In order for the operation of the condensing heat exchanger to be efficient, the flue gas temperature at the inlet to the heat exchanger should be reduced so that condensation can start from the very beginning of the exchanger. A possible way to reduce the flue gas temperature is the injection of water into the flue gas flow. Injected water additionally moistens the flue gas and increases its level of humidity. Therefore, more favorable conditions are created for condensation and heat transfer. The results presented in the second paper of the series on condensation heat transfer indicate that water injection into the flue gas flow drastically changes the distribution of temperatures along the heat exchanger and enhances local total heat transfer. The injected water causes an increase in the local total heat transfer by at least two times in comparison with the case when no water is injected. Different temperatures of injected water mainly have a major impact on the local total heat tra... [more]

Fresh rice noodle was usually coated in a large amount of oil to avoid stickiness and extend the shelf life. Pre-treatment has been applied to reduce the quantity of oil in rice noodle. In this research, the pre-treatment and temperature effect on the rice noodle quality subjected to hot air drying, heat pump drying, and freeze drying was investigated. Texture, color, oil content, and starch gelatinization of the dried noodle was further evaluated. Results revealed that there were significant differences (p < 0.05%) in texture, color, oil content, and starch gelatinization in rice noodle subjected to pre-treatment. Furthermore, the texture, color, oil content, and starch gelatinization demonstrated a significant difference (p < 0.05%) in freeze drying rather than hot air drying and heat pump drying. The findings indicate that the qualitative features of the dehydrated noodle are synergistic to pretreatment and drying temperature. Despite superior quality shown by freeze drying, t... [more]

Due to the target of carbon neutrality, energy saving has become more important than ever. At the same time, the widespread use of distributed energy systems and the regional utilization of industrial waste heat leads to the existence of multiple heat sources in an area. Therefore, how to design an economical and reliable pipeline network to meet energy-saving demand under multiple heat source conditions becomes a problem. In this work, an optimization method is established to determine the optimal pipeline network topology with minimum total annual cost. In this optimization method, Star tree algorithm, Kruskal algorithm and GeoSteiner algorithm are combined with a linear programming model to establish a distributed energy pipeline network for multiple heat sources. The model incorporates Euclidean Steiner Minimum Tree and Rectilinear Steiner Minimum Tree in the consideration of the topology optimization of Distributed Energy System pipeline networks. Four pipeline network topologies,... [more]

A digitalization of business process through utilizing Digital Twins is an approach that assists companies to align themselves with changes of technology development, and accordingly, improve their outcomes. To take full advantage of implementing Digital Twins, the importance of the creative phase role as pillars of this technology on the performance of the other parts and overall outcome should not be overlooked. This research addresses the lack of an integrated framework for setting up the creative phase of digital twins. To design the proper framework, by relying on a qualitative empirical method, an interview with persons who are experts in the Digital Twin area was organized to collect the information about all obvious and hidden aspects of this phase and manifest what kind of entities participate in this phase, what potential challenges and obstacles exist and what solution is effective to overcome them. The structural feature of the proposed framework continuously prepares the s... [more]

This paper presents a framework for the use of variable pricing to control electricity imported/exported to/from both fixed and unfixed residential distributed energy resource (DER) network designs. The framework shows that networks utilizing much of their own energy, and importing little from the national grid, are barely affected by dynamic import pricing, but are encouraged to sell more by dynamic export pricing. An increase in CO2 emissions per kWh of energy produced is observed for dynamic import and export, against a baseline configuration utilizing constant pricing. This is due to feed-in tariffs (FITs) that encourage CHP generation over lower-carbon technologies. Furthermore, batteries are shown to be expensive in systems receiving income from FITs and grid exports, but for the cases when they sell to/buy from the grid using dynamic pricing, their use in the networks becomes more economical.

The greenness evaluation of literature analytical methods for pterostilbene (PT) analysis was not performed. Accordingly, the rapid, sensitive, and green/sustainable reversed-phase high-performance thin-layer chromatography (RP-HPTLC) method was developed and compared to the normal-phase (NP)-HPTLC (NP-HPTLC) for the estimation of PT with a classical univariate calibration. The RP quantification of PT was performed using green solvent systems; however, the NP analysis of PT was performed using routine solvent systems. The PT was detected at 302 nm for both of the methods. The greenness scores for the current analytical assays were evaluated by the analytical GREEnness (AGREE) metric approach. The classical univariate calibration for RP and NP methods indicated the linearity range as 10−1600 and 30−400 ng band−1, respectively. The RP method was more reliable for PT analysis compared to the NP method. The PT contents in commercial capsule dosage form were found to be 100.84% using the RP... [more]

The novelty of this study is twofold: AgNPs were obtained and characterized using Artemisia absinthium (A. absinthium), Humulus lupulus (H. lupulus), and Thymus vulgaris (T. vulgaris) plants extracts; moreover, a green and environmentally friendly approach for the synthesis of silver nanoparticles (AgNPs) using aqueous extracts was developed. This paper discusses new approaches about the synthesis of AgNPs. T. vulgaris, H. lupulus, and A. absinthium, which are renewable and common plants, perfect as reducing, stabilizing, and capping agent for green synthesis of silver nanoparticles (AgNPs). The extracts and synthesized AgNPs were characterized by various physico-chemical, phytochemical, morphological scanning electron microscope (SEM/EDS) and transmission electron microscope scanning (TEM), and antibacterial activity. The antioxidant activity of extracts and AgNPs were also assessed by 2,2′-azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS•+), 2,2-diphenyl-1-picrylhydrazyl (DPP... [more]

The presence of antibiotics in different environmental matrices is a growing concern. The introduction of antibiotics into the soil is mainly due to sewage treatment plants. Once in the soil, antibiotics may become toxic to microbial communities and, as a consequence, can pose a risk to the environment and human health. This study evaluates the potential toxicity of the antibiotic clarithromycin (CLA) in relation to the bacterial community of 12 soils with different characteristics. Bacterial community growth was evaluated in soils spiked in the laboratory with different concentrations of CLA after 1, 8, and 42 incubation days. The results indicated that the addition of clarithromycin to the soil may cause toxicity in the bacterial communities of the soil. In addition, it was observed that toxicity decreases between 1 and 8 incubation days, while the bacterial community recovers completely in most soils after 42 incubation days. The results also show that soil pH and effective cation e... [more]

The long-term field experiment on the Kastanozem showed that the standard moldboard plowing to a depth of 22 cm (control), chiseling to a depth of 35 cm, and three-tier plowing (machine type PTN−40) to a depth of 45 cm was incapable of providing a stable soil structure and aggregate system. The transcendental Biogeosystem Technique (BGT*) methodology for intra-soil milling of the 20−45 cm layer and the intra-soil milling PMS−70 machine were developed. The PMS−70 soil processing provided the content of 1−3 mm sized aggregate particle fraction in the illuvial horizon of about 50 to 60%, which was 3-fold higher compared to standard plowing systems. Soil bulk density reduced in the layer 20−40 cm to 1.35 t m−3 compared to 1.51 t m−3 in the control option. In the control, the rhizosphere developed only in the soil upper layer. There were 1.3 roots per cm2 in 0−20 cm, and 0.2 roots per cm2 in 20−40 cm. The rhizosphere spreads only through the soil crevices after chilling. After three-tier pl... [more]

Global warming and the increase in organic waste from agro-industries create a major problem for the environment. In this sense, microbial fuel cells (MFC) have great potential for the generation of bioelectricity by using organic waste as fuel. This research produced low-cost MFC by using zinc and copper electrodes and taking blueberry waste as fuel. A peak current and voltage of 1.130 ± 0.018 mA and 1.127 ± 0.096 V, respectively, were generated. The pH levels were acid, with peak conductivity values of 233. 94 ± 0.345 mS/cm and the degrees Brix were descending from the first day. The maximum power density was 3.155 ± 0.24 W/cm2 at 374.4 mA/cm2 current density, and Cándida boidinii was identified by means of molecular biology and bioinformatics techniques. This research gives a new way to generate electricity with this type of waste, generating added value for the companies in this area and helping to reduce global warming.

In this work, an effective numerical simulation method was developed and used to analyze the effects of natural gas mixing ratio and pilot-main injection, main-post injection, and pilot-main-post injection strategies on the combustion and emission characteristics of diesel engine fueled with dual fuel. Firstly, the one-dimensional calculation model and three-dimensional CFD model of the engine were established by AVL-BOOST and AVL-Fire, respectively. In addition, the simplified chemical kinetics mechanism was adopted, which could accurately calculate the combustion and emission characteristics of the engine. The results show that the cylinder pressure and heat release rate decrease with the increase of the natural gas mixing ratio and the NOx emission is reduced. When the NG mixing ratio is 50%, the NOx and CO emission are reduced by 47% and 45%, respectively. When the SODI3 is 24 °CA ATDC, the NOx emission is reduced by 29.6%. In addition, with suitable pilot-main injection and pilot-... [more]

A collaborative framework by the synergy of Hazard and Operability (HAZOP) process and the Decision-Matrix Risk Assessment (DMRA) in association with safety-color mapping (SCM) is presented, in order to identify critical points and prioritize risks, and also to visualize the occupational safety and health (OSH) situation, at the workplaces (i) of a sour crude-oil processing industry (SCOPI), and (ii) of a measurement and regulatory station (MRS) in a gas transportation system (GTS), situated in Greece. Firstly, the conventional HAZOP analysis is executed in order to identify the potential fault causes of abnormal conditions (deviations) in the plants. The application of the DMRA-modus is valuable to rank the identified risks (hierarchy of risks). In view of the results, both of the HAZOP pattern (for identifying the hazards) and also the DMRA one (for assessing and ranking the risks), SCMs have been derived for the specific workplaces of the SCOPI and the MRS/GTS station, which could b... [more]

Analyzing the entire liquefaction cycle, using a large temperature span with many degrees of freedom, may not always result in a practical solution. The objective of this paper is to investigate the feasibility of using an environmentally friendly refrigerant compound, ammonia, in the mixed refrigerant (MR) for the liquefied natural gas (LNG) pre-cooling cycle through thermodynamic performance, economic analyses and environmental impact. Fifteen cases studies within three major mixed refrigerants groups of MR-1, MR-2 and MR-3 were developed by adding ammonia to various molar compositions of lighter and heavier hydrocarbons. The thermodynamic analysis shows increasing ammonia’s concentrations in the mixed refrigerant by 10% had the largest enhancement on coefficient of performance (COP) of MR-1 by 0.67 and decreased the specific energy consumption of the pre-cooling cycle by 128 kJ/kg compared to the base case. Economic analyses revealed that the mixed refrigerant MR-1, with ammonia, me... [more]

By activating PPAR-γ, thiazolidinediones normalize glucose levels in animal models of type 2 diabetes and in patients with this pathology. The aim of the present study was to analyze 219 new derivatives in silico and select the best for synthesis, to be evaluated for acute oral toxicity in female rats and for control of diabetes-related parameters in a rat model of streptozotocin-induced diabetes. The best compound was chosen based on pharmacokinetic, pharmacodynamic, and toxicological parameters obtained in silico and binding orientation observed by docking simulations on PPAR-γ. Compound 1G was synthesized by a quick and easy Knoevenagel condensation. Acute oral toxicity was found at a dose greater than 2000 mg/Kg. Compound 1G apparently produces therapeutic effects similar to those of pioglitazone, decreasing glycaemia and triglyceride levels in diabetic animals, without liver damage. Moreover, it did not cause a significant weight gain and tended to reduce polydipsia and polyphagia... [more]

A multi-staged direct contact membrane distillation (MDCMD) system is designed considering a novel bispacer configuration in the present study. The proposed bispacer DCMD, which has not been addressed in the literature to best of our knowledge, is considered with two purposes, including increasing mechanical stability and turbulence. As increasing turbulence leads to increasing Nusselt number, the bispacer MDCMD provides higher permeate flux. An analytical approach is considered using energy and mass balance correlation. The effect of bispacer and feed operating conditions, including feed temperature, feed flow rate, feed salinity, and the number of stages on permeate flux and salt rejection of the developed MDCMD, are examined both analytically and experimentally. The performance and sustainability of the developed system were investigated by analyzing the parameters, including thermal efficiency (η), gained output ratio (GOR), and temperature polarization coefficient (TPC).

By converting bicarbonates via Chlorella vulgaris photosynthesis, one can obtain valuable biofuel products and find a route toward carbon-derived fossil fuel conversion into renewable carbon. In this research, experiments were carried out in the PhotoBioCREC prototype under controlled radiation and high mixing conditions. Sodium bicarbonate (NaHCO3) was supplied as the inorganic carbon-containing species, at different concentrations, in the 18 to 60 mM range. Both the NaHCO3 concentrations and the organic carbon concentrations were quantified periodically during microalgae culture, with the pH being readjusted every day to the 7.00 level. It was found that sodium bicarbonate was converted with a selectivity up to 33.0% ± 2.0 by Chlorella vulgaris. It was also observed that the reaction rate constant for inorganic carbon conversion was 0.26 ± 0.09 day−1, while the maximum reaction rate constant for organic carbon formation was achieved with a 28 mM NaHCO3 concentration and displayed a 1... [more]

Three products hydrocyclone screen (TPHS) can be considered as the combination of a conventional hydrocyclone and a cylindrical screen. In this device, particles are separated based on size under the centrifugal classification coupling screening effect. The objective of this work is to explore the characteristics of fluid flow in TPHS using the computational fluid dynamics (CFD) simulation. The 2 million grid scheme, volume fraction model, and linear pressure−strain Reynolds stress model were utilized to generate the economical grid-independence solution. The pressure profile reveals that the distribution of static pressure was axisymmetric, and its value was reduced with the increasing axial depth. The maximum and minimum were located near the tangential inflection point of the feed inlet and the outlets, respectively. However, local asymmetry was created by the left tangential inlet and the right screen underflow outlet. Furthermore, at the same axial height, the static pressure grad... [more]

Soil contamination by mercury, which is one of the most toxic heavy metals due to its bioaccumulative capacity, poses a risk to the environment as well as health. The Almadén mining district in Ciudad Real, Spain is one of the most heavily-polluted sites in the world, making the soils unusable. Bioremediation, and more specifically phyto-rhizoremediation, based on the synergistic interaction established between plant and Plant Growth Promoting Rhizobacteria (PGPR), improves the plant’s ability to grow, mobilize, accumulate, and extract contaminants from the soil. The objective of this study is to evaluate the plant growth-promoting ability of four PGPR strains (and mixtures), isolated from the bulk soil and rhizosphere of naturally grown plants in the Almadén mining district, when they are inoculated in emerged seeds of Lupinus albus, var. Dorado in the presence of high concentrations of mercury. After 20 days of incubation and subsequent harvesting of the seedlings, biometric measurem... [more]

Long-term structure stability of aerobic granules is critical to maintaining stable wastewater treatment performance. In this study, granulation and long-term stability of sludge-treating synthetic wastewater with a low chemical oxygen demand to nitrogen (COD/N) ratio of 4:1 and COD concentration of 400 mg/L in anoxic-oxic conditions were investigated for over 300 days. Inoculated suspended sludge gradually transformed into granules-dominant sludge on day 80. Due to the improved sludge volume index after 30 min settling (SVI30), mixed liquor suspended solids (MLSS) reached 5.2 g/L on day 140. Without any external intervention or disturbance, aerobic granules started to disintegrate from day 140, causing the increase in SVI and the decrease in biomass concentration until day 210, with the average sludge size reduced to 243 µm. From day 210, granular sludge started to be re-established by re-granulation, and the average granule size increased to 500 µm on day 302. During these disintegra... [more]

One of the influential models in the artificial neural network (ANN) research field for addressing the issue of knowledge in the non-systematic logical rule is Random k Satisfiability. In this context, knowledge structure representation is also the potential application of Random k Satisfiability. Despite many attempts to represent logical rules in a non-systematic structure, previous studies have failed to consider higher-order logical rules. As the amount of information in the logical rule increases, the proposed network is unable to proceed to the retrieval phase, where the behavior of the Random Satisfiability can be observed. This study approaches these issues by proposing higher-order Random k Satisfiability for k ≤ 3 in the Hopfield Neural Network (HNN). In this regard, introducing the 3 Satisfiability logical rule to the existing network increases the synaptic weight dimensions in Lyapunov’s energy function and local field. In this study, we proposed an Election Algorithm (EA)... [more]

The stress environments of rock masses are complex. To explore the mechanical properties of sandstone under earthquake or disturbance loads, laboratory triaxial creep tests under different disturbance loads were conducted on sandstone from Fuxin, Liaoning Province, China. Given the disturbance load, a creep deformation pattern for sandstone was analyzed, and the influence of the disturbance load on the mechanical properties of rock was considered. Thus, a constitutive model of rock under creep disturbance load was established. The results show that (1) the creep curve can be divided into four stages: attenuation creep, steady creep, disturbance creep, and acceleration creep; the increment of disturbance creep varies for different disturbance loads and the larger the disturbance load, the larger the disturbance creep deformation; (2) with increasing disturbance loads, the long-term strength, failure time, and elastic modulus of sandstone decreases linearly, while the peak strain increas... [more]

Microbial fuel cells (MFCs) are a recent biotechnology that can simultaneously produce electricity and treat wastewater. As the nature of industrial wastewater is very complex, and it may contain a variety of substrates—such as carbohydrates, proteins, lipids, etc.—previous investigations dealt with treatment of individual pollutants in MFCs; the potential of acetic acid, sucrose, albumin, blood, and their mixture has rarely been reported. Hence, the current investigation explored the contribution of each substrate, both separately and in mixture. The voltage generation potential, current, and power density of five different substrates—namely, acetic acid, sucrose, albumin, blood, and a mixture of all of the substrates—was tested in a dual-chambered, anaerobic MFC operated at 35 °C. The reaction time of the anaerobic batch mode MFC was 24 h, and each substrate was treated for 7 runs under the same conditions. The dual-chambered MFC consisted of anode and cathode chambers; the anode cha... [more]

In situ leaching (ISL) uranium mining technology is an in situ mining technology in which the chemical solution is injected into the ore-bearing strata through drilling wells, and the solution moves along the ore bed by controlling the hydraulic gradient of the flow field and reacts with the ore to form uranium-bearing solution. To reduce leaching dead angle in the process of leaching, each pumping and injection unit should achieve uniform leaching at the end of production, and appropriate pumping and injection mode should be adopted for pumping and injection wells of each unit in the mining area. In this paper, on the basis of the actual production data of a sandstone uranium mine, we established the unit flow model of ISL uranium mining area by using GMS software. The unit flow balance of 72 boreholes in the whole mining area was analyzed and optimized through the model. The concept of flow microbalance of pumping and injection unit in the mining area is put forward for the first tim... [more]

Attachment of particles and droplets to bubbles—the latter being of various fine sizes and created by different techniques (as described in detail)—forms the basis of flotation, a process which indeed was originated from mineral processing. Nevertheless, chemistry often plays a significant role in this area, in order for separation to be effective, as stressed. This (brief) review particularly discusses wastewater treatment applications and the effect of bubble size (from nano- to micro-) on the flotation process.

Blanks, an important raw material for the manufacturing industry, are semi-finished products for further processing. The energy consumption and processing efficiency in the process of blank production and use can be determined to a great extent in the blank design stage. The design of appropriate blank dimensions is an important means of realizing ecological civilization. Current blank designs seldom consider the production conditions of enterprises. In order to design energy-saving and efficient blanks on the basis of the actual conditions of an enterprise, this paper establishes the blank dimension optimization design model from the perspective of a business compass. With energy savings and efficiency as the goals, and the blank production and use-process equipment parameters as variables, the blank dimensions were optimized by an NSGA-II algorithm, and the results showed that the energy efficiency and processing efficiency of the designed blank dimensions were significantly better t... [more]