Aerogel-based renders have been the subject of research in the last few years due to their high thermal insulation characteristics and the need for buildings to become more energy-efficient. This study compares the hygrothermal behaviour of an aerogel-based render (reference) with the same base formulation, replacing the powder with three different fibres (aramid 0.5%, sisal 0.1%, and biomass 0.1%, by total volume) that can be used in buildings’ envelopes. The experimental programme allowed us to characterise and compare the thermophysical properties of the different formulations and then simulate the hygrothermal performance of these solutions when applied to walls for different climatic conditions, considering additional parameters such as total water content, drying potential, water content levels, and thermal insulating performance. These thermophysical parameters were then included in hygrothermal numerical simulations. The results allowed us to verify that the incorporation of fi... [more]

The work focuses on the minimization of the body deflection from its equilibrium position after a deflection by force applied to the wheel with the task of simulating obstacles encountered by the wheel. The model presents a quarter of the car’s suspension with a nonlinear spring and a damper with magnetorheological fluid, by which the damping of the suspension is modified. The system was created in harmony with Lyapunov’s stability. The model was designed using Matlab-Simulink. The model was designed for testing many different damaged parts of the suspension, for example, a spring or a damper. In further attempts, the model was tested for numerous damaged parts, and the sequence of events was different. The model was tested for different characteristics of springs and dampers and variable method deflection wheel from its equilibrium position such as force and displacement. This work discusses the detection of damage to the suspension along with the possibility of adapting the MR damper... [more]

PV technology offers a sustainable solution to the increased energy demand especially based on mono- and polycrystalline silicon solar cells. The most recent years have allowed the successful development of perovskite and tandem heterojunction Si-based solar cells with energy conversion efficiency over 28%. The metal oxide heterojunction tandem solar cells have a great potential application in the future photovoltaic field. Cu2O (band gap of 2.07 eV) and ZnO (band gap of 3.3 eV) are very good materials for solar cells and their features completely justify the high interest for the research of tandem heterojunction based on them. This review article analyzes high-efficiency silicon-based tandem heterojunction solar cells (HTSCs) with metal oxides. It is structured on six chapters dedicated to four main issues: (1) fabrication techniques and device architecture; (2) characterization of Cu2O and ZnO layers; (3) numerical modelling of Cu2O/ZnO HTSC; (4) stability and reliability approach.... [more]

Tritium extraction is one of the key open issues toward the development of the WCLL BB (Water-Cooled Lithium−Lead Breeding Blanket) of EU DEMO reactors, and different technologies have been proposed to address it. Among them, the Permeator Against Vacuum (PAV) has promising features, but it has never been tested in a relevant environment. This work presents the first experimental results ever obtained for a PAV mock-up. The experiments were carried out at ENEA Brasimone R.C. with the TRIEX-II facility on a mock-up characterized by a shell and tube configuration and using niobium as a membrane material. The experimental campaign was carried out with LiPb flowing at about 450 °C and 1.2 kg/s, while the hydrogen partial pressure was varied in the range 170−360 Pa. The characterization of the PAV performance was conducted by measuring the hydrogen partial pressure drop across the mock-up and the hydrogen permeated flux through a leak detector calibrated with an external hydrogen calibratio... [more]

Thermal energy storage is an essential technology for improving the utilization rate of solar energy and the energy efficiency of industrial processes. Heat storage and release by the dehydration and rehydration of Ca(OH)2 are hot topics in thermochemical heat storage. Previous studies have described different methods for improving the thermodynamic, kinetic, and structural stability of Ca(OH)2 to improve energy storage density, energy storage rate, and cycle stability, respectively. Here, the mechanisms and effects of different techniques on the performance improvement of Ca(OH)2 and some common problems were reviewed. Specific problems were also clarified based on the characteristics of different technologies. Finally, suggestions for the future development of Ca(OH)2 heat storage materials were provided.

The influence of Bi doping on the structural and thermoelectric properties of Cu2Se is presented in this work. Cu2−xBixSe (x = 0.00, 0.004, 0.008, 0.012) samples were prepared using conventional solid-state reaction techniques. According to room temperature XRD results, Cu2−xBixSe samples have a monoclinic crystal structure. Doping Bi to the Cu site acts as a donor, lowering the hole concentration, except for the sample with x = 0.004. The resistivity of the Cu2−xBixSe sample increases with an increase in Bi content. Seebeck coefficient data confirm that the holes are the charge carriers in Cu2−xBixSe samples. At 700 K, the Cu1.988Bi0.012Se sample has the highest power factor of 1474 μWm−1K−2, showing great potential in developing high-performance Cu2Se based thermoelectric materials.

With the increasing attention to environmental protection and strict national standards, the production of high-quality clean gasoline is more and more required in modern refineries. At present, the molecular-level online modeling of the gasoline blending process is rarely reported due to the lack of a proper characterization method. In this study, we have developed a molecular reconstruction method based on near-infrared (NIR) spectroscopy. We established a library that comprises an NIR spectrum and molecular composition of known reformates. We developed the sample selection algorithm that finds the sample with an NIR spectrum close to the target sample. The method-solving algorithm based on multiple linear regression was used to obtain the molecular composition of gasoline quickly. The method combines online measurement methods and molecular management technology to achieve online composition reconstruction. Seventy-five groups of reformates were collected to verify the feasibility o... [more]

Chemical compatibility and cation interdiffusion between the double perovskite cobaltites RBaCo2O6−δ (R = Gd, Pr) and proton-conducting electrolyte BaZr0.8Y0.2O3−δ were studied. Chemical interaction was found to occur already at 1100 °C as a result of the partial dissolution of RBaCo2O6−δ (R = Gd, Pr) in BaZr0.8Y0.2O3−δ. Analysis of the element distribution along the cross sections of diffusion couples RBaCo2O6−δ(R = Gd, Pr)|BaZr0.8Y0.2O3−δ showed strong interdiffusion of cations, with cobalt being the most mobile one. Its diffusion depth in the electrolyte reaches up to several hundreds of micrometers. The addition of NiO as a sintering aid to BaZr0.8Y0.2O3−δ promotes cation diffusion especially through the grain boundary mechanism, increasing the diffusion depth of Co. The possible implications of cation interdiffusion on the performance of proton-conducting SOFCs are discussed based on the results obtained.

Methane and methanol are promising products for CO2 hydrogenation for carbon capture and utilization concepts. In the search for effective, robust, easy-to-manufacture and stable catalysts, supported metal-based catalysts have proven advantageous. Whereas nickel for methane synthesis and copper for methanol synthesis stand out as efficient and cost-effective catalytically active metals, the best choice of support material is still a matter of ongoing debate. This review discusses the potential of the alkaline earth metal oxide MgO as support material for CO2 hydrogenation catalysts. Due to its basicity, it gives access to bifunctional catalysts as it shows pronounced CO2 adsorption capacity. Whereas carbonate formation seems to be beneficial in CO2 methanation, it may even have an adverse effect in methanol synthesis from CO2.

Spray cooling is a heat transfer technology that has already shown its advantages and limitations. There has been increasing interest from academia and industry in combining this technology with nanofluids as coolants, owing to their potential for heat transfer enhancement. Nevertheless, there is a lack of understanding of the physical mechanism leading to this enhancement with the presence of technical problems that prevent the use of nanofluids in spray cooling applications. In this study, we investigate the effect of water-based TiO2 nanofluids on both spray characteristics and heat transfer using an industrial full-cone pneumatic nozzle. For this purpose, three mass concentrations (0.05 wt.%, 0.1 wt.%, and 0.2 wt.%) were prepared and tested. We monitored the droplet sizes and velocity profiles with a particle dynamics analysis system. Moreover, the temporal temperature decrease of a heated aluminum block from 190 to 65 °C was measured via an infrared camera to calculate the heat tr... [more]

Hybrid organic inorganic perovskites have been considered as a potential candidate for the next generational solar cell due to their outstanding optoelectronic properties and rapid development in recent years. However, the biggest challenge to prevent them from massive commercial use is their long-term stability. Photoemission spectroscopy has been widely used to investigate properties of the perovskites, which provide critical insights to better understand the degradation mechanisms. In this article, we review mainly our photoemission studies on the degradation processes of perovskite thin films and single crystals with different environmental factors, such as gases, water, and light by monitoring changes of chemical composition and electronic structure. These studies on the effects by different environmental parameters are discussed for the understanding of the stability issues and the possible solutions.

The digitalization of a medium voltage network requires huge efforts from distributed system operators and electric utilities. The main reason is attributed to the costs associated with the replacement or introduction of new intelligent electronic devices capable of collecting and digitalizing current and voltage measurements. To this purpose, this paper introduces a new idea of a stand-alone merging unit (SAMU), which features real-time and hardware-in-the-loop technology, completed with accurate voltage and current sensors. Furthermore, the characterization procedure that allows an evaluation of the metrological performance of a complex device, such as a SAMU, is fully described. From the results, it is highlighted that (i) the developed SAMU is capable of performing highly accurate voltage, current, and power measurements; (ii) the characterization procedure is simple and exploitable for all kinds of SAMUs and other synchronized measurement devices.

During an in-situ operation of machines, used for the exploitation of energy raw materials, a damaging impact of the environment on the components of these machines is experienced. The action of degrading factors is mostly shown in the form of a clear synergistic effect. In particular, this effect can be seen during an exploitation of driving elements of scraper conveyors, used as one of the basic machines in the hard coal mining process. In the article, the subject−matter, connected with an operation of sprockets in scraper conveyors, is presented. Special attention is paid to a mutual reaction of the mineral abrasive and the presence of mine water. The main objective of the research work was a determination of the interactive component of the factor causing an abrasive wear−quartz abrasive connected with the associated action and the factor intensifying electrochemical corrosion−water with and without the NaCl salt content. Experimental tests were conducted in the conditions similar... [more]

Significant amounts of produced water, spent drilling fluid, and drill cuttings, which differ in composition and characteristics in each drilling operation, are generated in the oil and gas industry. Moreover, the oil and gas industry faces many technological development challenges to guarantee a safe and clean environment and to meet strict environmental standards in the field of processing and disposal of drilling waste. Due to increasing application of nanomaterials in the oil and gas industry, drilling wastes may also contain nanometer-scale materials. It is therefore necessary to characterize drilling waste in terms of nanomaterial content and to optimize effective methods for their determination, including a key separation step. The purpose of this study is to select the appropriate method of separation and pre-concentration of silver nanoparticles (AgNPs) from drilling wastewater samples and to determine their size distribution along with the state of aggregation using single-pa... [more]

The electrochemical performance of modified natural graphite (MNG) and artificial graphite (AG) was investigated as a function of electrode density ranging from 1.55 to 1.7 g∙cm−3. The best performance was obtained at 1.55 g∙cm−3 and 1.60 g∙cm−3 for the AG and MNG electrodes, respectively. Both AG, at a density of 1.55 g∙cm−3, and MNG, at a density of 1.60 g∙cm−3, showed quite similar performance with regard to cycling stability and coulombic efficiency during cycling at 30 and 45 °C, while the MNG electrodes at a density of 1.60 g∙cm−3 and 1.7 g∙cm−3 showed better rate performance than the AG electrodes at a density of 1.55 g∙cm−3. The superior rate capability of MNG electrodes can be explained by the following effects: first, their spherical morphology and higher electrode density led to enhanced electrical conductivity. Second, for the MNG sample, favorable electrode tortuosity was retained and thus Li+ transport in the electrode pore was not significantly affected, even at high ele... [more]

The building sector is one of the most critical branches of the economy influencing global warming today. Following the European Union’s Construction Products Regulation (CPR), the sustainable use of natural resources in construction is one of the seven basic buildings’ requirements. However, due to the lack of provisions in this regard, construction products are not yet subject to mandatory assessment and verification of the constancy of performance in this area. The paper presents the research results with the participation of 842 respondents who are investors, architects, contractors, and sellers of building materials. The analysis of their perceptions of issues related to the term sustainable development and knowledge of selected documents functioning in construction is presented. The share of people who correctly assigned the term sustainable development to equal treatment of environmental protection, economic development, and social development ranged between 52.5% and 65.7%. Kno... [more]

This paper presents a method to limit the arc energy and hence the hazard risk category value according to IEEE 1584 by using a system of two oppositely connected multi-sectional thyristor branches. A test circuit for testing the effectiveness of a thyristor arc eliminator was designed and constructed. Arc ignition inside electrical switchgear can be a source of danger for technical personnel. The arc energy calculated according to the algorithms in IEEE 1584 can be significantly reduced by using multi-sectional arc eliminator MSAE. For the actual measuring object, the calculation of the hazardous arc flash zone and the hazard category was carried out for the system not equipped with an arc eliminator, and then the same was performed in a system with an arc eliminator. In parallel, the pressure inside the closed polyvinyl chloride (PVC) electrical box enclosure was measured and then compared with the calculated pressures that could occur during an arc fault. It was found that a Multi-S... [more]

The incorporation of phase change materials (PCM) in buildings has the potential to enhance the thermal efficiency of buildings, reduce energy cost, shift peak load, and eventually reduce air pollution and mitigate global warming. However, the initial capital cost of PCM is still high, and thus the establishment of a control strategy has become essential to optimize its use in buildings in an effort to lower investment costs. In this paper, an extensive review has been made with regard to various control strategies applied to PCM-enhanced buildings, such as ON/OFF control, conventional control methods (classical control, optimal, adaptive, and predictive control) and intelligent controls. The advantages and disadvantages of each control strategy are evaluated. The paper further discusses the opportunities and challenges associated with the design of PCM-enhanced buildings in combination with control strategies.

To assist in light weighting of electric vehicles by improving the volumetric and gravimetric energy density and the structural performance of the battery pack, a modelling methodology based on a macro finite element model of a pouch cell has been developed. This model treats the core cell structure as a homogeneous orthotropic honeycomb block with the pouch material being defined as an orthotropic fabric with compressive stress elimination. The model considers five compression and bending load cases simultaneously and allows a level of element discretisation that is computationally efficient and appropriate for inclusion in full vehicle and sub-system simulations. The methodology is scalable in that it can be applied to a range of chemistries, external geometries and internal cell constructions. When considering stacks of cells, the model is predictive for both lateral compression and three-point bend, but further work is required to improve the confined compression response.

In the manufacturing process of lithium-ion batteries, the current organic solvent-based processes will inevitably be replaced with eco-friendly water-based processes. For this purpose, the current organic-soluble binder should be replaced with a water-soluble or water-dispersed binder. In this study, a new polyacrylate latex dispersed in water was successfully applied as a binder of lithium-ion battery cathodes for the first time. One of the biggest advantages of the polyacrylate binder is that it is electrochemically stable at the working voltage of typical cathodes, unlike a conventional water-dispersed styrene-butadiene binder. This implies that the water-dispersed polyacrylate has no limitations for the usage of a cathodic binder. The performance of the polyacrylate binder for lithium iron phosphate cathodes was compared with those of a conventional organic-based polyvinylidene fluoride binder as well as a water-dispersed styrene-butadiene binder. The polyacrylate binder exhibited... [more]

This perspective article describes the application opportunities of carbon nanotube (CNT) films for the energy sector. Up to date progress in this regard is illustrated with representative examples of a wide range of energy management and transformation studies employing CNT ensembles. Firstly, this paper features an overview of how such macroscopic networks from nanocarbon can be produced. Then, the capabilities for their application in specific energy-related scenarios are described. Among the highlighted cases are conductive coatings, charge storage devices, thermal interface materials, and actuators. The selected examples demonstrate how electrical, thermal, radiant, and mechanical energy can be converted from one form to another using such formulations based on CNTs. The article is concluded with a future outlook, which anticipates the next steps which the research community will take to bring these concepts closer to implementation.

The following article presents comprehensive research results for the insulation material based on polystyrene wastes. The presented product has the form of plates to be applied for thermal insulation of external envelopes from the inside. The laboratory tests were focused on the determination of basic technical parameters for this type of materials, i.e., thermal conductivity coefficient, diffusion resistance coefficient, reaction to fire, material sorption, and strength characteristics. For the recycling material, the obtained thermal conductivity value was 0.055 [W/mK]. The diffusion resistance coefficient was 5 [−], and therefore, this component has been qualified to a group of solutions that allow for interstitial condensation in the envelope. For the developed product, in situ tests were carried out on the actual wall system in a historical building. Based on the research, temperature and humidity profiles were obtained in the selected planes of the envelope. The performance of t... [more]

The business model of building-integrated photovoltaics (BIPV) is developing expeditiously and BIPV will soon be recognised as a building envelope material for the entire building skins, among other alternatives such as brick, wood, stone, metals, etc. This paper investigates the effect of climate on the solar radiation components on building skins and BIPV materials in the northern hemisphere. The selected cities are Stavanger in Norway, Bern in Switzerland, Rome in Italy, and Dubai in the UAE. The study showed that for all the studied climates, the average incident radiation on the entire building skins is slightly more than the average incident radiation on the east or west facades, regardless of the orientations of the building facades. Furthermore, the correlation between solar radiation components and different BIPV technologies is discussed in this paper. It is also found that when it comes to the efficiency of different BIPV cells, the impact of the climate on some of the BIPV... [more]

Chemical composition in seawater of marine sediments, as well as the physical properties and chemical composition of soils, influence the phase behavior of natural gas hydrate by disturbing the hydrogen bond network in the water-rich phase before hydrate formation. In this article, some marine sediments samples, collected in National Antarctic Museum in Trieste, were analyzed and properties such as pH, conductivity, salinity, and concentration of main elements of water present in the sediments are reported. The results, obtained by inductively coupled plasma-mass spectrometry (ICP-MS) and ion chromatography (IC) analysis, show that the more abundant cation is sodium and, present in smaller quantities, but not negligible, are calcium, potassium, and magnesium, while the more abundant anion is chloride and sulfate is also appreciable. These results were successively used to determine the thermodynamic parameters and the effect on salinity of water on hydrates’ formation. Then, hydrate fo... [more]

The perovskite nanopowders of lanthanum strontium cobalt ferrite (LSCF) have been synthesized using the alginate mediated ion-exchange process. This perovskite-based material is a promising cathode for intermediate-temperature solid oxide fuel cells (IT-SOFCs) due to its high electrical conductivity, low polarizability, high catalytic activity for oxygen reduction, enhanced chemical stability at an elevated temperature in high oxygen potential environment and high compatibility with the ceria based solid electrolytes. Phase pure LSCF 6428, LSCF 6455, and LSCF 6482 corresponding to La0.6Sr0.4Co0.2Fe0.8O3-δ, La0.6Sr0.4Co0.5Fe0.5O3-δ, and La0.6Sr0.4Co0.8Fe0.2O3-δ, respectively were successfully synthesized. The simultaneous thermal analysis (DSC-TGA) and XRD were used to determine the optimum calcination temperature for the dried ion-exchanged beads. Single phase nanopowders of LSCF (6428, 6455, and 6482) have been successfully prepared at a calcination temperature of 700 °C. The TGA anal... [more]