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Records with Type: Published Article
10844. LAPSE:2023.28292
Optimal Planning of Hybrid Electricity−Hydrogen Energy Storage System Considering Demand Response
April 11, 2023 (v1)
Subject: Planning & Scheduling
Keywords: active distribution network (ADN), demand response (DR), energy storage system (ESS), life cycle cost (LCC), multiple objective particle swarm optimization (MOPSO)
In recent years, the stability of the distribution network has declined due to the large proportion of the uses of distributed generation (DG) with the continuous development of renewable energy power generation technology. Meanwhile, the traditional distribution network operation mode cannot keep the balance of the source and load. The operation mode of the active distribution network (ADN) can effectively reduce the decline in operation stability caused by the high proportion of DG. Therefore, this work proposes a bi-layer model for the planning of the electricity−hydrogen hybrid energy storage system (ESS) considering demand response (DR) for ADN. The upper layer takes the minimum load fluctuation, maximum user purchase cost satisfaction, and user comfort as the goals. Based on the electricity price elasticity matrix model, the optimal electricity price formulation strategy is obtained for the lower ESS planning. In the lower layer, the optimal ESS planning scheme is obtained with t... [more]
10845. LAPSE:2023.28291
Special Issue: Processing Foods: Process Optimization and Quality Assessment
April 11, 2023 (v1)
Subject: Food & Agricultural Processes
For a long time, the basic as well as the only function of foods is to provide the nutrients and energy needed for human physiological processes [...]
10846. LAPSE:2023.28290
Effect of Nano-La2O3 and Mo on Wear Resistance of Ni60a/SiC Coatings by Laser Cladding
April 11, 2023 (v1)
Subject: Materials
Keywords: composite coating, friction and wear, laser cladding, microstructure
To improve the wear resistance of the TMR blade and investigate the effect of nano-La2O3 and Mo on the wear resistance of laser cladding coating. 65Mn blade as the substrate, La2O3, Mo and Mo-La2O3 composite powders were added into Ni60a/SiC composite powder. Using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and the CFT-I surface synthesizer, the phase composition, element distribution and friction and wear properties of the coating were analyzed to obtain the best composition of the composite coating. The results showed that the wear resistance of Mo-La2O3-Ni60a/SiC composite coating was the best. The coating was analyzed by X-ray diffraction and X-ray photoelectron spectroscopy. The coating contained hard phases such as CrB, CrC and Cr7C3, and the element distribution was uniform. It can be seen from the scanning electron microscope that the addition of nano-Mo and La2O3 improves the toughness and compactness of Ni60a/SiC composite coating, and t... [more]
10847. LAPSE:2023.28289
High Step-Up Thirteen Level Switched-Capacitor Inverter Topology for HFAC Power System
April 11, 2023 (v1)
Subject: Energy Systems
Keywords: aerospace application, boost inverter, high-frequency inverter, switched-capacitor inverter
This article proposes two new high-frequency, thirteen-level switched capacitor inverter topologies. Compared with the counterpart existing topologies, which were recently published, the switch count, capacitor voltage, and voltage stress on the switch are reduced. In addition, the proposed topologies have inherited merits such as six-time voltage boosting levels and self-balanced capacitor voltages as well. The capacitor ripple voltages and the proposed topology performance are analyzed. The prototype setup is developed for 500W, and the results are verified. The maximum efficiency is approximately equal to 97.5% for simulation. Furthermore, it is approximately equal to 96.1% for experimental, and both are measured at an output power of 500 W. Finally, the characteristics of the proposed topologies are tested under several scenarios, such as modulation index variations and load changes, and the findings are reported.
10848. LAPSE:2023.28288
Numerical Simulation of Impinging Jet Drying Multiphase Flow in Gravure Printing Water-Based Ink Based on the Volume of Fluid Method
April 11, 2023 (v1)
Subject: Modelling and Simulations
Keywords: heat and mass transfer, impinging air jets drying, Simulation, water-based ink
Gravure printing is widely used in food, pharmaceutical, and other packaging industries. As a green printing material, water-based ink has problems such as non-volatile and poor drying on non-absorbent packaging substrates, which has a great impact on its application. To solve these difficulties, this study adopts the volume of fluid (VOF) method and user-defined function (UDF) to establish a multiphase flow impinging air jets drying model of water-based ink in the gravure printing process, taking a water-based ink droplet as an example. The model was used to simulate the ink drying state in the impinging air jets region and analyze the effects of impinging air jets’ temperature and velocity, as well as ink viscosity and thickness, on the ink drying efficiency. Meanwhile, the heat and mass transfer mechanism between impinging air jets and water-based ink was investigated. The results show that the higher impinging air jet temperature and velocity, the faster the drying rate of the ink;... [more]
10849. LAPSE:2023.28287
Indolyl-Derived 4H-Imidazoles: PASE Synthesis, Molecular Docking and In Vitro Cytotoxicity Assay
April 11, 2023 (v1)
Subject: Biosystems
Keywords: azaheterocycles, C-H functionalization, imidazoles, in vitro cytotoxicity assay, indoles, molecular docking, neurodegenerative diseases, nucleophilic substitution of hydrogen, PASE
The strategy of the nucleophilic substitution of hydrogen (SNH) was first applied for the metal-free C-H/C-H coupling reactions of 4H-imidazole 3-oxides with indoles. As a result, a series of novel bifunctional azaheterocyclic derivatives were obtained in yields up to 95%. In silico experiments on the molecular docking were performed to evaluate the binding possibility of the synthesized small azaheterocyclic molecules to the selected biotargets (BACE1, BChE, CK1δ, AChE) associated with the pathogenesis of neurodegenerative diseases. To assess the cytotoxicity for the synthesized compounds, a series of in vitro experiments were also carried out on healthy human embryo kidney cells (HEK-293). The leading compound bearing both 5-phenyl-4H-imidazole and 1-methyl-1H-indole moieties was defined as the prospective molecule possessing the lowest cytotoxicity (IC50 > 300 µM on HEK-293) and the highest binding energy in the protein−ligand complex (AChE, −13.57 kcal/mol). The developed compounds... [more]
10850. LAPSE:2023.28286
A Scientometric Review on Imbibition in Unconventional Reservoir: A Decade of Review from 2010 to 2021
April 11, 2023 (v1)
Subject: Optimization
Keywords: imbibition, oil and gas exploitation, shale, unconventional reservoir
Spontaneous imbibition is a phenomenon of fluid displacement under the action of capillary force, which is of great significance to reservoir protection, enhanced oil recovery, flow-back optimization, and fracturing fluid selection in unconventional oil and gas reservoirs. Remarkable progress has been made in the imbibition research of oil and gas, and the overall research situation of research needs to be analyzed more systematically. This paper aims to provide a scientometric review of imbibition studies in unconventional reservoirs from 2010 to 2021. A total of 1810 papers are collected from the Web of Science Core Correction database based on selected keywords and paper types. Using CiteSpace software, a quantitative scientific analysis is carried out on the main aspects of national cooperation, institutional cooperation, scholarly cooperation, keyword co-occurrence, journal co-citation, article co-citation, and keyword clustering. The principal research countries, institutions, sc... [more]
10851. LAPSE:2023.28285
Effect of Gold Tailing Addition on the Mechanical Properties and Microstructure of Foam Ceramics
April 11, 2023 (v1)
Subject: Materials
Keywords: compressive strength, crystallisation, foam ceramic, glass granule, gold tailing, microcrystalline foam ceramics
Tailings, with their low utilisation rate and value, pose an urgent problem that needs to be solved. This study focused on foam ceramics and glass granules, which were prepared using gold tailings as the main raw materials, and the prepared microcrystalline foam ceramics were investigated. The optimum sample (S6) of foam ceramics consists of 77 wt% of gold tailings, 6 wt% of talc, 9 wt% of bentonite, 2 wt% of calcite, 0.9 wt% of foaming agent and 0.6% of water reducer. The optimum foaming temperature is 1190 °C, and the holding time is 60 min. The compressive strength and bulk density of the samples are 7.4 MPa and 396.4 kg/m3; nucleation temperature, crystallisation temperature, and crystallisation activation energy of glass particles are 700 °C ± 50 °C, 1100 °C ± 50 °C, and 1572 kJ/mol, respectively. Microanalysis results showed that the crystal phases of foam ceramics were mainly quartz, calcium silicate, and aluminium silicate, and crystallinity increases with increasing gold taili... [more]
10852. LAPSE:2023.28284
Intake Valve Profile Optimization for a Piston-Type Expander Based on Load
April 11, 2023 (v1)
Subject: Planning & Scheduling
Keywords: electro-pneumatic driving, intake valve duration angle, trajectory planning, variable valve system
Intake valve parameters significantly affect the performance of the piston-type expander (PTE). To improve compressed energy utilization efficiency, intake valve parameters need to be regulated according to load. In this paper, an electro-pneumatic variable valve actuation (EPVVA) system was proposed for independent control distributing valve parameters. The trajectory planning for the intake valve was proposed to obtain good mechanical properties. Then, the intake valve duration angle was optimized, and the optimum intake valve lift curves were obtained at different rotational speeds. Results show that the energy efficiency decreased with the intake valve duration angle increasing. The output power ascended sharply with increasing intake valve duration angle, but the amplitude of power growth decreased. The output power had a maximum value at a specific intake valve duration angle. The gray relation analysis (GRA) method was applied to obtain the optimum intake duration angle based on... [more]
10853. LAPSE:2023.28283
Review on Energy Conservation of Construction Machinery for Pumping Concrete
April 11, 2023 (v1)
Subject: Process Control
Keywords: concrete pump, control strategy, energy conservation, energy management, hybrid power, parameter matching
The excessive consumption of fossil fuel, energy shortage and global warming along with environmental deterioration have increasingly become a global issue. In order to deal with the energy crisis, energy conservation has been developed and applied in vehicles and construction machineries, i.e., excavators, loaders and forklifts. Due to the shortcoming of low efficiency, high-energy consumption and bad exhaust, the energy conservation of construction machinery for pumping concrete is necessary and urgent. This paper aims to carry out a review on energy conservation of construction machinery for pumping concrete. The research methodology comprises a quantitative analysis method and literature investigation method. First, the structure and working principle of construction machinery for pumping concrete are expounded, and energy consumption ways of construction machinery for pumping concrete are analyzed. Then, research developments in the energy conservation of construction machinery fo... [more]
10854. LAPSE:2023.28282
Identification of Indoor Air Quality Factors in Slovenian Schools: National Cross-Sectional Study
April 11, 2023 (v1)
Subject: System Identification
Keywords: cross-sectional study, indoor air quality factors, outdoor air quality factors, primary school, questionnaire
Poor indoor air quality (IAQ) in schools is associated with impacts on pupils’ health and learning performance. We aimed to identify the factors that affect IAQ in primary schools. The following objectives were set: (a) to develop a questionnaire to assess the prevalence of factors in primary schools, (b) to conduct content validity of the questionnaire, and (c) to assess the prevalence of factors that affect the IAQ in Slovenian primary schools. Based on the systematic literature review, we developed a new questionnaire to identify factors that affect the IAQ in primary schools and conducted its validation. The questionnaires were sent to all 454 Slovenian primary schools; the response rate was 78.19%. The results show that the most important outdoor factors were the school’s micro location and the distance from potential sources of pollution, particularly traffic. Among the indoor factors, we did not detect a pronounced dominating factor. Our study shows that the spatial location of... [more]
10855. LAPSE:2023.28281
Valorization of Food Waste to Produce Value-Added Products Based on Its Bioactive Compounds
April 11, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: bioactive compound, food waste, value-added product, waste to wealth
The rapid growth of the global population and changes in lifestyle have led to a significant increase in food waste from various industrial, agricultural, and household sources. Nearly one-third of the food produced annually is wasted, resulting in severe resource depletion. Food waste contains rich organic matter, which, if not managed properly, can pose a serious threat to the environment and human health, making the proper disposal of food waste an urgent global issue. However, various types of food waste, such as waste from fruit, vegetables, grains, and other food production and processing, contain important bioactive compounds, such as polyphenols, dietary fiber, proteins, lipids, vitamins, organic acids, and minerals, some of which are found in greater quantities in the discarded parts than in the parts accepted by the market. These bioactive compounds offer the potential to convert food waste into value-added products, and fields including nutritional foods, bioplastics, bioene... [more]
10856. LAPSE:2023.28280
On the Importance of Model Selection for CFD Analysis of High Temperature Gas-Solid Reactive Flow; Case Study: Post Combustion Chamber of HIsarna Off-Gas System
April 11, 2023 (v1)
Subject: Modelling and Simulations
Keywords: CFD modelling, combustion modelling, gas-solid reaction, HIsarna ironmaking, radiation modelling, turbulence modelling, turbulence-chemistry interaction
In this paper a CFD analysis of HIsarna off-gas system for post combustion of CO-H2-carbon particle mixture is presented to evaluate the effect of different sub-models and parameters on the accuracy of predictions and simulation time. The effects of different mesh type, mesh grid size, radiation models, turbulent models, kinetic mechanism, turbulence chemistry interaction models, including and excluding gas-solid reactions, number of reactive solid particles are investigated in detail. Based on the accuracy of the predictions and agreement with counterpart measured values, the best combination is selected and conclusions are derived. It was found that radiation and turbulence chemistry interaction model have a major effect on the temperature and composition profile prediction along the studied off-gas system, compared to the variations in other models. The effect of these two models becomes even more evident when the temperature and fuel content of the flue gas are high.
10857. LAPSE:2023.28279
The Short-Circuit Fault Current Impact Mechanism and Adaptive Control Strategy of an MMC-HVDC
April 11, 2023 (v1)
Subject: Process Control
Keywords: adaptive control, HVDC, MMC, three-phase short-circuit fault
A modular multilevel converter (MMC) is voltage-sourced and can supply fault currents to an AC system. To clarify the fault current impact mechanism of an MMC, this paper examines the control and capacitor discharge processes of an MMC when an AC system has a three-phase short grounding fault. The theoretical analysis shows that the outer loop control of the MMCs changes the fault injection. In different control modes, the nonzero reference value of the outer MMC loop forces the converter to inject and absorb the current into the AC system when a fault occurs. The limiter of the control determines the final injecting current value of the MMC. To help the MMC adjust the AC system’s fault current, adaptive strategies are also proposed, which include an adaptive reference control, an adaptive limiter control, and an adaptive capacitor control. On the basis of the proposed strategies, the fault currents could be increased or decreased within the MMC’s capacity. The simulations verify the t... [more]
10858. LAPSE:2023.28278
S-Wave Velocity Forecasting Using Drill Cuttings and Deep Hybrid Neural Networks: A Case Study on a Tight Glutenite Reservoir in Mahu Sag, Junggar Basin
April 11, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: drill cuttings, glutenite reservoir, hybrid model, neural network, rock physics, Vs
S-wave velocity (Vs) is a critical petrophysical parameter for reservoir characterization. It is desirable to predict Vs based on conventional logging data, but the logging cost is high. Therefore, a deep hybrid neural network coupling the convolutional neural network (CNN), Stacked gated recurrent unit (SGRU) is proposed to predict the Vs, where the inputs to the model are drill cutting features. In the proposed CNN-SGRU hybrid model, CNN is adopted to capture the spatial features from the input data, and SGRU is used to extract the temporal patterns of variation from both the forward and backward directions. To illustrate the prediction effect, the glutenite reservoir in the Baikouquan Formation of Mahu Sag, Junggar Basin is taken as an example. Mineral and pore information of drill cuttings, including siliciclastic content, clay content, quartz content, and void area ratio is chosen as the input data of the CNN-SGRU hybrid model. Three indices are used to quantitatively evaluate the... [more]
10859. LAPSE:2023.28277
Recent Developments of Light-Harvesting Excitation, Macroscope Transfer and Multi-Stage Utilization of Photogenerated Electrons in Rotating Disk Photocatalytic Reactor
April 11, 2023 (v1)
Subject: Environment
Keywords: electricity conversion, hydrogen evolution reaction, light harvesting, nitrate reduction, photocatalytic reactor
The rotating disk photocatalytic reactor is a kind of photocatalytic wastewater treatment technique with a high application potential, but the light energy utilization rate and photo quantum efficiency still need to be improved. Taking photogenerated electrons as the starting point, the following contents are reviewed in this work: (1) Light-harvesting excitation of photogenerated electrons. Based on the rotating disk thin solution film photocatalytic reactor, the photoanodes with light capture structures are reviewed from the macro perspective, and the research progress of light capture structure catalysts based on BiOCl is also reviewed from the micro perspective. (2) Macroscope transfer of photogenerated electrons. The research progress of photo fuel cell based on rotating disk reactors is reviewed. The system can effectively convert the chemical energy in organic pollutants into electrical energy through the macroscopic transfer of photogenerated electrons. (3) Multi-level utilizat... [more]
10860. LAPSE:2023.28276
New Application of Polyoxometalate Salts as Cathode Materials in Single Chamber MFC Using Wastewater for Bioenergy Production
April 11, 2023 (v1)
Subject: Materials
Keywords: cobalt, electrocatalyst, energy production, Keggin polyoxometalate salt, microbial fuel cell, photocathode, wastewater treatment
Microbial fuel cells (MFCs) are a promising technology that can be applied in a bifunctional process in which wastewater treatment is used for renewable electric power generation. In this study, novel transition metal-modified Keggin-type lacunar polyoxometalate salts (L-POMs) Cs5PMo11M(H2O)O39 (M = Fe, Co), were synthesized and characterized by X-ray diffraction, SEM, EDX, IR, TGA/DSC, and UV-Vis/DSR spectroscopies to be tested, for the first time, as a cathode component in wastewater-fed air chamber MFCs. Both materials were tested in the presence and absence of light to evaluate their photocatalytic behavior. The best performance in terms of electricity production was obtained for the MFC containing the Co-modified POM-based cathode, which showed a maximum power of 418.15 mW/m2 equivalent to 331 mW per cubic meter of treated wastewater, and a maximum COD removal percentage of 97% after 96 h of MFC operation. Co- and Fe-modified POMs had outstanding optical behavior with lower energy... [more]
10861. LAPSE:2023.28275
Analysis of the Shear Stresses in a Filling Line of Parenteral Products: The Role of Tubing
April 11, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Computational Fluid Dynamics, filling line, parenteral products, shear stress
Parenteral products appear to be sensitive to process conditions in bioprocessing steps, such as interfacial stress and shear stress. The combination of these elements is widely believed and proven to influence product stability, but the defined roles of these players in the product damage process have not yet been identified. The present work addresses a current industrial problem, by focusing on the analysis of shear stress on protein-based therapeutics flowing in tubing by means of Computational Fluid Dynamics simulations. The purpose of this article is not to pinpoint the mechanism triggering the damage of the product, but it represents the first step towards wider experimental investigations and introduces a new strategy to quantify the average shear stress. The field of scale-down approaches, used to scale the commercial process down to the laboratory level, is also explored. Since quality control is critical in the pharmaceutical realm, it is essential that the scale-down approa... [more]
10862. LAPSE:2023.28274
Life Cycle Assessment and Cumulative Energy Demand Analyses of a Photovoltaic/Thermal System with MWCNT/Water and GNP/Water Nanofluids
April 11, 2023 (v1)
Subject: Environment
Keywords: cooling PV module, cumulative energy demand, energy payback time, life cycle assessment, total energy requirement
The global climate crisis has led society toward cleaner energy sources. Another reason is the limited reserves of fossil energy resources. Efforts to increase the efficiency of photovoltaic modules (PVs) have gained momentum. The high temperature is the biggest factor causing a decrease in the efficiency of PVs. In this study, a commercial PV was cooled with distilled water, a multiwalled carbon nanotubes (MWCNT)/water mixture, and a graphene nanoplatelets (GNP)/water mixture. The environmental impact of electricity, total energetic efficiency, energy payback time, energy return on investment, and embodied energy of the PV/thermal (PV/T) system were compared using life cycle assessment and cumulative energy demand. The electrical efficiency of the PV/T changed between 13.5% and 14.4%. The total efficiency of PV/T changed between 39.5% and 45.7%. The energy returns on investment were 1.76, 1.80, and 1.85 for PV/T-distilled water, the PV/T-MWCNT/water mixture, and the PV/T-GNP/water mix... [more]
10863. LAPSE:2023.28273
Recent Development and Future Prospective of Tiwari and Das Mathematical Model in Nanofluid Flow for Different Geometries: A Review
April 11, 2023 (v1)
Subject: Modelling and Simulations
Keywords: convective heat transfer, entropy generation, hybrid nanofluids, mathematical modeling geometries, nanofluids
The rapid changes in nanotechnology over the last ten years have given scientists and engineers a lot of new things to study. The nanofluid constitutes one of the most significant advantages that has come out of all these improvements. Nanofluids, colloid suspensions of metallic and nonmetallic nanoparticles in common base fluids, are known for their astonishing ability to transfer heat. Previous research has focused on developing mathematical models and using varied geometries in nanofluids to boost heat transfer rates. However, an accurate mathematical model is another important factor that must be considered because it dramatically affects how heat flows. As a result, before using nanofluids for real-world heat transfer applications, a mathematical model should be used. This article provides a brief overview of the Tiwari and Das nanofluid models. Moreover, the effects of different geometries, nanoparticles, and their physical properties, such as viscosity, thermal conductivity, and... [more]
10864. LAPSE:2023.28272
Prioritization and Optimal Location of Hydrogen Fueling Stations in Seoul: Using Multi-Standard Decision-Making and ILP Optimization
April 11, 2023 (v1)
Subject: Optimization
Keywords: analytic hierarchy process (AHP), hydrogen fueling station (HFS), integer linear programming (ILP), location select optimization, multi standard decision making (MSDM)
Thus far, the adoption of hydrogen fuel cell vehicles (HCEVs) has been hampered by the lack of hydrogen fueling infrastructure. This study aimed to determine the optimal location and prioritization of hydrogen fueling stations (HFSs) in Seoul by utilizing a multi-standard decision-making approach and optimization method. HFS candidate sites were evaluated with respect to relevant laws and regulations. Key factors such as safety, economy, convenience, and demand for HCEVs were considered. Data were obtained through a survey of experts in the fields of HCEV and fuel cells, and the Analytic Hierarchy Process method was applied to prioritize candidate sites. The optimal quantity and placement of HFSs was then obtained using optimization software, based on the acceptable travel time from intersections of popular roads in Seoul. Our findings suggest that compliance with legal safety regulations is the most important factor when constructing HFSs. Furthermore, sensitivity analysis revealed th... [more]
10865. LAPSE:2023.28271
Investigation of Aeroelastic Energy Extraction from Cantilever Structures under Sustained Oscillations
April 11, 2023 (v1)
Subject: Energy Management
Keywords: aeroelastic flutter, composite, electrical energy, energy harvesting, external perturbations, PVEH
The present article is focused on a detailed computationalinvestigation of energy production capacity of various lightweight materials that are employed with piezoelectric vibration energy harvesters (PVEHs) subjected to various aeroelastic effects. Piezoelectric transducers are primarily employed to capture vibrational energy, which yields predictable and locally storable electrical energy. Higher energy extraction is possible under larger deflections of the structures when they are employed with PVEHs. In order to estimate the largest possible deflection of the structures, the response of them under external perturbations is estimated. An airplane wing consists of tapered planform, an advanced wind turbine blade, and the rectangular wings of an unmanned aerial vehicle (UAV) are considered for the vibrational analysis as the feasibility of achieving larger deflection is high compared with other aerodynamic surfaces. The stated elastic structures are modelled with different lightweight... [more]
10866. LAPSE:2023.28270
Practical Online Characterization of the Properties of Hydrocracking Bottom Oil via Near-Infrared Spectroscopy
April 11, 2023 (v1)
Subject: Materials
Keywords: ethylene cracking, hydrocracking bottom oil, kernel partial least squares, near-infrared, online measurement
Providing real-time information on the chemical properties of hydrocracking bottom oil (HBO) as the feedstock for ethylene cracker while minimizing processing time, is important to improve the real-time optimization of ethylene production. In this study, a novel approach for estimating the properties of HBO samples was developed on the basis of near-infrared (NIR) spectra. The main noise and extreme samples in the spectral data were removed by combining discrete wavelet transform with principal component analysis and Hotelling’s T2 test. Kernel partial least squares (KPLS) regression was utilized to account for the nonlinearities between NIR data and the chemical properties of HBO. Compared with the principal component regression, partial least squares regression, and artificial neural network, the KPLS model had a better performance of obtaining acceptable values of root mean square error of prediction (RMSEP) and mean absolute relative error (MARE). All RMSEP and MARE values of densi... [more]
10867. LAPSE:2023.28269
Self-Sustaining Control Strategy for Proton-Exchange Membrane Electrolysis Devices Based on Gradient-Disturbance Observation Method
April 11, 2023 (v1)
Subject: Modelling and Simulations
Keywords: disturbance observation method, electrothermal-coupling dynamic model, gradient method, proton-exchange membrane electrolysis device, self-sustaining control
This paper proposes a self-sustaining control model for proton-exchange membrane (PEM) electrolysis devices, aiming to maintain the temperature of their internal operating environment and, thus, improve the electrolysis efficiency and hydrogen production rate. Based on the analysis of energy−substance balance and electrochemical reaction characteristics, an electrothermal-coupling dynamic model for PEM electrolysis devices was constructed. Considering the influence of the input energy−substance and the output hydrogen and oxygen of PEM electrolysis devices on the whole dynamic equilibrium process, the required electrical energy and water molar flow rate are dynamically adjusted so that the temperature of the cathode and the anode is maintained near 338.15 K. The analytical results show that the hydrogen production rate and electrolysis efficiency are increased by 0.275 mol/min and 3.9%, respectively, by linearly stacking 100 PEM electrolysis devices to form a hydrogen production system... [more]
10868. LAPSE:2023.28268
A Model for the Flow Distribution in Dual Cell Density Monoliths
April 11, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Computational Fluid Dynamics, dual cell density, flow distribution, monolith, substrate
Monoliths are promising as catalytic structured supports due to their many operational advantages. Compared to pellets, monoliths offer low backpressure and good heat distribution, even at high flow rates. There is interest in the industry for improving temperature control in highly exothermic systems, such as the catalytic hydrogenation of CO2 for e-fuels synthesis. In this context, novel substrate shapes, such as non-homogeneous cell density monoliths, show good potential; however, to date, they have only been sparsely described. This work focuses on a dual cell density substrate and uses a computational model of a straight-channel monolith with two concentric regions to analyze its flow distribution. The central (core) and peripheral (ring) regions of the substrate differ in cell density in order to obtain a non-homogeneous cross-section. The model is validated against classical data in the literature and theoretical equations. Then, the flow fraction passing through each region of... [more]
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