This article reviews a method of hydrogen production based on partial non-catalytic oxidation of natural gas in an original synthesis gas generator. The working principles of the unit are similar to those of liquid-propellant rocket engines. This paper presents a description of the operation and technical characteristics of the synthesis gas generator. Its application in the creation of small-scaled plants with a capacity of up to 5−7 thousand m3/h of hydrogen is justified. Hydrogen production in the developed installation requires a two-stage method and includes a technological unit for producing a hydrogen-containing gas. Typical balance compositions of hydrogen-containing gas at the synthesis gas generator’s outlet are given. To increase the hydrogen concentration, it is proposed to carry out a two-stage steam catalytic conversion of carbon monoxide contained in the hydrogen-containing gas at the synthesis gas generator’s outlet using a single Cu−Zn−cement-containing composition. Ba... [more]

This study evaluates temperatures measured at district heating (DH) valves in manholes and their usability for non-destructively assessing the thermal performance of buried DH pipes. The study was conducted as a field test in which part of a DH network was shut down and the temperature decline in the valves was analysed in terms of absolute temperature and thermal response time from the DH pipe to the top of the valve. The calculated and measured supply pipe temperatures by the drainage valves were in good agreement, with 1% deviation. The valve measurement analysis from this study shows that the drainage valve has good potential to serve as a measurement point for assessing the thermal status of a DH network. However, the shutdown valve measurements were greatly affected by the manhole environment.

Smart cities are an extremely important, multi-faceted subject, both in terms of their practical aspects and in terms of research. This is expressed, among other things, in the multitude of approaches to this concept. These approaches differ based on the emphasis placed on individual aspects: some focus more on technology, and others put more weight on social issues, while still others value sustainable development issues. Currently, an important topic of discussion about the development of the smart city—the importance of which has become even greater in the context of the COVID-19 pandemic—is the digital transformation of the city. The use of robotic process automation (RPA) tools can be a part of such a transformation, as such tools, using advanced software, enable the automation of those tasks carried out thus far by humans. Although such an approach has, to date, been widespread in the case of enterprises (in particular, those operating in the financial and BPO/SSC sectors, but le... [more]

Six supplementary cementitious materials (SCMs) were identified to be incorporated in concrete exposed to high-temperature cycling conditions within the thermal energy storage literature. The selected SCMs are bauxite, chamotte, ground granulated blast furnace slag, iron silicate, silica fume, and steel slag. A microstructural characterization was carried out through an optical microscope, X-ray diffraction analysis, and FT-IR. Also, a pozzolanic test was performed to study the reaction of SCMs silico-aluminous components. The formation of calcium silica hydrate was observed in all SCMs pozzolanic test. Steel slag, iron silicate, and ground granulated blast furnace slag required further milling to enhance cement reaction. Moreover, the tensile strength of three fibers (polypropylene, steel, and glass fibers) was tested after exposure to an alkalinity environment at ambient temperature during one and three months. Results show an alkaline environment entails a tensile strength decrease... [more]

The electronic oxygen regulator (EOR) is a new type of aviation oxygen equipment which uses electronic servo control technology to control breathing gas pressure. In this paper, the control method of EOR was studied, and the dynamic model of the aviation oxygen system was established. A disturbance-observer-based controller (DOBC) was designed by the backstepping method to achieve the goal of stable and fast breath pressure control. The sensitivity function was proposed to describe the effect of inspiratory flow on breath pressure. Combined with the frequency domain analysis of the input sensitivity function, the parameters of the DOBC were analyzed and designed. Simulation and experiment studies were carried out to examine the control performance of DOBC in respiratory resistance and positive pressurization process under the influence of noise and time delay in the discrete electronic control system, which could meet the aviation physiology requirements. The research results not only... [more]

Accurate forecasting of a building thermal performance can help to optimize its energy consumption. In addition, obtaining the Heat Loss Coefficient (HLC) allows characterizing the thermal envelope of the building under conditions of use. The aim of this work is to study the thermal inertia of a building developing a new methodology based on Long Short-Term Memory (LSTM) neural networks. This approach was applied to the Rectorate building of the University of Basque Country (UPV/EHU), located in the north of Spain. A comparison of different time-lags selected to catch the thermal inertia has been carried out using the CV(RMSE) and the MBE errors, as advised by ASHRAE. The main contribution of this work lies in the analysis of thermal inertia detection and its influence on the thermal behavior of the building, obtaining a model capable of predicting the thermal demand with an error between 12 and 21%. Moreover, the viability of LSTM neural networks to estimate the HLC of an in-use build... [more]

Drilling boreholes in gas zones and in zones with the possibility of migration or gas exhalation requires a high index of well tightness. An important parameter determining the effectiveness of sealing the annular space is the adhesion of the cement sheath to the rock formation. Low values of adhesion of the cement sheath to the rock formation and to the casing surface result in the formation of uncontrolled gas flows. The lack of adhesion also reduces the stabilization of the pipe column. To obtain the required adhesion, the annular space should be properly cleaned. Thorough removal of filter cake from the drilling fluid increases adhesion and reduces gas migration from the annular space. Therefore, in this work, the authors focus on determining the effect of cleaning the annular space on the adhesion of the cement sheath to the rock formation. The results of the research work allow for further research on the modification of spacers and cement slurries in order to obtain the required... [more]

A DC converter with the benefits of reverse power capability, less switching loss and wide voltage operation is presented and implemented for wide input voltage applications such as fuel cell energy, photovoltaic (PV) system and DC wind power. Two full bridge resonant circuits are used in the presented converter to achieve bidirectional power flow capability and reduce switching losses on active devices. To overcome the wide input DC voltage variation problem for fuel cell energy and PV solar panel, the topology morphing between the half bridge circuit and full bridge circuit is adopted on the primary side to obtain low (or high) voltage gain under a high (or low) input voltage condition. Therefore, the stable DC voltage is controlled at the load side by using the variable switching frequency modulation. The studied hybrid CLLC converter is tested by a 1 kW prototype and the performance is verified and confirmed by experiments.

Magnetic beamforming techniques can enhance the power transfer efficiency using focused magnetic fields by the multiple transmitters to the receivers. However, the intra-couplings that cause power leakage and phase distortion among the arrayed coils inevitably occur due to the deployment of coils having strong couplings between each other. Here, we analyze the adverse influences of intra-couplings and present the advantages of magnetically independent transmitters for multiple-inputs and single-output (MISO) WPT. The independent coil array can achieve focused magnetic fields by simply adjusting the amplitude of the transmitter voltage source without phase adjustment. The system also can eliminate the reactive power with the independent coil array to efficiently use the supplying power from the source. The analytical studies are verified by numerical and circuit simulation and experiments. Our analysis can be generalized to the MISO-WPT with an arbitrary number of transmitters. It can p... [more]

The large-scale interconnection of the power grid has brought great benefits to social development, but simultaneously, the frequency of large-scale fault accidents caused by extreme weather is also rocketing. The power grid is regarded as a representative complex network in this paper to analyze its functional vulnerability. First, the actual power grid topology is modeled on the basis of the complex network theory, which is transformed into a directed-weighted topology model after introducing the node voltage together with line reactance. Then, the algorithm of weighted reactance betweenness is proposed by analyzing the characteristic parameters of the power grid topology model. The product of unit reliability and topology model’s characteristic parameters under extreme weather is used as the index to measure the functional vulnerability of the power grid, which considers the extreme weather of freezing and gale and quantifies the functional vulnerability of lines under wind load, ic... [more]

In many electrical grids, the share of renewable energy generation increases. As these generators are typically connected to the grid via inverters, the level of grid inertia decreases. Such grids may therefore suffer from high rates of change of frequency during power imbalances. Modern wind turbines can help in controlling the frequency in such grids by providing synthetic inertia. A controller to provide synthetic inertia with wind turbines was developed at the Wind Energy Technology Institute in collaboration with Suzlon Energy. For this controller the influence of providing synthetic inertia on the mechanical loads of the wind turbine is assessed for different grid frequency scenarios. Such a scenario-based load analysis has not been published before, especially as the scenarios are derived from real measurements. The effect of the loads strongly depends on the analyzed grid frequency behavior. Ten months of high quality grid frequency measurements of the Indian grid are analyzed... [more]

In the present study, we provide useful data related to one of the most promising materials in thin-film solar cell technologies: Cu2ZnSnS4 (CZTS) kesterite structures. Sol-gel spin coating and chemical bath deposition methods were used to fabricate and further investigate Mo/CZTS/CdS/ZnO/AZO heterostructures. In order to examine the crystal structure of the samples, Raman scattering measurements using two excitation wavelengths (514.5 nm and 785 nm) were performed. Three Raman bands related to CZTS were found, as well as one that had its origin in CdS. By using laser ablation and performing Raman spectroscopy on these modified samples, it was shown that during the manufacturing process a MoS2 interlayer was formed between the CZTS and Mo layers. Our method proved that the CZTS layer in a multilayer device structure fabricated by solution-based methods can be decomposed, and thus a detailed analysis of the layer can be performed. Subsequently, current-voltage curves were investigated i... [more]

In this paper, the authors discuss the problem of the influence of the level of electrification in African countries on their sustainable development. The first aim of the article is to determine the relationship between changes in the electrification index and changes in the indicators showing individual components of sustainable development for African countries. The analyzed indicators of sustainable development include GDP per capita, Human Deveopment Index (HDI), and the CO2 emissions per capita indicator. The second goal of the article was to develop a synthetic indicator of sustainable development. This study uses the method of relationship research based on Gray Systems Theory—Gray Incidence Analysis. The main conclusion from the research carried out is that improving access to electricity is a necessary condition for the sustainable development of African countries. The lack of improvement in the availability of electricity is a basic barrier to development, especially in the... [more]

The filtered mass density function (FMDF) model has been employed for large-eddy simulations (LES) of compressible high-speed turbulent mixing and reacting flows. However, the mixing model remains a pressing challenge for FMDF methods, especially for compressible reactive flows. In this work, a temporal development mixing layer with two different convective Mach numbers, Mc=0.4 and Mc=0.8, is used to investigate the mixing models. A simplified one-step reaction and a real hydrogen/air reaction are employed to study the mixing and turbulence-chemistry interaction. Two widely used mixing models, interaction by exchange with the mean (IEM) and Euclidean minimum spanning tree (EMST), are studied. Numerical results indicate that no difference is observed between the IEM and EMST models in simple reaction flows. However, for hydrogen/air reactions, the EMST model can predict the reaction more accurately in high-speed flow. For mixing models in compressible reactive flows, the requirement of... [more]

The energy transition is accompanied by developing a digital decentralized low-carbon energy infrastructure with renewable-based generating plants as its main elements. In 2020, 15 photovoltaic power plants (PVPs) with an installed capacity of 364 MW were commissioned in Russia, which is 21.08% of the total installed PVP capacity of Russia. The findings of an analysis of Russia’s current regulatory and technical documents (RTD) concerning the frequency and active power flow control are presented. They indicate that all PVPs must participate in the general primary frequency control (GPFC). This requirement is due to large frequency deviations of transient processes resulting from an emergency active power shortage, which can shut down frequency-maintaining generating plants by relay or process protection devices and industrial consumers with significant damage to them. The requirements suggest full-scale tests of PVP to confirm their readiness for participation in GPFC. The program and... [more]

High energetic efficiency is a major requirement in industrial processes. The poor thermal conductivity of conventional working fluids stands as a limitation for high thermal efficiency in thermal applications. Nanofluids tackle this limitation by their tunable and enhanced thermal conductivities compared to their base fluid counterparts. In particular, carbon-based nanoparticles (e.g., carbon nanotubes, graphene nanoplatelets, etc.) have attracted attention since they exhibit thermal conductivities much greater than those of metal-oxide and metallic nanoparticles. In this work, thermal conductivity data from the literature are processed by employing rigorous statistical methodology. A high-accuracy regression equation is developed for the prediction of thermal conductivity of graphene nanoplatelet-water nanofluids, based on the temperature (15−60 °C), nanoparticle weight fraction (0.025−0.1 wt.%), and graphene nanoparticle specific surface area (300−750 m2/g). The strength of the impa... [more]

A vibration control concept based on vibration energy conversion and storage with respect to a serial-stiffness-switch system (4S) has previously been proposed. Here, we first present a rotational electromagnetic serial-stiffness-switch system as a novel practical vibration control system for experimental validation of the concept and, furthermore, an improved control strategy for higher vibration suppression performance is also proposed. The system consists of two spring-switch elements in series, where a parallel switch can block a spring. As an alternating mechanical switch, the experimental system uses two electromagnets with a shared armature. By connecting the armature to the rotating load or the base, the electromagnets decide which of the two spiral springs is blocked, while the other is active. A switching law based on the rotation velocity of the payload is used. Modelling and building of the experimental system were carried out. The corresponding experiment and simulation we... [more]

Autothermal reforming of bioethanol (ATR of C2H5OH) over promoted Ni/Ce0.8La0.2O1.9 catalysts was studied to develop carbon-neutral technologies for hydrogen production. The regulation of the functional properties of the catalysts was attained by adjusting their nanostructure and reducibility by introducing various types and content of M promoters (M = Pt, Pd, Rh, Re; molar ratio M/Ni = 0.003−0.012). The composition−characteristics−activity correlation was determined using catalyst testing in ATR of C2H5OH, thermal analysis, N2 adsorption, X-ray diffraction, transmission electron microscopy, and EDX analysis. It was shown that the type and content of the promoter, as well as the preparation mode (combined or sequential impregnation methods), determine the redox properties of catalysts and influence the textural and structural characteristics of the samples. The reducibility of catalysts improves in the following sequence of promoters: Re < Rh < Pd < Pt, with an increase in the... [more]

The main objective of the paper was comparative analyses of natural gas quantities delivered through the existing pipeline capacities in the last decade and new pipeline capacities for the prediction of possible future flows of gas import to Europe. Changes in physical flows have been influenced by European energy strategies that became green oriented resulting with a high amount of non-utilized transmission capacities. The research findings have shown that there is a significant decrease observed in transit of Russian gas through Ukraine in 2020 than previously. Concerning the high increase of LNG import to Europe in the same year, the start of operation of TurkStream, planned start of operation of Nord stream 2, authors project the gradual decrease of transit of Russian gas through Ukraine until the year 2025 with the total stop of transit of Russian gas until the year 2030. The change of supply routes will be also under the economic influence of low gas prices and coal and gas fuel... [more]

To improve the utilization of steel slag (SS) in CO2 capture and making building materials, the paper mainly discussed the effects of desulphurization gypsum (DG) and w/s ratio on strength development and CO2 capture capability of high Al content SS. It showed that 10 wt% DG enhanced the strength of hydration-curing SS by 262% at 28 days. Similarly, adding 6 wt% DG in carbonation-curing SS contributed to increases in strength and CO2 uptake by 283% and 33.54%, reaching 42.68 MPa and 19.12%, respectively. Strength decreases and CO2 uptake increases with w/s. Microanalysis (QXRD, SEM-EDS, TG-DTG, FTIR, XPS, and MIP) revealed that the main hydration products of SS were C-S-H gel and C4AH13, which transformed to ettringite with DG addition. The carbonation products were mainly calcite and aragonite. Additionally, the amount of aragonite, mechanically weaker than calcite, decreased and calcite increased significantly when DG was added in carbonation-curing samples, providing a denser struct... [more]

The prevention and evaluation of explosions requires suitable standards of measurement. As such, for this study two ignition thresholds, the ignition temperature and the minimum ignition irradiance were selected as the assessment criteria. These ignition threshold values were experimentally determined by heating stationary inert silicon carbide particles via thermal radiation with a large spot size in order to ignite quiescent methane-air fuel mixtures. A high-speed Schlieren camera was used to capture the progression of the formation and propagation of the flames throughout the experiments. The results of the experiments show that the irradiance and temperature threshold are directly and inversely proportional to the particle size, respectively. Furthermore, the irradiance and temperature thresholds have similar tendencies within the flammability limits; wherein, the minimum value corresponds to fuel mixtures at a stoichiometric ratio, and increases as the equivalence ratio shifts tow... [more]

Boosting the externalities across the water, energy, food, and waste (WEFW) sectors is challenging, especially considering tightening constraints such as population growth, climate change, resource-intensive lifestyles, increased waste production, sanitary crises and many others. The nexus approach supports the transition to a more sustainable future because intersectoral trade-offs can be reduced and externalities exploited, making imperative for decision makers, entrepreneurs, and civil society to simultaneously engage, with respect to all the components of the nexus. This research addressed intersectoral synergies and trade-offs in the case of the WEFW nexus in Romania, judging from the perspectives of entrepreneurial activity and economic results. The objective of this research was to explore the nexus in-depth by statistically analyzing the financial and economic indicators reported by active enterprises at county-level, based on the Romanian Ministry of Public Finance data. Resea... [more]

In this study, we numerically investigated the effects of design parameters, such as the strut geometry or diffusion angle, on the performance of an industrial turbine exhaust diffuser. Turbine exhaust diffusers are commonly used to change the kinetic energy of exhaust gases from the outlet of turbine stages into the static pressure. The turbine exhaust diffuser investigated in this work consisted of an annular diffuser with five identical struts equally spaced around the front circumference and a conical diffuser with a hub extension at the rear. Four design parameters were considered and several values for each parameter were tested in this study. The aerodynamic performances of the studied diffusers were evaluated according to their pressure recovery coefficients and rates of total pressure loss. Contours for the velocity, pressure, and entropy increase were plotted and compared for the various diffuser shapes. The numerical results showed that the strut thickness and the axially sw... [more]

The huge influence of the sampling rate on the performance of the digital PID control of a voltage source inverter (VSI) is revealed. It is shown that an appropriately chosen continuous-time model of a digital controller with the PWM power converter behaves like the actual discrete-time system, which allows for a simple controller analysis and design. The variable structure nature of the inverter with both the RC rectifier and an abruptly changing resistive load with two modes of operation within the sampling period is directly taken into account. Two simulation models, a discrete-time PWM and a continuous-time, of an inverter are presented, which are used to tune the PID controller and to evaluate the control performance. The behavior of the system in both modes is explained on the basis of the root loci and frequency characteristics. The results obtained for three sampling rates: 12.8, 25.6, and 51.2 kHz, are presented and compared with an actual VSI experiment. A comparison with oth... [more]

One of the methods of converting thermal energy into electricity is the use of thermoelectric generators (TEG). The method can be used in low-temperature waste heat conversion systems from industrial installations, but its serious limitation is the low efficiency of thermolectric generators and the relatively low power of the electric waveforms obtained. Increasing the obtained power values is done by multiplying the number of TEGs used, grouped into modules (MTEG). In such systems, the design of the module is extremely important, as it should ensure the best possible heat transfer between both sides of the TEG (hot and cold), and thus obtaining maximum electrical power. The article presents an analysis of a two-section flat plate heat hot side exchanger MTEG. The key parameters like effectiveness of exchange and MTEG efficiency and their impact on the efficiency of heat use and generated electric power were indicated. The tests showed an improvement in these main system parameters for... [more]