIN composite. It was established that when the amount of silicon dioxide in the samples of the BIN composite changes, the mechanical characteristics of the BIN composites, such as strength and plasticity, can be quantitatively described using generalized fractal pixel dimensions of the MPIs of the BIN composite... [more]

An innovative method to improve the efficiency of a single-phase electric-grid 125 kVA, 50 Hz shell type and distribution transformer is presented. The diamagnetism characteristic of a bulk high-temperature superconductor (HTS), designed in a specific dimension, is used to construct a magnetic shield around the air gaps that form between the core joints and among the coils of the transformer. Consequently, the shielded flux engages the core area and increases the flux density in the core, resulting in an increase in the output power, and hence an improved transformer efficiency. The transformer was designed and simulated using advanced electromagnetic software. Simulation results indicate that the width and thickness of the HTS material, as its precise location placed on the air gaps around the core and the coils, can be a substantial factor in generating a magnetic shield that results in an efficiency improvement, superior compared to conventional transformers. The most enhanced perfo... [more]

Gypsum-salt caprock is one of the most important caprocks in petroliferous basins around the world. Its sealing capacity extremely affects hydrocarbon accumulation and distribution. However, there are numerous variables that affect caprock sealing performance, making a quantitative evaluation challenging. The analytic hierarchy process (AHP), which has the advantage of turning several influencing factors into multi-level single objectives, can be utilized in this context to quantify the weight of each element impacting caprock sealing capacity. As a result, using the Tarim Basin’s Cambrian as an example, this article quantitatively assessed the gypsum-salt caprock sealing capacity using AHP. The results show that factors affecting the sealing capacity of Cambrian gypsum-salt caprock in the Tarim Basin can be summarized into three major categories and nine sub-categories, including the lithology (rock assemblage type and lithology zoning), the thickness (total thickness of thick single... [more]

The carboniferous carbonate reservoirs in the North Truva Oilfield have undergone complex sedimentation, diagenesis and tectonic transformation. Various reservoir spaces of pores, caves and fractures, with strong reservoir heterogeneity and diverse pore structures, have been developed. As a result, a quantitative description of the pore structure is difficult, and the accuracy of logging identification and prediction is low. These pose a lot of challenges to reservoir classification and evaluation as well as efficient development of the reservoirs. This study is based on the analysis of core, thin section, scanning electron microscope, high-pressure mercury injection and other data. Six types of petrophysical facies, PG1, PG2, PG3, PG4, PG5, and PG6, were divided according to the displacement pressure, mercury removal efficiency, and median pore-throat radius isobaric mercury parameters, combined with the shape of the capillary pressure curve. The petrophysical facies of the wells with... [more]

The global energy industry works towards an increased use of carbon-neutral biomass. Nutshell represents a regional bio-waste, i.e., a bio-energy resource. Pyrolysis is a common method for processing biomass into valuable energy products. The heat demand, however, limits pyrolysis applications. Yet, such demand may be addressed via exothermic pyrolysis reactions under selected operation conditions. Making the pyrolysis of Siberian pine nutshell autothermic comprised the objective of the study. The study involved analytical methods together with a pyrolysis experiment. The analytical methods included a thermogravimetric analysis combined with differential scanning calorimetry and an integrated gas analyzer. Thermophysical characterization was executed using a thermal diffusivity analyzer with the laser flash method. At 650 °C, pyrolytic heat was released in the amount of 1224.6 kJ/kg, exceeding the heat demand of 1179.5 kJ/kg. Pyrolysis at a lower temperature of 550 °C remained endother... [more]

Field observations of active and fossil natural geothermal fields indicate that geothermal fluids are primarily transported along dikes and fault zones. Fluid transport along dikes (commonly through fractures at their margins) is controlled by the cubic law where the volumetric flow rate depends on the aperture of the fracture in the 3rd power. Dikes (and inclined sheets) also act as heat sources for geothermal fields. In high-temperature fields in volcanoes in Iceland dikes and inclined sheets constitute 80−100% of the rock at crustal depths of 1.5−2 km. Holocene feeder-dikes are known to have increased the activity of associated geothermal fields. Fault zones transport geothermal fluids along their two main hydromechanical units, the core and the damage zone. The core is comparatively thin and primarily composed of breccia, gouge, and clay and related low-permeability porous materials. By contrast, the fault damage zone is characterised by fractures whose frequency is normally highes... [more]

The comminution of fuelwood for efficient transportation and handling exposes the material to various biological and chemical decomposition processes. The stockpiling of fuel chips can result in significant dry matter losses (DML) and consequent release of CO2 into the atmosphere. The decomposition processes could be controlled by managing the chip moisture content (MC). MC control by utilizing the self-heating of stockpiled stemwood chips together with wind-driven ventilation was tested in a practical storage experiment, using uncovered and plastic-covered piles as references. The data were analyzed with linear mixed models. The predicted DML was 2.4−3.8% during the monitoring period of 5.9 months, but no significant differences appeared between the storage treatments. The increase in the basic density of the chips decreased DML. On average 1.7−3.5% of the recoverable energy content of the chips was lost during the experiment. The predicted average decline in the MC was ca. 4−8 percen... [more]

In recent years, heat storage technology has attracted wide attention in the fields of renewable energy storage for its relatively high melting point, high heat storage capacity and economy, Na2CO3 and eutectic salt mixtures containing Na2CO3 are promising candidates in the field of solar energy storage. In this paper, a molecular dynamics (MD) simulation of Na2CO3 was conducted with the Born−Mayer potential function. The simulated solid−liquid phase change temperature is 1200 K, and the error is 5.4%. The heat capacity at constant pressure (Cp) is higher in liquid than in solid, the average Cp of solid is 1.45 J/g and that of liquid is 1.79 J/g, and the minimum error is 2.8%. The simulation results revealed the change rules of density and thermal expansion coefficient of Na2CO3 in the process of heating up, and these changes were analyzed by radial distribution functions (RDF) and angular distribution functions (ADF). Moreover, the RDF and ADF results show that the atomic spacing of N... [more]

The Shahejie Formation (Fm) in the Bohai Bay Basin is well-known for its substantial conventional resource potential and long-term history of exploration. Shale oil has been confirmed as a sustainable resource following breakthroughs in shale exploration in the first and third members of the Paleogene Shahejie Fm (Mbr1 and Mbr3) in Qikou Sag, particularly Mbr3, which has a more desirable output. However, the limited distribution of exploration wells for shale oil around the southwest of Qikou Sag calls for a comprehensive evaluation of shale oil (or gas) potential in all of Qikou Sag. Here, we clarify the shale oil (or gas) resource potential and areas favorable for exploration in Mbr3 by using a hydrocarbon generation potential model (HGPM) based on the material balance method and the principle of hydrocarbon (HC) generation dynamics. Apart from the quantified characteristics of the oil generation process of Mbr3 source rocks, the source rocks of both Mbr1 and Mbr3 were compared to in... [more]

The Cretaceous lacustrine shales of the Qingshankou Formation (K2qn) from the Songliao Basin are recognized as a potential shale oil reservoir in China. Pore structure of shale within the oil window could be significantly influenced by several factors, including mineral and organic matter (OM) compositions. For a better understanding of the factors controlling the pore structure of these shales, 15 core shales from the K2qn were subjected to low-pressure N2 adsorption measurement for both the initial and solvent extracted samples, and the relationships between shale compositions and pore structure parameters were discussed. The results show that the average specific surface area (SSA) and pore volume (PV) increase from 10.14 m2/g to 29.74 m2/g and from 0.0276 cm3/g to 0.0554 cm3/g respectively after extraction, which suggests that the nanopores in these shales could be significantly occupied by the soluble OM, especially for the pores smaller than 10 nm in size. For the extracted sampl... [more]

The purpose of this work is to describe the thermodynamic properties of bismuth in a broad scope of mechanical and thermal effects. A model of the equation of state in a closed form of the functional relationship between pressure, specific volume, and specific internal energy is developed. A new expression is proposed for the internal energy of a zero-temperature isotherm in a wide range of compression ratios, which has asymptotics to the Thomas−Fermi model with corrections. Based on the new model, an equation of state for bismuth in the region of body-centered cubic solid and liquid phases is constructed. The results of calculating the thermodynamic characteristics of these condensed phases with the new EOS are compared with the available experimental data for this metal in waves of shock compression and isentropic expansion. The parameters of shock waves in air obtained earlier by unloading shock-compressed bismuth samples are reconsidered. The newly developed equation of state can b... [more]

The solar thermochemical two-step splitting of H2O and CO2 based on metal oxide compounds is a promising path for clean and efficient generation of hydrogen and renewable synthetic fuels. The two-step process is based on the endothermic solar thermal reduction of a metal oxide releasing O2 using a high-temperature concentrated solar heat source, followed by the exothermic oxidation of the reduced oxide with H2O and/or CO2 to generate pure H2 and/or CO. This pathway relates to one of the emerging and most promising processes for solar thermochemical fuel production encompassing green H2 and the recycling/valorization of anthropogenic greenhouse gas emissions. It represents an efficient route for solar energy conversion and storage into renewable and dispatchable fuels, by directly converting the whole solar spectrum using heat delivered by concentrating systems. This eliminates the need for photocatalysts or intermediate electricity production, thus bypassing the main limitations of the... [more]

Research on the utilization of the Earth’s heat focuses mainly on effective sourcing of energy accumulated in rock mass. One of the most important parameters is thermal conductivity, which can be modified using various compositions of cement grouts. Hardened cement slurry is intended to improve thermal conductivity. It should function as a sort of extension of the rock mass to the outer diameter of heat exchanger tubes. Regardless of the thermal conductivity of the rock, high conductivity of the grout increases the energy efficiency of the BHE. Heat accumulated in the rock mass can be extracted using borehole heat exchangers (BHE), in which high thermal conductivity of cement slurry is wanted over the entire length of the exchanger. Generally, in case of deep borehole heat exchangers (DBHE), it is recommended to use two types of cement slurry, one with reduced thermal conductivity in the upper part of the exchanger and grout with increased thermal conductivity in its lower part. When c... [more]

With concerns about global warming and energy security, people are reducing fossil fuel use and turning to clean energy technologies. Mineral resources are used as materials for various energy technologies, and with the development of clean energy technologies, the demand for mineral resources will increase. China is a large country with various mineral resources, but its structural supply problem is severe. For China to reach the targets of carbon peaking before 2030 and carbon neutrality before 2060, they have set specific milestones for developing each clean energy industry; thus, the demand for mineral resources in clean energy will increase. We first summarise the mineral resources supply for China’s development of clean energy technologies. We analyse the demand for various mineral resources in specific clean energy technology sectors under the stated policies scenario and sustainable development scenario through scenario setting. Finally, we combine current domestic mineral reso... [more]

Nuclear thermal propulsion is an enabling technology for future space missions, such as crew-operated Mars missions. Nuclear thermal propulsion technology provides a performance benefit over chemical propulsion systems by operating with light propellants (e.g., hydrogen) at elevated engine chamber conditions. Therefore, nuclear thermal propulsion reactor cores exhibit high propellant velocities and elevated propellant and fuel temperatures, subsequently leading to relatively high thermal stresses and geometrical deformation. This paper details the numerical approach to solve the thermo-elastic equations, which was implemented into the recently developed ntpThermo code. In addition, this paper demonstrates the extension of the Basilisk multiphysics framework to perform full-core coupled neutronic, thermal-hydraulic, and thermo-mechanical analysis of nuclear thermal propulsion reactors. The analyses demonstrate and quantify thermo-mechanical feedback, which for the investigated cases, ac... [more]

The current work aims to study the thermal degradation of the flame retardant polyurethane aerogel (FR_PU_aerogel) through multiple milligram-scale experimental methods. A systemic methodology for measuring the reaction kinetics and thermodynamics of the thermal degradation of FR_PU_aerogel is detailed. Specifically, the thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were performed simultaneously in inert atmosphere to measure the mass loss and heat flow data, and a numerical framework called ThermaKin2Ds was used to inversely model these experimental data. First, a reaction mechanism with six first-order consecutive reactions was developed based on the inverse analysis of the TGA data. The corresponding reaction kinetics were optimized using the hill climbing optimization algorithm. Subsequently, the heat capacities of each condensed phase component and the heat of the reactions were obtained through inversely modeling the heat flow data. Furthermore, the... [more]