With the increasing installed capacity of renewable energy in the energy system, the uncertainty of renewable energy has an increasingly prominent impact on power system planning and operation. Renewable energy such as wind and solar energy is greatly affected by the external weather. How to use a reasonable method to describe the relationship between weather and renewable energy output, so as to measure the uncertainty of renewable energy more accurately, is an important problem. To solve this problem, this paper proposes a renewable energy scenario generation method based on a conditional generation countermeasure network and combination weighting method (CWM-CGAN). In this method, the combination of AHP and the entropy weight method is used to analyze the meteorological factors, the weather classification is defined as the condition label in the conditional generation countermeasure network, and the energy scenario is generated by the conditional generation confrontation network. In... [more]

Biodiesel is one of the most environmentally friendly and renewable fuels, as it is a non-polluting fuel and is made from living resources, such as vegetable oils. The steel industry generates a variety of solid wastes, including electric arc furnace slag (EAFS). The synthesis of biodiesel from waste sunflower cooking oil was examined in this study, utilizing EAFS as a catalyst, which mainly contains ferric and ferrous oxides, calcium oxide, and silica. To evaluate their impact on biodiesel production, four independent variables were chosen: temperature (50−70 °C), catalyst loading (1−5%), methanol-to-oil (M:O) molar ratio (5−20), and time (1−4 h). The response surface methodology (RSM) was used to examine the impact of independent variables on reaction response, which is the biodiesel yield. This process was carried out using a design expert program by central composite design (CCD). A model was constructed, and showed that the biodiesel yield was directly proportional to all independ... [more]

The paper presents a useful engineering model for the design of preliminary hybrid rocket engines. This model involves the experimentally obtained equation regarding the speed of the burning interface between solid fuel and gaseous phase, called the regression rate. This regression rate characterizes the mass rate of the burning fuel and additionally the mass rate of the oxidizer through the imposed ratio of these mass rates during combustion. The preliminary design is applied to combustion using pure HTPB and gaseous oxygen and was developed for three cases, constant regression rate, constant oxygen mass flow rate and constant O/F (ratio of mass rates of oxygen and of fuel). The design evaluates the initial fuel port geometry, the initial mass of fuel and oxygen, the combustion time, the thrust at sea level, and the time-dependent functions of regression rate, of fuel and oxygen mass rates, and of thrust. It was assumed that the regression rate formula applies at any time of combustio... [more]

Transient stability during grid fault is experienced differently in modern power systems, especially in wind-turbine-dominated power systems. In this paper, transient behavior and stability issues of a direct drive wind turbine during fault recovery in DC-link voltage control timescale are studied. First, the motion equation model that depicts the phase and amplitude dynamics of internal voltage driven by unbalanced active and reactive power is developed to physically depict transient characteristics of the direct drive wind turbine itself. Considering transient switch control induced by active power climbing, the two-stage model is employed. Based on the motion equation model, transient behavior during fault recovery in a single machine infinite bus system is studied, and the analysis is also divided into two stages: during and after active power climbing. During active power climbing, a novel approximate analytical expression is proposed to clearly reveal the frequency dynamics of th... [more]

The intersection behavior of hydraulic fractures and single natural fractures has been studied in detail; however, in fractured reservoirs, natural fractures are numerous and interlaced and the intersection of hydraulic fractures and multiple natural fractures occurs during the fracturing process. This intersection behavior is more complex and there is a lack of research on this topic at present. In this study, a numerical simulation model of the interaction between hydraulic fractures and a series of natural fractures was established, the main factors that affect the formation scale of a fracture network during the hydraulic fracturing of a fractured reservoir were studied using the numerical simulation method, and the parameters were also studied. The results showed that the natural fracture trend, in situ stress difference, and injection flow rate have an impact on the scale of a fracture network. The larger the in situ stress difference, the smaller the scale of the fracture networ... [more]

The increasing share of variable renewable energies in the power grid is an incentive to explore demand response strategies. Chlor-alkali processes are high potential candidates, according to previous publications. Within Germany’s chemical industry, chlorine production accounts for approximately 20% of electricity use and could play a significant role in power grid stabilisation on the consumer end. This study focuses on the feasibility of load flexibilisation in epichlorohydrin plants, with the second biggest estimated demand response potential for chlorine-based products in Germany. A plant model with allyl chloride storage was created based on real data and literature values. Results from this model, spot market and balancing power prices, and future electricity market scenarios were used in a mixed-integer linear optimisation. We find that benefits from demand response can be generated as soon as additional power and storage volume is provided. The composition of provided types of... [more]

New trends and future prospects for small capacity systems of Renewable Energy-driven DESalination (REDES) are reviewed and assessed in this paper over a nominal desalination capacity range of 3−1000 m3/d. A thorough literature review is reported in order to evaluate current research and developing activities. Outstanding commercial prospects in the near future are identified for two off-grid REDES technologies under development. First, wave energy converters with direct coupling to seawater desalination. Second, solar micro gas turbines with biofuel backup coupled to reverse osmosis (RO) desalination and/or zero liquid discharge water treatment. These systems, as well as mature REDES plants (namely PV/RO and wind turbines/RO), will benefit from forthcoming advances in energy efficiency in the RO process itself. The Closed Circuit RO desalination (CCROTM) concept may be a key configuration for enhancing RE-driven RO desalination. Additionally, opportunities for innovation in seawater R... [more]

Temporary plugging and diverting fracturing (TPDF) is widely used to improve the stimulation effectiveness in coal seam. To study the fracture propagation behavior during TPDF in coal formation, a series of laboratory hydraulic fracturing experiments were performed on natural coal samples. Based on the results of sample splitting and fracture reconstruction, the influences of horizontal stress difference and the size of temporary plugging agent (TPA) as well as the concentration of TPA on hydraulic fracture growth were analyzed. Experimental results show that TPDF is beneficial for improving the fracture complexity even under high stress difference of 8 MPa. When the TPA of small particle size (70/100 mesh) was applied, the primary fracture could not be fully blocked whereas increasing the particle size of TPA to 20/40 mesh tended to cause accumulation and bridging in the wellbore, resulting in an abnormally high fracturing pressure. TPA with particle size of 40/70 mesh tended to be a... [more]

This paper reviews experimental works on the effects of single nozzle location and multi-nozzle atomization on the mechanism of particle agglomeration in spray drying. In addition to the naturally occurring primary agglomeration, forced and secondary agglomeration is observed as an effect of different nozzle positions or multiple-nozzle atomization in spray drying. Particle size diameters in the spray drying process for atomization from a single nozzle located at the top of the tower are larger than at the bottom of the tower because of the lower ambient air temperatures and longer residence time in the agglomeration zone. The trend of reduction in particle size is observed in all analyzed works when the nozzle is moved down towards the air inlet, due to droplets’ exposure to higher air temperatures and shorter residence time in the drying chamber. Conditions of droplet−droplet, dry−dry or sticky−dry collisions leading to the development of coalescence, agglomeration and rebound zones... [more]

While traditional one-dimensional and three-dimensional numerical simulation techniques require a lot of tests and time, emerging Machine Learning (ML) methods can use fewer data to obtain more information to assist in engine development. Combustion phasing is an important parameter of the spark-ignition (SI) engine, which determines the emission and power performance of the engine. In the engine calibration process, it is necessary to determine the maximum brake torque timing (MBT) for different operating conditions to obtain the best engine dynamics performance. Additionally, the determination of the combustion phasing enables the Wiebe function to predict the combustion process. Existing studies have unacceptable errors in the prediction of combustion phasing parameters. This study aimed to find a solution to reduce prediction errors, which will help to improve the calibration accuracy of the engine. In this paper, we used Support Vector Regression (SVR) to reconstruct the mapping r... [more]

As the main reactor type of the fourth-generation nuclear power systems, sodium-cooled fast reactors are now designed and built worldwide. A sodium pool cooling circulation process is indispensable in a sodium-cooled fast reactor. However, the sodium pool fire design is the basis of accidents in sodium-cooled fast reactors. The fire hazard caused by the sodium−oxygen reaction and fast reactor safety have attracted extensive attention. Dry powder is widely used as an effective fire-extinguishing agent to control sodium fire. The sodium will burn in an oxygen-depleted atmosphere when using dry powder to cover fire. In this study, the change law of thermogravimetry of melted sodium is studied by thermogravimetric analysis (TGA) and the apparent activation energy (Ea) is obtained, which has a linear relationship with the oxygen concentration. The results can provide a reference for improving the engineering design standards of sodium fire suppression systems and can also be incorporated in... [more]

In this study, the engineering properties of Ordinary Portland Cement (OPC) and alkali-activated slag (AAS) mortar with electric arc furnace ladle slag (EAFLS) were investigated to reveal the effects of EAFLS on the expansion of cementitious mortars. Additionally, the effects of these two types of mortar were explored based on their compressive strength, especially at high temperatures. EAFLS in OPC mortars significantly reduced the compressive strength and caused serious soundness problems in the mortars after autoclaving due to the presence of free-CaO and free-MgO in the EAFLS slag. On the other hand, the AAS mortars produced with EAFLS had compressive strength comparable to ordinary OPC mortars and maintained soundness after autoclaving. During a 550 °C heat treatment, the OPC mortar cracked and lost residual strength, but the AAS mortar retained more than 90% of its residual strength. Even after an 800 °C heat treatment, the AAS mortar maintained 14% of its residual strength (abou... [more]

The synthesis of sulfide solid electrolytes in ball mills by mechanochemical routes not only is efficient but also can enable the upscaling of material synthesis as required for the commercialization of solid-state battery materials. On a laboratory scale, the Emax high energy ball mill accounts for high stresses and power densities, as well as for temperature control, to prevent damage to the material and equipment even for long process times. To overcome the merely phenomenological treatment, we characterized the milling process in an Emax by DEM simulations, using the sulfide solid electrolyte LPS as a model material for the calibration of input parameters to the DEM, and compared it to a planetary ball mill for a selected parameter set. We derived mechanistic model equations for the stressing conditions depending on the operation parameters of rotational speed, media size and filling ratio. The stressing conditions are of importance as they determine the outcome of the mechanochemi... [more]

In order to solve the inaccuracy in the calculation of the wellbore pressure distribution caused by large liquid production in the Donghai gas field, the gas−liquid production conditions of the Donghai gas field were simulated with indoor experiments, and the flow patterns for different pipe diameters, different inclinations, and different flow patterns were systematically analyzed using a flow pattern discrimination method, liquid holdup calculation method, and pressure drop calculation method. Using the experimental data, the division methods for different flow patterns were screened. Finally, based on the fact that the change trend for the flow patterns was consistent, the Kaya−Sarica−Brill method was selected to establish the flow pattern discrimination formula. According to the calculation method for the Mukherjee and Brill (M−B) liquid holdup, the M−B model was re-established according to a 75 mm pipe diameter and 60 mm pipe diameter using the instantaneous liquid holdup measured... [more]

Implementation of flue gas waste heat recovery is an effective way to improve the energy utilization of marine engines. This paper aims to model and optimize a marine four-stroke dual-fuel (DF) engine coupled with a flue gas waste heat recovery system. Firstly, the DF engine and waste heat recovery system were respectively modeled in GT-Power and Simulink environments and verified with experimental data. Then, a regression model was built using the response surface method, with the intake temperature, compression ratio, and pilot fuel injection timing as input parameters and parametric analysis was performed. Finally, multi-objective optimization of the waste heat recovery system was performed using a genetic algorithm. The result showed that the optimal solution is obtained when the intake temperature is 306.18 K, the geometric compression ratio is 14.4, and the pilot fuel injection timing is −16.68 °CA after the top dead center. The corresponding brake-specific fuel consumption was 1... [more]

The progress of high-efficiency non-precious metal anode catalysts for direct seawater splitting is of great importance. However, due to the slow oxygen evolution reaction (OER) kinetics, competition of chlorine evolution reaction (ClER), and corrosion of chloride ions on the anode, the direct seawater splitting faces many challenges. Herein, we develop a perovskite@NiFe layered double hydroxide composite for anode catalyst based on Ba0.5Sr0.5Co0.8Fe0.2O3 (BSCF) and NiFe layered double hydroxide (NiFe-LDH) heterostructure. The optimized BSCF@CeO2@NiFe exhibits excellent OER activity, with the potential at 100 mA cm−2 (Ej = 100) being 1.62 V in the alkaline natural seawater. Moreover, the electrolytic cell composed of BSCF@CeO2@NiFe anode shows an excellent stability, with negligible attenuation during the long-term overall seawater splitting with the remarkable self-recovery ability in the initial operation stage, and the direct seawater splitting potential increasing by about 30 mV at... [more]

The purpose of this paper is to investigate the feasibility of a wind−solar hybrid system on and off-grid power system for electricity generation at a selected location in Somalia using the renewable energy optimization software HOMER. The simulation model was successfully applied to find the best simulation results based on the energy-efficient system for the specific load. The technical and economic performance of an on-grid and stand-alone combination of 25 kW wind power and 60 kW solar photovoltaic was investigated. Since the city of Cadaado has not yet installed its own standard modern electricity grid and due to the great need to reduce energy costs in Somalia, a feasibility study was conducted on how to supply electricity to a sampled residential consumption. Based on the basic characteristics of renewable energy sources in central Somalia, the on-grid wind and solar photovoltaic systems could be economically feasible.

Efforts to engineer high-productivity crops to accumulate oils in their vegetative tissue present the possibility of expanding biodiesel production. However, processing the new crops for lipid recovery and ethanol production from cell wall saccharides is challenging and expensive. In a previous study using corn germ meal as a model substrate, we reported that liquid hot water (LHW) pretreatment enriched the lipid concentration by 2.2 to 4.2 fold. This study investigated combining oil recovery with ethanol production by extracting oil following LHW and simultaneous saccharification and co-fermentation (SSCF) of the biomass. Corn germ meal was again used to model the oil-bearing energy crops. Pretreated germ meal hydrolysate or solids (160 and 180 °C for 10 min) were fermented, and lipids were extracted from both the spent fermentation whole broth and fermentation solids, which were recovered by centrifugation and convective drying. Lipid contents in spent fermentation solids increased 3... [more]

This article presents the results of research on the possibilities of fragmentation of cultural, and especially agricultural, landscapes in a selected locality in eastern Slovakia, which is currently characterized by a high proportion of large-scale soil units used for growing cereals and crops subsequently used as energy sources (maize and oilseed rape, among others). Slovakia, as the country with the largest average field area in the European Union (EU), is facing a process of fragmentation of these units to counter climate change and increase the resilience of the landscape to erosion, soil fertility, and biodiversity loss. This paper presents a fragmentation method based on the restoration of former dividing lines, mainly formed by dirt roads, based on the historical mapping. The results show that in this way it is possible to achieve denser landscape fragmentation, to create dividing green belts, to increase the resilience of the environment to water and wind erosion, and to creat... [more]

The use of renewable energy for desalination started in the 1980s, in order to provide a sustainable water supply in windy/sunny areas with water shortages. Nevertheless, this initiative has been generally limited to the R&D field and prototypes, with few units operating under real conditions. The research tradition in this field carried out by the Canary Islands Institute of Technology, based on pilot facilities, resulted in wide expertise on practical issues, as well as a deep knowledge on the state of the art. This paper deals with the most relevant technical aspects to be considered in the optimal design and operation of wind/photovoltaic (PV)-powered reverse-osmosis (RO) systems, focusing on practical indications: appropriate pre-treatment, the use and selection of the RO energy recovery system (ERD), the selection of an energy storage system, key recommendations for the O&M actions in wind- and PV-powered RO systems (extracted from the experience of operating different units in r... [more]

Redox flow batteries hold promise as large-scale energy storage systems for off-grid electrification. The electrolyte is one of the key components of redox batteries. Inspired by the mechanism involved in solvents for extraction, a ternary deep eutectic solvent (DES) is demonstrated, in which glycerol is introduced into the original binary ethaline DES. Redox pairs (active substance) dissolved in the solvent have low charge transfer resistance. The results show that the viscosity of the solvent with the ratio of choline chloride to ethylene glycol to glycerol of 1:2:0.5 decreases from 51.2 mPa·s to 40.3 mPa·s after adding the redox pair, implying that the mass transfer resistance of redox pairs in this solvent is reduced. Subsequent cyclic voltammetry and impedance tests show that the electrochemical performance with the ternary DES as the electrolyte in redox flow batteries is improved. When the ratio of 1:2:0.5 ternary DES is used as the electrolyte, the power density of the battery... [more]

Temporary plugging fracturing in a horizontal well with multi-stages and multi-clusters is usually used to improve stimulation efficiency and increase the gas production from shale gas reservoirs. However, the fracture propagation geometry and the mechanism of temporary plugging are still unclear, which restricts the further optimization of temporary plugging fracturing scheme. In this study, taking the Longmaxi shale as the research object and considering the intrafracture and intrastage temporary plugging, the true tri-axial hydraulic fracturing system was used to put forward an experimental method for simulating the temporary plugging fracturing in a horizontal well with multi-stages and multi-clusters. Afterward, the effects of the size combination and concentration of temporary plugging agents and the cluster number in a stage on the fracture geometry created in the secondary fracturing were investigated in detail. The results show that an optimal fracture propagation geometry ten... [more]

Low-permeability reservoirs are important to the future growth of oil and gas reserves and production in China. Predicting the effective stress, σe, in reservoirs is vitally important due to its considerable impact on reservoir development through hydraulic fracturing. This paper presents methods for predicting the σe field in ultralow-permeability reservoirs through reservoir−geomechanics coupling, which involve the simulation and coupling of the tectonic stress σ and pore pressure Pp fields based on three-dimensional (3D) geological models. First, 3D geological models were constructed based on basic data for the oilfield where the reservoir of interest is located. Then, finite element and finite difference simulations were performed to construct the σ and Pp fields, respectively, in the reservoir. Different types of initial σe were coupled based on 3D geological models. Subsequently, a dynamic σe field in the reservoir was established based on oilfield production data in conjunction... [more]

Biodiesel is considered a renewable, green fuel as it is derived from renewable living resources like animal fats or vegetable oils. This research is utilized to investigate the possibility of using Solvay wastewater as a source of biodiesel catalyst, which is CaO. CaCl2 from Solvay wastewater reacts with CO2 to produce CaCO3. CaCO3 is then heated to produce pure CaO. Waste cooking oil, wastewater, and CO2, which are considered dangerous materials to the environment, are used to produce valuable products. This research has environmental and economic benefit benefits of using waste materials as a replacement for raw materials. The selected experimental parameters for the CaCO3 production step are stirring rate (500−1300) rpm, CO2 gas flow rate (900−2000) mL/min, amount of ammonia (15−35) mL, and glycerol volume (0−25) mL. The selected experimental parameters for the biodiesel production step are reaction time (2−6) h, methanol to oil ratio (9−15), catalyst loading (1−5) %, and reaction... [more]

A pressure-controlled jet crushing tool (PJCT) for the exploitation of deep-sea natural gas hydrate (NGH) was invented to achieve sediment crushing and cavity creation. The opening and closing of tool is controlled by changing the internal flow rate remotely. It can realize the controllable continuous switching of the working state between horizontal well drilling and cavity creation. A dynamic simulation model of the sliding core was established based on the innovative design scheme of the PJCT and the motion law of its slide core was analyzed under the influence of spring stiffness, friction coefficient, and flow rate loading scheme. Moreover, an engineering prototype of the PJCT was manufactured so that a sliding core motion experiment of the prototype was carried out. When the drilling fluid flow rate reaches 455 L/min, the PJCT can stably complete the self-locking and unlocking functions. Its sliding core needs more time to stabilize with an increase in spring stiffness. Meanwhile... [more]