Underground salt cavern gas storage is the best choice for the production peak adjustment and storage of natural gas, and is a basic means to ensure the safe supply of natural gas. However, in the process of these caverns dissolving due to water injection, argillaceous insoluble sediments in the salt layer will fall to the bottom of the cavity and expand, occupying a large amount of the storage capacity and resulting in the reduction of the actual gas storage space. Effectively reducing the volume of sediments at the bottom of the cavity is a potential way to expand the storage capacity of the cavity. In this study, a method to reduce the volume of argillaceous insoluble sediments with particle sizes ranging from 10 mesh to 140 mesh, via a chemical shrinkage agent, has been proposed. Firstly, the inorganic polymer shrinkage agent PAC30 was synthesized, and then a set of dynamic shrinkage evaluation methods was established to evaluate the influence of temperature, particle size, concent... [more]

Biodiesel, which possesses the dominant advantages of low emissions and environmental friendliness, is a competitive alternative fuel to petroleum-derived diesel. The cetane number, which indicates ignition delay characteristics, is considered the most significant fuel property of biodiesel. Determining the cetane number for biodiesel by general testing equipment is time-consuming and costly; hence, a simple and convenient predictive formula for the cetane number of biodiesel is a significant task to be carried out. A reliable and convenient predictive method for determining the cetane number is proposed in this study. The key parameters for the cetane number of biodiesel were first screened out. The analysis of multiple linear regressions using the available software SPSS for statistical analysis was carried out to obtain the regression coefficients of those key parameters and intercepts to establish the predictive model. Other available experimental data verified the validity of the... [more]

In order to study the influence of the change of the guide vane airfoil on the flow characteristics in the draft tube of a reversible hydraulic turbine, a reversible hydraulic turbine was used as the object of study, and the effect of the change on the flow pattern, energy loss, and pressure pulsation in the draft tube area was studied based on the SST k-ω turbulence model. The results show that under low flow conditions, the modified movable guide vane directly affects the direction and speed of water entering the draft tube, reduces the density of vortex in the draft tube area, reduces the impact on the near wall of the draft tube during the rotation of the vortex belt, and improves the stability of the unit operation. The turbulent energy comparison graph shows that the energy loss in the bent elbow section and the diffusion section of the draft tube is reduced, and the energy return coefficient of the draft tube is improved by calculating that the energy recovery level of the draft... [more]

Two different strategies are provided to generate solutions to the three-dimensional heat diffusion equation. The first strategy is inspired by the well-known one-dimensional heat polynomial, which consists of an infinite set of polynomials, which are solutions to the one-dimensional heat diffusion equation. The second strategy is based on an exponential type function. None of the solutions presented here can be obtained by the method of separation of variables. The mathematical developments proving that, indeed, the particular solutions generated with both strategies satisfy the three-dimensional heat diffusion equation are presented. The analytical solutions are validated by generating the corresponding numerical solutions with the method of finite differences. When comparing both analytical and numerical solutions, it is found that they are identical. In addition, as part of the results, it is found that there are exponential solutions that reproduce the behavior of polynomial solut... [more]

The constant emission of greenhouse gases into the atmosphere, due to the continuous burning of fossil fuels, has been driving researchers to develop an environmentally friendly alternative fuel solution. An experimental investigation was conducted on a laboratory scale, to evaluate the physicochemical qualities, performance, emissions, and combustion characteristics of sea mango oil biodiesel blends and pure diesel fuel on a single-cylinder, variable compression ratio (VCR) engine. Tests were conducted at 1500 rpm, 210 bar, and 23° bTDC, under varying loading circumstances of 0, 3, 6, 9, and 12 kgs, and compression ratios 16:1, 17:1, and 18:1, respectively. The findings revealed that higher compression ratios (CRs) improve the performance, emission, and combustion characteristics of an engine. At CR 18:1, BTHE, SFC, and EGT improved by 8.78%, 11.18%, and 2.52% more than the standard compression ratio (17:1). The CO, HC, and smoke emissions also lowered by 14.65%, 18.56%, and 11.56%, r... [more]

Shale oil reservoirs are characterized by having various types of vertical sublayers, a large contrast in rock mechanical properties, well-developed bedding, and high clay content, which are likely to cause rock elastic−plastic deformation. In numerical simulations of hydraulic fracture (HF) propagation in the shale oil reservoirs, the effects of rock elastic−plastic deformation and complex bedding structure on the layer-crossing behavior of HF are not considered. To understand the mechanism of HF height growth in shale oil reservoirs, we used the cohesive zone method to establish an elastic−plastic finite element model of HF propagation by considering the effects of shell limestone interlayers, the Mohr−Coulomb yield criterion for shear−plastic failure, the cross-mechanical interaction between bedding and shale oil reservoir, and the complex situations such as the HF height across high-electrical resistivity bedding and high-conductivity fractures. The effects of internal friction ang... [more]

The incursion of disruptive technologies, such as the Internet of Things, information technologies, cloud computing, digitalization and artificial intelligence, into current production processes has led to a new global industrial revolution called Industry 4.0 or Manufacturing 4.0. This new revolution proposes digitization from one end of the value chain to the other by integrating physical assets into systems and networks linked to a series of technologies to create value. Industry 4.0 has far-reaching implications for production systems and engineering education, especially in the training of mechatronic engineers. In order to face the new challenges of the transition from manufacturing 3.0 to Industry 4.0 and 5.0, it is necessary to implement innovative educational models that allow the systematic training of engineers. The competency-based education model has ideal characteristics to help mechatronic engineers, especially in the development of specific competencies. This article pr... [more]

Hydraulic fracture morphology and propagation mode are difficult to predict in layers of the various lithological strata, which seriously affects exploitation efficiency. This paper studies the fundamental mechanical and microscopic properties of the two main interfaces in inter-salt shale reservoirs. On this basis, cement-salt combination samples with composite interfaces are prepared, and hydraulic fracturing tests are carried out under different fluid velocities, viscosity, and stress conditions. The result shows that the shale bedding and salt-shale interface are the main geological interfaces of the inter-salt shale reservoir. The former is filled with salt, and the average tensile strength is 0.42 MPa, c = 1.473 MPa, and φ = 19.00°. The latter is well cemented, and the interface strength is greater than that of shale bedding, with c = 2.373MPa and φ = 26.15°. There are three basic fracture modes for the samples with compound interfaces. Low-viscosity fracturing fluid and high-vis... [more]

Conservation of energy usage is essential in chemical process plants due to the expanded energy users and demands alongside the carry-on hike of energy prices. This study analyzed the performance of energy savings in a heat exchanger network (HEN). It is based on decreasing utility usage while increasing process-to-process heat exchange in HEN using a path combination approach at different heat recovery approach temperatures (HRATs). The approach generates different combined path options for heat shifting from utilities to exchangers in a HEN. In terms of cost targeting, the optimal HRAT in a HEN is determined for each path’s combination option. The study focused on the HEN of crude oil preheat trains. Shifting heat load between utilities implies adding and subtracting loads to and from exchangers in a HEN. Therefore, a minor retrofit to compensate for the heat transfer area is required for some HEN exchangers. The optimum HRAT corresponding to the lowest total cost was determined for... [more]

The equilibrium potentials of iron in a LiF-BeF2-FeF2 melt were measured using the EMF method and were dependent upon the temperature and iron fluoride concentrations. The empirical equations for the isotherms and equilibrium polytherms of the iron fluoride concentration were obtained. The cathode polarization of iron fluoride in the molten mixture of lithium and beryllium fluoride was measured using the current switch off method from the stationary state. It was found that in the studied temperature and concentration ranges of iron fluoride in the LiF-BeF2 electrolyte, the valence state of iron in the melt is mainly +2. According to the experimental values of the equilibrium potentials of the iron electrode in the LiF-BeF2-FeF2 melt, the conditional standard potentials of iron were calculated relative to the fluoride reference electrode in the molten mixture of lithium and beryllium fluoride. The conditional standard values of the Gibbs energy change were calculated at the formation o... [more]

In recent years, the technology of storing and transporting natural gas in the form of hydrate has received a lot of attention. At present, the research on the synthesis of natural gas hydrate for the purpose of storage and transportation is still in the laboratory stage, and its synthesis process is in the design and conception stage. The influencing factors of natural gas hydrate synthesis under pilot-scale conditions are more complex. Moreover, pilot experiments are oriented to actual production, and its economic feasibility and operational convenience have higher requirements. This paper aimed to study the influencing factors of gas hydrate synthesis by spray method under pilot-scale conditions. Under specific conditions of surfactant and pressure, we carried out research on the effects of reaction temperature, different forms of atomizers, high-pressure pump flow, experimental water, and other factors. Experiments show that the optimal synthesis conditions were a temperature of −5... [more]

The preparation and application of ultra-clean coal is one of the important aspects of clean energy technology. However, the preparation of ultra-clean coal is mainly chemical methods, which are low in efficiency, high in energy consumption and expensive. It is urgent to find an effective method to prepare ultra-clean coal. In this paper, the combined method of grinding and the collector gasification flotation method was used to obtain ultra-clean coal. The effects of grinding time on the particle size composition, mineral dissociation, surface properties and flotation results of coal samples were studied. The grinding test results show that with the increase in grinding time, the particle size and the pore diameter of coal samples decreased gradually, while the specific surface area and pore volume of coal samples gradually increased. When the grinding time was 20 min, the D90 and D[4,3] of grinding products were 5.20 um and 4.23 um, respectively. The ash content of −1.3 g/cm3 was les... [more]

Aiming at the problem where the current engineering wake model does not describe the wind speed distribution of the wake in the complex terrain wind farm completely, based on the three-dimensional full wake model (3DJGF wake model), this paper proposed a wake model that can predict the three-dimensional wind speed distribution of the entire wake region in the complex wind farm, taking into account the Coanda effect, wind shear effect, and wake subsidence under the Gaussian terrain. Two types of Doppler lidar were used to conduct wind field experiments, and the inflow wind profile and three-dimensional expansion of the wake downstream of the wind turbine on the Gaussian terrain were measured. The experimental results showed that the wake centerline and terrain curve showed similar variation characteristics, and the near wake profile was similar to a super-Gaussian shape (asymmetric super-Gaussian shape) under low-wind-speed conditions, while the near wake profile presented a bimodal sha... [more]

Nitrous oxide is widely used as oxidizer or nitriding agent in numerous industrial activities such as production of adipic acid and caprolactam and even for production of some semiconductors. Further, it is used as an additive in order to increase the power output of engines, and as an oxidizer in propulsion systems of rockets, because it has a large heat of formation (+81.6 kJ mol−1). N2O is highly exothermic, and during its decomposition a supplementary heat amount is released, so it needs special handling conditions. The combustion of fuels in nitrous oxide atmosphere can lead to high unstable and turbulent deflagrations that speedily self-accelerate and therefore a deflagration can change to a detonation. The peak explosion pressure and the maximum rate of pressure rise of explosions in confined spaces are key safety parameters to evaluate the hazard of processes running in closed vessels and for design of enclosures able to withstand explosions or of their vents used as relief dev... [more]

In this paper, a novel high-efficiency bidirectional isolated DC−DC converter that can be applied to an energy storage system for battery charging and discharging is proposed. By integrating a coupled inductor and switched-capacitor voltage doubler, the proposed converter can achieve isolation and bidirectional power flow. The proposed topology comprises five switches and a common core coupled inductor that uses only a set of complementary pulse-width-modulated signals to control and achieve high voltage gain without requiring high turn ratios or excessive duty cycles. Moreover, the proposed topology can recover the leakage inductance energy to improve the conversion efficiency. The main switches exhibit zero-voltage switching, which reduces the switching losses. A 500-W bidirectional converter is used to verify the feasibility of the proposed bidirectional converter through theoretical analysis and experiments. The experimental results indicate that the highest efficiency of the propo... [more]

This work represents the point of view of a diabetic patient with an indirect experience in this specific field of research. As a chemical engineer and researcher in drug carrier production, he has always approached type-1 diabetes (T1D) in a scientific manner. Therefore, this work represents a description of almost 20 years of this illness treatment using a multi-injection insulin system, compared with the experience acquired with a newly adopted micro-infusion system, allowing automatized insulin administration. The use of the continuous system reduced significantly the Hb1Ac average values, from 8.8% to 6.6%, in less than 2 years. Moreover, a full 24 h control guaranteed the almost total elimination of the hypoglycemia risk, thanks to the automated control system, that can stop insulin administration in order to prevent critical situations. It is also important to note that the point of view underlined in this work does not presume to be that of a doctor or of a researcher who works... [more]

Aquila Optimizer (AO) and Artificial Rabbits Optimization (ARO) are two recently developed meta-heuristic optimization algorithms. Although AO has powerful exploration capability, it still suffers from poor solution accuracy and premature convergence when addressing some complex cases due to the insufficient exploitation phase. In contrast, ARO possesses very competitive exploitation potential, but its exploration ability needs to be more satisfactory. To ameliorate the above-mentioned limitations in a single algorithm and achieve better overall optimization performance, this paper proposes a novel chaotic opposition-based learning-driven hybrid AO and ARO algorithm called CHAOARO. Firstly, the global exploration phase of AO is combined with the local exploitation phase of ARO to maintain the respective valuable search capabilities. Then, an adaptive switching mechanism (ASM) is designed to better balance the exploration and exploitation procedures. Finally, we introduce the chaotic op... [more]

Sludges from the papermaking industry represent a challenging residue stream that is difficult to dewater using conventional processes. The successful development and scale-up of innovative processes from lab- to pilot- to industrial-scale are required to tackle challenges for waste treatment, including paper sludges. Biological paper sludge was treated via a mild hydrothermal carbonization process (TORWASH®) to improve dewaterability of the sludge, including long-duration, continuous testing. Initial lab-scale experiments indicated the optimal treatment temperature for sludge dewatering was 190 °C. Dewaterability improved with increasing temperature, but the obtained solid yield decreased. Scaling-up to a continuous flow pilot plant required a temperature of 200 °C to achieve optimum dewatering. Pilot-scale hydrothermal treatment and dewatering resulted in solid cakes with an average dry matter content of 38% and a solid yield of 39%. This study demonstrates the benefits of hydrotherm... [more]

SEM, particle size analysis, and contaminant content of coarse coal gasification slag (CCGS) produced by Shenhua Xinjiang Chemical Co., Ltd. were measured, respectively, and the physicochemical properties of the soil after improvement using gasification slag were investigated in this paper. The results showed that the slag was porous, the particle size was small and the pollutant content was extremely low. Its pollutants were closely related to the pollutants in the raw coal. The coarse slag had a limited effect on soil particle size and texture improvement; the soil water retention performance increased with the increase of proportion of the slag, while pH and conductivity decreased; the improvement effect on soil SOM and available potassium was remarkable; the larger the proportion of the slag, the stronger the effect on maintaining soil alkali-hydrolyzed nitrogen, ammonium nitrogen, and available phosphorus. However, the effect was small, and increased the ion content, especially th... [more]

This paper presents the results of applying hydrophobic deep eutectic solvents (HDESs) for the extraction of metal ions from a real hydrochloric acid solution after leaching the cathodes of three different types of Li-ion batteries. Aliquat 336-, D2EHPA- and menthol-based HDESs developed by us were used in this study. The optimal HCl leaching conditions chosen are 80 °C, 2 M HCl, 6 h, solid:liquid ratio = 1:25. The results of stepwise separation of the major elements using extraction with HDESs are presented. The HDESs used in the cross-current extraction made it possible to extract all elements with extraction ratios above 98%. It was shown that the suggested method could potentially be used in the process of recycling end-of-life Li-ion batteries.

The current scenario of society is to produce fuel from renewable energy resources. The purpose of this research work is to develop an integrated approach for glycerol valorization and biodiesel production. Employing a range of methodologies widely used in the industry, technical analysis and assessments of the process’s applicability in real-world situations are also made. The integrated process plant is simulated using Aspen Plus®. Several different sensitivity analyses are carried out to describe the process that improves efficiency and are designed to maximize hydrogen recovery from the reforming section. The integrated process results are compared with several existing standalone biodiesel production processes. Additionally, the results are verified with the theoretical studies on glycerol valorization. The outcomes of the process plant simulation reveal coherent results with the current industrial standards for the two processes. The results show that the amount of glycerol produ... [more]

Biosensors can be used for high-throughput screening, real-time monitoring of metabolites, and dynamic regulation of metabolic processes, which have been a popular research direction in recent years. Here, five promoters from Saccharomyces cerevisiae were selected to construct Malonyl-CoA sensors with the fapO/fapR system derived from Bacillus subtilis, and pCCW12 was finally selected for further optimization. Based on pCCW12, a series of sensors with different response sensitivities were obtained by selecting different fapO insertion sites and combining the best two or three of them. Then, through a combination of promoter hybrid, intron insertion, and transcription factor modification strategies, we obtained sensors with different effects, one of which, the H-pCCW12(TFBS)-Cti6~fapR sensor, had the lowest background noise, doubled response range and higher response sensitivity compared to the original sensor. Sensors with different characteristics constructed in this study, can be app... [more]

Polytungstate melts are used for the electrodeposition of oxide tungsten bronzes (OTBs). The scarce information on the ionic composition and properties of these electrolytes hinders effective control of the electrochemical synthesis of OTBs with desired electrical and optical properties. In this work, a comprehensive study of Na2WO4−WO3 melts that contained up to 55 mol% of tungsten trioxide was performed in the temperature range from 983 to 1073 K. Melt densities were measured using the Archimedes method. DFT calculations were carried out for various tungsten-containing compounds, including WxO3x−12+, WxO3x+12−, NaWxO3x+1−, and Na2WxO3x+1. The calculated values of the W−O bond energy indicate that the tested compounds are stable in the specified temperature range, and the  WO22+ cation is the most stable. The experimental dependences of the redox potential on the mole fraction of tungsten trioxide in the Na2WO4−WO3 melt were obtained using the EMF method. A model that considers t... [more]

To study the influence of control parameters under cold-start and low-load conditions on the performance of a heavy-oil, two-stroke, direct-injection, ignition engine for use in aviation, the operation of a two-stroke, direct-injection engine was studied in a bench test. The results were as follows: ① When the ambient temperature is 15 °C, the battery voltage is 12.4 V, and the peak speed of the starting motor is 1200 r/min. As the concentration factor increases, the cold-start speed increases, and the fuel consumption increases. The influence on the cold start is reduced after reaching a certain concentration. The cold-start time decreases with the increasing magnetization pulse width. The cold-start time is the shortest at an oil−gas interval of 6 ms. ② Under small-load conditions of 3000 r/min and 14% to 16% throttle, a higher ignition energy increases the engine power. Pollutant emissions are the lowest when the fuel injection is 7.5 mg and the excess air coefficient is approximate... [more]

The Changbei gas field is dominated by wells with large horizontal displacement, which have exhibited high gas production performance at an early stage of development. With the decrease in reservoir pressure, the liquid loading in the gas well is relatively high and gas production rapidly decreases. Therefore, suitable drainage measures are required to maintain stable gas production. Based on the characteristics of the unconnected oil jacket of gas wells in Changbei, a velocity string was used for drainage. A critical liquid-carrying model was established to determine the location of liquid loading in horizontal gas wells in Changbei. First, the coefficients of the liquid-carrying model were determined through theoretical analysis of the characteristics of the gas well formation. Then, the depth setting of the velocity string was analyzed. The critical liquid-carrying model was employed to calculate the liquid-carrying flow rate of each section; the calculated flow rates were compared... [more]