Including ecologic and environmental aspects in chemical engineering requires new methods for process design and optimization. In this work, a hydroformylation process of long-chain olefines is investigated. A thermomorphic multiphase system is employed that is homogeneous at reaction conditions and biphasic at lower temperatures for catalyst recycling. In an attempt to replace the toxic polar solvent N,N-dimethylformamide (DMF), ecologically benign alternatives are selected using a screening approach. Economic process optimization is conducted for DMF and two candidate solvents. It is found that one of the green candidates performs similarly well as the standard benchmark solvent DMF, without being toxic. Therefore, the candidate has the potential to replace it.

In this work we present the model of a counter-current spray column in which a triglyceride (tripalmitic triglyceride) is hydrolyzed by water and leads to fatty acid (palmitic acid) and glycerol. A finite volume model (FVM) of the column was developed to describe the reactive extraction process with a two-phase system and validated with an analytical model from the literature with the given data set encompassing six experimental runs. Global, variance-based (Sobol) sensitivity analysis allowed assessment of the sensitivity of the sweet water glycerol content in respect to liquid density, overall mass-transfer coefficient, reaction rate coefficient and the equilibrium ratio to rank them accordingly. Furthermore, parameter estimation with a differential evolution (DE) algorithm was performed to obtain among others the mass transfer, backmixing and reaction rate coefficients. The model was used to formulate and solve a process design problem regarding economic and sustainable performance.... [more]

Expired dairy products are often disposed of due to the potential health hazard they pose to living organisms. Lack of methods to recover valuable components from them are also a reason for manufactures to dispose of the expired dairy products. Milk encompasses several different components with their own functional properties that can be applied in production of food and non-food technical products. This study aims to investigate the novel approach of using liquid biphasic flotation (LBF) method for protein extraction from expired milk products and obtaining the optimal operating conditions for protein extraction. The optimized conditions were found at 80% concentration ethanol as top phase, 150 g/L dipotassium hydrogen phosphate along with 10% (w/v) milk as bottom phase, and a flotation time of 7.5 min. The protein recovery yield and separation efficiency after optimization were 94.97% and 86.289%, respectively. The experiment has been scaled up by 40 times to ensure it can be commerc... [more]

A high loading production in the manufacturing process of wheat germ (WG) drying is important for reducing the production costs. From a cost perspective, the drying performance become more effective in a batch process when the loading increases. The objective of this investigation was to evaluate the drying performance of WG with different loadings, from 2 to 9 kg, at 120 °C in a fluidized bed dryer. The moisture content, according to the American Association of Cereal Chemists (AACC) method, and the water activity using a thermal hygrometer were measured. The absolute humidity, diffusivity of moisture, and thermal efficiency were analyzed using a mathematical model. An analysis of the dehydration flux demonstrated a linear relationship between dehydration time and WG loading using a fluidized bed dryer. The kinetics of WG drying were observed with a simple exponential model used to match the experimental observation, indicating that the drying rate constant decreases with an increase... [more]

In this study, a simultaneous water extraction process for baicalin, wogonoside, and chlorogenic acid has been optimized. The effect of extraction temperature, extraction time, and liquid−solid ratio was scrutinized by single factor experiments and further analyzed by Box−Behnken design (BBD) approach using response surface methodology (RSM). The extraction yield of investigated compounds was determined by high performance liquid chromatography (HPLC). Single-factor experiments and response surface analysis results revealed that the optimized conditions are: Liquid to solid ratio 25:1 (mL/g), extraction temperature 93 °C, extraction time 2.4 h, and the extraction cycle two. Importantly, it has been noted that under the above conditions, concentrations of baicalin, wogonoside, and chlorogenic were 0.078, 0.031, and 0.013 mg/mL, respectively, and the overall desirability (OD) value was 0.76 which was higher than the non-optimized conditions and the deviation from the predicted OD value w... [more]

A solid vegetable waste stream was subjected to dilute acid (HCl) pretreatment with the goal of converting the waste into a form that is amenable to biochemical processes which could include microbial lipids, biohydrogen, and volatile organic acids production. Specifically, this study was conducted to identify the most suitable pretreatment condition that maximizes the yield or concentration of sugars while minimizing the production of compounds which are inhibitory to microbes (i.e., furfural, hydroxymethylfurfural, and organic acids). Temperatures from 50−150 °C and HCl loading from 0−7 wt % were studied to using an orthogonal central composite response surface design with eight center points. The effects of the variables under study on the resulting concentrations of sugars, organic acids, and furans were determined using the quadratic response surface model. Results indicated that the biomass used in this study contains about 5.7 wt % cellulose and 83.8 wt % hemicellulose/pectin. W... [more]

Fed-batch enzymatic hydrolysis has the potential to improve the overall process of converting cellulosic biomass into ethanol. This paper utilizes a process simulation approach to identify and quantify techno-economic differences between batch and fed-batch enzymatic hydrolysis in cellulosic ethanol production. The entire process of converting corn stover into ethanol was simulated using SuperPro Designer simulation software. The analysis was conducted for a plant capacity of 2000 metric tons of dry biomass per day. A literature review was used to identify baseline parameters for the process. The sensitivity of the ethanol production cost to changes in sugar conversion efficiency, plant capacity, biomass cost, power cost, labor cost, and enzyme cost was evaluated using the process simulation. For the base scenario, the ethanol unit production cost was approximately $0.10/gallon lower for fed-batch hydrolysis. The greatest differences were seen in facilities costs, labor costs, and capi... [more]

The enzyme-assisted aqueous extraction process (EAEP) is an environmentally friendly strategy that simultaneously extracts oil and protein from several food matrices. The aim of this study was to investigate the effects of pH (6.5−9.5), temperature (45−55 °C), solids-to-liquid ratio (SLR) (1:12−1:8), and amount of enzyme (0.5−1.0%) on the extraction and separation of oil and protein from almond flour using a fractional factorial design. Oil and protein extraction yields from 61 to 75% and 64 to 79% were achieved, respectively. Experimental conditions resulting in higher extractability were subsequently replicated for validation of the observed effects. Oil and protein extraction yields of 75 and 72% were achieved under optimized extraction conditions (pH 9.0, 50 °C, 1:10 SLR, 0.5% (w/w) of enzyme, 60 min). Although the use of enzyme during the extraction did not lead to significant increase in extraction yields, it did impact the extracted protein functionality. The use of enzyme and a... [more]

The blank’s dimensions are an important focus of blank design as they largely determine the energy consumption and cost of manufacturing and further processing the blank. To achieve energy saving and low cost during the optimization of blank dimensions design, we established energy consumption and cost objectives in the manufacturing and further processing of blanks by optimizing the parameters. As objectives, we selected the blank’s production and further processing parameters as optimization variables to minimize energy consumption and cost, then set up a multi-objective optimization model. The optimal blank dimension was back calculated using the parameters of the minimum processing energy consumption and minimum cost state, and the model was optimized using the non-dominated genetic algorithm-II (NSGA-II). The effect of designing blank dimension in saving energy and costs is obvious compared with the existing methods.

Corn husks are an important byproduct of the corn processing industry. Although they are a rich source of bioactive compounds, especially flavonoids, corn husks are usually disposed of or used as animal feed. In this paper, we investigate their recovery by an enzyme-assisted extraction process consisting of a pretreatment of the plant material with cellulase followed by solvent extraction with aqueous ethanol. A four-factor, three-level Box−Behnken design combined with the response surface methodology was used to optimize the enzyme dosage (0.3−0.5 g/100 g), incubation time (1.5−2.5 h), liquid-to-solid ratio (30−40 mL g−1) and ethanol concentration in the solvent (60−80% v/v). Under the optimal conditions, about 1.3 g of total flavonoids per 100 g of dry waste were recovered. A statistical analysis of the results was performed to provide a quantitative estimation of the influence of the four factors, alone or in combination, on the extraction yields. Overall, the results from this stud... [more]

Palm kernel meal (PKM) is one of the main byproducts of the oil palm industry. PKM can be obtained as the result of solvent or mechanical extraction of palm kernel oil; in both cases, meal has a remaining oil content that could be recovered. In this work, PKM coming from a mechanical pressing extraction system with an initial oil content between 7 to 8% (wt.) was treated with subcritical water in a batch stirred reactor. To find the proper operational conditions, a three-step experimental process was performed. Extraction temperature, reaction time, particle size and alkaline catalyst usage were selected as process factors. After subcritical extraction, the system was cooled down and depressurized; then oil phase was separated by centrifugation. After extraction, meal was oven-dried at 80 °C. A maximum recovery of 0.034 kg-oil/kg-meal was obtained at 423 K, 720 s and particles smaller than 0.001 m. The experimental procedure showed consistent extraction yields of 40% without modifying... [more]

In the present work, the sludge treatment performance of a sludge treatment using a rotor-stator type hydrodynamic cavitation reactor (HCR) was investigated. To verify the performance, a comparison with an ultrasonic bath was conducted in four experimental cases using three assessment factors. The HCR consisted of a rotor and three covers with inserted dimples resulting in variation of the cross-sectional area in a flow. The experimental cases were established using the same energy consumption for each device. Disintegration performance was analyzed with assessment factors using particle size distribution and sludge volume index (SVI), oxidation performance using total chemical oxygen demand (TCOD) and volatile suspended solids (VSS) reduction rate, as well as solubilization rate using soluble chemical oxygen demand (SCOD). As a result, the particle disintegration and oxidation performance of the HCR were generally superior to those of the ultrasonic bath. However, due to the contradic... [more]

In this study, the continuous Single-Pass Tangential Flow Filtration (SPTFF) concept is adapted for high protein concentrations. The work is based on the previously validated physico-chemical model for low concentrations and high viscosities. The model contains the Stagnant Film Model for concentration polarization, as well as the Boundary Layer Model for the mass transfer through the membrane. The pressure drop is calculated as a function of the Reynolds number. By performing preliminary experiments with a single ultrafiltration (UF) cassette, the model parameter are determined. The presented model is validated for a multi-step Single-Pass Tangential Flow Filtration. With subsequent simulation studies, an optimized process is found and confirmed by experiments. The outcome of this work shows the potential to optimize this multi-parameter dependent unit operation. This is reached by a model-based optimization allowing significant reduction of experimental efforts and applying the Quali... [more]

This study of process heat source change in industrial conditions has been developed to aid engineers and energy managers with working towards sustainable production. It allows for an objective assessment from energetic, environmental, and economic points of view, thereby filling the gap in the systematic approach to this problem. This novel site-wide approach substantially broadens the traditional approach, which is based mostly on “cheaper” and “cleaner” process heat sources’ application and only takes into account local changes, while neglecting the synergic effect on the whole facility’s operations. The mathematical model employed assesses the performance change of all the affected refinery parts. The four proposed aromatic splitting process layouts, serving as a case study, indicate feasible heat and condensate conservation possibilities. Although the estimated investment needed for the most viable layout is over €4.5 million, its implementation could generate benefits of €0.5−1.5... [more]

A general pattern, which can include different types of permanent magnet (PM) arrangement in PM synchronous motors (PMSMs) is presented. By varying the geometric parameters of the general pattern, the template can automatically produce different types of PM arrangement in the rotor. By choosing the best arrangement of PMs using optimization method, one can obtain a better performance and lower manufacturing cost. Six of the most widely used conventional types of rotor structures can be obtained through the parameter variation of the general pattern. These types include five embedded PM types and a traditional surface-mounted PM type. The proposed approach combines optimization method embedded with finite element method (FEM) for solving the multi-objective optimization for the PM structures. To save computing load, this paper employs a strategy of sub-group optimization, which is on account of the impact levels of the design parameters on the objective functions, and a parallel computa... [more]

A pump-driven actuator, which usually called an electro-hydrostatic actuator (EHA), is widely used in aerospace and industrial applications. It is interesting to optimize both its static and dynamic performances, such as weight, energy consumption, rise time, and dynamic stiffness, in the design phase. It is difficult to decide the parameters, due to the high number of objectives to be taken into consideration simultaneously. This paper proposes a simulation-based multi-objective optimization (MOO) design method for EHA with AMESim and a python script The model of an EHA driving a flight control surface is carried out by AMESim. The python script generates design parameters by using an intelligent search method and transfers them to the AMESim model. Then, the script can run a simulation of the AMESim model with a pre-set motion and load scenario of the control surface. The python script can also obtain the results when the simulation is finished, which can then be used to evaluate per... [more]

A mathematical model of a continuous moving-bed temperature-swing adsorption (MBTSA) process for post-combustion CO₂ capture in a coal-fired power plant context has been developed. Process simulations have been done using single component isotherms and measured gas diffusion parameters of an activated carbon adsorbent. While a simple process configuration with no gas re-circulation gives quite low capture rate and CO₂ purity, 86% and 65%, respectively, more advanced process configurations where some of the captured gas is recirculated to the incoming flue gas drastically increase both the capture rate and CO₂ purity, the best configuration reaching capture rate of 86% and CO₂ purity of 98%. Further improvements can be achieved by using adsorbents with higher CO₂/N₂ selectivity and/or higher temperature of the regeneration section.

This paper proposes a design methodology for a power split type plug-in hybrid electric vehicle (PHEV) by considering drivetrain losses. Selecting the input split type PHEV with a single planetary gear as the reference topology, the locations of the engine, motor and generators (MGs), on the speed lever were determined by using the mechanical point considering the system efficiency. Based on the reference topology, feasible candidates were selected by considering the operation conditions of the engine, MG1, and a redundant element. To evaluate the fuel economy of the selected candidates, the loss models of the power electronic system and drivetrain components were obtained from the mathematical governing equation and the experimental results. Based on the component loss model, a comparative analysis was performed using a dynamic programming approach under the presence or absence of the drivetrain losses. It was found that the selection of the operating mode and the operation time of ea... [more]

The Organic Rankine Cycle (ORC) is widely considered as a promising technology to produce electrical power output from low-grade thermal sources. In the last decade, several power plants have been installed worldwide in the MW range. However, despite its market potential, the commercialization of ORC power plants in the kW range did not reach a high level of maturity, for several reasons. Firstly, the specific price is still too high to offer an attractive payback period, and secondly, potential costumers for small-scale ORCs are typically SMEs (Small-Medium Enterprises), generally less aware of the potential savings this technology could lead to. When it comes to small-scale plants, additional design issues arise that still limit the widespread availability of the technology. This review paper presents the state of the art of the technology, from a technical and economic perspective. Working fluid selection and expander design are illustrated in detail, as they represent the bottlenec... [more]

Biomass gasification is a proven technology; however, one of the major obstacles in using product syngas for electric power generation and biofuels is the removal of tar. The purpose of this research was to develop and evaluate effectiveness of tar removal methods by cooling the syngas and using wood shavings as filtering media. The performance of the wood shavings filter equipped with an oil bubbler and heat exchanger as cooling systems was tested using tar-laden syngas generated from a 20-kW downdraft gasifier. The tar reduction efficiencies of wood shavings filter, wood shavings filter with heat exchanger, and wood shavings filter with oil bubbler were 10%, 61%, and 97%, respectively.

A conductive direct-write process of multilayered coils for micro electromagnetic generators is proposed. This novel approach of using silver ink to form the conductive structures largely reduces the fabrication complexity, and it provides a faster alternative to the conventional semiconductor methods. Multi-layered coils with insulation were accurately layered on a micromachined cantilevered diaphragm by a dispenser. Coils several layers thick could be used to increase the power output and double coils were separated by a layer of insulation. Six prototypes, all capable of efficient conversion of vibrational energy into electrical energy, were fabricated. The experimental results, which include measurements of the electromotive force and power output, are presented. Prototypes with two coils and thicker conducting layers had less resistance and the power output was much more than that of a single-coil unit. This generator can produce 82 nW of power at a resonance frequency of 275 Hz u... [more]

Investigation into clean energies has been focused on finding an alternative to fossil fuels in order to reduce global warming while at the same time satisfying the world’s energy needs. Biomass gasification is seen as a promising thermochemical conversion technology as it allows useful gaseous products to be obtained from low-energy-density solid fuels. Air⁻steam mixtures are the most commonly used gasification agents. The gasification performances of several biomass samples and their mixtures were compared. One softwood (pine) and one hardwood (chestnut), their torrefied counterparts, and other Spanish-based biomass wastes such as almond shell, olive stone, grape and olive pomaces or cocoa shell were tested, and their behaviors at several different stoichiometric ratios (SR) and steam/air ratios (S/A) were compared. The optimum SR was found to be in the 0.2⁻0.3 range for S/A = 75/25. At these conditions a syngas stream with 35% of H₂ + CO and a gas yield of 2 L gas/g fuel were obtain... [more]

The high efficiency performance of the Edinburgh Duck wave energy converter (WEC) in 2D regular wave tests makes it a promising wave energy conversion scheme. A solo Duck WEC will be able to apply the point absorber effect to further enhance its performance. Since released degree of freedom will decrease the efficiency, a Duck WEC with fixed pitching axis will be a better option. However, for fixed supported WECs, tide is a non-ignorable consideration. In this paper, a movable mass method is utilized in the whole tidal range to not only balance the Duck to appropriate beak angles, but also follow the variation of hydrodynamic coefficients to keep cancelling the reactance of the system impedance so that complex conjugate control can be realized to optimize the power capture performance of the Duck WEC in tide. Results show that the beak angle should be adjusted to as large a value as possible so that the response amplitude of the Duck at maximum relative capture width will be reasonable... [more]

In the Republic of Korea, efficient biogas-fuelled power systems are needed to use the excess biogas that is currently burned due to a lack of suitable power technology. We examined the performance of a biogas-fuelled micro-gas turbine (MGT) system and a bottoming organic Rankine cycle (ORC). The MGT provides robust operation with low-grade biogas, and the exhaust can be used for heating the biodigester. Similarly, the bottoming ORC generates additional power output with the exhaust gas. We selected a 1000-kW MGT for four co-digestion plants with 28,000-m³ capacity. A 150-kW ORC system was selected for the MGT exhaust gas. We analysed the effects of the system size, methane concentration, and ORC operating conditions. Based on the system performance, we analysed the annual performance of the MGT with a combined heat and power (CHP) system, bottoming ORC, or both a bottoming ORC and CHP system. The annual net power outputs for each system were 7.4, 8.5, and 9.0 MWh per year, respectivel... [more]

For efficient application of solar energy, a pebble bed energy storage heating system in a solar attic is optimally designed and operated. To study the characteristics of the heating system, a numerical model for the system is presented and is validated with the experiment data in the literature. Based on the model, the influence of the envelopes of the solar house and the meteorological condition on the system performance is investigated. The results show that the envelopes, except those on the north face, with more glazed exterior surfaces can be beneficial to raise the temperature of the solar house. It is also found that outdoor temperature may have less impact on the energy storage in the system compared with solar radiation. Furthermore, through optimizing the system design and operation, solar energy can account for 56% of the energy requirement in the heating season in Xi’an (about 34° N, 108° E), which has an average altitude of 397.5 m and moderate solar irradiation. Also, th... [more]