A large number of aromatic substances can be found in so-called coal tar (containing >10,000 individual compounds), which is a mixture of heavy liquid fractions (dense viscous black liquor, tended to solidification) obtained after the pyrolysis of coal (solid product—coke, gas products, and light liquid products are also produced during the process). Volatile monocyclic aromatic hydrocarbons, which are naturally occurring in coal tar, can be exploited as premium raw materials for the production of graphene by chemical vapor deposition (CVD). Moreover, aromatic chemicals (compounds with benzene rings) can produce graphene at lower temperatures than other small-molecule gas feedstocks (for graphene growth via methane gas, the temperature must be at least 900 °C). The intermediate reaction mechanism involved in the creation of graphene from various temperature ranges of monocyclic aromatic hydrocarbons in benzene ring structures has long been a fascinating enigma. Accordingly, in this pap... [more]

Domoic acid (DA) is a neurotoxin mainly produced by Pseudo-nitzschia diatom, which belongs to the genera Rhomboida. It can combine with the receptors of glutamate of neurotransmitters, then affecting the normal nerve signal transmission of the organism and causing nervous system disorders. However, as a natural marine drug, DA can also be used for pest prevention and control. Although the distribution of DA in the world has already been reported in the previous reviews, the time and location of its first discovery and the specific information are not complete. Therefore, the review systematically summarizes the first reported situation of DA in various countries (including species, discovery time, and collection location). Furthermore, we update and analyze the factors affecting DA production, including phytoplankton species, growth stages, bacteria, nutrient availability, trace metals, and so on. These factors may indirectly affect the growth environment or directly affect the physiol... [more]

The productivity prediction of gas wells in carbonate gas reservoirs is greatly affected by the characteristics of gas−water two-phase flow and fracture seepage parameters. Compared with numerical simulation, the productivity prediction based on the analytical model is fast and widely used, but the traditional analytical model is fairly simplified while dealing with the nonlinear problem of the two-phase seepage equation, leading to a large discrepancy in the results of dynamic analysis. To solve this problem, this paper considers the characteristics of gas−water two-phase flow in the reservoir and fracture, uses the dual-medium model to characterize the stress sensitivity of the fracture and reservoir, and establishes a gas−water two-phase productivity prediction model for carbonate gas reservoirs. Combining the flowing material balance equation with the Newton iteration method, the nonlinear parameters of the percolation model are updated step by step with the use of average formatio... [more]

Aquatic algae are a rich source of a wide range of bioproducts intended to compete for a sizable global market share. Thanks to the gradual shift towards the use of natural products, microalgae-derived bioactive compounds offer an ecofriendly and vegan option to the cosmeceutical sector, whose products aim to improve skin health but currently consist of mostly synthetic chemicals. In particular, algae-derived vitamins and their precursors are being explored and widely used in the cosmeceuticals industry as compounds that contain biologically active ingredients with therapeutic benefits. The present review highlights the current strategies for industrial production of an array of vitamins from algae for cosmeceutical applications. When compared to traditional plant sources, algae have been found to accumulate vitamins, such as A, B1, B2, B6, B12, C and E, in high concentrations. The purpose of this review is to provide context for the development of a green and sustainable algae-derived... [more]

To overcome the shortage of traditional temperature sensors, this paper adopts infrared thermal imaging technology for temperature measurement. To avoid the spatial information loss issue during the image data vectorization process, this paper adopted the spatial relationship between pixels in principal component analysis (PCA) model training, which is called spatial information-based PCA (SIPCA). Then, spatial information is also used in the fault localization method to enhance the fault location performance. Tested by an experimental tank system, the proposed method achieves better performance than the traditional PCA approach, and it can detect heat leakage faults on the surface of the equipment.

Food packaging systems are continually impacted by the growing demand for minimally processed foods, changing eating habits, and food safety risks. Minimally processed foods are prone to the growth of harmful microbes, compromising quality and safety. As a result, the need for improved food shelf life and protection against foodborne diseases alongside consumer preference for minimally processed foods with no or lesser synthetic additives foster the development of innovative technologies such as antimicrobial packaging. It is a form of active packaging that can release antimicrobial substances to suppress the activities of specific microorganisms, thereby improving food quality and safety during long-term storage. However, antimicrobial packaging continues to be a very challenging technology. This study highlights antimicrobial packaging concepts, providing different antimicrobial substances used in food packaging. We review various types of antimicrobial systems. Emphasis is given to... [more]

Over the last decade, the market has experienced a growing interest in hybrid photovoltaic-thermal (PVT) technologies, although more long-term studies are needed before air-based PVT panels are fully implemented. In this paper, we present the experimental framework developed around an air-based PVT collector, consisting of a high-quality photovoltaic laminate and a newly designed thermal absorber. The experimental performance of the collector was measured both in lab testing and in a pilot plant during one of the field operations. Results show an almost constant electrical performance of 15−19%, and a thermal performance that changes a lot, ranged between 15−52% for the individual panel and 11−35% for the system of 2.5 panels in series (to maximize output temperature). Field operation presents average thermal and electrical efficiencies ranged between 16−20% with an electrical−thermal generation ratio close to 1:1.

The electrowetting display (EWD) has obtained much attention as its readability in sunlight and flexible displays. Oil motion control is an important factor for the display performance of EWD. In this paper, we propose a low-cost drive and detection scheme for EWD. The dynamic drive and detection scheme for EWD consists of a low-cost camera, computer and graphical detection system, and portable driving control system. The proposed scheme can detect oil leaking, splitting, and non-recovered defects successfully. Moreover, surface defects such as the hydrophobic layer burned and scratch can also be captured and analyzed by the proposed scheme. We hope that this scheme can provide a drive and detection platform for other EWD researchers.

The growing demand for energy and the concern about environmental impacts reinforce the necessity for renewable energy sources such as biofuels. In this study, cake generated in the babassu oil extraction was evaluated as a potential feedstock for solid biofuel production, and it contains a blend of cashew nutshell, sugarcane bagasse, carnauba straw, and carnauba stalk. All samples were characterized by proximate analysis and Higher Heating Value. Carbonization was used to improve energy performance and compaction to understand the mechanism and the characteristics of the biomasses compacted. In the extraction of babassu oil, fresh and aged (90 days) kernel samples were used. The fresh samples reached a yield of 59.8%, and the aged samples reached a yield of 70.66%. The carbonization of babassu cake was carried out in a Muffle furnace at temperatures of 250, 300, 350, and 400 °C. The fresh babassu cake showed an HHV of 23.06 MJ kg−1 and after carbonization of 28.07 (250 °C), 30.69 (300... [more]

The procedure of FEM calculations was presented in the paper. The numerical calculations concerned a simulation of crack distribution and propagation in concrete beams reinforced longitudinally without shear reinforcement. The analysis of the obtained FEM results showed different modes of failure in the beams when shear span-to-depth ratio was a/d = 2.5 and a/d = 1.8. In the analyzed beams, the ratio of longitudinal reinforcement and the mechanical properties of the steel bars were also changing parameters. The FEM results have showed that the shear failure of reinforced concrete beams without transverse reinforcement significantly depends on the ratio and yield strength of longitudinal steel bars. Furthermore, the results of numerical calculation for the beams of a/d = 2.5 were also juxtaposed with experiments performed by the author on two longitudinally reinforced concrete beams.

Heavy-fuel aviation piston engines (HF-APEs) are widely used in general aviation and unmanned aerial vehicle (UAV) due to their safety and fuel economy. This paper describes a numerical and experimental study of scavenging and combustion processes on a 2-Stroke Direct Injected HF-APEs for light aircraft, with its cylinder specifically designed as cross scavenging. A 3-Dimentional transient model of in-cylinder flow and combustion process is established by the Forte platform, and the engine test system is set up. By comparing the simulation results to the experimental results, it showed that multi-ports cross scavenging can generate unbalanced aerodynamic torque in the cylinder. In the compression process, the swirl ratio (SR) gradually increases, and the peak SR reaches 15. Moreover, approximately 25% of exhaust residual gas in the cylinder is conducive to the fuel atomization and evaporation process in a high-altitude environment. When the injection timing is between −8 °CA and −16 °C... [more]

The aim of is paper is to address the problem of identifying critical factors in the analysis of non-coal mine explosion accidents as well as to improve the rationality and accuracy of the risk analysis results. Hence, we developed a risk identification method for non-coal mine explosion accidents, combining the Systems-Theoretic Accident Model and Process (STAMP) and the Rank-order Centroid (ROC) method based on the Poset decision-making theory. The proposed method was applied to identify risk in engineering cases. Findings showed that four main dangerous events (out of twelve identified ones) were the primary culprits of related accidents, which were the events “Blasters without licenses and illegal operation” at the basic level, the event of “the confusion about the safety management system of non-coal mine companies” at the control level, and the event of “the failure about the emergency management departments” and “public security departments” at the supervision level. The approxi... [more]

Adsorption kinetics of As and Pb onto composite beads synthesized with stone powder, chitosan, and maghemite (SCM beads) with weight ratio of 1:1:0.5 were investigated in batch mode. Several kinetic models such as pseudo-first order kinetic model (PFOKM), pseudo-second order kinetic model (PSOKM), two compartment first order kinetic model (TCFOKM), and modified two compartment first order kinetic model (MTCFOKM) were utilized to analyze the kinetics. Although the beads had low specific surface area and pore volume, MTCFOKM, one of two compartment models, could predict the most accurately because the As and Pb were adsorbed onto at least two kinds of adsorption sites such as functional groups in chitosan and Fe in maghemite. In MTCFOKM, both the fast adsorption fraction (f1’) and the fast adsorption constant (k1’) for Pb were higher than those for As. Therefore, the equilibrium time (teq) for Pb adsorption was shorter than that for As adsorption, indicating that Pb adsorption was more a... [more]

In order to obtain the damage characteristics of a roadway wall caused by a gas explosion, the damage evaluation theory of a roadway wall under the dynamic and static loads of a gas explosion is analyzed in this paper. Meanwhile, an evaluation method (overpressure−impulse criterion) is selected to evaluate the damage of the roadway wall under the impact load of the gas explosion. A mathematical model and a physical analysis model of the roadway wall damage are established by LS-DYNA software. The dynamic response of the roadway wall caused by the dynamic and static loads of the gas explosion is numerically simulated. The overpressure and impulse of gas explosion propagation are measured, while the damage data of the roadway wall under different overpressure and impulse loads are obtained. The P-I curves of the roadway wall under different dynamic and static loads of gas explosion are drawn. The fitting formula of P-I curves of the roadway wall is obtained. The influence of different ge... [more]

Excessive fertilizer application in the cropping industry leads to excessive nitrogen and phosphorus in surrounding water bodies, which causes farmers to increase economic cost and damage the environment. To address the problem, we built a crop-soil runoff soil column test system, setting eight fertilizer application levels for eggplants. Then, crop yield, soil fertility and pollutant concentrations in the receiving water bodies were measured. The process of fertilizer application on the water quality of surrounding receiving water bodies and the rationality of fertilizer application were analyzed. The results showed that crop yield, soil fertility, and pollutant concentrations in the receiving water increased with the increase in fertilizer application. The crop yield stabilized when the fertilizer application amount was higher than 0.12 kg/m2; the concentrations of total nitrogen (TN) and total phosphorus (TP) in the water increased significantly with the increase in fertilizer appli... [more]

Successful progress in industrial development requires the use of cost-effective materials and advanced innovative materials with improved properties [...]

A sustainable separation concept for large-scale recycling of NdFeB magnets under atmospheric pressure was developed by utilizing a combination of two separation concepts known from the literature: (I) selective pre-separation by in situ chlorination and evaporation of ground oxidized NdFeB material and (II) subsequent distillation for high-purity recovery of all recyclable chlorinated material components, especially its Rare Earth Elements (REEs). Theoretically, simplified estimations of the time conversion curves at 1173 K, 1273 K, and 2000 K of a single particle resulted in the idea of realizing chlorination in some kind of combustion chamber, fluidized bed, or continuous combustion chamber. After chlorination, all non-volatile components, such as REE chlorides, are condensed out of the vapor phase in a single-stage phase separator. For subsequent fine separation by distillation (1292−1982 K for Rare Earth Chlorides and 418−867 K at 2500 kPa for boron and zirconium chloride recovery... [more]

The multicomponent reaction of 2-nitroacetophenone (or nitroacetone), acetaldehyde diethyl acetal, β-dicarbonyl compound, and ammonium acetate in an acetic acid solution allowed the acquisition of previously undescribed 4-methyl-substituted derivatives of 5-nitro-1,4-dihydropyridine in satisfactory yields. The oxidation of the obtained 5-nitro-1,4-dihydropyridine derivatives resulted in the corresponding 2,4-dimethyl-5-nitropyridines. In addition, for the first time in the synthesis of unsymmetrical 1,4-dihydropyridines by the Hantzsch reaction acetaldehyde, diethyl acetal was used as a source of acetaldehyde. The use of more volatile and sufficiently reactive acetaldehyde in this reaction did not lead to a controlled synthesis of unsymmetrical 5-nitro-1,4-dihydropyridines. The proposed multicomponent approach to the synthesis of 4-methyl-substituted 5-nitro-1,4-dihydropyridines and their subsequent aromatization into pyridines made it possible to obtain previously undescribed and hard... [more]

The production of fused magnesia is a process in which raw materials are melted and recrystallized in the electric-fused magnesia furnace (EFMF). Temperature is the key factor that affects production, but it is difficult to be observed and monitored due to the high internal temperature. Thus, the working current is the standard for workers to judge whether the production process is normal. In order to master heat transfer characteristics in the furnace and accurately control the processes, a three-dimensional mathematical model of coupling the magnetic−fluid−thermal multifield has been established in a six-electrode EFMF. The model also considers the thermal decomposition of magnesium carbonate in the furnace. The phase change of materials is simulated by the solidification and melting model. The results show that the current density and Joule heat are concentrated in the region below the electrode. When the current size increases to 12,500 A, the molten pool begins to be connected. Th... [more]

This paper proposes a timetable coordination method for transfer problems in a bus transit system. With a given bus network, a stochastic mixed-integer linear programming (MILP) model has been formulated to obtain coordinated bus timetables with the objective of minimizing a weighted sum of the average value of total waiting time and its average absolute deviation value, allowing for random bus travel time. The vital decision variable is the terminal departure offset time of each target bus trip within a certain off-peak period. The robust MILP model can also be used to solve the first-bus transfer problem with the introduction of several new linear constraints. A solution method based on the Monte Carlo simulation has been developed to solve the MILP model. Numerical experiments have been conducted for different scenarios. The results indicate that bus timetables coordinated by the developed model are capable of substantially reducing waiting time for transfer and non-transfer passeng... [more]

This work established a finite element analysis (FEA) model of an inserted tooth-type slip assembly under bear setting load and axial load, calculated the differences between the inserted teeth of the sidetracking packer slip-formed furrow shapes on the casing face, and analyzed the setting reliability of the inserted tooth slip sidetracking packer. The orthogonal optimization analysis of the structural parameters of the sidetracking packer was carried out on the basis of the furrow effect. Finally, the setting experiment was conducted with the inserted tooth slip sidetracking packer developed to verify correctness of the FEA model and the simulation results. The results show that in the FEA and calculation of the setting process of the inserted tooth-type slip, it is not only necessary to consider the furrow friction coefficient, but also the effect of the ridge on the furrow friction coefficient. The corresponding furrow friction coefficient varies according to the different furrow e... [more]

This paper characterizes the body of knowledge on remote sensing from 1999 to 2021 by employing bibliometric techniques based on the Science Citation Index databases and the Social Science Citation Index of the Web of Science, abbreviated to “SCI” and “SSCI”, respectively. A total of 28,438 articles were analyzed from various aspects of the publication characteristics, such as countries, institutes, subjects, journals, and keywords. Dynamic changes in published remote sensing research were examined by segregating the 19-year period into 4 stages. Co-occurrences of keywords from three aspects were evaluated, including technology, methodology, and applications. Results show that “hyperspectral remote sensing”, “classification”, “monitoring” and “MODIS” in the category of technology have emerged more frequently in recent years, and there are strong co-occurrences of “remote sensing” and “GIS” in the remote sensing technology category. In addition, there was a marked shift from traditional... [more]

To accurately evaluate the shale oil resources in the Funing Formation of the Gaoyou Sag, Subei Basin, light and heavy hydrocarbon correction models of S1 were developed based on the rock pyrolysis of liquefrozen, conventional, and oil-washed shales. The improved ΔlogR technique was applied to establish the TOC, S1, and S2 logging evaluation methods. The results showed that the S2 values after oil washing were significantly lower than before. The difference between these two S2 (ΔS2) values is the heavy hydrocarbon correction amount of S1, which is about 0.69 S2. There was almost no loss of light hydrocarbons during liquefrozen shales’ pyrolysis tests; the ratio of liquefrozen to conventional S1 values is the light hydrocarbon correction factor, which is about 1.67. The corrected S1 is about 3.2 times greater than the conventional shale-tested value. The S1 and TOC are obviously “trichotomous”; a TOC greater than 1.5% and corrected S1 larger than 4.0 mg/g corresponds to the enriched re... [more]

Multiphase vortices are widely present in the metallurgical pouring processes, chemical material extraction, hydroelectric power plant energy conversion, and other engineering fields. Its critical state detection is of great significance in improving product yield and resource utilization. However, the multiphase vortex is a complex dynamics problem with highly nonlinear features, and its fluid-induced vibration-generation mechanism faces significant challenges. A fluid-solid coupling-based modeling method is proposed to explore mass transfer process with the vorticity distribution and vibration-generation mechanism. A vibration-processing method is utilized to discuss the four flow-state transition features. A fluid-induced vibration experiment platform is established to verify the numerical results. It is found that the proposed modeling method can better reveal the vibration-evolution regularities of the fluid-solid coupling process. The flow field has a maximum value in the complex... [more]

This paper proposed a semi-theoretical model to quantitatively predict leakage rate of tubing and casing premium connections. The geometric parameters of the sealing surface profile approximated by a sinusoidal micro-convex surface were first obtained based on the random normal distribution sampling method. With the actual area prediction formula for elastic−plastic contact of an axisymmetric sinusoidal micro-convex body based on the equivalent simulation principle, the circumferential leakage width and radial average leakage height of the micro-leakage channel between sealing surfaces were then acquired with the surface roughness and geometric mean contact pressure. At last, the actual micro-leakage rate of the premium connection was derived by considering the non-uniform contact pressure distribution between sealing surfaces. An example was investigated to validate the model and reveal the sealing and leakage characteristics, and anti-leakage measures were proposed. The results show... [more]