LAPSE:2023.2583
Published Article

LAPSE:2023.2583
Thermal Characteristic Analysis of Sodium in Diluted Oxygen via Thermogravimetric Approach
February 21, 2023
Abstract
As the main reactor type of the fourth-generation nuclear power systems, sodium-cooled fast reactors are now designed and built worldwide. A sodium pool cooling circulation process is indispensable in a sodium-cooled fast reactor. However, the sodium pool fire design is the basis of accidents in sodium-cooled fast reactors. The fire hazard caused by the sodium−oxygen reaction and fast reactor safety have attracted extensive attention. Dry powder is widely used as an effective fire-extinguishing agent to control sodium fire. The sodium will burn in an oxygen-depleted atmosphere when using dry powder to cover fire. In this study, the change law of thermogravimetry of melted sodium is studied by thermogravimetric analysis (TGA) and the apparent activation energy (Ea) is obtained, which has a linear relationship with the oxygen concentration. The results can provide a reference for improving the engineering design standards of sodium fire suppression systems and can also be incorporated into simulation software to improve the accuracy of fire suppression simulations.
As the main reactor type of the fourth-generation nuclear power systems, sodium-cooled fast reactors are now designed and built worldwide. A sodium pool cooling circulation process is indispensable in a sodium-cooled fast reactor. However, the sodium pool fire design is the basis of accidents in sodium-cooled fast reactors. The fire hazard caused by the sodium−oxygen reaction and fast reactor safety have attracted extensive attention. Dry powder is widely used as an effective fire-extinguishing agent to control sodium fire. The sodium will burn in an oxygen-depleted atmosphere when using dry powder to cover fire. In this study, the change law of thermogravimetry of melted sodium is studied by thermogravimetric analysis (TGA) and the apparent activation energy (Ea) is obtained, which has a linear relationship with the oxygen concentration. The results can provide a reference for improving the engineering design standards of sodium fire suppression systems and can also be incorporated into simulation software to improve the accuracy of fire suppression simulations.
Record ID
Keywords
apparent activation energy, oxygen concentration, sodium oxygen reaction, sodium pool fire, thermogravimetric analysis
Subject
Suggested Citation
Chen F, Dong XL, Tang Y, Huang AC, Zhang ML, Kang QC, Shu ZJ, Xing ZX. Thermal Characteristic Analysis of Sodium in Diluted Oxygen via Thermogravimetric Approach. (2023). LAPSE:2023.2583
Author Affiliations
Chen F: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Dong XL: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Tang Y: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Huang AC: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China [ORCID]
Zhang ML: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Kang QC: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Shu ZJ: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Xing ZX: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Dong XL: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Tang Y: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Huang AC: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China [ORCID]
Zhang ML: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Kang QC: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Shu ZJ: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Xing ZX: School of Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China
Journal Name
Processes
Volume
10
Issue
4
First Page
704
Year
2022
Publication Date
2022-04-05
ISSN
2227-9717
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Original Submission
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PII: pr10040704, Publication Type: Journal Article
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LAPSE:2023.2583
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https://doi.org/10.3390/pr10040704
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Feb 21, 2023
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