Ventilation is becoming increasingly important to improve indoor air quality and prevent the spread of COVID-19. This study analyzed the indoor air quality of office spaces, where occupants remain for extended periods, among multi-use facilities with an increasing need for ventilation system application. A “tool for office space CO2 prediction and indoor air quality improvement recommendation” was developed. The research method was divided into four steps. Step 1: Analysis of indoor air quality characteristics in office spaces was carried out with a questionnaire survey and indoor air quality experiment. Based on the CO2 concentration, which was found to be a problem in the indoor air quality experiment in the office space, Step 2: CO2 concentration prediction tool for office spaces, which requires inputs of regional and spatial factors and architectural and equipment elements, was developed. In Step 3: Development and verification of prediction tool considering economic feasibility, t... [more]

In recent years, the dramatic increase of greenhouse gases concentration in atmosphere, especially of carbon dioxide, determined many researchers to investigate new mitigation options. Thermodynamic studies play an important role in the development of new technologies for reducing the carbon levels. In this context, our group investigated the phase behavior (vapor−liquid equilibrium (VLE), vapor−liquid−liquid equilibrium (VLLE), liquid−liquid equilibrium (LLE), upper critical endpoints (UCEPs), critical curves) of binary and ternary systems containing organic substances with different functional groups to determine their ability to dissolve carbon dioxide. This study presents our results for the phase behavior of carbon dioxide + n-butanol structural isomers binary systems at high-pressures. Liquid−vapor critical curves are measured for carbon dioxide + isobutanol and carbon dioxide + tert-butanol binary systems at pressures up to 147.3 bar, as only few scattered critical points are av... [more]

This study deals with gaseous insulation contaminated by free moving particles. Two gases were investigated: SF6 (0.45 MPa) and a CO2/O2 gas mixture (0.75 MPa). Video recordings were used to track a free particle moving between a plate and a Rogowski electrode for validation of a 1D particle motion model. The effect of fixed and free particles (4 or 8 mm, Ø 0.9 mm) on the breakdown voltage and the mean time between breakdowns was determined in a concentric set of electrodes. The value of the breakdown voltage for a free particle was between those of a particle fixed to the enclosure and the central electrode. The particle motion in the concentric case could not be observed in the experimental set-up and was therefore simulated using a 1D model. For the 4 mm free particle, the breakdown seemed to be initiated in the inter-electrode gap in CO2 and at the crossing in SF6, while for the 8 mm particle, breakdown occurred at lift-off in both gases. A parameter k describing the width of the t... [more]

The emissions of vehicles are measured in laboratories with roller-type chassis dynamometers, which simulate road driving resistances. Hub-coupled dynamometers, which are not included in the regulations for emission measurements, are commonly used for research and development purposes, for example, to assess powertrain capabilities, simulate on-road trips, and calibrate the control of individual wheels. As they do not need particular infrastructure and offer a wider range of applications, they could be a more economical alternative, especially if they could also be used for emission measurements for the type approval of vehicles. Nevertheless, the two types have not been directly compared in the literature, and, thus, their equivalency, especially regarding emission measurements, is not known. In this study, the emissions of a diesel and a gasoline plug-in vehicle were compared using the same analytical equipment and by switching only the roller and hub dynamometers. The diesel vehicle... [more]

Carbonated produced water injection (CPWI) might be considered an efficient alternative to handle the largest waste stream while enhancing the oil recovery and storing carbon dioxide (CO2) underground. This study was an attempt to get a deeper understanding of the oil recovery process through synergy between spontaneous imbibition and isothermal titration calorimetry (ITC) experiments. The results from the spontaneous imbibition experiments showed 7% to 11% additional oil recovery in comparison with plain produced water. Rock−fluid and fluid−fluid interactions, evaluated by isothermal titration calorimetry (ITC) experiments, confirmed that the CPW interactions with oil+EFB+chalk and oil+EFB systems are much more exothermic than those with plain PW in those systems. The synergy between spontaneous imbibition and ITC experiments provides an improved understanding of carbonated water injection in carbonate reservoirs.

A printed circuit heat exchanger (PCHE) is an efficient and compact heat exchanger that can work under high temperature and high pressure. For Z-shaped channel PCHEs, the corner structure could enhance heat transfer at the expense of increasing the flow resistance. In order to optimize the structural design and control the pressure loss caused by the corner, a three-dimensional numerical simulation using ICEM and Fluent is conducted to study the flow and heat transfer characteristics of carbon dioxide in a PCHE by inserting straight sections (offset distance 0.5−4 mm) or arc segments (radius of curvature 0.5−4 mm) at the zigzag corners of conventional Z-shaped channels. The overall performance of the PCHEs with different structures was compared based on the comprehensive evaluation factor. The results show that the pressure loss of the PCHE can be significantly reduced by inserting straight sections and arc segments at the zigzag corners, with the mass flow rate varying from 100 to 400... [more]

This study investigates the capability of the Southeast Mesohellenic Trough (SE MHT) sandstone formations to serve as a potential reservoir for CO2 storage in response to the emerging climate change issues by promoting environmentally friendly mineral sequestration applications. Sandstone samples, for the first time, were evaluated for their petrographic characteristics, mineral chemistry, geochemical properties, as well as their petrophysical and gas adsorption properties through tests. The sandstones were tested and classified into distinct groups. The most promising site to be considered for pilot CO2 storage testing is the Pentalofos Formation locality since its sandstones display specific mineral phases with the proper modal composition to conceivably react with injected CO2, leading to the development of newly formed and stable secondary mineral phases. The gas adsorption results are also more encouraging for sandstones from this sedimentary formation. All the measured UCS (uniax... [more]

The dry ice sublimation process of carbon dioxide (CO2) is a unique, environmentally friendly technology that can achieve a temperature of −56 °C or lower, which is a triple point of CO2 in CO2 refrigeration systems. In this study, a cyclone separator-evaporator was proposed to separate dry ice particles in an evaporator. As an initial step before introducing the cyclone separator-evaporator into an actual refrigeration system, a prototype cyclone separator-evaporator was constructed to visualize dry ice particles in a separation chamber. A high-speed camera was used to visualize the non-uniform flow of dry ice particles that repeatedly coalescence and collision in a swirl section. Consequently, the dry ice particle size and the circumferential and axial velocities of dry ice were measured. The results show that the equivalent diameter of the most abundant dry ice particles in the cyclone separation chamber is 2.0 mm. As the inner diameter of the separation section decreases, dry ice p... [more]

Understanding the phase behaviour of (CO2 + water + permanent gas) systems is critical for implementing carbon capture and storage (CCS) processes, a key technology in reducing CO2 emissions. In this paper, phase behaviour data for (H2O + N2) and (CO2 + H2O + N2) systems are reported at temperatures from 323 to 473 K and pressures up to 20 MPa. In the ternary system, the mole ratio between CO2 and N2 was 1. Experiments were conducted in a newly designed analytical apparatus that includes two syringe pumps for fluid injection, a high-pressure equilibrium vessel, heater aluminium jacket, Rolsi sampling valves and an online gas chromatograph (GC) for composition determination. A high-sensitivity pulsed discharge detector installed in the GC was used to measure the low levels of dissolved nitrogen in the aqueous phase and low water levels in the vapour phase. The experimental data were compared with the calculation based on the γ-φ and SAFT-γ Mie approaches. In the SAFT-γ Mie model, the li... [more]

An increasing amount of CO2 emissions from the household sector of Iran led us to analyze the inequality and understand the possible driving force behind the CO2 emissions. The study of inequality provides information to policy-makers to point policies in the right direction. By considering the differences in the socio-economic factors of provinces, the study aims to analyze the inequality in CO2 emissions and different kinds of energy consumption, including oil, gas and electricity, for the household sector of Iran’s provinces between 2000 and 2017. For this aim, the Theil index and Kaya factor, as a simple and common method, were considered to evaluate the inequality in both CO2 emissions and energy consumption, and determine the driving factor behind CO2 emissions. According to the results, inequality in oil and natural gas consumption were increasing, electricity was almost constant; however, CO2 emissions experienced a decreasing trend for the study period. The Theil index changed... [more]

The stringent regulations set by the International Maritime Organization on pollutant emissions combined with the rise in fuel prices have stimulated research on cleaner fuels and new propulsion systems. This study describes a new method for evaluating alternative technologies and cleaner fuels that can be utilised in the marine sector to replace heavy fuel oil and diesel engines, and thus improve their performance while lowering carbon dioxide and nitrogen oxide emissions. The proposed techno-environmental technique allows consistent evaluation of simple intercooler/reheat gas and steam combined cycles fuelled by marine diesel fuel and liquefied natural gas, instead of a two-stroke diesel engine fuelled by marine diesel fuel, as a propulsion system of a large container ship. The implementation of the enhanced combined gas and steam cycles, and combined gas and steam cycles, fuelled by liquefied natural gas, increases the engine’s efficiency by 11% as compared with that of two-stroke d... [more]

While the contribution of renewable energy technologies to the energy system is increasing, so is its level of complexity. In addition to new types of consumer systems, the future system will be characterized by volatile generation plants that will require storage technologies. Furthermore, a solid interconnected system that enables the transit of electrical energy can reduce the need for generation and storage systems. Therefore, appropriate methods are needed to analyze energy production and consumption interactions within different system constellations. Energy system models can help to understand and build these future energy systems. However, although various energy models already exist, none of them can cover all issues related to integrating renewable energy systems. The existing research gap is also reflected in the fact that current models cannot model the entire energy system for very high shares of renewable energies with high temporal resolution (15 min or 1-h steps) and hi... [more]

In the context of green energy and decarbonization, carbon dioxide storage in underground facilities, such as salt caverns, is one promising technical solution that has aroused attention. However, the thermodynamic behavior of CO2 and the geomechanical response of salt cavities have not been studied comprehensively. In this study, we proposed a thermomechanical model that integrated a salt cavity and wellbore and implemented a series of simulations for carbon dioxide storage in a salt cavern. The model was verified by gas capacity calculations using field testing data. The thermodynamic behaviors of CO2 were determined and compared to methane. The results showed that the critical point coordinates of carbon dioxide were within the storage operation conditions, a phase transition could occur, and the thermodynamic properties around the critical point varied dramatically. For a short CO2 withdrawal operation, the salt cavity remained stable, while the near-wellbore area (NWA) was prone t... [more]

Particulate mass concentration is a crucial parameter for characterising air quality. The diesel particulate filter (DPF) is the primary technology used to limit vehicle particle emissions, but it needs periodic cleaning, a process called regeneration. This study aims to assess the impact of active DPF regeneration on the performance and emissions of Euro 5 and 6 vehicles. The study examined both carbon dioxide (CO2) and pollutant (nitrogen oxides (NOx) and particle number (PN)) emissions for eight vehicles tested in the laboratory and on the road. Apart from the DPF, a wide range of emission control systems was covered in this experimental campaign, including exhaust gas recirculation (EGR), diesel oxidation catalyst (DOC), lean NOx trap (LNT) and selective catalytic reduction (SCR) catalyst, revealing the different impacts on NOx emissions. The regeneration frequency and duration were also determined and used to calculate the Ki factor, which accounts for the emissions with and witho... [more]

The NiO-MgO solid solution has been proven to be an efficient catalyst for the carbon dioxide reforming of methane (CRM). However, the challenge is still there for the facilely controlled synthesis of the single-phase solid solution with the uniform composition, and the interactions between NiO and MgO are not consistently correlated with the CRM performance. To address these issues, in this work, the complex-decomposition method was applied to regulate the chemical and structural properties of NiO-MgO catalysts via simply changing the complexing agent, calcination temperature, and Ni/Mg molar ratio. The catalysts were comparatively evaluated for CRM under severe reaction conditions of 750 °C, 0.1 MPa, CH4/CO2 = 1, and a gas hourly space velocity of 60000 mL·g−1·h−1. Irrespective of the complexing agents investigated, NiO-MgO solid solution was exclusively formed. However, the structural and reductive properties of the NiO-MgO catalysts were strongly dependent on the complexing agent,... [more]

The reaction heat of CO2 absorption by organic amines is directly related to the regenerative heat consumption of absorbers. Therefore, it is necessary to study and determine the heat of absorption reaction and heat of regeneration reaction of CO2 capture solvent before its industrial validation and application. According to the law of thermodynamics, a computer model of the heat of absorption reaction and desorption reaction is established and verified. The heat of reaction of the AEP-DPA phase transition absorption system was studied under different ratios, absorption temperatures, reaction concentrations and reaction pressures. The heat of reaction increases with concentration and decreases with pressure. The reaction heat of the AEP-DPA phase transition absorption system and MEA were compared. The optimum reaction conditions were as follows: AEP-DPA ratio 6:4, absorption temperature 40 °C. The reduction rate of absorption heat and regenerative heat of the AEP-DPA phase change absor... [more]

Carbon dioxide (CO2) storage in underwater reservoirs is a valuable method of reducing carbon emissions. Saline aquifers such as those in the South Yellow Sea Basin (SYSB), China, have great potential for geological CO2 storage. Thus, we use the recommended calculation method of USDOE and a formation volume model to determine the geological conditions for CO2 storage and estimate the CO2 storage capacity of the Cenozoic saline aquifers in the SYSB (depth: 800−3200 m). Overall, the SYSB exhibits weak fault activity and seismicity, medium and low geothermal fields, four types of source sandstone reservoir, and four sets of carbon reservoir−caprock assemblages developed from the Cenozoic strata, providing relatively good geological conditions for CO2 storage. The estimated capacity of the Cenozoic strata ranges from 39.59 Gt to 426.94 Gt (average: 155.25 Gt), indicating an extensive storage capacity that can meet the carbon sequestration needs of Shandong and Jiangsu Provinces for approxi... [more]

In the present study, energy and exergy analyses of a simple supercritical, a split supercritical and a cascade supercritical CO2 cycle are conducted. The bottoming cycles are coupled with the main two-stroke diesel engine of a 6800 TEU container ship. An economic analysis is carried out to calculate the total capital cost of these installations. The functional parameters of these cycles are optimized to minimize the electricity production cost (EPC) using a genetic algorithm. Exergo-economic and exergo-environmental analyses are conducted to calculate the cost of the exergetic streams and various exergo-environmental parameters. A parametric analysis is performed for the optimum bottoming cycle to investigate the impact of ambient conditions on the energetic, exergetic, exergo-economic and exergo-environmental key performance indicators. The theoretical results of the integrated analysis showed that the installation and operation of a waste heat recovery optimized split supercritical... [more]

Although highly developed countries are trying to diversify away from coal-based energy, many economies rely on this resource. Its consumption results in the production of carbon dioxide, which promotes global warming, necessitating its sequestration. This paper presents the sorption−dilatometric relationships of hard coal samples differing in vitrinite and inertinite content. The studies were carried out under isothermal conditions (298 K) at a free pressure drop complemented by measurements under non-isothermal conditions (298 K to 323 K). The tests were performed on an original apparatus, based on the operation of an Arduino microcontroller. For the natural porosity to be preserved and for a better representation of the behaviour of the coal−gas system, samples in the form of cuboidal blocks were used, making this apparatus unique worldwide. Based on the study, it appears that the difference in petrographic composition affects the behaviour of the coal structure, influencing differe... [more]

The production of cement accounts for 5 to 7% of carbon dioxide emissions in the world, and its broad-scale use contributes to climate imbalance. As a solution, biotechnology enables the cultivation of bacteria and fungi for the synthesis of calcium carbonate as one of the main constituents of cement. Through biomineralization, which is the initial driving force for the synthesis of compounds compatible with concrete, and crystallization, these compounds can be delivered to cracks in concrete. Microencapsulation is a method that serves as a clock to determine when crystallization is needed, which is assisted by control factors such as pH and aeration. The present review addresses possibilities of working with bioconcrete, describing the composition of Portland cement, analysis methods, deterioration, as well as environmental and energetic benefits of using such an alternative material. A discussion on carbon credits is also offered. The contents of this paper could strengthen the prosp... [more]

Reducing CO2 emissions from coal-fired power plants is an urgent global issue. Effective and precise monitoring of CO2 emissions is a prerequisite for optimizing electricity production processes and achieving such reductions. To obtain the high temporal resolution emissions status of power plants, a lot of research has been done. Currently, typical solutions are utilizing Continuous Emission Monitoring System (CEMS) to measure CO2 emissions. However, these methods are too expensive and complicated because they require the installation of a large number of devices and require periodic maintenance to obtain accurate measurements. According to this limitation, this paper attempts to provide a novel data-driven method using net power generation to achieve near-real-time monitoring. First, we study the key elements of CO2 emissions from coal-fired power plants (CFPPs) in depth and design a regression and physical variable model-based emission simulator. We then present Emission Estimation N... [more]

Nowadays, increased urbanization is visible in most European Union countries. At the same time, it can be noticed that in the studied period (2000−2018), GDP per capita increased, and CO2 emissions per capita and energy consumption per capita decreased. These trends should be assessed in an unequivocally positive way. Considering these trends, especially with regard to economic development, our research goal is to answer the following questions: is there a long-run relationship between urbanization, energy consumption, economic growth, and carbon dioxide emissions, and what roles do urbanization and energy consumption play in the concept of the environmental Kuznets curve? This study aims to contribute to this growing area of research by exploring the European Union countries in the period covering the accession of new member states from Central Europe that needs intensifying European environmental policy. In order to test cointegration, we used Pedroni and Westerlund’s panel tests. To... [more]

In this work, hydrolysis lignin with nickel compounds deposited on the surface was prepared. The resulting material was introduced into the process of carbon dioxide assisted conversion and the catalytic activity of the deposited nickel compounds in this reaction was evaluated. Use of the obtained catalytic system increases CO2 conversion by more than 30% in the temperature range 450−800 °C. After the conversion process, the material was subjected to a study using a variety of physico-chemical analysis methods (TEM, SEM-EDX, and X-ray phase analysis). Physico-chemical methods of analysis of a sample calcined at 300 °C to decompose nickel nitrate revealed NiO nanoparticles with an average particle size of 16.9 nm.

In this work, a novel ejector design concept of a swirl-bypass nozzle is proposed to improve off-design performance of CO2 two-phase ejectors. The swirl-bypass nozzle allows part of the flow to bypass into the ejector mixing chamber to generate swirl. The design of such a device is investigated using a 3D multiphase CFD model. An extensive experimental test campaign is conducted to validate the baseline homogeneous equilibrium CFD model. The model’s prediction motive mass flow rate within 2−12% error and suction mass flow rate was predicted with 3−50% error. Based on the tested ejector geometry, simulations of different ejector swirl-bypass inlets are conducted. The results show that, for the current design, total entrainment of the ejector is reduced by 2−20% with the swirl-bypass inlet. The axial position of the bypass inlet plays a primary role in the bypass inlet flow rate, and, consequently, in suction flow reduction. This is found to be due to the bypass flow blocking off the suc... [more]

This work presents a multiscale experimental and numerical investigation of CO2 foam generation, strength, and propagation during alternating injection of surfactant solution and CO2 at reservoir conditions. Evaluations were conducted at the core-scale and with a field-scale radial simulation model representing a CO2 foam field pilot injection well. The objective of the experimental work was to evaluate foam generation, strength, and propagation during unsteady-state surfactant-alternating-gas (SAG) injection. The SAG injection rapidly generated foam based upon the increased apparent viscosity compared to an identical water-alternating-gas (WAG) injection, without surfactant. The apparent foam viscosity of the SAG continually increased with each subsequent cycle, indicating continued foam generation and propagation into the core. The maximum apparent viscosity of the SAG was 146 cP, whereas the maximum apparent viscosity of the WAG was 2.4 cP. The laboratory methodology captured transi... [more]