In this paper, we presented a novel microbial fuel cell (bMFC) structure, with a bipolar membrane separating the anode and cathode chambers. A bipolar membrane divides the bMFC into anode and cathode chambers. The bipolar membrane comprises anion and cation exchange layers. The anode chamber side has the cation exchange layer, while the cathode chamber side has the anion exchange layer. The anode chamber of the bMFC was loaded with Shewanella oneidensis MR-1 and lactic acid, while the cathode chamber was loaded with pure water and iron (III) hydroxide. The bMFC generated electrons for 20 days at a maximum current density of 30 mA/m2 and the ohmic resistance value was estimated to be 500 Ω. During the operation of the bMFC, both the anode and cathode chambers kept anaerobic conditions. There was no platinum catalyst in the cathode chamber, which is required for the reaction of protons with oxygen. Therefore, oxygen could not serve as an electron acceptor in the bMFC. We considered a bMF... [more]

This work studies the effects of graphene nanoplatelets (GNPs) and hexagonal boron nitride (hBN) on the thermal and mechanical properties of polydimethylsiloxane (PDMS) matrix for use as thermal interface materials (TIMs). Solution mixing of 10 wt% GNPs and 40 wt% hBN with PDMS produced TIMs with through-plane thermal conductivity (TC) of 1.24 W m−1 K−1 showing a 519% increase relative to the neat matrix. A synergistic effect between GNPs and hBN was particularly demonstrated when in samples with 48 wt% total filler content, 8 wt% hBN was replaced by GNPs, and the TC was increased by 33%. The elongation at break of the hBN (40 wt%)/GNP (8 wt%) samples reached 151%, representing a 160% increase when compared to samples with only 40 wt% hBN. Moreover, the shore hardness of samples containing 40 wt% hBN was 68 A, and the introduction of 8 wt% GNPs caused a decrease to 38 A. DSC measurements on samples filled with hBN and GNPs showed a reduction up to 65% in Ultimate Heat of Curing, which... [more]

In solar cell modules, thermal cycling stresses can cause cracking in the ribbon wire, leading to an increase in series resistance and a drop in the power output of the module. Quantitative analysis was conducted to study the increase in series resistance, considering two cracking models: continuous and random. In the continuous model, it was expected that if all the ribbon wires on the front side of the module cracked, the current would decrease linearly from 0 to 100%, and the series resistance would increase exponentially to infinity. In the random crack model, the current dropped slowly, and the series resistance increased less compared with that in the continuous one. A mathematical model based on the bypass mechanism of the currents was proposed to explain the differences between the two models. The study found that cracking in the solder layer under thermal cycling can be described by a combination of continuous and random models, which can represent the upper and lower levels o... [more]

The double-layer composite electrode has attracted increasing attention in the field of intermediate-temperature solid oxide electrolysis cells (IT-SOEC). To investigate the effects of the cathode diffusion layer (CDL) and cathode functional layer (CFL) structure on performance, a three-dimensional multi-scale IT-SOEC unit model is developed. The model comprehensively considers the detailed mass transfer, electrochemical reaction and heat transfer processes. Meanwhile, percolation theory is adopted to preserve the structural characteristics and material properties of the composite electrode. The mesostructure model and the macroscopic model are coupled in the solution. The effects of the porosity of the CDL, the electrode particle size and the composition of the composite electrode in the CFL on the mass transport process and electrolysis performance of the IT-SOEC unit are analyzed. The results show that the appropriate mass flux and energy consumption in the electrode are obtained wi... [more]

The production and use of terpene-based fuels represents a renewable source of energy in the transportation sector, especially in the aviation sector. The literature on the conversion of terpenes into valuable compounds is not new but has been based on the production of products for cosmetics and pharmaceutics. Several established chemical routes are also a way to develop drop-in fuels. The present work explores all the main chemical processes that can transform terpenes into more valuable fuels or additives, focusing on the use of heterogeneous catalysis, catalyst type, operating conditions, and reaction performance. α-pinene is the most studied catalyst, since it is the main component of turpentine. Isomerization is the most frequently applied chemical pathway used to enhance fuel properties, and a wide group of heterogeneous catalysts have been reported, with sulphonic acid resin catalysts, transition metals, alumina, and silicates being the most used. This work also explores the cu... [more]

China’s Yangtze River Basin has an increasingly strong demand for crude oil. As a seaborne import port for crude oil, Ningbo-Zhoushan Port is under pressure to undertake the transshipment of crude oil to various oil terminals in the Yangtze River Basin. To alleviate the stress of crude oil transportation in Ningbo-Zhoushan Port, the port operator proposed the crude oil sea−river transshipment scheme in Nantong Port. Therefore, this paper aims to verify the feasibility of this scheme. We used the discrete event system modeling and entity relationship diagram method to construct the hierarchical and concept models of the Yangtze River Basin’s crude oil sea−river transportation system. Furthermore, we developed corresponding simulation modules on the Witness platform and carried out a simulation experiment of the crude oil sea−river transfer scheme. In the experiment, we analyzed the influence of the transshipment ratio on berth utilization, waiting time, and sailing time of other ports b... [more]

The concept of peer-to-peer (P2P) energy trading leads to the flexible energy transaction of prosumers and consumers, for which the P2P business model is normally the main attention. It still requires system operators to address the challenges in trading and constraint problems. In this context, this work regards the congestion constraint in conjunction with energy trading. Firstly, a matching approach based on the cost path is proposed. It is consistent with the cost for the dispatch along each route, making a suitable matching in both distance and bids. In combination with the matching process, the available capacity has to be considered to avoid line congestion. Secondly, the bus transfer factor (BTF) and the partitioning zone approach are proposed to overcome the issue. BTF refers to a response of bus power to the congested line power. The partitioning zone, separated into the source and the load area, enables a simple management strategy. Thereby, the power adjustment in each area... [more]

In order to meet the demands of desirable efficiency, transformerless DC/DC equipment with great voltage step-down are inevitable needed. This research offers a unique type of high-frequency, high-voltage-gain DC/DC converter, which comprises a switched capacitor (SC) converter and a buck converter. Thanks to the transformation of a two-stage converter to a single-stage converter, it has a considerable ratio of step-down voltage transformation and a reasonable duty cycle. In addition, it can permit low voltage stress on the switches. The simple control method and easy driving circuit implementation makes it scalable for high-power-level devices. Low cost can be realized as fewer components are needed. Under all operational circumstances, total soft-charging and low equipment voltage stresses are accomplished. Compared to those classic high-voltage-gain converters, the proposed converter exhibits merits of higher efficiency, higher flexibility, lower ripples, and lower costs. A comprehe... [more]

Thermoacoustic instabilities in gasturbine combustor systems can be predicted in the design phase with a thermoacoustic network model. In this model, the coupling between acoustic pressure fluctuations and the combustion rate is described by the Flame Transfer Function. The present paper introduces a new, efficient, and robust method for deriving the FTF from CFD predictions by means of a discrete multi-frequency sinusoidal fuel flow excitation method. The CFD-based FTF result compares well with experimental data for the time delay, but for the gain, only up to 400 Hz. Above 400 Hz, the CFD result reveals a smooth low-amplitude gain, which is not found in the measured data. A novel, accurate continuous correlation function for the FTF gain is computed based on the results for discrete frequencies. When this is implemented into a 1D acoustic network model, the stability map shows, below 600 Hz, two eigenfrequencies, by both the experiment and CFD-based FTF, that are identical. The CFD-b... [more]

Internal combustion engines face increased market, societal, and governmental pressures to improve performance, requiring researchers to utilize modeling tools capable of a thorough analysis of engine performance. Heat release is a critical aspect of internal combustion engine diagnostic analysis, but is prone to variability in modeling validity, particularly as engine operation is pushed further from conventional combustion regimes. To that end, this effort presents a comprehensive open-source, zero-dimensional equilibrium heat release model. This heat release analysis is based on a combined mass, energy, entropy, and exergy formulation that improves upon well-established efforts constructed around the ratio of specific heats. Furthermore, it incorporates combustion using an established chemical kinetics mechanism to endeavor to predict the global chemical species in the cylinder. Future efforts can augment and improve the chemical kinetics reactions for specific combustion conditions... [more]

This paper presents coupled electromagnetic (EM)−thermal modelling of the steady-state dynamic performances, such as torque speed curve and the efficiency map, for surface-mounted permanent magnet machines. One important feature of such a model is that it considers the demagnetization caused by magnet temperature rise at different rotor speeds. EM-only simulations, which often assume that the machines operate under constant temperature, have been widely used in the literature. However, the interaction between EM and thermal performances could lead to very different dynamic performance prediction. This is because the material properties, e.g., magnet remanence, coercivity, and copper resistivity are temperature-dependent. The temperature rise within electrical machines reduces torque/power density, PM eddy current losses, and iron losses but increases copper loss. Therefore, the coupled EM−thermal modelling is essential to determine accurate temperature variation and to obtain accurate... [more]

Assets deteriorate over time, as well as being covered, corroded, or becoming old in less obvious ways. Maintenance can extend the remaining useful life (RUL) of an asset system, but sooner or later it must surely be replaced. In this study, we propose a new RUL estimation methodology to assist in decision making for the maintenance and replacement of assets from prioritizing equipment in a renovation plan. Our methodology uses advanced data analysis techniques that consider multiple competing criteria with the goal of maximizing values of the asset throughout its life cycle, while considering the rules of remuneration and service quality of the current regulation, as well as the values at risk according to the decisions and actions taken. Experimental results with real datasets show the efficiency of the proposed approach. Finally, this work also presents the development of an analytical tool to optimize asset renewal decisions applying the RUL estimation methodology proposed and its... [more]

The ambitious goal of the European Union (EU) countries is to achieve carbon neutrality by providing inclusive economic growth, which requires the development of relevant incentives and initiatives. Furthermore, such incentives and initiatives should guarantee the achievement of the declared goals. Energy sectors are the core determinant of inclusive economic growth. Traditional energy resources (coal oriented) have a higher negative impact on nature and people’s well-being than on economic and social benefits. However, the transition to renewable energy raises new issues in achieving goals of inclusive economic growth: affordable and clean energy, responsible energy consumption, and energy infrastructure. The analysis of the theoretical framework found that the digitalization of government could be a core instrument for handling the abovementioned issues. The paper aims to justify the role of green energy in achieving inclusive economic growth empirically. The study applies the follow... [more]

Regulating the parameters of the atmospheric pressure plasma jet (APPJ) is meaningful for industrial applications. Since plasma is a typical functional fluid in the magnetic field, it is possible to control the discharge characteristics via the Lorentz force. In this study, the effects of a locally divergent magnetic field on the generation and propagation of APPJ were examined experimentally. The experiments used a coplanar dielectric barrier discharge (CDBD) device driven by a 30 kHz AC high-voltage source to generate a helium APPJ. A locally divergent magnetic field of 250 mT (maximum) was applied coupled with the electric field, and noticeable enhancement was observed. The results showed that the magnetic field changed the motion state of electrons and promoted collision ionization, leading to a 40% improvement in the APPJ length (0.6 cm) and a 23% increase in the intensity of line O (777.2 nm). In addition, the spatiotemporal evolution and flow field of APPJ were diagnosed by ICCD... [more]

This article studies a recently proposed dc-dc converter and its optimization in terms of capacitors selection through the Particle Swarm Optimization (PSO) algorithm. The converter under study is the so-called Low Energy Storage Quadratic Boost Converter (LES-QBC), a quadratic type of converter that offers a smaller Output Voltage Ripple (OVR) compared to the traditional quadratic boost topology with capacitors of the same characteristics. This study presents a way to select the capacitors for minimizing the OVR while achieving a constraint of a maximum stored energy in capacitors. The capacitor’s stored energy is given as a design specification. The results are compared against the traditional quadratic boost converter and the LES-QBC without optimization (equal capacitance in capacitors). The optimization algorithm used was the so-called Particle Swarm Optimization (PSO). The experimental results demonstrate the effectiveness of the proposition. For the design exercise used for the... [more]

This paper presents an analysis and simulation of the mathematical model associated to the DC/DC Boost converter−full-bridge Buck inverter system to regulate the voltage output of the DC/DC Boost converter allowing bipolar voltages higher than the input voltage via the full-bridge Buck inverter. To validate the model, the differential flatness property is applied via the flat outputs of the system (energy for the DC/DC Boost converter and the voltage of the full-bridge Buck inverter) considering the complete dynamics, in conjunction with fixed and time-variant trajectory planning. In the simulation results, it is observed that the error signals of the states versus the reference trajectories are acceptable. Regarding the validation of the model, this is performed with open-loop simulations at the circuit level using the SimPowerSystems Toolbox of Matlab-Simulink. The simulation results validate the good performance of the system under study. In this way, the main contribution of this w... [more]

This paper presents a precise analysis of the efficiency characteristic of the synchronous generator under both normal and SAGE conditions. In this work, various losses of the synchronous generator are computed by the qualitative theoretical model and the finite element analysis in detail. Further, the generator efficiency model is proposed according to the relationship between the output power and the loss. The presented model is verified in a 5-kW non-salient synchronous generator. The result demonstrates that the loss increases and the efficiency reduce as the SAGE intensifies.

Iron additives are effective in the anaerobic sewage sludge digestion process, but the composition and dosage of these additives are not precisely defined. This research investigates the effects of three iron oxides-based additives on the destruction of volatile solids, the production and quality of biogas, as well as the quality of the supernatant. Additive No 1 contained >41.5% of FeO and >41.5% of Fe2O3, additive No 2 contained ≥86% of Fe3O4, and additive No 3 contained ≥98% of Fe3O4. The best results were obtained by applying an iron oxides-based additive with a higher content of divalent iron oxide. The increase in efficiency of the VSs destruction was not significant and on average 2.2%. The increase in biogas production was on average 20% while the average increase in the content of methane in the biogas was 6.3%. Applying the additive, the reduction in the concentration of ammonium nitrogen in the supernatant was up to 28%, as well as a reduction in the concentration of phospha... [more]

Oxygen concentration is a significant factor affecting soot formation and oxidation. However, there are few studies that have focused on the morphology and nanostructure characteristics of soot in aviation kerosene, oxygen-depleted combustion flames. In the present paper, five coflow flames under initial oxygen volume concentrations of 18.5%, 19%, 20%, 21%, and 23.5% were studied. The pneumatic probe sampling method and high-resolution transmission electron microscopy (HRTEM) analysis were conducted to quantify the morphology and nanostructure parameters, and laser extinction (LE) was applied to determine the soot volume fraction. Among the cases of different oxidizer oxygen concentrations (23.5% to 18.5%), the change in soot volume fraction was quantified, and the degree of graphitization of soot particles, i.e., the maturity, were compared. The results show that the peak value of soot volume fraction of the flames increased by 0.73 ppm as the oxygen concentration increased from 21% t... [more]

CO2 replacement is a promising method of gas hydrate recovery. However, the influence of residual water in the replacement process and selections of a suitable mining area remain uncertain. To better understand this method, we examined the influence of the particle size and initial hydrate saturation on the replacement process while using the same amount of residual free water. The results showed that during the replacement process, two stages of rapid reaction and slow reaction occurred, which were manifested by the speed of pressure change in the reactor. The CO2 sequestration ratio decreased with the increase in sediment particle size and increased with the increase in initial hydrate saturation. During the replacement process, two reactions occurred: CH4 was replaced by CO2 and CO2 hydrate was formed, and the replacement amount and recovery efficiency of CH4 increased with a decrease in sediment particle size. When the sediment particle size was less than 166 μm, the CH4 recovery e... [more]

The partial replacement of fossil fuels with biomass provides an alternative to producing cleaner and more sustainable energy and fuels. Conventional shale oil production infrastructure can potentially be used in co-pyrolysis with biomass to reduce the use of oil shale and decrease its environmental impact. The effect of adding 10 and 30 wt% woody biomasses (spruce, alder, pine, and birch) into oil shale was studied through intermediate co-pyrolysis. The experiments were carried out in a batch reactor at 520 °C, with a 20 min residence time, in CO2, CO2-H2O 1:1, and Ar gas atmospheres. The solid products were collected and analyzed for elemental composition and surface area, while the composition of the gases was determined through gas chromatography. The difference in experimental and theoretical mass balances of fuel blends was lower than 2.5 wt% in all gas environments, indicating slight interactions between the fuels. CO2 atmospheres contributed to increased decomposition, with up... [more]

The investigation of a series of secondary aromatic nitramines was performed to reveal the impact of incremental methylene groups on the stability, shock impulse, and energetic properties of these compounds. Becke’s three-parameter hybrid functional approach with non-local correlation provided by Lee, Yang, and Parr and a cc-pVTZ basis set was used to obtain the geometry, total energy, and heat of formation of the most stable conformers of these aromatic nitramines. These parameters were used to evaluate the density, resistance to shock stimuli, detonation pressure, and velocity of the nitramines under study. Referring to the results obtained, we concluded that the thermal stability and resistance to shock stimuli of the compound investigated was directly CH2 chain length-dependent, while their energetic- properties, such as detonation pressure and velocity, were worsened due to this chain increase. We also found that the stability of the compounds increases more significantly than the... [more]

This study investigates the transferability of aluminum-silicate-based fuel additivation as a primary, fuel-based mitigation measure for inorganic alkali-based particulate matter (PM) emissions during the complete combustion of wood chips. Therefore, wood chips are additivated with 0.5 wt% of three different types of the aluminum-silicate-based additive kaolin, which differ mainly in their particle size distribution, and with one type of kaolinite. The subsequent combustion trials with non-additivated and additivated wood chips are carried out in a small-scale combustion plant. To evaluate the effect of the additivation of the wood chips, the total particulate matter (TPM) emissions, the potassium (K) emissions, the ultra-fine PM emissions and the carbon monoxide (CO) emissions, as well as the chemical composition of the resulting ashes, are analyzed. In order to compare the primary, fuel-side mitigation measure of fuel additivation with the established secondary mitigation measures, a... [more]

Prestack depth-migrated seismic data, having more accurate imaging position and amplitude fidelity than prestack time-migrated seismic data, are supposed to produce a higher quality reservoir prediction result by using depth-domain inversion. Some researchers have developed different methods of depth-domain seismic inversion. However, it has not been widely used in the industry probably because of two reasons: (1) it is a complex process to conduct depth-domain seismic inversion due to the nonstationary depth-domain seismic wavelet; and (2) time-domain seismic inversion is considered capable of solving the problem with less cost, both in regard to time and the economy. In this paper, we try to use the seismic waveform indicator inversion method in the depth domain. First, a forward model was built to demonstrate that seismic waveforms both in the time domain and the depth domain are highly correlated with lithologic associations. Second, a quantitative evaluation method of seismic data... [more]

Pressurized liquefied natural gas (PLNG) is a new natural gas liquefaction solution proposed in recent years for reducing the construction and operating costs of floating liquefied natural gas (FLNG). For natural gas, the liquefaction temperature is strongly influenced by the pressure; when the pressure increases, the liquefaction temperature of natural gas increases accordingly. The increase in the liquefaction temperature of natural gas leads to a higher solubility of impurities such as carbon dioxide, which means that the pretreatment standards for liquefied natural gas can be reduced. Therefore, the use of PLNG technology can simplify pretreatment plants and significantly reduce construction and operating costs. In order to better apply PLNG technology to FLNG, it is necessary to understand the solubility of carbon dioxide in pressurized LNG and the phase change during liquefaction. To achieve this, experimental setups are needed to simulate the temperature and pressure environment... [more]