The article aims to enhance understanding of how relations, behavior and attitude of the executives and contractors to achieving the objectives by energy supplying companies affect the efficiency of the latter’s overall development. There is offered a factor-reflexive approach to diagnosing the executives’ and contractors’ attitude to realizing the tasks of developing the energy supplying companies. This approach includes models to identify and analyze the factors that influenced the change in contractors’ behavior based on the combination of expert techniques, correlation and regression analysis and evaluation of the personnel response to organizational, resource and staffing projects development, through accumulating sufficient statistical information based on the enterprise’s features, relations and environment. This approach to diagnosing executives’ and contractors’ response to the implementation of tasks and the resulting changes takes into account the subjective component of the... [more]

The reaction and separation sections are the keys to the methanol-to-olefins (MTO) chemical processes, and they should be optimized to reduce the cost of production. This work develops a framework for the simultaneous design and optimization of the reaction and distillation sections. An optimization model with shortcut and rigorous methods combined is established for distillation columns to improve accuracy and efficiency. With the auxiliary devices and the selection of utilities considered, the reaction and distillation sections are integrated to maximize profits. The genetic algorithm targets the optimal parameters, including the catalyst’s coke content and reaction temperature, each column’s operating pressure, and the allocation of utilities and auxiliary devices. For the studied MTO process, the optimal reaction temperature and catalyst’s coke content were identified to be 496 °C and 7.8%, respectively. The maximum profit is 15.3% greater than that identified with only the separat... [more]

Reduction of carbon dioxide emission from natural and industrial flue gases is paramount to help mitigate its effect on global warming. Efforts are continuously deployed worldwide to develop efficient technologies for CO₂ capture. The use of environment friendly amino acids as rate promoters in the present amine systems has attracted the attention of many researchers recently. In this work, the reaction kinetics of carbon dioxide with blends of N-methyldiethanolamine and L-Arginine was investigated using stopped flow technique. The experiments were performed over a temperature range of 293 to 313 K and solution concentration up to one molar of different amino acid/amine ratios. The overall reaction rate constant (kov) was found to increase with increasing temperature and amine concentration as well as with increased proportion of L-Arginine concentration in the mixture. The experimental data were fitted to the zwitterion and termolecular mechanisms using a nonlinear regression techniqu... [more]