Adsorption-based processes using metal-organic frameworks (MOFs) are a promising option for carbon dioxide (CO2) capture from flue gases and biogas upgrading to biomethane. Here, the adsorption of CO2, methane (CH4), and nitrogen (N2) on Zn(dcpa) MOF (dcpa (2,6-dichlorophenylacetate)) is reported. The characterization of the MOF by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), and N2 physisorption at 77 K shows that it is stable up to 650 K, and confirms previous observations suggesting framework flexibility upon exposure to guest molecules. The adsorption equilibrium isotherms of the pure components (CO2, CH4, and N2), measured at 273−323 K, and up to 35 bar, are Langmuirian, except for that of CO2 at 273 K, which exhibits a stepwise shape with hysteresis. The latter is accurately interpreted in terms of the osmotic thermodynamic theory, with further refinement by assuming that the free energy difference between the two metastable structures of Zn(dcpa) is a norma... [more]

Carbon capture, utilization, and storage (CCUS) is an attractive technology for the decarbonization of global energy systems. However, its early development stage makes impact assessment difficult. Moreover, rising popularity in carbon pricing necessitates the development of a methodology for deriving carbon abatement costs that are harmonized with the price of carbon. We develop, using a combined bottom-up analysis and top-down learning curve approach, a levelized cost of carbon abatement (LCCA) model for assessing the true cost of emissions mitigation in CCUS technology under carbon pricing mechanisms. We demonstrate our methodology by adapting three policy scenarios in Canada to explore how the implementation of CO2-to-diesel technologies could economically decarbonize Canada’s transportation sector. With continued policy development, Canada can avoid 932 MtCO2eq by 2075 at an LCCA of CA$209/tCO2eq. Technological learning, low emission hydroelectricity generation, and cost-effective... [more]

The transport sector powered by internal combustion engines (ICE) requires novel approaches to achieve near-zero CO2 emissions. In this direction, using CO2 capture and storage (CCS) systems onboard could be a good option. However, CO2 capture in mobile sources is currently challenging due to the operational and space requirements to install a CCS system onboard. This paper presents a systematic review of the CO2 capture in ICE driven transport to know the methods, techniques, and results of the different studies published so far. Subsequently, a case study of a CCS system working in an ICE is presented, where the energy and space needs are evaluated. The review reveals that the most suitable technique for CO2 capture is temperature swing adsorption (TSA). Moreover, the sorbents with better properties for this task are PPN-6-CH2-DETA and MOF-74-Mg. Finally, it shows that it is necessary to supply the energy demand of the CCS system and the option is to take advantage of the waste heat... [more]

The aim of this paper is to analyze the factors affecting hydrogen and Carbon Capture and Storage Technologies (“CCS”) policies, taking into consideration Fossil Fuel Consumption, Oil Reserves, the Debt/GDP Ratio, the Trilemma Index and other variables with respect to OECD countries. STATA 17 was used for the analysis. The results confirm the hypothesis that countries with high fossil fuel consumption and oil reserves are investing in blue hydrogen and CCS towards a “zero-carbon-emission” perspective. Moreover, countries with a good Debt/GDP ratio act most favorably to green policies by raising their Public Debt, because Foreign Direct Investments are negatively correlated with those kinds of policies. Future research should exploit Green Finance policy decision criteria on green and blue hydrogen.

At present, mitigating carbon emissions from energy production and industrial processes is more relevant than ever to limit climate change. The widespread implementation of carbon capture technologies requires the development of cost-effective and selective adsorbents with high CO2 capture capacity and low thermal recovery. Coal fly ash has been extensively studied as a raw material for the synthesis of low-cost zeolite-like adsorbents for CO2 capture. Laboratory tests for CO2 adsorption onto coal fly ash zeolites (CFAZ) reveal promising results, but detailed computational studies are required to clarify the applicability of these materials as CO2 adsorbents on a pilot and industrial scale. The present study provides results for the validation of a simulation model for the design of adsorption columns for CO2 capture on CFAZ based on the experimental equilibrium and dynamic adsorption on a laboratory scale. The simulations were performed using ProSim DAC dynamic adsorption software to... [more]

Carbon capture and storage (CCS) is a key strategy to reduce carbon dioxide (CO2) emissions from industrial point sources. Gas absorption into aqueous amine solutions is an immediate technology for carbon capture that has been tested in many demonstration plants. One concern of using the amine-based carbon capture process is the environmental impacts and health risk caused by emissions of gaseous amines from the process to the atmosphere. This work applied the knowledge of air dispersion modelling to map out the atmospheric dispersion and resulting ground surface level concentration of gaseous amine, namely Monoethanolamine (MEA), from a coal-fired power plant (with a carbon capture unit) and in surrounding areas, in case of an accidental leaking of amine from the CCS system to the atmosphere. The chosen study area was centered on a coal-fired power plant in the province of Saskatchewan, Canada. The Environmental Protection (EPA) approved air pollution model (CALPUFF), together with me... [more]

The potential of bio-electro-jet fuel (BEJF) production with integration into an existing biomass-based combined heat and power (CHP) facility was investigated. The BEJF is produced via Fischer−Tropsch (F−T) synthesis from biogenic CO2 and H2 obtained by water electrolysis. Techno-economic (TEA)- and life. cycle (LCA)- assessments were performed to evaluate the production cost and environmental impact of the BEJF production route. The BEJF mass fraction reached 40% of the total F−T crude produced. A reduction of 78% in heating demands was achieved through energy integration, leading to an increase in the thermal efficiency by up to 39%, based on the F−T crude. The total production cost of BEJF was in the range of EUR 1.6−2.5/liter (EUR 169−250/MWh). The GWP of the BEJF was estimated to be 19 g CO2-eq per MJ BEJF. The reduction potential in GWP in contrast to the fossil jet baseline fuel varied from 44% to more than 86%. The findings of this study underline the potential of BEJF as a re... [more]

The International Maritime Organisation (IMO) calls for the maritime industry to restrict its CO2 emissions by −40% (IMO2030) and −70% (IMO2050). This paper answered the following research question: “Which technical, economic and emissions-related conditions predominantly determine the feasibility of a conceptual supply chain of liquid CO2 that is captured from the exhaust gases of LNG powered offshore vessels?” The captured CO2 is transported to land where it is utilized by a final customer. The study followed a systems engineering approach. Problem definition was followed by a requirements analysis (technology, emissions, economy and operations), design with scenarios and a case study with realistic vessel deployment, modeling and evaluation. All designs have technical uncertainties and financial risks, but the sale of captured CO2 could be a crucial advantage of the proposed concept over other concepts. The main conclusion is that emission and financial targets (payback time) can be... [more]

Reduction of greenhouse gases emissions is a key challenge for the power generation industry, requiring the implementation of new designs and methods of electricity generation. This article presents a design solution for a novel thermodynamic cycle with two new devices—namely, a wet combustion chamber and a spray-ejector condenser. In the proposed cycle, high temperature occurs in the combustion chamber because of fuel combustion by pure oxygen. As a consequence of the chemical reaction and open water cooling, a mixture of H2O and CO2 is produced. The resulting working medium expands in one turbine that combines the advantages of gas turbines (high turbine inlet temperatures) and steam turbines (full expansion to vacuum). Moreover, the main purpose of the spray-ejector condenser is the simultaneous condensation of water vapour and compression of CO2 from condensing pressure to about 1 bar. The efficiency of the proposed cycle has been estimated at 37.78%. COM-GAS software has been used... [more]

In this study, new composite materials of montmorillonite, biochar, or aerosil, containing metal−organic frameworks (MOF) were synthesized in situ. Overall, three different MOFs—CuBTC, UTSA-16, and UiO-66-BTEC—were used. Obtained adsorbents were characterized using powder X-ray diffraction, thermogravimetric analysis, nitrogen adsorption porosimetry, scanning electron microscopy, energy-dispersive X-ray spectroscopy, and Fourier transform infrared spectrophotometry. Additionally, the content of metallic and nonmetallic elements was determined to investigate the crystalline structure, surface morphology, thermal stability of the obtained MOF-composites, etc. Cyclic CO2 adsorption analysis was performed using the thermogravimetric approach, modeling adsorption from flue gasses. In our study, the addition of aerosil to CuBTC (CuBTC-A-15) enhanced the sorbed CO2 amount by 90.2% and the addition of biochar (CuBTC-BC-5) increased adsorbed the CO2 amount by 75.5% in comparison to pristine CuB... [more]

Carbon capture, utilization, and storage (CCUS) refers to technologies that capture carbon dioxide (CO2) emissions from sources such as power plants, industrial facilities, and transportation, and either store it underground or use it for beneficial purposes. CCUS can play a role in reducing greenhouse gas emissions and mitigating climate change, as CO2 is a major contributor to global warming. In the Baltic Sea region countries (BSR), patent searches from 2000 to 2020 reveal that CCUS technologies are focused on CO2 storage, monitoring, utilization, and transport. However, the adoption and deployment of these technologies has been slow due to a variety of factors, including a lack of government action on climate change, public skepticism, increasing costs, and advances in other options such as renewables and shale gas. Overall, CCUS has the potential to significantly reduce CO2 emissions and contribute to climate change mitigation efforts, but more work is needed to overcome the barri... [more]

Liquified natural gas (LNG) is a clean primary energy source that is growing in popularity due to the distance between natural gas (NG)-producing countries and importing countries. The large amount of cold energy stored in LNG presents an opportunity for sustainable technologies to recover and utilize this energy. This can enhance the energy efficiency of LNG regasification terminals and the economic viability of the LNG supply chain. The energy stored in LNG in the form of low temperatures is referred to as cold energy. When LNG is regasified, or converted back into its gaseous form, this cold energy is released. This process involves heating the LNG, which causes it to vaporize and release its stored energy. The current state-of-the-art techniques for LNG cold energy utilization, including power generation, air separation, traditional desalination, and cryogenics carbon dioxide (CO2) capture are discussed in this review. While most of the current LNG cold energy utilization systems a... [more]

It is widely accepted that carbon capture and utilization technologies are an effective way of lowering the amount of greenhouse gases released into the atmosphere. A bibliometric analysis is presented in this article to investigate the development of carbon capture and utilization. The study was conducted to identify the trends in publishing, dominant contributing authors, institutions, countries, potential publishing sources, and the most cited publications in this research area. A total of 4204 articles published between 2007 and 2021 were analyzed, covering 13,272 authors, 727 journals, and 88 countries. The findings indicate that the most productive and influential authors have British and American affiliations. The United States, the United Kingdom, and China have conducted most studies on the aforementioned topic. Imperial College London, United Kingdom, has the highest number of publications in this field of research. Furthermore, the collaborative analysis was developed by cre... [more]

A methanol island, powered by solar or wind energy, indirectly captures atmospheric CO2 through the ocean and combines it with hydrogen gas to produce a synthetic fuel. The island components include a carbon dioxide extractor, a desalinator, an electrolyzer, and a carbon dioxide-hydrogen reactor to complete this process. In this study, the optimal locations to place such a device in the Mediterranean Sea were determined, based on three main constraints: power availability, environmental risk, and methanol production capability. The island was numerically simulated with a purpose built python package pyseafuel. Data from 20 years of ocean and atmospheric simulation data were used to “force” the simulated methanol island. The optimal locations were found to strongly depend on the power availability constraint, with most optimal locations providing the most solar and/or wind power, due to the limited effect the ocean surface variability had on the power requirements of methanol island. Wi... [more]

Energy Intensive Industries (EII) are high users of energy and some of these facilities are extremely dependent on Natural Gas for processing heat production. In European countries, where Natural Gas is mostly imported from external producers, the increase in international Natural Gas prices is making it difficult for some industries to deliver the required financial results. Therefore, they are facing complex challenges that could cause their delocalization in regions with lower energy costs. European countries lack on-site Natural Gas resources and the plans to reduce greenhouse gas emissions in the industrial sector make it necessary to find an alternative. Many different processes cannot be electrified, and in these cases, synthetic methane is one of the solutions and also represents an opportunity to reduce external energy supply dependency. This study analyzes the current development of power-to-gas technological solutions that could be implemented in large industrial consumers t... [more]

By converting bicarbonates via Chlorella vulgaris photosynthesis, one can obtain valuable biofuel products and find a route toward carbon-derived fossil fuel conversion into renewable carbon. In this research, experiments were carried out in the PhotoBioCREC prototype under controlled radiation and high mixing conditions. Sodium bicarbonate (NaHCO3) was supplied as the inorganic carbon-containing species, at different concentrations, in the 18 to 60 mM range. Both the NaHCO3 concentrations and the organic carbon concentrations were quantified periodically during microalgae culture, with the pH being readjusted every day to the 7.00 level. It was found that sodium bicarbonate was converted with a selectivity up to 33.0% ± 2.0 by Chlorella vulgaris. It was also observed that the reaction rate constant for inorganic carbon conversion was 0.26 ± 0.09 day−1, while the maximum reaction rate constant for organic carbon formation was achieved with a 28 mM NaHCO3 concentration and displayed a 1... [more]

Tertiary amines have been used as alternative absorbents for traditional primary and secondary amines in the process of carbon capture. However, the carbon dioxide (CO2) absorption rates in these kinds of amine are relatively slow, which implies greater investment and construction costs and limits the large-scale application of carbon capture. Carbonic anhydrase (CA) is considered to be an ideal homogeneous catalyst for accelerating the rate of CO2 into aqueous amine solution. In this work, CO2 absorption combining CA with two single aqueous tertiary amines, namely triethanolamine (TEA) and 2-(diethylamino)ethanol (DEEA), was studied by use of the stopped-flow apparatus over temperature ranging from 293 to 313 K. The concentrations of selected aqueous amine solution and CA used in the experiment were ranging among 0.1−0.5 kmol/m3 and 0−50 g/m3 , respectively. Compared to the solution without the addition of CA, the pseudo first-order reaction rate in the presence of CA (k0,withCA) is s... [more]

In this work, the Life Cycle Assessment (LCA) methodology is used to examine the implications of CO2 capture from a natural gas combined cycle power plant with post-combustion carbon capture (NGCC-CCS) in Iraq, taking into account two different design scenarios. In the first scenario (retrofit), the carbon capture unit is considered as an end pipe technology that can be linked to an existing power plant. The second scenario considers a grassroots design, in which a new power plant equipped with a carbon capture unit needs to be constructed. The LCA is carried out based on different impact assessment (LCIA) methodologies of ReCipe 2016 Midpoint (H), TRACI 2.1, and IMPACT 2002+ to investigate whether the chosen LCIA method influences the LCA scenario analysis for decision support in process development. The results of three impact categories applied to both scenarios reveal a 28% reduction in Global Warming Potentials (GWPs) and a 14% and 17% increase in the Particulate Matter Formation... [more]

Plastic products are widely used due to their superior performance, but there are still limitations in the current methods and technologies for recycling and processing of waste plastics, resulting in a huge wasting of resources and environmental pollution. The element composition of waste plastics determines its great gasification potential. In this paper, three different waste plastic gasification processes are designed in a process simulator based on the conventional Integrated Gasification Combined Cycle (IGCC) system to achieve waste conversion and utilization as well as carbon capture. Design 1 is based on the cryogenic air separation (CAS) process to obtain oxygen, which is sent to the gasifier together with steam and pretreated waste plastics. The synthesis gas is purified and synthesized into methanol, and the residual gas is passed to the gas turbine and steam turbine to achieve multiple production of heat, electricity, and methanol. Design 2 uses a Vacuum Pressure Swing Adso... [more]

Under the guidance of China’s goal of achieving carbon neutrality by 2060, the petrochemical industry is increasingly adopting energy-saving and emission-reduction technologies. To realize the low carbon operation of the LNG (liquefied natural gas) receiving terminal, an innovative SCV (submerged combustion vaporizer) flue gas carbon capture system using LNG cold energy was established, and the system also combined with an ORC (organic Rankine cycle). HYSYS software was used to simulate the process of the SCV flue gas carbon capture system and the LNG regasification system. The simulation results showed that the proposed system has low carbon emission and low energy consumption performance. Moreover, the sensitivity analysis of the evaporation pressure of working fluids, CO2 capture pressure, and CO2 capture temperature was carried out. The key parameters were optimized by HYSYS software to achieve the optimal operation cost of the system. When the evaporation pressure of working fluid... [more]

Utilization of bioenergy with carbon capture can realize carbon-negative syngas production. The quadruple fluidized bed gasifier (QFBG) integrates a chemical looping oxygen generation process and a dual fluidized bed gasifier with limestone as bed material. It is one promising device that can convert biomass to H2-rich syngas whilst capturing CO2 with little energy penalty. However, experimental or numerical simulation of QFBG is rarely reported on due to its complex structure, hindering the further commercialization and deployment of QFBG. In this work, a new computational fluid dynamics (CFD) solver is proposed to predict the complex physicochemical processes in QFBG based on the multi-phase particle in cell (MPPIC) methodology with the assistance of the open source software, OpenFOAM. The solver is first validated against experimental data in terms of hydrodynamics and reaction kinetics. Then, the solver is used to investigate the QFBG property. It is found that the QFBG can operate... [more]

This work attempts to address the quest of removing carbon dioxide from flue gas streams to help preserve the environment. It is based on a model that is able to describe the solid-liquid-vapour and solid-vapour phase equilibria for the ternary system of N2-O2-CO2 at pressures from 5 to 130 bar and over a wide range of temperature (140 to 220 K). Furthermore, a corresponding state-of-the art solid-vapor (SV) CO2 capture/separation unit is developed and introduced in this work. The SV unit was modeled using the Aspen Custom Modeler software by implementing the thermodynamic model developed before. It was then simulated using the Aspen Plus simulator; its performance was studied and analyzed. Moreover, the performance of the unit was optimized and compared to the most conventional corresponding technology used by the industry (i.e., amine-scrubbing). Results proved that for the same output clean gas composition, which contains only 0.3% CO2, the developed state-of-the-art SV unit consume... [more]

The climate change impact associated with greenhouse gas emissions is a major global concern. This work investigates perovskite compounds for oxygen separation from air to supply oxygen to oxyfuel energy systems to abate these significant environmental impacts. The perovskites studied were Me0.5Sr0.5Co0.8Cu0.2O3−δ (MeSCC) where the A-site substitution was carried out by four different cations (Me = Ca, Mg, Sr, or Ba). SEM analysis showed the formation of small particle (<1 µm) aggregates with varying morphological features. XRD analysis confirmed that all compounds were perovskites with a hexagonal phase. Under reduction and oxidation reactions (redox), Ba and Ca substitutions resulted in the highest and lowest oxygen release, respectively. In terms of real application for oxygen separation from air, Ba substitution as BaSCC proved to be preferable due to short temperature cycles for the uptake and release of oxygen of 134 °C, contrary to Ca substitution with long and undesirable te... [more]

Example Aspen Plus chemical process simulations used in the book Exergy Tables: A Comprehensive Set of Exergy Values to Streamline Energy Efficiency Analysis, by Lingyan Deng, Thomas A. Adams II, and Truls Gundersen (McGraw-Hill Education, 2023). The examples are:

1. Medium-pressure steam generation using a natural-gas powered boiler
2. Medium-pressure steam generation using a natural-gas powered boiler with an economizer
3. Medium-pressure steam generation using an off-gas powered boiler
4. Postcombustion CO2 capture using diglycolamine (DGA) with CCS

Note, stream conditions may vary slightly from those in the book when simulated with different versions of the software.

Files are Aspen Plus v12.1, but should be openable on any version 12.1 or later.

Carbon capture, utilization, and storage (CCUS) is a combination of technologies capable of achieving large-scale reductions in carbon dioxide emissions across a variety of industries. Its application to date has however been mostly limited to the power sector, despite emissions from other industrial sectors accounting for around 30% of global anthropogenic CO2 emissions. This paper explores the challenges of and requirements for implementing CCUS in non-power industrial sectors in general, and in the steel sector in particular, to identify drivers for the technology’s commercialization. To do so we first conducted a comprehensive literature review of business models of existing large-scale CCUS projects. We then collected primary qualitative data through a survey questionnaire and semi-structured interviews with global CCUS experts from industry, academia, government, and consultancies. Our results reveal that the revenue model is the most critical element to building successful CCUS... [more]