Hydrogen adsorption measurements were taken by the weighting method using the Sartorius low-pressure microbalance. Experiments were conducted at two temperatures: 77.5 and 300 K; the adsorbent used was active carbon obtained from wood and modified with potassium hydroxide. The porous structure of the carbon prior to and after modification was evaluated based on the nitrogen adsorption and desorption data. Thus, the densimetric characteristic of active carbon was modified; porous structures were developed in the range of micro-, meso- and macropores and the volume of hydrogen adsorbed at 77.5 K showed an almost four-fold increase. Modified active carbons are found to be suitable for applications in hydrogen storage systems.

Climate neutrality is one of the greatest challenges of our century, and a decarbonised energy system is a key step towards this goal. To this end, the electricity system is expected to become more interconnected, digitalised, and flexible by engaging consumers both through microgeneration and through demand side flexibility. A successful use of these flexibility tools depends widely on the evaluation of their effects, hence the definition of methods to assess and evaluate them is essential for their implementation. In order to enable a reliable assessment of the benefits from participating in demand response, it is necessary to define a reference value (“baseline”) to allow for a fair comparison. Different methodologies have been investigated, developed, and adopted for estimating the customer baseline load. The article presents a structured overview of methods for the estimating the customer baseline load, based on a review of academic literature, existing standardisation efforts, an... [more]

We propose a mathematical model that allows us to determine the temperature field of a parallel-sided electrically conductive plate element subject to uniform non-stationary electromagnetic action. We formulate initial-boundary value problems to determine the parameters of the non-stationary electromagnetic field (NEMF) and the temperature. We develop a methodology to solve these initial-boundary value problems using the approximation of determining functions by cubic polynomials over thickness of the plate element. General solutions for the related Cauchy problems at uniform non-stationary electromagnetic action are obtained. Based on these solutions, the temporal variation of Joule’s heat and temperature in the plate element, subject to short-term induction heating by an NEMF in the mode of impulse modulating signal (MIMS), is analyzed. Temperature dependencies on the different values of electromagnetic field stress and on the different time duration were obtained. The choice of the... [more]

This paper is concerned with the airborne-laser-data-based sag estimation for wide-area transmission lines. A systematic data processing framework is established for multi-source data collected from power lines, which is applicable to various operating conditions. Subsequently, a k-means-based clustering approach is employed to handle the spatial heterogeneity and sparsity of powerline corridor data after comprehensive performance comparisons. Furthermore, a hybrid model of the catenary and XGBoost (HMCX) method is proposed for sag estimation, which improves the accuracy of sag estimation by integrating the adaptability of catenary and the sparsity awareness of XGBoost. Finally, the effectiveness of HMCX is verified by using power data from 116 actual lines.

This paper presents a new technique to mitigate the high voltage stress on the secondary gallium nitride (GaN) transistor in a high step-up flyback application. GaN devices provide a means of achieving high efficiency at hundreds (and thousands) of kHz of switching frequency. Presently however, commercially available GaN is limited to only a 650 V absolute voltage rating. Such a limitation is challenging in high step-up flyback applications due to the secondary leakage. The leakage imposes high voltage stress on the secondary GaN rectifier during its turn-off transient. Such stress may cause irreversible damage to the GaN device. A new method of leakage bypass is presented to mitigate the high voltage stress issue. The experimental results suggest that when compared to conventional secondary active clamp, a 2.3-fold reduction in overshoot voltage stress percentage is achievable with the technique. As a result, it is possible to utilize GaN as the rectifier while keeping the peak voltag... [more]

To solve the problem of rising energy use and CO2 emissions, China issued the 14th Five-Year Plan in 2020, emphasizing the need to reduce its carbon intensity and achieve a carbon emission peak before 2030. In order to estimate the future path of carbon peak in China, a novel dataset was constructed to analyze 30 provinces in China, and found that the realization of carbon peaking in 2025 requires a reduction of 1.072 million tons of carbon emissions in 2025, at which point peak carbon emissions will be 11,008.4 million tons. Due to this energy gap caused by carbon emission reduction the total amount of clean electricity has reached 3600 billion kWh. In carbon emission allowance trading, provinces with large carbon emissions, like Jiangsu and Guangdong, prefer to buy carbon allowances, while those with small carbon emissions like Shanxi and Inner Mongolia prefer to sell carbon allowances. In the energy trading market, the overall situation meets the 14th Five-Year Plan of west-east and... [more]

The services based on Unmanned Aerial Vehicles (UAVs) have started to be used in many countries but not on a large scale yet. The paper describes the present status of UAV services and a concept of a solution for large-scale deployment of safe and reliable UAV services that use the 5G network for communication with UAVs. Based on the Standards Developing Organizations and related industry fora activities, unmanned traffic and airspace regulations, especially the commonly supported concept of Unmanned Aircraft Systems Traffic Management (UTM), UAV-related communication requirements and 5G System (5GS) features, we have developed an alternative approach to the integration of UAV and 5GS. The proposed concept includes a set of enablers that can be provided by Mobile Network Operators in order to not only support but also leverage UAV services. As work on many items is still in progress, we identify a list of open issues and challenges and present them at the end of the paper with the main... [more]

Carbon peaking and neutralization in the next 20 to 40 years are significant to limit the temperature increase to well below 2 °C and avoid the negative impacts of climate change caused by the sharp increase in carbon dioxide emissions [...]

This article describes a simple cogging torque minimization procedure for interior permanent magnet synchronous machines (IPMSMs), consisting of a progressive modification of the rotor lamination geometry. This procedure can be generalized for the main topologies of PMSM, independently of the number of stator slots or the location of the permanent magnets. For this purpose, a basic IPMSM structure is analyzed by means of the FEM (finite element method) approach, and then, several other IPMSM geometries, obtained by adequately modifying the rotor lamination geometry of the basic IPMSM model without changing its stator configuration, are proposed and discussed. The trends of the cogging torque generated by each model are computed and compared. From this comparison, it is demonstrated that, by simply acting on the shape of the rotor lamination and by choosing the optimized pattern, the cogging torque components can be theoretically canceled.

Due to the high acid, oxygen and water contents of fast pyrolysis oil, it requires the improvement of its fuel properties by further upgrading, such as catalytic hydrodeoxygenation (HDO). In this study, Nb2O5 was evaluated as a support of Pd-based catalysts for HDO of fast pyrolysis oil. A Pd/SiO2 catalyst was used as a reference. Additionally, the impact of iron as a promoter in two different loadings was investigated. The activity of the synthesized catalysts was evaluated in terms of H2 uptake and composition of the upgraded products (gas phase, upgraded oil and aqueous phase) through elemental analysis, Karl Fischer titration, GC-MS/FID and 1H-NMR. In comparison to SiO2, due to its acid sites, Nb2O5 enhanced the catalyst activity towards hydrogenolysis and hydrogenation, confirmed by the increased water formation during HDO and a higher content of hydrogen and aliphatic protons in the upgraded oil. Consequently, the upgraded oil with Nb2O5 had a lower average molecular weight and w... [more]

In this study, 3D premixed turbulent ammonia-hydrogen flames in air were studied using DNS. Mixtures with 75%, 50% and 25% ammonia (by mole fraction in the fuel mixture) and equivalence ratios of 0.8, 1.0 and 1.2 were studied. The studies were conducted in a decaying turbulence field with an initial Karlovitz number of 10. The flame structure and the influence of ammonia and the equivalence ratio were first studied. It was observed that the increase in equivalence ratio smoothened out the small scale wrinkles while leading to strongly curved leading edges. Increasing the amount of hydrogen in the fuel mixtures also led to increasingly distorted flames. These effects are attributed to local increases in the equivalence ratio due to the preferential diffusion effects of hydrogen. The effects of curvature on the flame chemistry were studied by looking at fuel consumption rates and key reactions. It was observed that the highly mobile H2 and H species were responsible for differential rate... [more]

This work investigated the influence of the reaction time and catalyst-to-residual fat ratio by catalytic upgrading from pyrolysis vapors of residual fat at 400 °C and 1.0 atmosphere, on the yields of reaction products, physicochemical properties (density, kinematic viscosity, and acid value) and chemical composition of bio-oils, over a catalyst fixed-bed reactor of activated carbon pellets impregnated with 10.0 M NaOH, in semi-pilot scale. The experiments were carried out at 400 °C and 1.0 atmosphere, using a process schema consisting of a thermal cracking reactor of 2.0 L coupled to a catalyst fixed-bed reactor of 53 mL, without catalyst and using 5.0%, 7.5%, and 10.0% (wt.) activated carbon pellets impregnated with 10.0 M NaOH, in batch mode. Results show yields of bio-oil decreasing with increasing catalyst-to-tallow ratio. The GC-MS of liquid reaction products identified the presence of hydrocarbons (alkanes, alkenes, ring-containing alkanes, ring-containing alkenes, and aromatics... [more]

This paper investigates the effects of coronavirus disease 2019 (COVID-19) on the performance of arbitrage trading in the energy market using daily data covering the period between 1 January 2015 and 5 December 2021. The investigation was achieved by utilizing a parametric pairs-trading model, where pairs of energy-related securities, including futures, stocks and ETFs traded in the United States, are formed. The empirical results suggest that the out-of-sample performances of pair trading declined sharply in the face of COVID-19. Dividing the whole data sample into two sub-samples, we found that the strategy performed well before COVID-19 but yielded poor results in the pandemic era. The analysis presented in this paper could serve as a benchmark for arbitrage-based trading models in the energy market during the pandemic.

This article presents a new method for the estimation of active power losses based on a “field” approach, i.e., on the theory of the electromagnetic field and the theory of propagation of electromagnetic waves in a dielectric medium. Electromagnetic waves are assumed to transmit energy from the traction substation to electric rolling stock through the airspace of the inter-substation zone (i.e., not through the wires of the traction network) and meet electrically conductive surfaces on their way. The waves are partially reflected from the surfaces and partially penetrate them, thus creating thermal losses, the determination of which is the main task of this article. The analytical expressions for specific losses of active power are obtained by solving the system of Maxwell’s equations. Calculations of specific power losses in the catenary, rails, roofs, and bottoms of carriages and electric locomotives are performed. Power losses in carriages and electric locomotives are found to be at... [more]

In the context of smart electricity consumption, demand response is an important way to solve the problem of power supply and demand balance. Users participate in grid dispatching to obtain additional benefits, which realises a win-win situation between the grid and users. However, in actual dispatching, community users’ strong willingness to use energy leads to low enthusiasm of users to participate in demand response. Psychological research shows a direct connection between users’ herd mentality (HM) and their decision-making behavior. An optimal dispatching strategy based on user herd mentality is proposed to give full play to the active response-ability of community flexible load to participate in power grid dispatching. Considering that herd mentality is generated by the information interaction between users, by calling on some users to share the experience of successfully participating in demand response in the community information center and using the Nash social welfare functi... [more]

Utilizing sintered ore catalysts (SOC), which are used in the sintering industry for NH3-SCR denitration, is a feasible and economical way to reduce NOx emission in sintering flue gas. Therefore, in order to enhance the denitration efficiency of SOC, sintered ore modified by sulfuric acid and sulfated sintered ore catalysts (SSOC-5) were prepared. Kinetic analyses of these two catalysts for denitration were carried out in this study. On the basis of eliminating the influence of internal and external diffusion, the relationship between reactants and reaction rate was studied by a power function kinetic model. This clarified that the adsorption ability of the acid-modified catalyst for reaction gas adsorption was stronger than that of sintered ore catalysts, and the reaction rate was also accelerated. The NO, NH3 and O2 reaction orders of SOC were 1, 0.3 and 0.16 at 250~300 °C, while these values of SSOC-5 were 0.8, 0.06 and 0.09, respectively. The apparent activation energy of SOC was 8... [more]

This study analyzed factors that influence the ignition delay characteristics of n-heptane/methane-blended fuel. The effects of chemical species, exhaust gas recirculation rate, compression ratio, cool/hot flames, and combustion chamber conditions (temperature, pressure, and O2 concentration) were determined and analyzed using CHEMKIN Pro. The experiment conditions for verification were 550−1000 K at 15 bar with 50% H2/50% CH4 fuel. The main combustion reactions were confirmed through reactivity analysis and sensitivity analysis on the ignition delay time. The ignition delay time at 14.7% O2 concentration was significantly higher than that at 21% O2 concentration by more than 30%. In addition, a higher ratio of methane in the blended fuel increased the ignition delay time as a result of methane dehydrogenation, delaying the ignition of heptane.

A variety of modulation strategies for suppressing output common-mode voltage (CMV) of indirect matrix converters (IMC) have been proposed, but most of them mainly reduce the peak of CMV by 42.3%. The frequency-domain characteristics of CMV have not been deeply analyzed. In order to improve the theory of frequency-domain characteristics of output common-mode voltage of IMC, this paper proposed a common-mode frequency domain analysis of five common-mode voltage peak suppression modulation methods for IMC. The common-mode voltage spectrum corresponding to the five modulation methods is obtained by the triple Fourier series, and the variation laws of the output common-mode components of the five modulation methods under different modulation indexes are compared and analyzed. By comparing and analyzing the low-frequency amplitude characteristics and high-frequency amplitude characteristics of five modulation methods, the suppression performance of the five modulation methods is evaluated.... [more]

The existing productivity models of staged fractured horizontal wells in tight oil reservoir are mainly linear flow models based on the idealized dual-medium fracture network structure, which have a certain limitation when applied to the production prediction. Aiming at the difficulty in describing the shape of the complex fractal fracture network, a two-dimensional heterogeneous structure model of the fracture network is proposed in this paper. Considering the deformation characteristics of porous media and the characteristic of non-Darcy fluid flow, a three-zone steady-state productivity model with the combination of radial and linear flow is established. To eliminate strong nonlinear characteristics of the mathematical model, a fractional step method is employed to deduce the production formulas of staged fractured horizontal wells under infinite and finite conductivity fractures. The established productivity model is verified with the actual data of three horizontal wells in differ... [more]

As the cooling requirement and the energy prices are increasing rapidly across the world, the need to develop highly efficient cooling equipment is rising as well. Adiabatic cooling employs evaporation to pre-cool the air flowing through a closed-loop coil. This study examines various adiabatic evaporative cooling pads in terms of their pre-cooling potential and advantages over currently available technological solutions through isolating three cross-sectional metal cooling pad shapes (W, Z and Z1). The results of the study suggest that the correlation between Δt↓ and RH↑ is somewhat close in all three cases; however, a slightly higher temperature drop is observed when using a W-shaped metal sheet. Pressure drop variability was negligible under current cooling pad configurations and experimental boundary conditions. Further studies focusing on measurement continuity, longevity and boundary conditions’ variability are recommended.

Accurate short-term solar forecasting is challenging due to weather uncertainties associated with cloud movements. Typically, a solar station comprises a single prediction model irrespective of time and cloud condition, which often results in suboptimal performance. In the proposed model, different categories of cloud movement are discovered using K-medoid clustering. To ensure broader variation in cloud movements, neighboring stations were also used that were selected using a dynamic time warping (DTW)-based similarity score. Next, cluster-specific models were constructed. At the prediction time, the current weather condition is first matched with the different weather groups found through clustering, and a cluster-specific model is subsequently chosen. As a result, multiple models are dynamically used for a particular day and solar station, which improves performance over a single site-specific model. The proposed model achieved 19.74% and 59% less normalized root mean square error (... [more]

A new mathematical model was developed to predict the cylindrical effect of the membrane performance in the pressure retarded osmosis process. The cylindrical membrane transport layers (the draw side boundary and the porous membrane) were divided into very thin sublayers with constant mass transport parameters, among others with a constant radius in every sublayer. The obtained second-order differential mass balance equations were solved analytically, with constant parameters written for every sublayer. The algebraic equation system involving 2N equations was then solved for the determinant solution. It was shown that the membrane properties, water permeability (A), salt permeability (B), structural parameter (S) and the operating conditions (inlet draw side solute concentration and draw side mass transfer coefficient) affect the water flux strongly, and thus the membrane performance, due to the cylindrical effect caused by the variable surface and volume of the sublayers. This effect... [more]

The use of energy sharing models in smart grids has been widely addressed in the literature. However, feasible technical solutions that can deploy these models into reality, as well as the correct use of energy forecasts are not properly addressed. This paper proposes a simple, yet viable and feasible, solution to deploy energy management systems on the end-user-side in order to enable not only energy forecasting but also a distributed discriminatory-price auction peer-to-peer energy transaction market. This work also analyses the impact of four energy forecasting models on energy transactions: a mathematical model, a support-vector machine model, an eXtreme Gradient Boosting model, and a TabNet model. To test the proposed solution and models, the system was deployed in five small offices and three residential households, achieving a maximum of energy costs reduction of 10.89% within the community, ranging from 0.24% to 57.43% for each individual agent. The results demonstrated the pot... [more]

A corresponding-states correlation for predicting the critical heat flux (CHF) in pool boiling conditions is proposed, and only requires knowledge of physical property constants of the fluid at any fluid temperature: molar mass, critical temperature, critical pressure, and the Pitzer acentric factor. If a fourth corresponding equation of state (EoS) parameter is added, a more accurate CHF correlation is obtained and matches Kutateladze−Zuber prediction within ±10% in the reduced temperature range of 0.55−0.95. This way, CHF can be easily predicted for any reduced temperature within the range of correlation’s validity by only knowing basic properties of the fluid. Additionally, two corresponding-states correlations for determining the capillary length are proposed and also do not rely on any temperature- and pressure-dependent fluid properties. A simpler correlation only using the Pitzer acentric factor is shown to be imprecise, and a more complex correlation also accounting for the fou... [more]

Implementation of the smart transformer concept is critical for the deployment of IIoT-based smart grids. Top manufacturers of power electrics develop and adopt online monitoring systems. Such systems become part of high-voltage grid and unit transformers. However, furnace transformers are a broad category that this change does not affect yet. At the same time, adoption of diagnostic systems for furnace transformers is relevant because they are a heavy-duty application with no redundancy. Creating any such system requires a well-founded mathematical analysis of the facility’s condition, carefully selected diagnostic parameters, and setpoints thereof, which serve as the condition categories. The goal hereof was to create an expert system to detect insulation breach and its expansion as well as to evaluate the risk it poses to the system; the core mechanism is mathematical processing of trends in partial discharge (PD). We ran tests on a 26-MVA transformer installed on a ladle furnace at... [more]