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Showing records 3495 to 3519 of 4494. [First] Page: 1 137 138 139 140 141 142 143 144 145 Last
Analysis of the Thermal Performance of Isothermal Composite Heat Accumulators Containing Organic Phase-Change Material
Michał Musiał, Lech Lichołai, Agnieszka Pękala
February 22, 2023 (v1)
Subject: Materials
Keywords: construction composite, energy-efficient construction, latent heat, short-term heat storage
This paper presents the results of material tests, experimental tests and statistical analysis of the thermal performance of three types of heat accumulators containing an organic phase-change material and two materials of a higher thermal conductivity: a copper mesh and porous coke recyclate. The aim of the research was to empirically and statistically compare the increase in the PCM heat distribution through a copper conductor and coke recyclate. The research was conducted in accordance with an incomplete central compositional experimental design and using the Statistica software. The studies of the structure and chemical composition of the coke recyclate used and the empirical testing of the finished heat accumulators confirmed an improvement in the distribution and storage of heat by the accumulator with the phase-change material and coke recyclate compared to the pure phase-change material and copper-conductor accumulators, as the holding time of a temperature of 20 °C was extende... [more]
Pore-Scale Investigation of Low-Salinity Nanofluids on Wetting Properties of Oil Carbonate Reservoir Rocks Studied by X-ray Micro-Tomography
Anastasia Ivanova, Azhar Kuandykova, Alexander Rodionov, Andrey Morkovkin, Alexander Burukhin, Alexey Cheremisin
February 22, 2023 (v1)
Subject: Materials
Keywords: carbonate reservoirs, high salinity, high temperature, low-salinity flooding, nanofluids, surfactants, wettability alteration, X-ray microtomography
Low-salinity surfactant nanofluids have recently shown promising results in the wettability alteration of reservoir rocks from oil-wet state towards more water-wet state. However, the investigation of pore-level interactions of nanofluids injection in real oil carbonate rocks at reservoir conditions, which determines the overall fluid dynamics, is lacking. Therefore, in this work, we studied the effect of nanoparticles augmented low-salinity surfactant flooding on the wettability alteration of hydrophobic carbonate rocks with harsh reservoir conditions via X-ray micro-tomography. The designed experiment scheme involved core flooding with an X-ray transparent core-holder developed for studying the flow properties of fluids at the micro level (pore scale). The wettability was quantified by measuring the differences in contact angles after the injection of low salinity, low-salinity surfactant, and low-salinity surfactant nanofluid. The findings illustrate that surfactant flooding with si... [more]
Improved Electrical and Thermal Conductivities of Graphene−Carbon Nanotube Composite Film as an Advanced Thermal Interface Material
Youcheng Jiang, Shangzhi Song, Mengjuan Mi, Lixuan Yu, Lisha Xu, Puqing Jiang, Yilin Wang
February 22, 2023 (v1)
Subject: Materials
Keywords: carbon nanotube, composite film, reduced graphene oxide, thermal interface materials
Thermal management has become a crucial issue for the rapid development of electronic devices, and thermal interface materials (TIMs) play an important role in improving heat dissipation. Recently, carbon−based TIMs, including graphene, reduced graphene oxide, and carbon nanotubes (CNTs) with high thermal conductivity, have attracted great attention. In this work, we provide graphene−carbon nanotube composite films with improved electrical and thermal conductivities. The composite films were prepared from mixed graphene oxide (GO) and CNT solutions and then were thermally reduced at a temperature greater than 2000 K to form a reduced graphene oxide (rGO)/CNT composite film. The added CNTs connect adjacent graphene layers, increase the interlayer interaction, and block the interlayer slipping of graphene layers, thereby improving the electrical conductivity, through−plane thermal conductivity, and mechanical properties of the rGO/CNT composite film at an appropriate CNT concentration. T... [more]
Biomass Origin Waste as Activators of the Polyurethane Foaming Process
Patrycja Zakrzewska, Beata Zygmunt-Kowalska, Monika Kuźnia, Artur Szajding, Tadeusz Telejko, Małgorzata Wilk
February 22, 2023 (v1)
Subject: Materials
Keywords: biomass ash, biomass waste, foaming process, rigid polyurethane foam
Rigid polyurethane foams (RPUFs) are characterized by their excellent viable properties; thus, these materials can be successfully used as thermal insulation materials. The main problem, the solution of which is partly indicated in this paper, is that the products for the synthesis of RPUFs are produced from petrochemicals. Due to this, the use of natural fillers in the form of waste biomass is introduced for the synthesis of RPUFs. The biodegradable biomass waste used in the RPUF production process plays multiple roles: it becomes an activator of the RPUF foaming process, improves selected properties of RPUF materials and reduces the production costs of insulating materials. The paper presents the results of the foaming process with the use of six different fillers: sunflower husk (SH), rice husk (RH), buckwheat husk (BH), sunflower husk ash (SHA), rice husk ash (RHA) and buckwheat husk ash (BHA). In all cases, composites of rigid polyurethane foam with 10 wt.% of filler were produced... [more]
A Hybrid Analytical Model for the Electromagnetic Analysis of Surface-Mounted Permanent-Magnet Machines Considering Stator Saturation
Wenbiao Lu, Jie Zhu, Youtong Fang, Pierre-Daniel Pfister
February 22, 2023 (v1)
Subject: Materials
Keywords: analytical model, hybrid model, magnetic saturation, permanent-magnet machine, reluctance network
This article presents the process of building a hybrid analytical model (HAM) for surface-mounted permanent-magnet machines. The HAM couples a reluctance network (RN) model in the stator region with a magnetic scalar potential analytical model in the air gap and magnets regions. This hybrid model can deal with the slotting effect with straight teeth, and takes magnetic saturation into account in the stator iron material using the RN model. It is calculated under open-circuit and loaded conditions. The magnetic flux density, flux linkage, back electromotive force (EMF), and torque of the machines are also calculated. This hybrid model is compared with the subdomain method. It is also compared with the finite element method (FEM) both in terms of the size of the matrix that needs to be calculated and in terms of the torque error. We analyzed this method for two surface-mounted permanent-magnet machines, one with a symmetry factor of four and another with a symmetry factor of three. In bo... [more]
Noise Spectroscopy: A Tool to Understand the Physics of Solar Cells
Giovanni Landi, Sergio Pagano, Heinz Christoph Neitzert, Costantino Mauro, Carlo Barone
February 22, 2023 (v1)
Subject: Materials
Keywords: electric noise processes, electron–hole recombination, electron–phonon interaction, photovoltaic cells, solar cell reliability
Noise spectroscopy is essentially focused on the investigation of electric fluctuations produced by physical mechanisms intrinsic to conductor materials. Very complex electrical transport phenomena can be interpreted through the study of the fluctuation properties, which provide interesting information both from the point of view of basic research and of applications. In this respect, low-frequency electric noise analysis was proposed more than twenty years ago to determine the quality of solar cells and photovoltaic modules, and, more recently, for the reliability estimation of heterojunction solar cells. This spectroscopic tool is able to unravel specific aspects related to radiation damage. Moreover, it can be used for a detailed temperature-dependent electrical characterization of the charge carrier capture/emission and recombination kinetics. This gives the possibility to directly evaluate the system health state. Real-time monitoring of the intrinsic noise response is also very i... [more]
Review on Test Benches Studying Sliding Electrical Contact and Synthesis of Experimental Results
Théo Kziazyk, Eric Gavignet, Pierre-Henri Cornuault, Philippe Baucour, Didier Chamagne
February 22, 2023 (v1)
Subject: Materials
Keywords: contact material, electric wear, pantograph–catenary interaction, sliding electrical contact, slip ring interaction
Sliding electrical contacts are commonly used with a slip ring to collect the current in moving system generators, alternators, or electrical motors. These contacts are also found in electrical transports without batteries, which are mostly supplied by means of a pantograph−catenary system. These systems are fraught with numerous issues. Among them, it is worth highlighting wear and heating, which lead to failures and pre-worn materials. Moreover, with the increase in speed and improvements in technologies and materials, new problems emerge. This is the case with the substitution of the classic copper strip with graphite or copper-impregnated graphite. Multiple works that studied sliding electrical contacts have been achieved recently, some by trying to create a model of the system based on experimental results, and others only based on experimental works and measurements. This paper aims to review articles from this last category by making a synthesis of different test benches used an... [more]
An Environmental and Technical Evaluation of Vacuum-Based Thin Film Technologies: Lithium Niobate Coated Cathode Active Material for Use in All-Solid-State Battery Cells
Deidre Wolff, Svenja Weber, Tobias Graumann, Stefan Zebrowski, Nils Mainusch, Nikolas Dilger, Felipe Cerdas, Sabrina Zellmer
February 22, 2023 (v1)
Subject: Materials
Keywords: All-Solid-State Batteries, Atomic Layer Deposition, Cathode Active Material coating, environmental assessment, lithium niobate, NCM811, Physical Vapor Deposition, prospective assessment, technical assessment
Research on All-Solid-State Batteries (ASSBs) currently focuses on the development of innovative materials, cell concepts, and production processes, aiming to achieve higher energy densities compared to other battery technologies. For example, it is been demonstrated that coating the Cathode Active Material (CAM) can enhance the rate capability and cycle life and reduce the interfacial resistance of an ASSB cell. For this reason, various techniques for coating the CAM have been explored, along with a variety of coating materials, including lithium niobate. Since ASSBs are still an emerging technology, more research is needed to determine how their production processes will perform from a technical, economic, and environmental perspective. In this paper, two innovative techniques for producing lithium niobate-coated CAMs are presented and evaluated. Particularly, Atomic Layer Deposition (ALD) and Physical Vapor Deposition (PVD) techniques for coating NCM811 particles are investigated. T... [more]
Improved Performance of Latent Heat Energy Storage Systems in Response to Utilization of High Thermal Conductivity Fins
Wenwen Ye, Dourna Jamshideasli, Jay M. Khodadadi
February 22, 2023 (v1)
Subject: Materials
Keywords: extended surfaces, fins, fusible materials, melting, phase change materials, phase transformation, solidification, thermal conductivity enhancers
Analytical, computational and experimental investigations directed at improving the performance of latent heat thermal energy storage systems that utilize high thermal conductivity fins in direct contact with phase change materials are reviewed. Researchers have focused on waste heat recovery, thermal management of buildings/computing platforms/photovoltaics/satellites and energy storage for solar thermal applications. Aluminum (including various alloys), brass, bronze, copper, PVC, stainless steel and steel were the adopted fin materials. Capric-palmitic acid, chloride mixtures, dodecanoic acid, erythritol, fluorides, lauric acid, naphthalene, nitrite and nitrate mixtures, paraffins, potassium nitrate, salt hydrates, sodium hydrate, stearic acid, sulfur, water and xylitol have been the adopted fusible materials (melting or fusion temperature Tm range of −129.6 to 767 °C). Melting and solidification processes subject to different heat exchange operating conditions were investigated. St... [more]
Insights on the Effects of Magnetic Forces on the Efficiency of Vibration Energy Harvesting Absorbers in Controlling Dynamical Systems
Tyler Alvis, Mikhail Mesh, Abdessattar Abdelkefi
February 22, 2023 (v1)
Subject: Materials
Keywords: magnetic force, nonlinear characterization, nonlinear dynamics, vibration energy harvesting, vibration mitigation
This study investigates the effects of magnetic constraints on a piezoelectric energy harvesting absorber while simultaneously controlling a primary structure and harnessing energy. An accurate forcing representation of the magnetic force is investigated and developed. A reduced-order model is derived using the Euler−Lagrange principle, and the impact of the magnetic force is evaluated on the absorber’s static position and coupled natural frequency of the energy harvesting absorber and the coupled primary absorber system. The results show that attractive magnet configurations cannot improve the system substantially before pull-in occurs. A rigorous eigenvalue problem analysis is performed on the absorber’s substrate thickness and tip mass to effectively design an energy harvesting absorber for multiple initial gap sizes for the repulsive configurations. Then, the effects of the forcing amplitude on the primary structure absorber are studied and characterized by determining an effective... [more]
Evolution of Equipment in Electromobility and Autonomous Driving Regarding Safety Issues
Christodoulos Katis, Athanasios Karlis
February 22, 2023 (v1)
Subject: Materials
Keywords: autonomous driving, electric vehicle apparatus, electromobility, risks, safety issues
Over the years, an increase in the traffic of electric and hybrid electric vehicles and vehicles with hydrogen cells is being observed, while at the same time, self-driving cars are appearing as a modern trend in transportation. As the years pass, their equipment will evolve. So, considering the progress in vehicle equipment over the years, additional technological innovations and applications should be proposed in the near future. Having that in mind, an analytical review of the progress of equipment in electromobility and autonomous driving is performed in this paper. The outcomes of this review comprise hints for additional complementary technological innovations, applications, and operating constraints along with proposals for materials, suggestions and tips for the future. The aforementioned hints and tips aim to help in securing proper operation of each vehicle part and charging equipment in the future, and make driving safer in the future. Finally, this review paper concludes wi... [more]
A Numerical Analysis of the Hybrid Nanofluid (Ag+TiO2+Water) Flow in the Presence of Heat and Radiation Fluxes
Asad Ullah, Nahid Fatima, Khalid Abdulkhaliq M. Alharbi, Samia Elattar, Ikramullah, Waris Khan
February 22, 2023 (v1)
Subject: Materials
Keywords: bv4c, energy loss, heat transfer, magnetic field, nanoparticles, symmetric flow, thermal hybrid nanofluid
The hydrothermal characteristics of (Ag+TiO2+H2O) hybrid nanofluid three dimensional flow between two vertical plates, in which the right permeable plate stretches as well as rotates, are investigated by employing varying magnetic, heat and radiation fluxes. The motion is governed by coupled PDEs (nonlinear) obeying suitable boundary conditions. The PDEs coupled system is transformed to a coupled set of nonlinear ODEs employing appropriate similarity transformation relations. The resultant equations are numerically solved through the bv4c solver. The impact of the changing strength of associated parameters on the flow is investigated graphically and through tables. It has been found that the velocity gradient and velocity initially increase and then decrease with increasing Grashof number values in both the suction and injection cases. The enhancing magnetic field first augments and then lowers the velocity gradient in the presence of radiation source of maximum strength. The increasin... [more]
Preparation of Biomass Hydrochar and Application Analysis of Blast Furnace Injection
Guangwei Wang, Renguo Li, Jiayun Dan, Xiang Yuan, Jiugang Shao, Jiawen Liu, Kun Xu, Tao Li, Xiaojun Ning, Chuan Wang
February 22, 2023 (v1)
Subject: Materials
Keywords: Biomass, blast furnace injection, CO2 emission reduction, hydrochar, hydrothermal carbonization
Hydrothermal carbonization (HTC) technology was used to carbonize and improve biomass raw material to obtain hydrochar. The effects of HTC temperature and holding time on the yield, composition, structure, combustion behavior, and safety of hydrochar were studied systematically. In addition, the results show that with the increase in HTC temperature and the prolongation of holding time, the yield of hydrochar gradually reduces, the fixed carbon content of hydrochar increases, the volatile content decreases, and a large number of ash and alkali metals enter the liquid phase and are removed. Further, the analysis of the combustion properties and the structure of hydrochar can be observed in that, as the HTC process promotes the occurrence of polymerization reactions, the specific surface area gradually reduces, the degree of carbon ordering increases, and the combustion curve moves toward the high-temperature zone and gradually approaches bituminous coal. Since biomass hydrochar has the... [more]
Free-Base Porphyrin Aggregates Combined with Nickel Phosphite for Enhanced Alkaline Hydrogen Evolution
Bogdan-Ovidiu Taranu, Eugenia Fagadar-Cosma, Paula Sfirloaga, Maria Poienar
February 22, 2023 (v1)
Subject: Materials
Keywords: electrocatalysis, modified electrode, nickel phosphite, porphyrin, water splitting
In response to the escalating global energy requests and the need to address them in a sustainable manner, researchers have identified hydrogen as an energy vector that provides a practical way to store and use energy from renewable sources. To make a step forward, the electrocatalytic properties for the hydrogen evolution reaction in an alkaline medium of graphite electrodes modified with combinations of nickel phosphite and free-base porphyrins were investigated voltammetrically. The sample obtained by combining the respective phosphite with 5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin exhibited the highest catalytic activity, surpassing that observed for the specimens manufactured using the individual catalysts and thus providing enhanced water-splitting performance. The best electrode displayed an overpotential of 0.43 V (at i = −10 mA/cm2) and a Tafel slope of 0.14 V/dec. Since the catalytic activity of the compositions containing the metal salt and the porphyrins has not been pr... [more]
Experimental Analysis of Hysteresis in the Motion of a Two-Input Piezoelectric Bimorph Actuator
Dariusz Grzybek
February 22, 2023 (v1)
Subject: Materials
Keywords: hysteresis loop, macro fiber composite, piezoelectric material, single-input actuator, two-input actuator
This article presents a comparison of hysteresis courses in the motion of a two-input actuator (bimorph) and hysteresis in the motion of a single-input actuator (unimorph). The comparison was based on the results of laboratory and numerical experiments, the subject of which was an actuator built of three layers: a carrier layer from a glass-reinforced epoxy laminate and two piezoelectric layers from Macro Fiber Composite. The layers were glued together, and electrodes in the Macro Fiber Composite layers were connected to a system that included an analogue/digital board and a voltage amplifier. The main purpose of this research was to compare the characteristic points of the hysteresis curves of the displacement of the bimorph actuator with the characteristic points of the hysteresis curves of the unimorph actuator. Based on the research results, it was noticed that, in the bimorph, the maximum hysteresis and mean hysteresis values increase faster than the maximum displacement of a beam... [more]
Experimental and Theoretical Investigation of Single-Slope Passive Solar Still with Phase-Change Materials
Ewelina Radomska, Łukasz Mika, Karol Sztekler, Wojciech Kalawa, Łukasz Lis, Kinga Pielichowska, Magdalena Szumera, Paweł Rutkowski
February 22, 2023 (v1)
Subject: Materials
Keywords: desalination, Distillation, paraffin wax, phase-change materials, solar still
Many attempts are made worldwide to create cheap, efficient, and eco-friendly water desalination systems. Passive solar stills (SS) are considered to be such. This paper presents the results of the experimental and theoretical investigation of the effects of using phase-change materials (PCM) on the performance of SS. The experiments were conducted for two paraffin waxes, as PCM and 1.0, 2.5, and 5.0 kg of PCM were used. The results of the experimental studies were used to validate a mathematical model, which was based on the energy balance ordinary differential equations. The equations were solved numerically since the approximate solutions obtained numerically are sufficient and relatively simple as compared to the exact analytical solutions. A theoretical analysis was then carried out and a novel and detailed dependence on the water evaporation rate as a function of water temperature and the difference between water and cover temperature was determined. It was also found that the pr... [more]
Experimental Investigations on the Chemo-Mechanical Coupling in Solid-State Batteries and Electrode Materials
Jiaxuan Wang, Feng Hao
February 22, 2023 (v1)
Subject: Materials
Keywords: chemo-mechanical coupling, electrode materials, in situ experiment, solid-state batteries
Increasing attention has been paid to the safety and efficiency of batteries due to the rapid development and widespread use of electric vehicles. Solid-state batteries have the advantages of good safety, high energy density, and strong cycle performance, and are recognized as the next generation of power batteries. However, solid-state batteries generate large stress changes due to the volume change of electrode materials during cycling, resulting in pulverization and exfoliation of active materials, fracture of solid-electrolyte interface films, and development of internal cracks in solid electrolytes. As a consequence, the cycle performance of the battery is degraded, or even a short circuit can occur. Therefore, it is important to study the stress changes of solid-state batteries or electrode materials during cycling. This review presents a current overview of chemo-mechanical characterization techniques applied to solid-state batteries and experimental setups. Moreover, some metho... [more]
Molecular Dynamics Simulation Studies of Properties, Preparation, and Performance of Silicon Carbide Materials: A Review
Zefan Yan, Rongzheng Liu, Bing Liu, Youlin Shao, Malin Liu
February 22, 2023 (v1)
Subject: Materials
Keywords: molecular dynamics simulation, performance, preparation, property, silicon carbide
Silicon carbide (SiC) materials are widely applied in the field of nuclear materials and semiconductor materials due to their excellent radiation resistance, thermal conductivity, oxidation resistance, and mechanical strength. The molecular dynamics (MD) simulation is an important method to study the properties, preparation, and performance of SiC materials. It has significant advantages at the atomic scale. The common potential functions for MD simulations of silicon carbide materials were summarized firstly based on extensive literatures. The key parameters, complexity, and application scope were compared and analyzed. Then, the MD simulation of SiC properties, preparation, and performance was comprehensively overviewed. The current studies of MD simulation methods and applications of SiC materials were systematically summarized. It was found that the Tersoff potential was the most widely applied potential function for the MD simulation of SiC materials. The construction of more accu... [more]
Review on the Life Cycle Assessment of Thermal Energy Storage Used in Building Applications
Isye Hayatina, Amar Auckaili, Mohammed Farid
February 22, 2023 (v1)
Subject: Materials
Keywords: emerging technology, life cycle assessment (LCA), life cycle sustainability assessment (LCSA), phase change material (PCM), technology readiness level (TRL), thermal energy storage (TES), thermochemical energy storage (TCES)
To reduce building sector CO2 emissions, integrating renewable energy and thermal energy storage (TES) into building design is crucial. TES provides a way of storing thermal energy during high renewable energy production for use later during peak energy demand in buildings. The type of thermal energy stored in TES can be divided into three categories: sensible, latent, and sorption/chemical. Unlike sensible TES, latent TES and sorption/chemical TES have not been widely applied; however, they have the advantage of a higher energy density, making them effective for building applications. Most TES research focuses on technical design and rarely addresses its environmental, social, and cost impact. Life cycle assessment (LCA) is an internationally standardized method for evaluating the environmental impacts of any process. Life cycle sustainability assessment (LCSA) is an expansion of LCA, including economic and social sustainability assessments. This paper aims to provide a literature rev... [more]
GaAs/Si Tandem Solar Cells with an Optically Transparent InAlAs/GaAs Strained Layer Superlattices Dislocation Filter Layer
Yeonhwa Kim, May Angelu Madarang, Eunkyo Ju, Tsimafei Laryn, Rafael Jumar Chu, Tae Soo Kim, Dae-Hwan Ahn, Taehee Kim, In-Hwan Lee, Won Jun Choi, Daehwan Jung
February 22, 2023 (v1)
Subject: Materials
Keywords: molecular beam epitaxy, monolithic integration, Si tandem cell, solar cell
Epitaxial growth of III−V materials on Si is a promising approach for large-scale, relatively low-cost, and high-efficiency Si-based multi-junction solar cells. Several micron-thick III−V compositionally graded buffers are typically grown to reduce the high threading dislocation density that arises due to the lattice mismatch between III−V and Si. Here, we show that optically transparent n-In0.1Al0.9As/n-GaAs strained layer superlattice dislocation filter layers can be used to reduce the threading dislocation density in the GaAs buffer on Si while maintaining the GaAs buffer thickness below 2 μm. Electron channeling contrast imaging measurements on the 2 μm n-GaAs/Si template revealed a threading dislocation density of 6 × 107 cm−2 owing to the effective n-In0.1Al0.9As/n-GaAs superlattice filter layers. Our GaAs/Si tandem cell showed an open-circuit voltage of 1.28 V, Si bottom cell limited short-circuit current of 7.2 mA/cm2, and an efficiency of 7.5%. This result paves the way toward... [more]
The Flow of a Thermo Nanofluid Thin Film Inside an Unsteady Stretching Sheet with a Heat Flux Effect
Mohammed Alrehili
February 22, 2023 (v1)
Subject: Materials
Keywords: buongiornos nanofluid model, heat flux, liquid thin film, porous medium, viscoelastic nanofluid
This research investigated the flow and heat mass transmission of a thermal Buongiorno nanofluid film caused by an unsteady stretched sheet. The movement of the nanoparticles through the thin film layer is caused by the strength of the heat flow and the stretching force of the sheet working together. The thermal thin-film flow and heat mechanism, and the properties of mass transfer along the film layer, were comprehensively investigated. The consequences of the heat generation, magnetic field, and dissipation phenomenon were also thoroughly examined. Using appropriate dimensionless variables, the fundamental time-dependent equations of thin film nanofluid flow and heat mass transfer were modeled and converted to the ordinary differential equations system. Mathematica version 12 is the software that was used to build the numerical code here. Next, the shooting technique was applied to numerically solve the transformed equations. The elegance of the shooting technique and evidence of the... [more]
Chemically and Physically Pretreated Straw in Moderate Conditions: Poor Correlation between Biogas Production and Commonly Used Biomass Characterization
Shruthi Meenakshisundaram, Vincenzo Calcagno, Claire Ceballos, Antoine Fayeulle, Estelle Léonard, Virginie Herledan, Jean-Marc Krafft, Yannick Millot, Xiaojun Liu, Claude Jolivalt, André Pauss
February 22, 2023 (v1)
Subject: Materials
Keywords: anaerobic digestion, autoclave, Biomass, Fenton reaction, size reduction, straw pretreatment
Straw is a substantial agricultural by-product for biogas production. Hydrolysis of straw is found to be a rate-limiting step during its anaerobic digestion and could be enhanced by pretreatment. In this paper, the effect of various combinations of particle size reduction, autoclaving, and low-level Fenton reaction was studied on straw for biogas production. Grinding of straw contributed to the maximum increase in the biomethane potential. Only Fenton or only the autoclave process improves the kinetics slightly but does not considerably improve the biomethane potential. Combining autoclaving and low-concentration Fenton pretreatment considerably improves the BMP values. Lignin content, CHNSO elemental analysis, Scanning Electronic Microscopy (SEM), Simon’s staining, infrared spectroscopy (DRIFT and ATR), Nuclear magnetic resonance spectroscopy, and wide-angle X-ray diffraction analysis (WAXD) were used to characterize the physical and chemical changes of straw due to pretreatment. Resu... [more]
Determination of Rheological Parameters of Non-Newtonian Fluids on an Example of Biogas Plant Substrates
Honorata Jankowska, Aleksandra Dzido, Piotr Krawczyk
February 22, 2023 (v1)
Subject: Materials
Keywords: biogas plant substrates, Herschel–Bulkley, non-linear least squares, non-Newtonian fluids, rheological parameters, rheology, viscosity
Non-Newtonian fluids are commonly used in a wide range of industries; one example are in biogas power plants. Proper measurements and modeling of such fluids can be crucial from the design and operations point of view. Results presented in this study covered seven samples from three plants (a sewage sludge treatment plant, utilization biogas station and a biogas plant in a sugar factory), including mechanically thickened excessive activated sludge (MTEAS), sugar beet pulp (SBP), liquid fruit and vegetable waste (FVW), beet roots (BR) and corn waste (CW); their mixtures were prepared as in a real plant. The total solid content remained below 6.8% for all samples. The apparent viscosity (15 RPM) did not exceed 10 Pas in any sample. A correlation analysis for solvent type influence on the viscosity was carried out. The obtained results were analyzed, and the Herschel−Bulkley rheological model was selected for the fluid description. Then, the Moullinex method was applied to determine the H... [more]
Time Domain Source Parameter Estimation of Natural and Man-Induced Microearthquakes at the Geysers Geothermal Field
Valeria Longobardi, Sahar Nazeri, Simona Colombelli, Raffaele Rea, Grazia De Landro, Aldo Zollo
February 22, 2023 (v1)
Subject: Materials
Keywords: earthquake source parameters, induced seismicity, The Geysers geothermal field, time domain technique
Water injection in geothermal areas is the preferential strategy to sustain the natural production of geothermal resources. In this context, monitoring microearthquakes is a fundamental tool to track changes in the reservoirs in terms of soil composition, response to injections, and resource exploitation with space and time. Therefore, refined source characterization is crucial to better estimate the size, source mechanism, and rupture process of microearthquakes, as they are possibly related to industrial activities, and to identify any potential variation in the background seismicity. Standard approaches for source parameter estimation are ordinarily based on the modelling of Fourier displacement spectra and its characteristic parameters: the low-frequency spectral level and corner frequency. Here, we apply an innovative time domain technique that uses the curves of P-wave amplitude vs. time along the seismogram. This methodology allows estimation of seismic moment, source radius, an... [more]
Oxygen Reduction at PtNi Alloys in Direct Methanol Fuel Cells—Electrode Development and Characterization
Ali Karaca, Andreas Glüsen, Klaus Wippermann, Scott Mauger, Ami C. Yang-Neyerlin, Steffen Woderich, Christoph Gimmler, Martin Müller, Guido Bender, Horst Weller, Marcelo Carmo, Detlef Stolten
February 22, 2023 (v1)
Subject: Materials
Keywords: alloys, catalyst, charge-transfer resistance, DMFC, EIS, Fuel Cells, nickel, ORR, platinum, supported catalysts
Catalyst layers made from novel catalysts must be fabricated in a way that the catalyst can function to its full potential. To characterize a PtNi alloy catalyst for use in the cathode of Direct Methanol Fuel Cells (DMFCs), the effects of the manufacturing technique, ink composition, layer composition, and catalyst loading were here studied in order to reach the maximum performance potential of the catalyst. For a more detailed understanding, beyond the DMFCs performance measurements, we look at the electrochemically active surface area of the catalyst and charge-transfer resistance, as well as the layer quality and ink properties, and relate them to the aspects stated above. As a result, we make catalyst layers with optimized parameters by ultrasonic spray coating that shows the high performance of the catalyst even when containing less Pt than commercial products. Using this approach, we can adjust the catalyst layers to the requirements of DMFCs, hydrogen fuel cells, or polymer elec... [more]
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