With the rapid development of industrialization, the problem of concentration determination based on the copper production process has been widely concerned, and the accurate determination of high-concentration copper ions (Cu2+) is of great significance for enterprise production, resource utilization, and pollution prevention. The characteristics of different spectrophotometric methods for the determination of Cu2+ are discussed, and it is found that these methods are suitable for the determination of trace or low concentration of Cu2+ (0.5 μg/L−5 mg/L), whereas for the determination of high Cu2+ concentration pre-treatments such as dilution, complexation, and coloring are required. In this study, a method based on ultraviolet-visible spectroscopy (UV-Vis) combined with partial least squares regression analysis (PLS) was proposed for the determination of high copper ions (>100 mg/L), which performs rapid and accurate determination of high Cu2+ concentration by preprocessing and featur... [more]

Reverse electrodialysis (RED) is one of the methods able to generate energy from the salinity gradient between sea- and river water. The technique is based on the diffusion of ions through membranes that specifically allow either cations or anions to pass through. This ion current is converted into an external electric current at electrodes via suitable redox reactions. Seawater contains mainly eight different ions and the description of transport phenomena in membranes in classical terms of isolated species is not sufficient because the different particles have different velocities—in the same direction or opposite—in the same membrane. More realistic is the Maxwell−Stefan (MS) theory that takes all interactions between the different particles in account; however, such a model is complex and validation is difficult. Therefore, a simplified system is used with solely NaCl in solution, using only 9 diffusivities in the calculation. These values are estimated from the literature and are... [more]

Reservoir damage is a key factor affecting reservoir evaluation, ensuring stable reservoir production and improving the utilization rate of oil and gas resources. At present, the evaluation of damage caused by reservoir drilling fluid is too empirical, and there is a lack of methods for the high-precision evaluation of reservoir damage after drilling fluid invasion and pollution. In a block in the East China Sea, the production capacity is limited due to an excessive balance of drilling fluid and long exposure time. In order to ensure safe drilling, the dynamic damage mechanism of drilling fluid during drilling was analyzed. The core of the main reservoir of well XH-1 in a block in the East China Sea was selected for carrying out an experiment evaluating the dynamic damage caused by drilling fluid. According to the experimental results, the damage rate of reservoir permeability caused by drilling fluid invasion ranges between 58.25 and 87.25%, and the overall dynamic damage degree can... [more]

Non-thermal plasma (NTP) conversion applications have become an emerging technology of increasing global interest due to their particular ability to perform at atmospheric pressure and ambient temperature. This study focuses on a specific case of a dielectric barrier discharge NTP reactor for carbon dioxide conversion with the usage of argon as diluent gas. The plasma computations in COMSOL® Multiphysics are compared to experimental results and coupled with previous thermodynamic characterization of argon species and fluid dynamic calculations. The model is defined as a time-dependent study with a 2D-Geometry of pure argon, with both fluid flow and plasma phenomena. Firstly, the model showcases an accurate understanding of the plasma physics involved, in the form of electron density, excited argon, argon ions, and mean electron energy. It also allows a direct comparison of the velocity, vorticity, pressure, and dynamic viscosity results with fluid flow computations. Secondly, the impac... [more]

Excessive alcohol intake leads to significant physiological complications, particularly alcoholic liver diseases (ALD). The extent of liver damage caused by ethanol correlates with increased oxidative stress and accumulation of lipids in the hepatic tissue. In this study, we investigated the defense properties of the aqueous extract of Perilla frutescens Briton Var. acuta Kudo (PF) on hepatic injury in chronically ethanol-treated mice. The mice were orally administered the water extract from PF for 4 weeks with ethanol treatment (3 g/kg. P.O.). The level of malondialdehyde (MDA) in the liver tissues was determined. A substantial increase in MDA generation was detected in the livers of mice subjected to ethanol exposure, whereas the administration of PF markedly reduced MDA levels in hepatic tissues. Additionally, histological analysis of the liver tissue was performed. Histopathological investigation revealed a significant reduction in hepatocellular necrosis in the PF-treated group. T... [more]

The Processes Editorial Office retracts the article titled “RETRACTED: In-Situ Yeast Fermentation Medium in Fortifying Protein and Lipid Accumulations in the Harvested Larval Biomass of Black Soldier Fly” [...]

The transient temperature of the wellbore plays an important role in the selection of downhole tools during the drilling of deep shale gas horizontal wells. This study established a transient temperature field model of horizontal wells based on the convection heat transfer between wellbore and formation and the principle of energy conservation. The model verification shows that the root mean squared error (RMSE) between the measured annular temperature neat bit and the predicted value is 0.54 °C, indicating high accuracy. A well in Chongqing, China, is taken as an example to study the effects of bottom hole assembly (BHA), drill pipe size, drilling fluid density, flow rate, inlet temperature of drilling fluid, and drilling fluid circulation time on the temperature distribution in wellbore annulus. It is found that the increase in annular temperature is about 1 °C/100 m in the horizontal section when a positive displacement motor (PDM) is used. A Φ139.7 mm drill pipe is more favorable f... [more]

Microplastics, primarily derived from plastic waste, are pervasive environmental pollutants found across aquatic and terrestrial ecosystems. This review investigates microplastics’ presence, distribution, and impacts in marine ecosystems, with a particular focus on fish species. Research indicates that microplastics are present in various anatomical parts of fish, including the gastrointestinal tracts and gills, with significant implications for marine biodiversity and human health through seafood consumption. The review also highlights the sources of microplastics, such as synthetic textiles, packaging, and personal care products, and explores the pathways through which these particles enter marine environments. Advanced detection techniques have identified microplastics in human tissues, underscoring the urgency of addressing this environmental threat. Comprehensive strategies are essential to mitigate microplastic pollution and protect both marine life and human health.

Herein, the Aspen models to the paper "Chemical recycling of plastic waste via production of ethylene from gasification syngas" are published. The model starts at syngas, as gasification was not modeled in Aspen Plus. Syngas is treated and fed into a methanation reactor. Ethylene is then produced via oxidative coupling of methane. The fractionation involves cryogenic distillation as well as CO2 capture. Latter one was modeled in a separate file.

Sugarcane accounts for around 80% of global sugar production. However, the sugar industry is known for producing significant amounts of organic wastewater with a high COD (5000−8000 mg/L) that severely pollutes the environment. A lab-scale trial was conducted to evaluate the efficacy of a horizontal subsurface flow wetland planted with Typha latifolia and Phragmites australis in removing pollutants from sugar industry wastewater. The wetland system was subjected to rigorous testing, operating at a high flow rate of 2.166 gallons per day and exposed to a high organic loading rate (3800 mg/L COD and 2470 mg/L BOD), as well as elevated levels of inorganic nitrogen, sulfate, and phosphate (100 mg/L, 80 mg/L, and 10 mg/L, respectively). Our findings indicate significant removal efficiencies, with the wetland system achieving removal rates of 88% for COD, 97% for BOD, 96% for total nitrogen, and 95% for sulfate. Remarkably, the system exhibited enhanced removal efficiency when exposed to dom... [more]

To uncover the reservoir characteristics and enrichment law of coal-measure gas in Julu sag, Hebei Province, and achieve co-exploration and co-mining, it is necessary to conduct a comprehensive analysis. In this study, we investigated the characteristics of coal-measure gas accumulation in the Taiyuan Formation and Shanxi Formation in the Julu area. This was achieved by collecting data on coal-measure source rocks and organic geochemistry, which were then combined with regional geological conditions. This study indicates that the coal seams and shales of Shanxi Formation and Taiyuan Formation in the study area serve as the primary source rocks. The predominant macerals found in coal rock are vitrinite. Furthermore, the organic matter type present in shale is primarily categorized as type II2, with the organic matter maturity falling within the immature−mature stage. Based on the simulation results of tectonic-burial history, thermal evolution history, and hydrocarbon generation history... [more]

Gob-side entry driving near an advancing working face can improve the recovery rate of coal resources and keep the balance between mining and development. However, the large displacement of the gob-side entry caused by the mining dynamics of abutment pressure challenges the safety and processes of coal mining. This article takes the 15102 tailentry of Xizhang Coal Mine in Changzhi City, Shanxi Province, as an example to study the stability of the coal pillar and the failure characteristics of the surrounding rock and proposes cooperative control strategies of surrounding rock stability. Field tests indicated that when the coal pillar width was 15 m, the displacements of the entry floor, roof, coal pillar side, and solid coal side were 1121 mm, 601 mm, 783 mm, and 237 mm, respectively. A meticulously validated numerical model, incorporating a double-yield model for the gob materials and calibrated parameters, was developed to investigate the stress changes and yield zone distribution ac... [more]

With the development of renewable energy power systems, electric vehicles, as an important carrier of green transportation, are gradually having an impact on the power grid load curve due to their charging behavior. However, the significant influx of electric vehicles (EVs) and distributed power sources has led to multiple uncertainties, increasing the difficulty in making grid scheduling decisions. Traditional robust scheduling strategies tend to be overly conservative, resulting in poor economic performance. Therefore, this paper proposes a robust and economic dispatch strategy for park power grids based on the information gap decision theory (IGDT). Firstly, based on the probabilistic characteristics of the spatial and temporal distribution of EVs charging, the Monte Carlo method is used to generate typical electricity usage scenarios for EVs. Simultaneously, an economic dispatch model for the park power grid is established with the objective of minimizing operating costs. Taking in... [more]

A longstanding concern in plant essential oil extraction is how to optimize extraction efficiency with limited materials. Supercritical CO2 extraction has been proven effective in enhancing the yield and efficiency of extracting plant essential oils. However, the impact of temperature, pressure, and co-solvent content on extracting Hetian rose essential oil remains unclear. There is a lack of research on the influence of pretreatment methods. This study focuses on investigating supercritical CO2 extraction of rose essential oils from Xinjiang Hetian. The research analyzes the effects of pressure and temperature on the extraction rate and validates the efficiency by calculating the solubility of essential oils in supercritical fluid. Under conditions of 35 MPa, 40 °C, 10 L/h, and a particle size of 0.8 mm, this study evaluates the extraction efficiency using Xinjiang Hetian rose materials pretreated with salt solutions at concentrations of 5%, 10%, and 20%, as well as enzyme solutions a... [more]

The massive integration of distributed renewable energy sources and nonlinear power electronic equipment has given rise to power quality issues such as waveform distortion, voltage instability, and increased harmonic components. Nowadays, the pollution of power quality is becoming increasingly severe, posing a potential threat to the security of the power grid and the stable operation of electrical equipment. Due to the presence of significant noise interference in the collected signals, existing methods still face issues such as low accuracy in disturbance identification and high computational complexity. To address these problems, this paper proposes a hybrid data-driven strategy that can significantly improve the accuracy and speed of identification. Firstly, the wavelet packet transform (WPT) method is employed to denoise the power disturbance signals. Subsequently, the local mean decomposition (LMD) algorithm is used to adaptively decompose the nonlinear and complex time series in... [more]

As deep oil and gas resources and Carbon Capture and Storage (CCS) are developed, enhancing drilling efficiency in hard rock formations has emerged as a critical technology in oil and gas extraction. The advancement of ultrasonic, high-frequency vibration rock-breaking technology significantly facilitates efficient rock crushing. When subjected to ultrasonic high-frequency vibrations, the rock’s response is a crucial issue in implementing ultrasonic vibration rock crushing technology. This study employed numerical simulation and theoretical deduction methods, utilizing a multi-physics approach that couples solid mechanics with pressure acoustics. It integrated information on common influencing parameters of ultrasonic generators and reservoir rock properties to establish model parameters, analyze simulation results, and perform theoretical deductions. The research investigated the response patterns of different-sized rock samples under high-frequency ultrasound vibration excitation acr... [more]

Bangladesh is increasing agricultural mechanization to reduce labor-intensive drudgery and to address labor shortages in farming. Agricultural equipment, such as power tillers and threshers, are used to achieve this goal and require regular replacement of the spare parts that experience significant wear in use. Spare parts are currently imported at twice the cost of domestic ones. This paper supports the development of domestic manufacturing by analyzing the manufacturing processes for two fast-moving spare agricultural parts, tiller blades and threshing teeth, and providing a method to develop more efficient processes. The manufacturing processes, which focused on the design of forging and bending dies, reflect the constraints of the manufacturing equipment and stock materials available in Bangladesh. The die designs and manufacturing processes were verified by FEA simulations and by experimental testing. The experiments and simulations suggest that the spare parts should be made at e... [more]

The efficient development of tight gas reservoirs is significantly enhanced by multi-stage and multi-cluster fracturing techniques in conjunction with horizontal well technology, leading to substantial increases in reservoir drainage volume and individual well productivity. This study presents a tailored fine-fracturing approach for horizontal wells in tight gas reservoirs, supported by a gas−water two-phase numerical simulation model. Utilizing the orthogonal experimental design method, we simulated and optimized various fracture distribution schemes to refine fracturing parameters for maximum efficiency. The optimization was further validated through a comparison with actual well completion and development dynamics. The quantitative results highlight the optimal fracture distribution for horizontal wells, with a horizontal section length of 1400 to 1600 m and 14 to 16 fracturing stages. The pattern features a “dense at both ends and sparse in the middle” strategy, with stage spacing... [more]

This work aimed to study the influence of two factors on oil composition: the altitude of olive groves and the age of olive trees, as well as the duration olive oil was stored in the dark and at room temperature. Firstly, quality parameters (free acidity, peroxide value, K232 and K270), minor compounds (pigments, total phenolic compounds, tocopherol fraction and fatty acid profile) and oxidative stability measured at 98.0 °C (by Rancimat) made it possible to evaluate the quality of the samples during one year of storage. A significant difference was reported in pigment contents as a function of altitude. In particular, several changes were observed during storage, which led on the one hand to a continuous increase in free acidity, peroxide value, K232, K270 and on the other hand a degradation of natural antioxidants such as phenolic compounds, pigments and tocopherols and consequently to oxidation stability. However, the modification of the fatty acid composition was small and did not... [more]

Incorporating anthocyanins, valuable natural pigments, into a powder can improve their stability, but exposure to high temperatures during processing can cause them to degrade. The purpose of this study was to investigate how the inlet air temperature during spray drying affects the physical and chemical characteristics as well as the flowability of a grape pomace anthocyanin powder obtained through ultrasound-assisted extraction using acidified water as the solvent. An anthocyanin solution containing 13% (w/v) maltodextrin was subjected to spray drying at temperatures ranging from 120 to 170 °C. Tukey’s test was applied to compare the means of the samples. The samples dried at temperatures between 130 and 170 °C were adequate, with a moisture content < 5% and a water activity < 0.3, indicating that the powder was stable. The highest anthocyanin retention (91.94 ± 1.59%) and process yield (50.00 ± 3.06%) were achieved at 140 °C, while higher temperatures resulted in anthocyanin degr... [more]

During oil and gas development in permafrost, hot fluids within the wellbore can cause ice melting around wellbore and a decrease in sediment strength, as well as wellbore instability. In the present work, the experimental system for evaluating the insulation effectiveness was established, and the applicability of this experimental system and methodology was verified. It was found that the difference between the experimentally obtained and actual thermal conductivity of the ordinary casings are all within 1.0 W/(m·°C). Meanwhile, the evaluation of insulation effect found that the decrease in fluid temperature, ambient temperature, and vacuum degree can improve its insulation performance. Finally, the numerical simulation was conducted on ice melting and borehole stability during the drilling operation in permafrost. The investigation results demonstrate that the use of vacuum-insulated casings significantly reduces the total heat transferred during the simulation by 86.72% compared to... [more]

This article addresses the problem statement and objective by exploring the necessity, scope, and execution of digital transformation in the oil and gas industry from a psychological perspective. It highlights the cognitive barriers faced by non-ICT professionals, which are often overlooked in traditional approaches. The study integrates case studies and empirical evidence from a mixed-methods approach, including qualitative interviews with industry experts and quantitative surveys among employees, to provide a comprehensive understanding of the transformation process. The research emphasizes the integration of psychological theories with practical digital transformation strategies, illustrating key obstacles and solutions. By adopting a holistic approach that incorporates both technological advancements and psychological insights, the study aims to enhance the effectiveness and sustainability of digital transformation efforts. Major contributions include identifying cognitive barriers... [more]

Sodium borohydride (NaBH4) is a nontoxic and ideal storage material for hydrogen due to its safety and high hydrogen storage capacity. In order to improve the practicality of the sodium borohydride hydrogen production system, we deposited non-precious metal catalytic materials on readily available polymer foams using a simple chemical plating method, developing a suitable 3D catalyst. Its high specific surface area enables it to produce hydrogen at a rate of up to 3.92 L min−1 g−1. Its unique structure gives the catalyst excellent durability. In addition, an efficient NaBH4-based H2 supply system was developed using this catalyst. Co-Cu-B can facilitate stable hydrogen production from NaBH4, yielding a consistent power output ranging from 0 to 100 W. This work provides a new pathway for developing high-efficiency monolithic self-supported catalysts for industrial applications.

Plasma technology, relatively new in the fields of biomedicine, agriculture, and ecology, is the subject of intensive research as a prospective means of decontamination of various microorganisms (bacteria, viruses, and fungi). The objectives of the present study were to follow the effect of cold atmospheric plasma (CAP) treatment on in vitro grown plum plants (Prunus domestica L. ‘Kyustendilska sinya’ cv.) and the possibility of eradicating or inactivating plum pox virus (PPV) causing Sharka disease by CAP. The source tree is naturally co-infected by PPV (both M and D strains). In the experiments, two different plasma sources were used. First, a surface-wave-sustained Argon plasma torch and second, an underwater diaphragm discharge. For the treatments, nodal segments (10 mm in length) from in vitro cultured plum plants with or without one leaf were prepared. Apical shoots from treated plants (PPV-positive and negative clones as well non-treated controls) were cultivated in vitro for fo... [more]

Potassium-containing feldspars provide a high potential for producing potash, a product with widespread use in agriculture. The present work assesses applying the anti-solvent crystallization method for the purification and recovery of high-purity muriate of potash (KCl) from feldspar leaching solutions. Initially, screening experiments were carried out on a synthetic leaching solution with the aim of analyzing the crystallization behavior of key components. Screening experiments were performed using five anti-solvents, namely methanol, ethanol, acetone, 2-propanol, and ethylene glycol. Acetone and 2-propanol were viable options for crystallization of potassium chloride. Then, the effects of anti-solvent ratio (O/A), time, and anti-solvent addition rate on potassium-chloride crystallization were further investigated using acetone and 2-propanol. A recovery of 83% of potassium was achieved when using acetone at the O/A of 5 with the addition rate of 10 mL/min, at room temperature with a... [more]