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Transactive Energy Market for Energy Management in Microgrids: The Monash Microgrid Case Study
Mohsen Khorasany, Donald Azuatalam, Robert Glasgow, Ariel Liebman, Reza Razzaghi.
March 24, 2023 (v1)
Keywords: demand response, distributed energy resources, energy management, flexibility market, local markets, microgrid energy market, Renewable and Sustainable Energy, transactive energy.
Transactive energy is a novel approach for energy management and trading, which can be used in microgrids to facilitate the integration of distributed energy resources (DERs) in existing networks. The key feature in transactive energy is using market-based solutions for energy management. Hence, an appropriate transactive energy market (TEM) framework should be designed to enable and incentivize DER owners to participate in different markets. The efficient implementation of TEM for microgrid energy management encompasses the application of a variety of design principles. In this rapidly developing area, this paper presents a complete proposal of the TEM as a framework for the design, implementation, and deployment of transactive energy solutions for energy management in microgrids. In particular, we outline the requirements to design an effective market mechanism for the TEM. The applicability of this perspective is demonstrated through the introduction of the Monash Microgrid as a rea... [more]
Energy Efficiency of Novel Interior Surface Layer with Improved Thermal Characteristics and Its Effect on Hygrothermal Performance of Contemporary Building Envelopes
Jan Fořt, Jiří Šál, Jan Kočí, Robert Černý.
March 24, 2023 (v1)
Keywords: climate, computation simulation, passive cooling, plaster, recuperation heat, thermal energy storage.
Facing the consequences of climate change and fuel price rises, the achievement of the requirements for low-energy consumption of buildings has become a challenging issue. On top of that, increased demands on indoor hygrothermal conditions usually require the utilization of additional heating, ventilation, and air-conditioning (HVAC) systems to maintain a comfortable environment. On this account, several advanced and modern materials are widely investigated as a promising way for reduction of the buildings’ energy consumption including utilization of passive heating/cooling energy. However, the efficiency and suitability of passive strategies depending on several aspects including the influence of location, exterior climatic conditions, load-bearing materials used, and insulation materials applied. The main objective of this study consists of the investigation of the energy performance benefits gained by the utilization of advanced materials in plasters by computational modeling. Resul... [more]
Energy Fluctuations in the Homogenized Hyper-Elastic Particulate Composites with Stochastic Interface Defects
Damian Sokołowski, Marcin Kamiński, Artur Wirowski.
March 24, 2023 (v1)
Keywords: deformation energy, hyper-elasticity, interface defects, Monte-Carlo simulation, multi-scale homogenization technique, particulate composite, Stochastic Finite Element Method, stochastic perturbation method.
The principle aim of this study is to analyze deformation energy of hyper-elastic particulate composites, which is the basis for their further probabilistic homogenization. These composites have some uncertain interface defects, which are modelled as small semi-spheres with random radius and with bases positioned on the particle-matrix interface. These defects are smeared into thin layer of the interphase surrounding the reinforcing particle introduced as the third component of this composite. Matrix properties are determined from the experimental tests of Laripur LPR 5020 High Density Polyurethane (HDPU). It is strengthened with the Carbon Black particles of spherical shape. The Arruda−Boyce potential has been selected for numerical experiments as fitting the best stress-strain curves for the matrix behavior. A homogenization procedure is numerically implemented using the cubic Representative Volume Element (RVE). Spherical particle is located centrally, and computations of deformatio... [more]
Influence of Superabsorbent Polymers on Moisture Control in Building Interiors
Jan Fořt, Jan Kočí, Jaroslav Pokorný, Robert Černý.
March 24, 2023 (v1)
Keywords: computational modeling, moisture moderation, plaster, relative humidity, superabsorbent polymer.
Moisture loads in building interiors are accompanied by a deterioration of the indoor air quality. Such a phenomenon may induce serious health risks for building inhabitants as well as degradation of furnishing. Unfortunately, the employment of additional heat, ventilation and air conditioning (HVAC) devices does not comply with the sustainability principle due to increased energy consumption, thus cannot be viewed as an efficient solution. This study deals with the use of superabsorbent polymers (SAP) in cement-lime plasters, thus extends the current state of knowledge and outlines further possible development of novel moisture responsive plasters since lightweight aggregates do not provide the desired performance. To be specific, this paper contemplates the experimental analysis of novel plasters modified by 0.5, 1 and 1.5 wt. % of SAP to obtain input parameters for computational modeling. Based on the obtained outputs, the incorporation of SAP admixture resulted in a substantial inc... [more]
Space Charge Accumulation at Material Interfaces in HVDC Cable Insulation Part I—Experimental Study and Charge Injection Hypothesis
Espen Doedens, E. Markus Jarvid, Raphaël Guffond, Yuriy V. Serdyuk.
March 24, 2023 (v1)
Subject: Materials
Keywords: charge injection, field enhancement factor, HVDC extruded cable, insulation interfaces, physical interfaces, pulsed-electro-acoustic method, roughness enhanced charge injection, space charge measurement, surface roughness.
On-site installation of accessories on extruded polymeric high voltage cables in a common practice. The procedure requires the shaping of the physical interface between the cable insulation surface and the pre-molded accessory body. On such interfaces, rough surfaces should be avoided in order to limit space charge accumulation in the insulation, which affects the cable performance by reducing insulation life-time, creating conditions for local field enhancement, and, respectively, the formation of possible breakdown path e.g. by electrical treeing. Space charge measurements on cable insulation peelings were undertaken to assess the space charge injection and accumulation on interfaces with varying degrees of surface roughness in order to improve understanding on this subject. The results of the measurements confirm the hypothesis regarding the enhancement of charge injection from rough surfaces when electric field strength exceeds a certain level. The accumulated charge density in the... [more]
Numerical Optimization of a Four-Cylinder Double-Acting Stirling Engine Based on Non-Ideal Adiabatic Thermodynamic Model and SCGM Method
Chin-Hsiang Cheng, Yi-Han Tan.
March 24, 2023 (v1)
Keywords: double-acting Stirling engine, Optimization, thermodynamic model, wobble-yoke.
The aim of this study is to optimize a four-cylinder, double-acting α-type Stirling engine with wobble-yoke mechanism using an optimization scheme incorporated with an efficient thermodynamic model. In this study, the non-ideal adiabatic thermodynamic model is improved by taking into account factors including pressure drops due to the sudden expansion or contraction of flow cross-sectional areas in the engine, multiple nodes in the regenerator adopted to accurately capture the temperature gradient in the regenerator, and the dependence of the transport properties (thermal conductivity and dynamic viscosity) of the working fluid on temperature and pressure. A parametric analysis is firstly performed to identify the designed parameters that need to be optimized. In this study, engine optimization is carried out by using the simplified conjugate-gradient method (SCGM). The effects of the weighting coefficients of the objective function are studied. For a particular case considered, the op... [more]
Battery Energy Storage Systems in Microgrids: Modeling and Design Criteria
Matteo Moncecchi, Claudio Brivio, Stefano Mandelli, Marco Merlo.
March 24, 2023 (v1)
Keywords: battery models, developing countries, Energy Storage, microgrids, Optimization, rural electrification.
Off-grid power systems based on photovoltaic and battery energy storage systems are becoming a solution of great interest for rural electrification. The storage system is one of the most crucial components since inappropriate design can affect reliability and final costs. Therefore, it is necessary to adopt reliable models able to realistically reproduce the working condition of the application. In this paper, different models of lithium-ion battery are considered in the design process of a microgrid. Two modeling approaches (analytical and electrical) are developed based on experimental measurements. The derived models have been integrated in a methodology for the robust design of off-grid electric power systems which has been implemented in a MATLAB-based computational tool named Poli.NRG (POLItecnico di Milano—Network Robust desiGn). The procedure has been applied to a real-life case study to compare the different battery energy storage system models and to show how they impact on t... [more]
A Coordinated Voltage Control for Overvoltage Mitigation in LV Distribution Grids
Edoardo De Din, Marco Pau, Ferdinanda Ponci, Antonello Monti.
March 24, 2023 (v1)
Keywords: distributed energy resources, distributed optimization, dual decomposition, hosting capacity, overvoltage mitigation, renewable energy sources, storage management, voltage control.
The design of intelligent strategies for grid management is a cost-effective solution to increase the hosting capacity of distribution grids without investing in the reinforcement of the grid assets. This paper presents a distributed voltage control algorithm to coordinate Energy Storage Systems (ESSs) and Distributed Generation (DG) in a scenario of high renewable penetration. The proposed control algorithm relies on a dual decomposition approach and aims at mitigating possible voltage rise events occurring in the Low Voltage (LV) grid by solving an optimization problem of power minimization. Instead of using local control strategies, in the proposed solution, the voltage control burden is distributed among all the available resources in the grid, which cooperate to resolve the existing voltage violations. The performance of the developed voltage control has been tested under realistic distribution grid scenarios, using stochastic load profiles together with photovoltaic generation pr... [more]
Dynamic Reconfiguration Systems for PV Plant: Technical and Economic Analysis
Giuseppe Schettino, Filippo Pellitteri, Guido Ala, Rosario Miceli, Pietro Romano, Fabio Viola.
March 24, 2023 (v1)
Subject: Energy Policy
Keywords: economic analyses, energy policies related to PV power plants, monitoring and case studies.
Solar plants suffer of partial shading and mismatch problems. Without considering the generation of hot spots and the resulting security issues, a monitoring system for the health of a PV plant should be useful to drive a dynamic reconfiguration system (DRS) to solve bottlenecks due to different panels’ shading. Over the years different DRS architectures have been proposed, but no suggestions about costs and benefits have been provided. Starting from technical subjects such as differences of the topologies driving the hardware complexity and number of components, this paper identifies the cost of DRS and its lifetime, and based on these issues it provides an economic analysis for a 6 kWp PV plant in different European Union countries, in which the dissimilar incentive policies have been considered.
Air Conditioning Energy Saving from Cloud-Based Artificial Intelligence: Case Study of a Split-Type Air Conditioner
Dasheng Lee, Fu-Po Tsai.
March 24, 2023 (v1)
Keywords: cloud-based artificial intelligence, cooling season power factor (CSPF), energy efficiency ratio (EER), fuzzy + proportional-integral-differential (PID), model-based predictive control (MPC), split-type air conditioner.
This study developed cloud-based artificial intelligence (AI) that could run AI programs in the cloud and control air conditioners remotely from home. AI programs in the cloud can be altered any time to provide good control performances without altering the control hardware. The air conditioner costs and prices can thus be reduced by the increasing energy efficiency. Cloud control increased energy efficiency through AI control based on two conditions: (1) a constant indoor cooling rate and (2) a fixed stable range of indoor temperature control. However, if the two conditions cannot be guaranteed or the cloud signals are lost, the original proportional-integral-differential (PID) control equipped in the air conditioner can be used to ensure that the air conditioner works stably. The split-type air conditioner tested in this study is ranked eighth among 1177 air conditioners sold in Taiwan according to public data. It has extremely high energy efficiency, and using AI to increase its ene... [more]
Modified Modelling for Heat Like Equations within Caputo Operator
Hassan Khan, Adnan Khan, Maysaa Al-Qurashi, Rasool Shah, Dumitru Baleanu.
March 24, 2023 (v1)
Keywords: Caputo operator, fractional-order heat equations, Iterative Laplace Transform method, Mittag–Leffler function.
The present paper is related to the analytical solutions of some heat like equations, using a novel approach with Caputo operator. The work is carried out mainly with the use of an effective and straight procedure of the Iterative Laplace transform method. The proposed method provides the series form solution that has the desired rate of convergence towards the exact solution of the problems. It is observed that the suggested method provides closed-form solutions. The reliability of the method is confirmed with the help of some illustrative examples. The graphical representation has been made for both fractional and integer-order solutions. Numerical solutions that are in close contact with the exact solutions to the problems are investigated. Moreover, the sample implementation of the present method supports the importance of the method to solve other fractional-order problems in sciences and engineering.
Spherical Sb Core/Nb2O5-C Double-Shell Structured Composite as an Anode Material for Li Secondary Batteries
Hyungeun Seo, Kyungbae Kim, Jae-Hun Kim.
March 24, 2023 (v1)
Subject: Materials
Keywords: anode, antimony, composite, Li battery, niobium oxide.
Antimony (Sb)-based materials are considered to be attractive for use in Li secondary battery anodes because of their high capacity. However, their huge volume change during Li insertion-extraction cycling limits their cycle performance. The Sb-active material can be combined with intercalation-based active materials to address these issues. In this study, spherical Sb core/Nb2O5 shell structured composite materials were synthesized through a simple solvothermal process and a carbon coating was simultaneously added during heat treatment using a naphthalene precursor. The resulting double-shelled materials were characterized with X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and electron microscopy. The electrochemical test results showed that a reversible capacity of more than 450 mAh g−1 was retained after 100 cycles. This improved performance is ascribed to the double-shelled structure. The large volume change of the nano-sized Sb core material was alleviat... [more]
Conceptual Design Development of a Fuel-Reforming System for Fuel Cells in Underwater Vehicles
Seung-Kyo Jung, Won-Sim Cha, Yeong-In Park, Shin-Hyung Kim, Jungho Choi.
March 24, 2023 (v1)
Keywords: Carbon Dioxide, fuel cell, fuel reforming, Methanol, underwater vehicle.
An air-independent propulsion system containing fuel cells is applied to improve the operational performance of underwater vehicles in an underwater environment. Fuel-reforming efficiently stores and supplies hydrogen required to operate fuel cells. In this study, the applicability of a fuel-reforming system using various fuels for underwater vehicles was analyzed by calculating the fuel and water consumptions, the amount of CO2 generated as a byproduct, and the amount of water required to dissolve the CO2 using aspen HYSYS (Aspen Technology, Inc., Bedford, MA, USA). In addition, the performance of the fuel-reforming system for methanol, which occupies the smallest volume in the system, was researched by analyzing performance indicators such as methanol conversion rate, hydrogen, yield and selectivity, and reforming efficiency under conditions at which pressure, temperature, steam-to-carbon ratio (SCR), and hydrogen separation efficiency vary. The highest reforming efficiency was 77.7−... [more]
Reactive Power Injection to Mitigate Frequency Transients Using Grid Connected PV Systems
Yujia Huo, Simone Barcellona, Luigi Piegari, Giambattista Gruosso.
March 24, 2023 (v1)
Keywords: ancillary service, DER, frequency-assisting, hardware-in-the-loop, Photovoltaic, PV Plant.
The increasing integration of renewable energies reduces the inertia of power systems and thus adds stiffness to grid dynamics. For this reason, methods to obtain virtual inertia have been proposed to imitate mechanical behavior of rotating generators, but, usually, these methods rely on extra power reserves. In this paper, a novel ancillary service is proposed to alleviate frequency transients by smoothing the electromagnetic torque of synchronous generators due to change of active power consumed by loads. Being implemented by grid-tied inverters of renewables, the ancillary service regulates the reactive power flow in response to frequency transients, thereby demanding no additional power reserves and having little impact on renewables’ active power generation. Differently from the active power compensation by virtual inertia methods, it aims to low-pass filter the transients of the active power required to synchronous generators. The proposed ancillary service is firstly verified in... [more]
Conceptual Design and Simulation of a Self-Adjustable Heaving Point Absorber Based Wave Energy Converter
Tunde Aderinto, Hua Li.
March 24, 2023 (v1)
Keywords: heaving point absorber, self-adjustable: design and performance, structural assessment, wave energy converters.
Different concepts and methods have been proposed and developed by many researchers to harvest ocean wave energy. In this paper, a new self-adjustable wave energy converter concept is presented, which changes its inertia through ballasting and de-ballasting using sea water. The trigger of ballasting and de-ballasting is controlled by the critical wave period. Therefore, the self-adjustable wave energy converter is able to interact at resonance with the ocean waves at two different resonant bandwidths. Ten years real wave data with hourly resolution from a selected location in Gulf of Mexico was used in this paper to decide the critical wave period and other parameters of the wave energy converter. The annual energy performance of the self-adjustable wave energy converter was also estimated and compared with non-adjustable wave energy converter with similar dimensions. Structural analysis including both static and fatigue analysis was performed on the self-adjustable wave energy convert... [more]
Validation and Numerical Sensitivity Study of Air Baffle Photovoltaic-Thermal Module
Yu-Jin Kim, Kwang-Seob Lee, Libing Yang, Evgueniy Entchev, Eun-Chul Kang, Euy-Joon Lee.
March 24, 2023 (v1)
Keywords: CFD (Computational Fluid Dynamics), numerical study, Photovoltaic-Thermal (PVT), Separate Effect Test (SET).
Photovoltaic-Thermal (PVT) is a type of technology that generates electricity and heat simultaneously at the point of use. The generated electricity could be used on site or exported to the grid while the thermal output could be utilized for space and water heating. There is a lot of research for solar air heating with experiment or CFD (Computational Fluid Dynamics), but CFD has the disadvantage that it would indicate impractical results. In this paper, a numerical PVT baseline model was developed and validated with Separate Effect Test (SET) data to increase reliability. The numerical study was conducted by considering the effect of baffle lengths and baffle slopes on outlet temperature, total heat transfer and pressure drop inside PVT air module. An optimum PVT baffle length and slope design were suggested. The baseline numerical PVT model agreed well with the test data set as indicated by 1.25% error for inlet−outlet temperatures difference. The sensitivity study was conducted by c... [more]
System Unbalance Analyses and Improvement for Rooftop Photovoltaic Generation Systems in Distribution Networks
Rong-Ceng Leou, Jen-Hao Teng, Yun-Fang Li, Wei-Min Lin, Yu-Hung Lin.
March 24, 2023 (v1)
Keywords: On Load Tap Changer, optimal phase arrangement, Rooftop Photovoltaic Generation Systems, stochastic analyses, system unbalance.
This paper studies the system unbalance caused by rooftop Photovoltaic Generation Systems (PVGSs) in distribution networks and proposes an improved method. The voltage and current unbalance studies for three extreme cases considering all rooftop PVGSs being connected to one single phase and then the stochastic analyses for the integration cases of rooftop PVGSs are considered. These three extreme cases lead to severe system unbalance problems. An improving method that combines the On Load Tap Changer (OLTC) and the optimal phase arrangement of distribution transformers is proposed in this paper to mitigate the system unbalance. The OLTC-based improving method is applied first. If the system unbalance is still out of range, the optimal phase arrangement of distribution transformers is further used to mitigate the system unbalance problem. The objective function of optimal phase arrangement is to minimize the system unbalance with the constraints of voltage limits, line flow limit, etc.... [more]
On Distributional Effects in Local Electricity Market Designs—Evidence from a German Case Study
Alexandra Lüth, Jens Weibezahn, Jan Martin Zepter.
March 24, 2023 (v1)
Keywords: distributional effects, electricity market design, energy communities, local energy sharing, mixed complementarity problem (MCP), peer-to-peer trading.
The European Commission’s call for energy communities has motivated academia to focus research on design and trading concepts of local electricity markets. The literature provides a wide range of conceptual ideas and analyses on the technical and economic framework of single market features such as peer-to-peer trading. The feasible, system-wide integration of energy communities into existing market structures requires, however, a set of legal adjustments to national regulation. In this paper, we test the implications of recently proposed market designs under the current rules in the context of the German market. The analysis is facilitated by a simplistic equilibrium model representing heterogeneous market participants in an energy community with their respective objectives. We find that, on the one hand, these proposed designs are financially unattractive to prosumers and consumers under the current regulatory framework. On the other hand, they even cause distributional effects withi... [more]
CFD Study of Diffuse Ceiling Ventilation through Perforated Ceiling Panels
Alessandro Nocente, Tufan Arslan, Steinar Grynning, Francesco Goia.
March 24, 2023 (v1)
Keywords: ceiling panels, comfort, Computational Fluid Dynamics, Diffuse Ceiling Ventilation (DCV).
Diffuse Ceiling Ventilation (DCV) is a promising concept to address internal air quality and thermal comfort requirements in contemporary buildings. Sound-absorbing perforated ceiling panels are common in office rooms and can be used as air diffusers without modifications. The optimization of such systems is not a trivial procedure, and numerical simulation can represent an important tool to carry out this task. Today, most of the numerical studies on DCV are performed using porous medium models and focus on the general system performance rather than on the optimization of the diffuser design. In previous studies, a CFD model was used to optimize the size and distribution of the ceiling perforation. In the study presented in this paper, the results of simulations conducted on a full-scale three-dimensional domain and the performance comparison between a continuous and non-continuous perforation distribution are given. The results show that the non-continuous diffuser design does not di... [more]
Biowaste Treatment and Waste-To-Energy—Environmental Benefits
Martin Pavlas, Jan Dvořáček, Thorsten Pitschke, René Peche.
March 24, 2023 (v1)
Subject: Environment
Keywords: biowaste, composting, Fermentation, global warming potential, greenhouse gases, waste-to-energy.
Biowaste represents a significant fraction of municipal solid waste (MSW). Its separate collection is considered as a useful measure to enhance waste management systems in both the developed and developing world. This paper aims to compare the environmental performance of three market-ready technologies currently used to treat biowaste—biowaste composting, fermentation, and biowaste incineration in waste-to-energy (WtE) plants as a component of residual municipal solid waste (RES). Global warming potential (GWP) was applied as an indicator and burdens related to the operation of facilities and credits obtained through the products were identified. The environmental performance of a WtE plant was investigated in detail using a model, implementing an approach similar to marginal-cost and revenues, which is a concept widely applied in economics. The results show that all of the treatment options offer an environmentally friendly treatment (their net GWP is negative). The environmental per... [more]
Shading, Dusting and Incorrect Positioning of Photovoltaic Modules as Important Factors in Performance Reduction
Ewa Klugmann-Radziemska.
March 24, 2023 (v1)
Keywords: dusting, energy losses, maximum power generation, optimal orientation, photovoltaic module, shading.
The amount of solar radiation reaching the front cover of a photovoltaic module is crucial for its performance. A number of factors must be taken into account at the design stage of the solar installation, which will ensure maximum utilization of the potential arising from the location. During the operation of a photovoltaic installation, it is necessary to limit the shading of the modules caused by both dust and shadowing by trees or other objects. The article presents an analysis of the impact of the radiation reaching the surface of the radiation module on the efficiency obtained. Each of the analyzed aspects is important for obtaining the greatest amount of energy in specific geographical conditions. Modules contaminated by settling dust will be less efficient than those without deposits. The results of experimental studies of this effect are presented, depending on the amount of impurities, including their origins and morphologies. In practice, it is impossible to completely elimi... [more]
A Novel Topology Optimization Approach for Flow Power Loss Minimization Across Fin Arrays
Ali Ghasemi, Ali Elham.
March 24, 2023 (v1)
Subject: Optimization
Keywords: Brinkman penalization, fin array, hydrodynamic power loss minimization, periodic flow, pseudo-spectral, topology optimization.
Fin arrays are widely utilized in many engineering applications, such as heat exchangers and micro-post reactors, for higher level of fluid−solid contacts. However, high fluid pressure loss is reportedly the major drawback of fin arrays and a challenge for pumping supply, particularly at micro-scales. Previous studies also indicate that fin shapes, spacing and alignment play an important role on the overall pressure losses. Therefore, we present a numerical tool to minimize pressure losses, considering the geometrical aspects related to fin arrays. In this regard, a density-based topology optimization approach is developed based on the pseudo-spectral scheme and Brinkman penalization in 2D periodic domains. Discrete sensitives are derived analytically and computed at relatively low cost using a factorization technique. We study different test cases to demonstrate the flexibility, robustness and accuracy of the present tool. In-line and staggered arrays are considered at various Reynold... [more]
The Influence of Different Facings of Polyisocyanurate Boards on Heat Transfer through the Wall Corners of Insulated Buildings
Tomas Makaveckas, Raimondas Bliūdžius, Arūnas Burlingis.
March 24, 2023 (v1)
Keywords: facings, heat flux, heat transfer, polyisocyanurate boards, thermal bridges.
Polyisocyanurate (PIR) thermal insulation boards faced with carboard, plastic, aluminum, or multilayer facings are used for thermal insulation of buildings. Facing materials are selected according to the conditions of use of PIR products. At the corners of the building where these products are joined, facings can be in the direction of the heat flux movement and significantly increase heat transfer through the linear thermal bridge formed in the connection of PIR boards with facing of both walls. Analyzing the installation of PIR thermal insulation products on the walls of a building, the structural schemes of linear thermal bridges were created, numerical calculations of the heat transfer coefficients of the linear thermal bridges were performed, and the influence of various facings on the heat transfer through the thermal bridge was evaluated. Furthermore, an experimental measurement using a heat flow meter apparatus was performed in order to confirm the results obtained by numerical... [more]
Analysis of Energy Consumption of the Reduction of Fe2O3 by Hydrogen and Carbon Monoxide Mixtures
Guanyong Sun, Bin Li, Wensheng Yang, Jing Guo, Hanjie Guo.
March 24, 2023 (v1)
Keywords: energy consumption, energy utilization, equilibrium state, gas utilization rate, gas-based direct reduction ironmaking, minimized Gibbs free energy principle, recoverable heat.
Energy consumption is directly related to the energy supply and production costs of gas-based direct reduction ironmaking, which is an effective choice to reduce the energy consumption of iron making. In this paper, the minimum Gibbs free energy principle was used to calculate the equilibrium composition under the conditions of reduction gas consisting of hydrogen and carbon monoxide (hydrogen concentration of 0−100%, reduction gas amount of 0−6.0 mol, reduction temperature of 790−1100 °C, and 0.5 mol Fe2O3). According to the enthalpy change, a simplified energy consumption model of a gas-based direct reduction ironmaking process was established, and the energy consumption per mole of metallic iron produced was calculated in detail. The following conclusions were drawn: at the stage when the reduction reaction occurred, the utilization rate of hydrogen or carbon monoxide remained unchanged with the increase in the amount of reduction gas or the increase in the hydrogen concentration of... [more]
Investigation of Reducing In-Plane Resistance of Nickel Oxide-Samaria-Doped Ceria Anode in Thin-Film Solid Oxide Fuel Cells
Yusung Kim, Sanghoon Lee, Gu Young Cho, Wonjong Yu, Yeageun Lee, Ikwhang Chang, Jong Dae Baek, Suk Won Cha.
March 24, 2023 (v1)
Keywords: anodic aluminum oxide, co-sputtering, NiO-SDC, thin-film solid oxide fuel cell.
Metal/NiO-Smarium-doped ceria (SDC) nano-composite thin film anodes were deposited on anodic aluminum oxide by co-sputtering to enhance the in-plane current-collecting ability and investigated by varying the composition of metal materials (Pt and Au). Full fuel cells with these nano-composites were fabricated and tested at 500 °C. Columnar anodes with a sponge structure were fabricated by varying the DC sputtering source power and they were thermally stable at the operating temperature. By adding metal material, the ohmic resistance, including the current collecting resistance, was drastically reduced and the polarization resistance also decreased. The nano-composite electrode with a Pt content of 61 at% showed the highest performance, which is a maximum power density of 212.5 mW/cm2 at 500 °C. In addition, Au was considered to reduce the current collecting resistance and the corresponding power density was 3 times higher than that with the NiO-SDC anode.
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