The contamination of surface and groundwater is of major concern around the globe due to the fast industrialization and urbanization. The groundwater and water quality of rivers, Ravi and Chenab in Faisalabad, Pakistan are contaminated due to the industrial wastewater. The aim of this study was the assessment of the physiochemical contaminants of Faisalabad’s industrial wastewater area and the adsorptive removal of ions present in high concentrations following the National Environmental Quality Standards (NEQS) for the municipal and industrial liquid effluents of Pakistan. One of the two samples was collected from a drain carrying wastewater from different industries and other from the outlet of a drain discharging wastewater into river Chenab. The analysis results obtained indicate that most of the contaminants were below the acceptable limit of industrial wastewater NEQS, Pakistan. However, contaminants like sulfate ions (714 mg/L), total dissolved solids (33,951−34,620 mg/L) and bar... [more]

Mining sites that combine energy-intensive operations with community living in areas remote from the electricity grid are increasingly developing dedicated micro-grids. Fossil oil gensets hybridization with renewable energy resources has gained momentum. Difficulties in assessing performance are experienced by operators who wish to benefit from improved performances. The designers of such systems also need additional knowledge to anticipate the solutions of the particular problems related to the power plant’s implementation area characteristics. The proposed approach gives more suitable tools on the effectiveness evaluation of hybridized microgrid, combining a Heavy Fuel Oil (HFO) thermal power station with photovoltaic generator powering mine activities in the Sahelian area. The authors provide key analyses and improvement factors by seasonal behavioral modelling (SBM) of the fuel consumption of the gensets related to the overall irradiance dynamics of the PV array. Several years of d... [more]

The safe operation of diesel engines performs a vital function in industrial production and life. Because diesel engines often work in harsh environmental conditions, they are prone to failure. Therefore, this paper proposes a fault analysis method based on a combination of optimized variational mode decomposition (VMD) and improved convolutional neural networks (CNN) to address the necessary need for preventive maintenance of diesel engines. The authentic vibration sign is first decomposed by using the (VMD) algorithm, then the greatest range of decomposition layers is decided by using scattering entropy and the useful components are preferentially chosen for reconstruction. The continuous wavelet transform (CWT) records preprocessing method is then delivered to radically change the noise-reduced vibration sign into a time-frequency map, which is fed into the CNN for model coaching and extraction of fault features. Finally, fault classification is realized by support vector machine (S... [more]

The separation of polyethylene glycols (PEGs) into single homologs by reversed-phase chromatography is investigated experimentally and theoretically. The used core−shell column is shown to achieve the baseline separation of PEG homologs up to molar weights of at least 5000 g/mol. A detailed study is performed elucidating the role of the operating conditions, including the temperature, eluent composition, and degree of polymerization of the polymer. Applying Martin’s rule yields a simple model for retention times that holds for a wide range of conditions. In combination with relations for column efficiency, the role of the operating conditions is discussed, and separations are predicted for analytical-scale chromatography. Finally, the approach is included in an efficient process model based on discrete convolution, which is demonstrated to predict with high accuracy also advanced operating modes with arbitrary injection profiles.

Biodiesel is considered an environmentally friendly alternative to petro-derived diesel. The cetane number indicates the degree of difficulty in the compression-ignition of liquid fuel-powered engines. The allylic position equivalent (APE), which represents the unsaturated degree of fatty acid esters, was one of the key parameters for the cetane number of biodiesel. Due to the significant attributes of APE for biodiesel properties, the impact of APE on engine performance and emission characteristics was investigated in this study. The engine characteristics could be improved by adjusting the biodiesel fuel structure accordingly. A four-stroke and four-cylinder diesel engine accompanied by an engine dynamometer and a gas analyzer were used to derive the optimum blending ratio of the two biodiesels from soybean oil and waste cooking oil. Three fuel samples composed of various proportions of those two biodiesels and ultra-low sulfur diesel (ULSD) were prepared. The amounts of saturated fa... [more]

Motivated by the donation subsidy policy, this paper studies a supply chain consisting of a manufacturer and a remanufacturer. The manufacturer sells new and remanufactured products and can also donate two products. The remanufacturer can only sell and donate remanufactured products. Using the Stackelberg game model, we investigate the optimal production and donation strategies of two competing firms and discuss how the subsidy policy affects these strategies. Our main results include the following: First, the donation strategies of the two firms are not only affected by the subsidies but could also be influenced by the competitor’s donation decision, especially when the subsidy is high. Second, the subsidized products for sale in the market will decline as the subsidy increases. Therefore, a high subsidy always causes insufficient market supply. Third, the first-mover advantage may not make the manufacturer avoid a dilemma; however, when the remanufacturer becomes the leader in the ma... [more]

Carbon nitride (C2N), a two-dimensional material, is rapidly gaining popularity in the photovoltaic (PV) research community owing to its excellent properties, such as high thermal and chemical stability, non-toxic composition, and low fabrication cost over other thin-film solar cells. This study uses a detailed numerical investigation to explore the influence of C2N-based solar cells with zinc magnesium oxide (Zn1−xMgxO) as a buffer layer. The SCAPS-1D simulator is utilized to examine the performance of four Mg-doped buffer layers (x = 0.0625, 0.125, 0.1875, and 0.25) coupled with the C2N-based absorber layer. The influence of the absorber and buffer layers’ band alignment, quantum efficiency, thickness, doping density, defect density, and operating temperature are analyzed to improve the cell performance. Based on the simulations, increasing the buffer layer Mg concentration above x = 0.1875 reduces the device performance. Furthermore, it is found that increasing the absorber layer th... [more]

In this paper, a fuzzy neural network based predefined-time trajectory tracking control method is proposed for the tracking problem of omnidirectional mobile robots (FM-OMR) with uncertainties. Considering the requirement of tracking error convergence time, a position tracking controller based on predefined-time stability is proposed. Compared with the traditional position tracking control method, the minimum upper bound of the convergence time can be explicitly set. In order to obtain more accurate angular velocity tracking, the inner loop controller combines Type 1 fuzzy neural network (T1FNN) to estimate the uncertainty. In addition, considering the problem of feedback channel noise, a Kalman filter combining velocity and position information is proposed. Finally, the simulation results verify the effectiveness of this method.

To lower maintenance costs and improve a metro company’s competitiveness, this research came up with an innovative technique using a considering sensitivity and analytic hierarchy process (CSAHP). Along with interviews with managers and workers at the Taipei Rapid Transit Corporation, this study was able to undertake quantitative analysis. To determine which subsystems and metro lines should be prioritized for outsourcing based on the CSAHP framework, we used the criterium decision plus (CDP) program. This research adds to the existing body of knowledge by advancing the existing analytic hierarchy process (AHP) technique and recommending the CSAHP strategy for assessment. According to the findings, the power supply system was the most in need of outsourcing, followed by air conditioning, firefighting, and elevator systems. When considering which of the four metro lines to outsource first, the blue line came out on top, followed by the red, green, and brown lines. By prioritizing the ou... [more]

Allergens are proteins and are, therefore, likely to be denatured when subjected to thermal treatment. Traditional cooking has so far been able to reduce allergen sensitivity by around 70−90%. This study was aimed at evaluating the effect of a broad range of thermal treatments on the reduction of soy immunoreactivity (IR) in a 5% slurry using a sandwich ELISA technique. Cooking at 100 °C (10−60 min) and different thermal processing conditions, such as in commercial sterilization (with a process lethality (Fo) between 3 and 5 min) and selected severe thermal processing conditions (Fo > 5 and up to 23 min) were used in the study to evaluate their influence on allergen IR. Based on an IR comparison with an internal soy allergen standard, the allergen concentration in the untreated soy sample was calculated to be equivalent to 333 mg/kg (ppm). Cooking conditions only reduced the IR sensitivity to about 10 mg/kg (~1.5 log reductions), while the thermal processing treatments lowered the alle... [more]

The adsorption pore structure is the key affecting the technology of enhanced coal bed methane recovery (ECBM). In this paper, nitrogen adsorption measurement (NAM) and low-field nuclear magnetic resonance (NMR) methods are used to test the structural parameters of adsorption pores of four coal samples with different metamorphic degrees. Combining with the fractal theory, the applicability and the physical significance of fractal dimensions obtained from different models are analyzed. Finally, the main factors affecting the complexity of the pore size structure and the influence of fractal characteristics on the adsorption properties of coal are discussed. The results show that with the increase in the degree of metamorphism, the ranking order of the volume and the specific surface area of adsorption pores of four coal samples are long flame coal > anthracite > gas coal > coking coal. The fractal dimension D2 calculated by the Frenkel−Halsey−Hill (FHH) fractal model ranges from 2.5 to... [more]

It is common knowledge that the world’s economic growth is mainly based on hydrocarbon exploitation and processing, regardless of the political efforts towards developing renewable energy [...]

Thirty years ago, at the United Nations’ (UN) Earth Summit in Rio de Janeiro, Brazil, 178 countries adopted Agenda 21, a global partnership for sustainable development to improve human lives and protect the environment [...]

Since conventional techniques are ineffective for NO removal at low concentrations, photocatalysis has become attractive in this regard, recently. However, in practice, photocatalytic NO removal has drawbacks such as limited light absorption and the proclivity of producing toxic by-products. To address these issues, novel defective Bi/Bi3NbO7 structures with good porosity were fabricated by a solvothermal method and used for enhanced photocatalytic NO removal under visible light irradiation. The morphological and structural properties of the prepared materials were comprehensively analyzed. The optimal photocatalytic activity of pore-defective Bi/Bi3NbO7 for NO removal was 60.3%, when the molar ratios of urea and Bi(NO)3•5H2O to pristine Bi3NbO7 were 1:25 and 1:2, respectively, under the following operational conditions: NO concentration of 700 ppb, catalyst dosage of 50 mg and irradiation time of 14 min. The induced defects and the surface plasmon resonance (SPR) effect of Bi nanodots... [more]

Due to the opaqueness of rock and the limitation of detection technology, it is impossible to accurately describe the crack growth process and determine the law of rock breakage. Based on smoothed particle hydrodynamics and the finite element method (SPH-FEM), a numerical model for high-speed water jet breaking was established in this work to simulate the fragmentation process of rock impacted by a high-speed water jet, and to study the effects of different jet angles on the propagation of microscopic cracks inside the rock. Additionally, we further analyzed the jet impact angle on the microscopic crack propagation trend of the rock by applying confining pressure to the rock. Theoretical and experimental analyses showed that the inclination angle of the jet determined the direction of axial crack propagation in the tension-type center. When the inclination angle of the jet exceeded 20°, the ability of water jet erosion was insufficient, and the efficiency of rock fragmentation was low.... [more]

CO2 biomethanisation is a rapidly emerging technology which can contribute to reducing greenhouse gas emissions through the more sustainable use of organic feedstocks. The major technical limitation for in situ systems is that the reaction causes CO2 depletion which drives up pH, potentially leading to instability and even digestion failure. The study aimed to test fundamentally derived predictive equations as tools to manage H2 addition to anaerobic digesters. The methodology used data from the literature and from experimental digesters operated with excess H2 to a point of failure and subsequent recovery. Two equations were tested: the first relating pH to CO2 partial pressure (pCO2), and the second extending this to include the influence of volatile fatty acids and ammonia. The first equation gave good agreement for data from studies covering a wide range of operating conditions and digester types. Where agreement was not good, this could usually be explained, and in some cases impr... [more]

Using honeysuckle as raw material, chlorogenic acid (CGA) was extracted with different alcohols. Based on the single-factor experiment design, the relationship between each parameter and the response value was explored by Box−Behnken method to optimize the process conditions. Best extraction results were obtained under the conditions of solid-to-liquid ratio of 1:20, the ultrasonic time of 40 min, the ultrasonic vibrator power of 240 w, and the CGA extraction rate of 2.98%. The experimental data show that the extraction rate of CGA is related to the length of the alcohol carbon chain and the number of hydroxyl groups in the extractant. The results from this work can provide technical basis for the safe and efficient production of CGA from honeysuckle.

The surface exchange and bulk transport of oxygen are highly relevant to ceria-based redox materials, which are envisaged for the solar thermochemical splitting of carbon dioxide in the future. Experimental investigations of oxygen isotope exchange on CeO2-δ, Ce0.9M3+0.1O1.95-δ (with M3+ = Y, Sm) and Ce0.9M4+0.1O2-δ (with M4+ = Zr) samples were carried out for the first time utilizing oxygen-isotope-enriched C18O2 gas atmospheres as the tracer source, followed by Secondary Ion Mass Spectrometry (SIMS), at the temperature range 300 ≤ T ≤ 800 °C. The experimental K˜O and D˜O data reveal promising results in terms of CO2 splitting when trivalent (especially Sm)-doped ceria is employed. The reaction temperatures are lower than previously proposed/reported due to the weak temperature dependency of the parameters K˜O and D˜O. The majority of isotope exchange experiments show higher values of K˜O and D˜O for Sm-doped cerium dioxide in comparison to Y-doped and Zr-doped ceria, as well as nomin... [more]

In the present study, the assessment of heavy metal contaminant migration from fresh mine tailings was conducted using the electrokinetic remediation technique (EKR). In this sense, a pilot EKR cell was designed to evaluate the recovery potential of copper, nickel, and cobalt species. In particular, the focus was on the impacts of electric field intensity and pH in initial mixture and testing their interaction in copper, nickel, and cobalt migration. Experiments were made using a 22 factorial experimental design with a central point, using DC electric fields from 1.0 to 2.0 V cm−1 and H2SO4 pretreatment solutions from 1.0 to 2.0 mol L−1, along with an ANOVA test with error reduction. The metal removal rates were approximately 7% for cobalt, neglectable for copper, and 6% for nickel. In the best cases, the highest concentrations by migration at the cathodic zone were 11%, 31%, and 30%, respectively. According to ANOVA tests, factor interaction was proven for each metal in the half cell... [more]

Predicting surface settlement in deep foundation pit engineering plays a central role in the safety of foundation pit construction. Recently, static or dynamic methods are usually applied to predict ground settlement in deep foundation pit projects. In this work, we propose a model combining wavelet noise reduction and radial basis neural network (XW-RBF) to reduce noise interference in monitoring data. The results show that the XW-RBF model predicts an average relative error of 0.77 and a root average square error of 0.13. The prediction performance is better than the original data prediction results with noise structure and has higher prediction accuracy. The noise data caused by the interference of construction and the surrounding environment in the original data can be removed via the wavelet noise reduction method, with the discreteness of the original data reducing by 30%. More importantly, our results show that the XW-RBF model can reflect the law of data change to predict the f... [more]

Due to the design of peanut harvesters and cleaners, peanut pods are often mixed with soil, gravel, peanut straw, and other impurities. To solve this problem, this study focused on designing a peanut pod cleaning device by integrating a negative pressure centrifugal fan, a hydrometric cleaning sieve, and a reversible long-mesh cleaning sieve. The relative motion of the peanut pod on the sieve was discussed, its stress analyzed, the design parameters of the sieve and fan determined, and the operation of the device was monitored by using sensors, which accurately recorded and adjusted the working parameters. Finally, the key parameters were tested, and the results showed that the design requirements were met at a vibration frequency of 5.5 Hz, a hydrometric cleaning sieve inclination of 15°, a reciprocating long mesh cleaning sieve inclination of 5°, and a fan speed of 1500 rev/min; the mean loss is 2.26%, and the mean impurity is 3.18%. The findings can be used to provide technical supp... [more]

At present, complex biological processes are used in many industrial areas [...]

In this study, a procedure for selecting the optimal heat-accumulating material based on phase transitions for the economical maintenance of poultry farms by applying ANOVA to complex solid bodies’ thermodynamic parameters is described. The relevance of the topic is due to its importance for the development of an energy-saving technology based on the release or absorption of significant heat during the crystallization or melting of materials. The applicability of one-way ANOVA for the selection of the optimal material with a specific functional purpose was demonstrated. As result, the best composition for maintaining a normal temperature regime in poultry farms that could meet all the requirements imposed on heat-storage materials was determined. It was found that magnesium sulphate heptahydrate is such a material.

From the textile manufacturers’ point of view, coarse and medullated fibers are undesirable in the production of fine woolen materials, but highly desirable in the production of textiles and yarns with special effects, especially in carpet production. For sustainability, the entire sheep fleece should be used, including the coarse and medullated fibers. The raw wool must be scoured to obtain clean wool fibers without damage or excessive fiber entanglement, with a certain moisture content, low dirt content and residual grease for further processing, and proper color. In order to remove the impurities in raw wool with maximum efficiency, save energy and minimize the environmental impact, this study investigated the changes in some fiber properties during the scouring process due to the effect of the enzyme complex on coarse wool fibers. The effects were studied through the amount of clean wool fibers and impurities within the fleece, the fiber diameter and color. Conventional and enzyme... [more]

Betulinic acid, BA, is a lupane derivative that has caught the interest of researchers due to the wide variety of pharmacological properties it exhibits towards tumor cells. Because of their prospective increased anti−proliferative efficacy and improved pharmacological profile, BA derivatives continue to be described in the scientific literature. The current work was conducted in order to determine the antiproliferative activity, under an in vitro environment of the newly developed 1,2,4−triazole derivatives of BA. The compounds and their reaction intermediates were tested on three cancer cell lines, namely RPMI−7951 human malignant melanoma, HT−29 colorectal adenocarcinoma, A549 lung carcinoma, and healthy cell line (HaCaT human keratinocytes). BA−triazole derivatives 4a and 4b revealed lower IC50 values in almost all cases when compared to their precursors, exhibiting the highest cytotoxicity against the RPMI−7951 cell line (IC50: 18.8 μM for 4a and 20.7 μM for 4b). Further biologica... [more]