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Records with Subject: Energy Systems
786. LAPSE:2023.34797
Micro-Grid Day-Ahead Stochastic Optimal Dispatch Considering Multiple Demand Response and Electric Vehicles
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: demand responses, electric vehicles, micro-grid, photovoltaic, uncertainty
Multiple demand responses and electric vehicles are considered, and a micro-grid day-ahead dispatch optimization model with photovoltaic is constructed based on stochastic optimization theory. Firstly, an interruptible load model based on incentive-based demand response is introduced, and a demand response mechanism for air conditioning load is constructed to implement an optimal energy consumption curve control strategy for air conditioning units. Secondly, considering the travel demand and charging/discharging rules of electric vehicles, the electric vehicle optimization model is built. Further, a stochastic optimization model of micro-grid with demand response and electric vehicles is developed because of the uncertainty of photovoltaic power output. Finally, the simulation example verifies the effectiveness of the proposed model. The simulation results show that the proposed model can effectively tackle the uncertainty of photovoltaic, as well as reduce the operating cost of micro-... [more]
787. LAPSE:2023.34795
Enhanced Gas Production from Class II Gas Hydrate Reservoirs by the Multistage Fractured Horizontal Well
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: gas production, multistage fractured horizontal well, natural gas hydrate, numerical simulation
In the two test productions that have been conducted in the hydrate reservoir test development zone in the South China Sea, the gas production capacity of single wells is low and the exploitation difficulty with the cost is too high for commercial demand economically. The low permeability of the hydrate-bearing layer (HBL) acts as the major barrier for pressure propagation during depressurization. Hydraulic fracturing by the combined depressurization is considered a promising hydrate production enhancement technology that can effectively improve the seepage state in the reservoir. In this study, to evaluate the effectiveness of the development methods association with fracturing, we established an idealized Class II hydrate reservoir and studied it using a multi-stage fractured horizontal well to assist in depressurization extraction. In order to evaluate the production enhancement effect of this method, we compared the gas production results of four methods, including single vertical... [more]
788. LAPSE:2023.34791
Performance Improvement of Grid-Integrated Doubly Fed Induction Generator under Asymmetrical and Symmetrical Faults
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: doubly fed induction generator, fault current limiter, low-voltage ride-through, point of common coupling, series grid-side converter, wind energy conversion system
The doubly fed induction generator (DFIG)-based wind energy conversion system (WECS) suffers from voltage and frequency fluctuations due to the stochastic nature of wind speed as well as nonlinear loads. Moreover, the high penetration of wind energy into the power grid is a challenge for its smooth operation. Hence, symmetrical faults are most intense, inflicting the stator winding to low voltage, disturbing the low-voltage ride-through (LVRT) functionality of a DFIG. The vector control strategy with proportional−integral (PI) controllers was used to control rotor-side converter (RSC) and grid-side converter (GSC) parameters. During a symmetrical fault, however, a series grid-side converter (SGSC) with a shunt injection transformer on the stator side was used to keep the rotor current at an acceptable level in accordance with grid code requirements (GCRs). For the validation of results, the proposed scheme of PI + SGSC is compared with PI and a combination of PI with Dynamic Impedance... [more]
789. LAPSE:2023.34787
Economic Assessment of a PV-HP System for Drying Alfalfa in The North of Spain
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: drying, economic assessment, heat pumps, photovoltaic
This paper presents an economic assessment of three drying systems (DS) with different configurations: diesel-powered (DDS), grid-powered (GDS), and photovoltaic-powered (PVDS). The third configuration, PVDS, presents important technological innovations regarding the electric configuration (stand-alone PV, without batteries or grid support) and the heat pump technology used (optimized for drying the recirculated air, which permits a reduction in the electricity consumption by more than 45% if compared to a diesel air-heater or an electric resistance). The profitability of the investment required for the installation of the three systems is proven by calculating the profitability index (PI), the internal rate of return (IRR), the payback period (PBP), and the levelized cost of energy (LCOE). All the indicators show good profitabilities for the three technologies (the PI values range from 6.78 to 10.11, the IRR values range from 24% to 37%, and the PBPs are between 3 and 4 years), but th... [more]
790. LAPSE:2023.34784
Hydrogen Production by Catalytic Supercritical Water Gasification of Black Liquor-Based Wastewater
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: black liquor, catalyst, hydrogen production, supercritical water gasification (SCWG), wastewater treatment
In this work, the wastewater obtained from the hydrothermal liquefaction of black liquor was treated and valorized for hydrogen production by supercritical water gasification (SCWG). The influence of the main process parameters on the conversion yield was studied. The experiments were conducted at three different temperatures (below and above the critical point of water): 350 °C, 450 °C and 600 °C. The results showed that by increasing the temperature from 350 °C to 600 °C, the total gas yield was highly improved (from 1.9 mol gas/kg of dried feedstock to 13.1 mol gas/kg of dried feedstock). The H2 composition was higher than that of CH4 and CO2 at 600 °C, and the HHV of the obtained gas was 61.2 MJ/kg. The total organic carbon (TOC) removal efficiency was also improved by increasing the temperature, indicating that the SCWG process could be used for both applications: (i) for wastewater treatment; (ii) for producing a high calorific gas. The experiments with the Raney-nickel catalyst... [more]
791. LAPSE:2023.34779
Development of a Photovoltaic-Based Module for Harvesting Solar Energy from Pavement: A Lab and Field Assessment
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: energy harvesting, photovoltaic energy, Renewable and Sustainable Energy, roads and highways, solar pavement
The concurrent worldwide energy crisis has become a strong incentive for researchers, governments, and industry professionals to focus on sustainable energy solutions. Consequently, pavement photovoltaic energy harvesting technologies, as one of the most common sustainable energy solutions, have recently seen a significant improvement, especially in the new innovative designs of pavement solar panels. In this study, an innovative design for a prototype energy harvesting system was proposed based on thin-film photovoltaic solar panels. In addition, the feasibility of utilizing the generated power of the proposed system to illuminate a pedestrian crosswalk to enhance the safety of an at-grade intersection was also analyzed. The designed prototype consists of a thin-film solar panel, a transparent cover to protect the solar panel, and a wooden frame to support the panel and distribute the load. Different materials for the transparent covering plates were investigated, including polycarbon... [more]
792. LAPSE:2023.34774
Evaporation and Autoignition Characteristics of JP-10 Droplets with Hyperbranched Polyester as Additive
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: droplet combustion, droplet evaporation, hyperbranched polyester, JP-10, micro-explosion
It was found in our previous work that hyperbranched polyester (HPE) can generate radicals and accelerate the chemical reactions of hydrocarbon fuels used as initiators. In this work, the evaporation and autoignition characteristics of JP-10 droplets with or without HPE were investigated using the high-speed backlight imaging technique in detail. The results indicate that the puffing and micro-explosion phenomena of HPE-blended JP-10 droplets can accelerate fuel evaporation and autoignition. When a 0.1% mass concentration of HPE was used, the droplet lifetime was reduced by 16.5% in evaporation at 850 K and 18.0% in autoignition at 900 K. A mechanism of HPE that promotes puffing and micro-explosions was proposed by analyzing droplet images of combustion and SEM images of combustion residues. Overall, this study provides a method for improving the evaporation and autoignition performance of JP-10.
793. LAPSE:2023.34769
Recent Advances in High-Temperature Steam Electrolysis with Solid Oxide Electrolysers for Green Hydrogen Production
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: hydrogen production, nuclear thermal energy, solid oxide electrolysers, solid oxide electrolytes, steam electrolysis, water electrolysis
Hydrogen is known to be the carbon-neutral alternative energy carrier with the highest energy density. Currently, more than 95% of hydrogen production technologies rely on fossil fuels, resulting in greenhouse gas emissions. Water electrolysis is one of the most widely used technologies for hydrogen generation. Nuclear power, a renewable energy source, can provide the heat needed for the process of steam electrolysis for clean hydrogen production. This review paper analyses the recent progress in hydrogen generation via high-temperature steam electrolysis through solid oxide electrolysis cells using nuclear thermal energy. Protons and oxygen-ions conducting solid oxide electrolysis processes are discussed in this paper. The scope of this review report covers a broad range, including the recent advances in material development for each component (i.e., hydrogen electrode, oxygen electrode, electrolyte, interconnect, and sealant), degradation mechanisms, and countermeasures to mitigate t... [more]
794. LAPSE:2023.34766
An Optimization Method of Steam Turbine Load Resilient Adjustment by Characterizing Dynamic Changes in Superheated Steam Energy
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: feedforward control, modeling and simulation, resilient adjustment, steam turbine, superheated steam energy
Improving the dynamic regulation ability of thermal power units is effective for realizing flexible scheduling in modern power systems. At present, the unit regulation capacity is usually reflected by the load adjustment of the main steam pressure and flow tracking ability, through the calculation of the given and real-time deviation to complete the load, and by pressure adjustment. However, although the calculation involved in this method is easy and the results are intuitive, overshoot and lag can easily occur. The main reason for this is that the process from boiler combustion to turbine works has strong hysteresis and inertia, and the feedback signal of the pressure and flow rate cannot dynamically reflect the change in boiler combustion and steam energy. According to the heat transfer process of the unit, the main steam temperature can directly reflect the energy transfer in the furnace combustion process and then reflect the changing trend of steam energy. Analyzing the changing... [more]
795. LAPSE:2023.34763
Biological Hydrogen Production from Biowaste Using Dark Fermentation, Storage and Transportation
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: biological hydrogen, biowaste, dark fermentation, storage hydrogen
Hydrogen is widely considered as the fuel of the future. Due to the challenges present during hydrogen production using conventional processes and technologies, additional methods must be considered, like the use of microorganisms. One of the most promising technologies is dark fermentation, a process where microorganisms are utilized to produce hydrogen from biomass. The paper provides a comprehensive overview of the biological processes of hydrogen production, specifically emphasizing the dark fermentation process. This kind of fermentation involves bacteria, such as Clostridium and Enterobacterium, to produce hydrogen from organic waste. Synthetic microbial consortia are also discussed for hydrogen production from different types of biomasses, including lignocellulosic biomass, which includes all biomass composed of lignin and (hemi)cellulose, sugar-rich waste waters, and others. The use of genetic engineering to improve the fermentation properties of selected microorganisms is also... [more]
796. LAPSE:2023.34753
Study of the Oxidation Characteristics and CO Production Mechanism of Low-Rank Coal Goaf
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: ambient temperature oxidation, CO production, early warning, low-rank coal, mechanism, spontaneous combustion
Affected by an insufficient understanding of oxidation characteristics and the CO production mechanism in low-rank coal goaf, the safety management of coal spontaneous combustion (CSC) faces severe challenges. In this study, in-depth research was conducted using ambient temperature oxidation (ATO), temperature-programmed, in situ FTIR experiments and DFT simulation after analyzing the oxidation scenario characteristics of low-metamorphic coal goaf. The results show the oxidation of low-rank coal goaf includes two processes of ATO in the dissipation zone and CSC in the oxidation zone. The CO production of ATO increases with a decrease in coal metamorphic degree, and the risk of CSC is influenced by ATO, with an inhibitory effect before the critical temperature, and an encouraging effect after that. The CO production mechanism of low metamorphic coal goaf from ATO to CSC is established. Before the critical temperature, CO mainly comes from the primary aldehyde functional groups, then per... [more]
797. LAPSE:2023.34752
Heat Recovery Using PCM in Decentralised Façade Ventilation
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: façade ventilation, heat exchanger, heat transfer, PCM, ventilation
A study of heat recovery in a façade ventilation unit was carried out under laboratory conditions using a climate chamber that allowed stable outdoor and indoor conditions to be simulated. The unit, equipped with a reversible fan and a chamber for the heat exchanger, controlled by an automation control system, was designed to exchange air in the room by alternating supply and exhaust cycles of specific durations. Three types of heat exchangers were tested, which were filled with different phase change materials, in order to estimate the efficiency of the façade ventilation unit in terms of its heat recovery capability. The efficiency of the unit was determined based on the temperature efficiency of heat recovery for 144 setting combinations. The best efficiency results between 73.56% and 76.29% were obtained with a solution using a heat exchanger consisting of cylinders with an external diameter of 10 mm and a wall thickness of 1 mm filled with jojoba oil in a one minute cycle. The tes... [more]
798. LAPSE:2023.34733
Total System Performance Ratio—A Systems Based Approach for Evaluating HVAC System Efficiency
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: HVAC system performance, net zero codes, performance-based codes
The prescriptive path is the most widely used approach for commercial code compliance in the United States. Though easy to implement, prescriptive approaches do not typically discriminate between minimally compliant, high-performing and poorly performing HVAC system configurations. Hence, to meet aggressive energy and carbon reduction goals, it is clear that energy codes will need to transition from prescriptive to performance-based approaches, a transition that is riddled with several challenges. This paper discusses a new HVAC system-based performance approach (HVAC System Performance) which provides a simpler solution to HVAV system evaluation compared to whole building performance, while keeping tradeoffs limited to specific building systems. The Total System Performance Ratio (TSPR) is a metric for evaluation of overall system efficiency instead of individual component efficiency, a solution which could also eventually facilitate the transition to a 100% performance-based code str... [more]
799. LAPSE:2023.34729
The Effect of Ammonia Toxicity on Methane Production of a Full-Scale Biogas Plant—An Estimation Method
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: ammonia toxicity, BMP test, methane production
Ammonia accumulation in biogas plants reactors is becoming more frequently encountered, resulting in reduced methane (CH4) production. Ammonia toxicity occurs when N-rich substrates represent a significant part of the biogas plant’s feedstock. The aim of this study was to develop an estimation method for the effect of ammonia toxicity on the CH4 production of biogas plants. Two periods where a biogas plant operated at 3200 mg·L−1 (1st period) and 4400 mg·L−1 (2nd period) of ammonium nitrogen (NH4+−N) were examined. Biomethane potentials (BMPs) of the individual substrates collected during these periods and of the mixture of substrates with the weight ratio used by the biogas plant under different ammonia levels (2000−5200 mg·L−1 NH4+−N) were determined. CH4 production calculated from the substrates’ BMPs and the quantities used of each substrate by the biogas plant was compared with actual CH4 production on-site. Biogas plant’s CH4 production was 9.9% lower in the 1st and 20.3% in the... [more]
800. LAPSE:2023.34724
Microscopic Analysis of Hydrogen Production from Methane Sono-Pyrolysis
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: hydroxyl radicals, methane, methane conversion, sono-hydrogen, sonolysis, ultrasound
The sonolysis of certain substrates in water has proved its effectiveness for the enhancement of the sonochemical production of hydrogen. In this study, the sonolysis of methane has been investigated for the first time in a single acoustic bubble (microreactor) over a frequency from 140 to 515 kHz. The obtained findings have been compared to those available in the literature. Independently of the methane dose (inside the bubble), the yield of H2 was improved especially with the decrease in wave frequency (from 515 to 140 kHz). For the driving frequencies 140, 213, 355, and 515 kHz, the production of hydrogen was maximized at 20, 15, 10, and 10% CH4, respectively. For 213 kHz, and the presence of 10% methane, the yield of hydrogen goes up by 111 fold compared to the case where the gas atmosphere is saturated only by argon. On the other hand, the highest methane conversions (~100% for 2, 5 and 7% CH4) were retrieved at 140 and 213 kHz. In terms of hydrogen formation and methane decay, th... [more]
801. LAPSE:2023.34722
A Perspective on the Overarching Role of Hydrogen, Ammonia, and Methanol Carbon-Neutral Fuels towards Net Zero Emission in the Next Three Decades
April 27, 2023 (v1)
Subject: Energy Systems
Arguably, one of the most important issues the world is facing currently is climate change. At the current rate of fossil fuel consumption, the world is heading towards extreme levels of global temperature rise if immediate actions are not taken. Transforming the current energy system from one largely based on fossil fuels to a carbon-neutral one requires unprecedented speed. Based on the current state of development, direct electrification of the future energy system alone is technically challenging and not enough, especially in hard-to-abate sectors like heavy industry, road trucking, international shipping, and aviation. This leaves a considerable demand for alternative carbon-neutral fuels such as green ammonia and hydrogen and renewable methanol. From this perspective, we discuss the overarching roles of each fuel in reaching net zero emission within the next three decades. The challenges and future directions associated with the fuels conclude the current perspective paper.
802. LAPSE:2023.34721
Enhancing Tidal Wave Predictions for the Estuary of the Nakdong River Using a Fixed-Lag Smoother
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: data assimilation, estuary, fixed-lag smoother, sensitivity analysis, tidal wave predictions
The prediction of tidal waves is essential for improving not only our understanding of the hydrological cycle at the boundary between the land and ocean but also energy production in coastal areas. As tidal waves are affected by various factors, such as astronomical, meteorological, and hydrological effects, the prediction of tidal waves in estuaries remains uncertain. In this study, we present a novel method that can be used to improve short-term tidal wave prediction using a fixed-lag smoother based on sequential data assimilation (DA). The proposed method was implemented for tidal wave predictions of the estuary of the Nakdong River. As a result, the prediction accuracy was improved by 63.9% through DA and calibration using regression. Although the accuracy of the DA diminished with the increasing forecast lead times, the 1 h lead forecast based on DA still showed a 44.4% improvement compared to the open loop without DA. Moreover, the optimal conditions for the fixed-lag smoother we... [more]
803. LAPSE:2023.34719
Effect of Eccentric Tension on the Response of Wrinkle Defects in Carbon Fiber-Reinforced Composite Laminates
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: fiber-reinforced composite laminates, fringe projection, optical–mechanical method, wrinkle defects
Composite pressure vessels (CPVs) have become the main equipment for hydrogen storage; however, the effect of defect in the laminates of CPVs is difficult to detect. In this paper, composite specimens containing wrinkle defects were investigated, and a heterogeneity model of a wrinkle defect is proposed. A three-dimensional finite element code was developed to predict the behavior of carbon fiber-reinforced composite laminates with wrinkle defects. The effect of the geometric asymmetry of clamping was distinguished from the whole response. It was found that wrinkle defects are sensitive to tension but completely insensitive to torsion and that the distortion of out-of-plane displacement is strongly dependent upon wrinkle defects. An optical−mechanical method based on fringe projection was presented to measure the response of wrinkle defects, which shows an outstanding performance on wrinkle location and deformation visualization.
804. LAPSE:2023.34717
Progress in Power-to-Gas Energy Systems
April 27, 2023 (v1)
Subject: Energy Systems
Hydrogen is expected to become a key component in the decarbonized energy systems of the future [...]
805. LAPSE:2023.34714
Determination of the Self-Ignition Behavior of the Accumulation of Sludge Dust and Sludge Pellets from the Sewage Sludge Thermal Drying Station
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: self-heating, sewage sludge, sludge dust, sludge pellets, spontaneous combustion
Sewage sludge may pose a fire risk. The safe storage of biomass waste is a challenge due to self-heating processes. This study aims to assess the propensity to spontaneously combust of sewage sludge in order to determine safe storage and transport conditions. The evaluation of spontaneous ignition hazard was assessed according to EN 15188, by the determination of the self-ignition temperature. Certain parameters assumed to affect the inclination of sewage sludge to self-ignite, including the moisture content, bulk density, elemental composition, and particle size, were discussed. The results showed the risk of self-ignition during the storage and transport of sludge dust and pellets. The usage of the smallest basket volume resulted in the highest self-ignition temperatures, which were 186 °C and 160 °C for sludge pellets and dust, respectively. The comparison of the two forms of thermally dry sludge showed, that despite sludge pellets being easier to store and handle issues, the more f... [more]
806. LAPSE:2023.34713
Does Price Distortion Affect Energy Efficiency? Evidence from Dynamic Spatial Analytics of China
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: Energy Efficiency, energy price distortion, spatial panel models
Despite market-oriented reforms, China’s energy sector is subject to energy price distortions, which are believed to be a crucial determinants of energy efficiency in China. This paper investigates the impact of energy price distortions on energy efficiency in China from the perspective of spatial correlation. Using the nonradial directional distance function approach, we first estimate the provincial-level energy efficiency in China. Paying attention to spatial correlation among the provinces of China, in stage two, we identify the determinants of energy efficiency. Our empirical results suggest that price distortions have a significant impact on energy efficiency in China. This impact holds when the cross-region effect is considered, i.e., besides its own energy price distortion, a region’s energy efficiency is also correlated to the adjacent provinces’ energy price distortions. Furthermore, we found that the levels of energy efficiencies in adjacent provinces are highly correlated.... [more]
807. LAPSE:2023.34708
Research on the HHT-Based Analysis Method of Tidal Power Generation Power Distribution Law
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: empirical mode decomposition (EMD), Hilbert-Huang Transform (HHT), intrinsic mode functions (IMF), the law of electrical energy distribution, tidal power generation
Tidal power generation technology has advanced quickly in recent years. In this study, the Hilbert-Huang transform (HHT) was used to examine the electrical energy distribution law of tidal power generation according to the time periods of days, months, and years based on observed data for tidal power generation. Our analysis summarized the tidal power generation law as follows: in the span of one day, the motor ran for 14 h before shutting off for 10 h. The frequency was 28 Hz, and the maximum voltage was 259 V. The tidal power generation swung twice a month, reaching its peak in the middle of the month and its trough at the beginning. The tidal power output fluctuated twice a year, reaching its peak in August, September, and October and its trough in February, March, and April. In the investigation of tidal power generation patterns, the HHT transformation’s precision and potency were confirmed.
808. LAPSE:2023.34704
A Modified Calculation Method for a Centered Water Nozzle Steam−Water Injector
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: calculation method, entrainment ratio, shock wave, steam–water injector
A centered water nozzle steam−water injector is driven by cold water to pump steam at a low pressure and to produce a high outlet water pressure. It can be used as a safety pump in a light water reactor to inject cooling water into the reactor core with no power supply in case of an accident. In this study, a modified calculation method for a centered water nozzle steam−water injector is proposed and verified by experimental data in the literature. The calculation method consists of a water nozzle model, a steam nozzle model, a mixing section model, and a shock wave model. Comparisons between the calculated results and the experimental results under different inlet steam pressures, inlet water pressures, and back pressures are conducted, and the calculated results show good agreement with the experimental results. The calculated results with different back pressures show that no shock wave occurs in the mixing section when the back pressure is small, but with the back pressure increasi... [more]
809. LAPSE:2023.34703
Experimental Investigations on Detonation Initiation Characteristics of a Liquid-Fueled Pulse Detonation Combustor at Different Inlet Air Temperatures
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: DDT distance, detonation initiation time, pulse detonation combustor, self-ignition, two-phase detonation
The detonation initiation characteristics of a single tube liquid-fueled pulse detonation combustor (PDC) is investigated at different inlet air temperatures in this paper. The inner diameter of the PDC is 62 mm. Gasoline and air are used as fuel and oxidant, respectively. The inlet air temperature is 288−523 K and the operating frequency of the PDC is 10~30 Hz. The experimental results show that the deflagration to detonation transition (DDT) distance, detonation initiation time, DDT time and jet ignition time decrease with the increasing operating frequency at the same inlet temperature. When the inlet temperature is 288 K, the DDT distance is shortened from 860.5 mm to 787.7 mm as the operating frequency increases from 10 Hz to 30 Hz. The detonation initiation time, the jet ignition time and the DDT time are reduced from 10.01 ms, 7.66 ms and 2.35 ms to 6.55 ms, 4.99 ms and 1.56 ms, respectively. When the inlet air temperature increases, the atomization and evaporation of the gasoli... [more]
810. LAPSE:2023.34694
A Study of Intermediate for Synthesis of Cs0.3WO3 with Near-Infrared Photothermal Response
April 27, 2023 (v1)
Subject: Energy Systems
Keywords: cesium tungsten bronze, hydrothermal, intermediate, near-infrared response, synthesis
Nanoscale tungsten bronze can convert near-infrared light into thermal energy. For a chemical synthesis, intermediate products and processes are potentially positive or negative to an end product. In this study, (NH4)2SO4 was added into the hydrothermal system of WO3, CsCl, CH3CH2CHO, and NH3·H2O to increase the Cs/W ratio in solution. An intermediate, Cs1.1W1.65O5.5, was isolated. Subsequently, it was confirmed via a kinetics experiment conducted for different times. The results of the NH3·H2O and NH4COOCH3 system indicate there are two influence factors that influence the formation of Cs1.1W1.65O5.5: the leaching out of W and imine reactions. A low leaching out rate induces a high Cs/W ratio and low-concentration W in solution, leading to the formation of Cs1.1W1.65O5.5. The imine reaction decreasing CH3CH2CHO restrains the reduction in Cs1.1W1.65O5.5. The increase in CH3CH2COO− with the reduction reaction results in both the micron-size sticks and nano-size equiaxial particles in po... [more]
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