The protection of human health and the environment (representing the main reason for waste management), as well as the sustainable use of natural resources, requires chemical, biological, physical and thermal treatment of wastes [...]

To study the distribution characteristics of typical pollutants in soil aggregates using different sieving methods, urban and arable soils were collected from Beijing and separated to different sizes by dry and wet sieving methods, to analyze present concentrations of inorganic chlorine and nine typical heavy metals (Cr, Mn, Co, Ni, Cu, Zn, Cd, As, and Pb). Results revealed that the distribution of wet-sieved aggregates was biased towards microaggregates (<250 μm), while the contrary result was found for the dry sieving method. Inorganic chlorine was more likely to be enriched in <53 μm fractions attained by both sieving methods. However, the content of inorganic chlorine in wet-sieved aggregates was significantly lower than in those that were dry sieved, which means the water’s effect on soluble ions was more pronounced. Heavy metals in urban soils were preferentially enriched in microaggregates no matter what kind of sieving method was applied. As for Mn and As found in agricul... [more]

We conducted molecular dynamics (MD) simulations to investigate the structural evolution of molten slag composed of wheat straw (WS) and Shenhua (SH) coal. The content of wheat straw in the slag was varied from 0 to 100 wt%. The MD results indicated a slight reduction in the sharpness of the radial-distribution-function curve of each ion−oxygen pair and a decrease in bonding strength with increasing WS content. WS introduced many metal ions to the ash system, increasing its overall activity. The number of bridging and non-bridging oxygen atoms changed upon straw addition, which affected the stability of the system. There were relatively few highly coordinated Si ions. The number of low-coordination Si was highest for a WS content of 30%, at which the density reached a minimum value. The degree of ash polymerization was analyzed by counting the number (Q) of tetrahedra with the number (n) of the bridging oxygen atoms. With increasing WS content, Q4 (tetrahedral Si) decreased, whereas Q3... [more]

Meat, fish, coffee, tea, mushroom, and spices are foods that have been acknowledged for their nutritional benefits but are also reportedly targets of fraud and tampering due to their economic value. Conventional methods often take precedence for monitoring these foods, but rapid advanced instruments employing molecular spectroscopic techniques are gradually claiming dominance due to their numerous advantages such as low cost, little to no sample preparation, and, above all, their ability to fingerprint and detect a deviation from quality. This review aims to provide a detailed overview of common molecular spectroscopic techniques and their use for agricultural and food quality management. Using multiple databases including ScienceDirect, Scopus, Web of Science, and Google Scholar, 171 research publications including research articles, review papers, and book chapters were thoroughly reviewed and discussed to highlight new trends, accomplishments, challenges, and benefits of using molec... [more]

The combination of a post-Brexit agricultural policy, the Global Methane Pledge announced during the last United Nations Climate Change Conference in Glasgow (COP26), and urgency of meeting climate goals means the UK has a unique opportunity to create an exemplar through recognition of the benefits of small-scale farm anaerobic digesters that valorise on-site wastes for renewable electricity and heat, cushioning agri-businesses against energy perturbations. To explore economic viability of farm-based biogas production, combinations of support levels, energy prices, capital cost, internal rate of return (IRR), and digestate value were analysed, employing a 550-cow dairy farm with access to other agricultural wastes. A 145 kWe system utilising 100% of CHP electricity (grid value: £0.1361 per kWh) and 70% of the heat (heating oil value: £0.055 per kWh) could achieve an IRR above 15.5% with a median electricity tariff of £0.1104 per kWh at a heat tariff from £0.0309 to £0.0873 per kWh ther... [more]

The pores in rocks are multi-scale and highly complex. Based on complex network theory, the topological properties of a sandstone flow network are studied. The results show that the sandstone pore scale network is a small-world network with an average shortest path of 5.720, and 80% of the network node degree is less than 3. This network structure can improve the security of the network and ensure the permeability of the pores under the action of external forces. In addition, nodes with appropriate degree distribution have a significant influence on permeability. Nodes with a larger degree will significantly reduce the average shortest path of the network, while nodes with a smaller degree will expand the coverage of the seepage network.

Water hyacinth (WH) is a free-floating perennial aquatic plant that is considered a pest, due to its rapid grown rate and detrimental effects on environment and human health. It is nearly impossible to control WH growth, with mechanical extraction being the most acceptable control method; nevertheless, it is costly and labor-intensive. WH lignocellulosic biomass represents a desirable feedstock for the sustainable production of liquid fuels and chemical products. In this work, optimal conditions of thermochemical pretreatment for the release of reducing sugars (RS) from WH biomass were established: 0.15 mm of particle size, 50 g of dried solid/L of H2SO4 (3% w/v) and 20 min of heating time at 121 °C. Applying this pretreatment, a conversion of 84.12% of the hemicellulose fraction in the raw WH biomass into reducing sugars (277 ± 1.40 mg RS/g DWH) was reached. The resulting pretreated biomass of WH (PBWH) was enzymatically hydrolyzed by using six enzymatic complexes (all from Novozymes)... [more]

With the continuous improvement of industrial production requirements, bearings work significantly under strong noise interference, which makes it difficult to extract fault features. Deep Learning-based approaches are promising for bearing diagnosis. They can extract fault information efficiently and conduct accurate diagnosis. However, the structure of deep learning is often determined by trial and error, which is time-consuming and lacks theoretical support. To address the above problems, an adaptive (Adaptive Depthwise Separable Dilated Convolution and multi-grained cascade forest) ADSD-gcForest fault diagnosis model is proposed in this paper. Multiscale convolution combined with convolutional attention mechanism (CBAM) concentrates on effectively extracting fault information under strong noise, and the Meta-Activate or Not (Meta-ACON) activation function is integrated to adaptively optimize the model structure according to the characteristics of input samples, then gcForest output... [more]

Fatigue, characterized by periods of exhaustion that interfere with normal activities and negatively affect quality of life, can be classified as prolonged fatigue (or short-term fatigue, SF) or chronic fatigue. Vitamin deficiency and chronic inflammation seem to be possible causes of fatigue. Due to the unavailability of effective remedies that attenuate fatigue and provide consumer satisfaction, the aim of this investigation is to assess whether a commercial food supplement consisting of pomegranate extract with known anti-inflammatory activity, B vitamins, and vitamin C can help fight SF. To this end, the chemical composition of whole fruit pomegranate dry extract was determined through a RP-UHPLC−HRMS method, which indicated the presence of ellagitannins, gallotannins, and organic and phenolic acids. In a survey of consumers of food supplements aimed at reducing fatigue, 78 subjects (21 men and 57 women) were recruited for one month to evaluate the efficacy and tolerability of this... [more]

Hydrothermal liquefaction (HTL) of biomass is establishing itself as one of the leading technologies for the conversion of virtually any type of biomass feedstock into drop-in biofuels and renewable materials. Several catalysis strategies have been proposed for this process to increase the yields of the product (biocrude) and/or to obtain a product with better properties in light of the final use. A number of different studies are available in the literature nowadays, where different catalysts are utilized within HTL including both homogeneous and heterogeneous approaches. Additionally, catalysis plays a major role in the upgrading of HTL biocrude into final products, in which field significant developments have been observed in recent times. This review has the ambition to summarize the different available information to draw an updated overall picture of catalysis applied to HTL. The different catalysis strategies are reviewed, highlighting the specific effect of each kind of catalys... [more]

This study aimed to find alternatives to sulphite as a preservative for dried fruits. Granny Smith apples were sanitised in a 200 ppm sodium chlorite solution, de-cored, peeled, and cut into slices. The sliced apples were pre-treated/dipped in a water solution containing the three weak acids, namely, ascorbic acid (AA), citric acid (CA), and potassium sorbate (PS) as well as Moringa oleifera leaf extract powder (MOLEP). A screening fractional factorial experiment consisting of five independent variables (AA, CA and PS, time and temperature and MOLEP) constrained at their upper and lower levels (AA: 0.5 to 2.0%, CA: 0.3 to 2.0%, MOLEP: 0.1 to 0.2%, time: 7 to 15 h and temperature: 57 to 70 °C) were evaluated for their effect on the colour of the dried sliced apples. An increase in the concentration of the CA significantly increased the lightness (p = 0.05) and decreased the redness (p = 0.0022) of the dried apple slices. AA and PS did not impact the lightness of the dried sliced apples.... [more]

Combinations of indigenous ingredients lacking in certain essential amino acids could be used to obtain a protein isolate with a better amino acid profile that can be used as a functional food ingredient and suitable raw material for the food industry. Functional properties and amino acid profile of Bambara groundnut and Moringa oleifera leaf protein complex and its precursors (Bambara groundnut protein isolates (BGNPI) and Moringa oleifera leaf protein isolate (MOLPI)) were evaluated. The protein, fat, ash, carbohydrate, and moisture content of the protein isolates and complex ranged from 39.42 to 63.51%, 2.19 to 11.52%, 1.60 to 7.09%, 24.07 to 51.29%, and 2.61 to 9.57%, respectively, and differed significantly (p < 0.05) from one another. The total amino acids of the protein isolates and complex were 75.11, 50.00, and 71.83 g/100 g, respectively. The protein complex is higher in threonine, phenylalanine, lysine, and leucine when compared to the FAO/WHO reference pattern. The oil a... [more]

Nowadays, Circular Economy (CE) is shifting from a nice-to-have marketing operation to a business development strategy that is central to the restoring and preservation of our natural ecosystem. However, despite motivated promotion efforts, the concrete application of this model at the micro-level is still in its infancy due to several challenges that companies face. One of these challenges is the uncertainty that businesses have in the estimation of the actual impact that adopting CE strategies can have on their activities from an environmental and economic perspective. This work aims to define a conceptual framework to be applied to the Life Cycle Extension Strategies (LCES) of products, which is meant to understand whether the application of a strategy is beneficial from an environmental and economic point of view. In order to address the identified need, a list of indicators to be exploited in the LCES performance analysis has been designed and divided into the two categories of en... [more]

Unrelated cord blood transplantation (CBT) for Diamond−Blackfan anemia (DBA), a systemic ribosomopathy affecting the disposition of conditioning agents, has resulted in outcomes inferior to those by transplantations from matched donors. We report the experience of the pharmacokinetics-guided myeloablative unrelated CBT in a DBA patient with a germline RPL11 mutation. The conditioning consisted of individualized dosing of fludarabine (based on weight and renal function with a target area under the curve (AUC) of 17.5 mg·h/L) and busulfan (based on therapeutic drug monitoring with a target AUC of 90 mg·h/L), as well as dosing and timing of thymoglobulin (based on body weight and pre-dose lymphocyte count to target pre-CBT AUC of 30.7 AU·day/mL and post-CBT AUC of 4.3 AU·day/mL, respectively). The pharmacokinetic measures resulted in a 27.5% reduction in busulfan and a 35% increase in fludarabine, as well as an over three-fold increase in thymoglobulin dosage with the start time changed t... [more]

Biochar application in the agriculture sector is a practical approach to minimize waste and maintain sustainable farming. However, the information regarding biochar application in tea cultivation is limited and especially rare in field research. In this study, a two-year biochar experiment was conducted in a tea yard subject to tea yield and soil characteristics. According to tea growth, the tea yard for the experiment was divided into weak and normal sectors. Biochar was made from tea processing waste, mainly the twigs. The results showed that biochar application increased tea production by 2.3- and 1.3-fold in the weak and normal sectors, respectively, suggesting that converting tea waste to biochar for soil amendment is beneficial to increasing tea production, particularly in the weak sector. The regression analysis on tea production and soil characteristics revealed that only soil electric conductivity (R2 = 0.6597), soil organic matter (R2 = 0.7024), and soil extractable phosphate... [more]

The effects of boric acid and ammonium sulfate on the electrochemical reduction process of Fe(II) Ni(II) were studied. A series of FeNi thin films were prepared by electrodeposition with different current density and Fe(II) concentration in solution. Linear sweep voltammetry (LSV) results show that the reduction current of Fe(II) is higher than that of Ni(II) at the same concentration of Fe(II) and Ni(II) as well as the same electrodeposition parameters. Adding H3BO3 to Fe(II) Ni(II) solution is beneficial to obtain brighter and compact coating, and adding (NH4)2SO4 is beneficial to obtain higher reduction current density. Energy dispersive X-Ray spectroscopy (EDS) results show that the current density has a significant and nonlinear effect on the Fe content in FeNi thin films. The highest Fe content is obtained at a current density of 25 A∙cm−2. SEM results show that the surface morphology of FeNi films is controlled by the content of Ni and Fe in the films. With increasing Fe content... [more]

In recent years, several high-performance nature-inspired metaheuristic algorithms have been proposed. It is important to study and compare the convergence, computational burden and statistical significance of these metaheuristics to aid future developments. This study focuses on six recent metaheuristics, namely, ant lion optimization (ALO), arithmetic optimization algorithm (AOA), dragonfly algorithm (DA), grey wolf optimizer (GWO), salp swarm algorithm (SSA) and whale optimization algorithm (WOA). Optimization of an industrial machining application is tackled in this paper. The optimal machining parameters (peak current, duty factor, wire tension and water pressure) of WEDM are predicted using the six aforementioned metaheuristics. The objective functions of the optimization study are to maximize the material removal rate (MRR) and minimize the wear ratio (WR) and surface roughness (SR). All of the current algorithms have been seen to surpass existing results, thereby indicating the... [more]

Chronic Helicobacter pylori infection produces several lesions in the human stomach, which can progress to chronic atrophic gastritis and gastric cancer. To date, there is very little information on gene expression in chronic atrophic gastritis and its relationship with progression to gastric cancer. In this study, we performed a gene expression analysis during chronic atrophic gastritis in order to identify possible biomarkers that allow an early diagnosis of gastric cancer. We studied biopsies from patients with chronic atrophic gastritis and gastric cancer. The biopsies were analyzed by a gene expression microarray and corroborated by qPCR and validated through immunohistochemistry. Our results revealed that gene expression profiles in patients with chronic atrophic gastritis showed molecular changes of the gastric mucosa, leading to gastric cancer. The gene expression profiles of CLDN1, CLDN7, OLFM4, C-MYC and MMP9 were more notable from the chronic atrophic gastritis. The gene exp... [more]

Allyl alcohol polyoxyethylene ether (APEG), hydroxyethyl methacrylate (HEMA) and styrene sodium sulfonate (SSS) were used as monomers to obtain a APEG-HEMA-SSS comb-like polymer, which was employed as the polysulfonate dispersant for pendimethalin suspensions in this paper. The comb-like polymer has an anionic polysulfonate backbone, hydrophilic APEG side chains and sulfonic acid groups, which makes the dispersant absorb easily on the surface of pendimethalin particles. The polysulfonate dispersant with good dispersion performance was screened out by orthogonal experiments. The surface tension, zeta potential, particle size and dynamic contact angle of the pendimethalin suspension with APEG-HEMA-SSS as dispersant were investigated. The dispersant improves the dispersibility and wettability of the pendimethalin suspension observably.

The cloud energy storage system (CES) is a shared distributed energy storage resource. The random disordered charging and discharging of large-scale distributed energy storage equipment has a great impact on the power grid. This paper solves two problems. On one hand, to present detailed plans for designing an orderly controlled CES system in a realistic power system. On the other hand, Monte Carlo simulation (MCS) is used for analyzing the load curves of five types of distributed energy storage systems to manage and operate the CES system. A method of its planning and the principles of CES for applied in a power grid, are presented by analyzing the impact based on five load curves including the electric vehicle (EV), the ice storage system, the demand response, the heat storage system, and the decentralized electrochemical energy storage system. The MCS simulates the random charging and discharging of the system over a five-year planned scaling of distributed energy storage from 2021... [more]

A new type of high elastic polyurea protective coating reinforced by nano silica is prepared by filler composite in order to avoid both the leakage of fluorine chemical pipelines containing highly toxic and dangerous media as well as the damage to fluorine chemical pipelines under impact loads. The aim is to improve the intrinsic safety of fluorine chemical pipelines and ensure the safety of the ecological environment, life and property. The effects of different processes and process parameters on the properties of polyurea coating were studied. The polyurea coating was blended and strengthened with nano silica modified by silane coupling agent KH-550. The suitable stirring speed, material addition sequence and nano silica concentration of the new polyurea material were put forward to prepare a new polyurea coating with excellent properties. The properties of the polyurea coating were characterized, including curing time, tensile strength, elongation at break and impact resistance. The... [more]

12Cr1MoV is commonly used for pressure pipes in thermal power plants. However, its service life has always prevented the development of such metallic materials. This experiment applies a tensile and impact experiment to investigate the metal cluster of 12Cr1MoV low-alloy and heat-resistant steel with 60,000 h service at 550 °C. Results indicate that, after 60,000 h of high-temperature exposure, the metal cluster of Cr, Mo, and V elements may gradually decrease. First, the decreasing elements will precipitate out of the solid solution. Then, the precipitated elements transform into carbides that accumulate and grow on the grain boundaries. The continuous growth of the precipitated carbide of alloy elements may also create pearlite in the cluster, which results in severe pearlite periodization and tensile fracture due to plastic, through-crystal fracture. Then, the solid solution-strengthened tissue disappears, which severely decreases the thermal strength of 12Cr1MoV low-alloy and heat-... [more]

Agricultural policies should be aimed at enhancing production per unit area and help to reduce the cultivated area. To that end, it is critical to conserve soil fertility, promote ecological agriculture, employ climate change adaptation technology, significantly enhance irrigated agriculture, and decrease agricultural production risks. Sustainable agricultural production requires optimized land usage, increased energy efficiency, reduced use of fossil fuels, and minimized environmental consequences. Energy has been used in agriculture in a dramatically increased manner, and the agri-food chain now accounts for 30% of the total global energy use. Energy analysis quantifies the amount of energy used in agricultural production, so it may be used to optimize energy consumption and boost energy efficiency, further propelling the sustainable development of agriculture. Recently, the Mongolian government has expressed concerns about how to realize food sustainability and self-sufficiency in w... [more]

Glucosinolates (GSL) (β-thioglucoside-N-hydroxy sulfates) are rich-sulfur secondary metabolites raising potential biofumigation interest due to their biological properties. Sinigrin and gluconapin are the main glucosinolates present in brown mustard seeds (Brassica juncea). These glucosinolates are very suitable for the development of phytosanitary products due to their fungicidal, bactericidal and insecticidal effects. In this work, the purification of sinigrin and gluconapin extracted from defatted mustard seeds was studied using macroporous anion exchange resins. A strongly and a weakly anionic resin were first tested according to the nature of their functional group and through their selectivity towards glucosinolates. Anion-exchange resin purification was first studied in static (batch) mode in order to determine the optimal operating conditions; it was then tested in a dynamic (continuous) mode (column) to validate the process. In static mode, the adsorption behavior and characte... [more]

The growing biopharmaceutical industry has reached a level of maturity that allows for the monitoring of numerous key variables for both process characterization and outcome predictions. Sensors were historically used in order to maintain an optimal environment within the reactor to optimize process performance. However, technological innovation has pushed towards on-line in situ continuous monitoring of quality attributes that could previously only be estimated off-line. These new sensing technologies when coupled with software models have shown promise for unique fingerprinting, smart process control, outcome improvement, and prediction. All this can be done without requiring invasive sampling or intervention on the system. In this paper, the state-of-the-art sensing technologies and their applications in the context of cell culture monitoring are reviewed with emphasis on the coming push towards industry 4.0 and smart manufacturing within the biopharmaceutical sector. Additionally,... [more]