LAPSE:2023.3545
Published Article

LAPSE:2023.3545
An Environmental and Technical Evaluation of Vacuum-Based Thin Film Technologies: Lithium Niobate Coated Cathode Active Material for Use in All-Solid-State Battery Cells
February 22, 2023
Abstract
Research on All-Solid-State Batteries (ASSBs) currently focuses on the development of innovative materials, cell concepts, and production processes, aiming to achieve higher energy densities compared to other battery technologies. For example, it is been demonstrated that coating the Cathode Active Material (CAM) can enhance the rate capability and cycle life and reduce the interfacial resistance of an ASSB cell. For this reason, various techniques for coating the CAM have been explored, along with a variety of coating materials, including lithium niobate. Since ASSBs are still an emerging technology, more research is needed to determine how their production processes will perform from a technical, economic, and environmental perspective. In this paper, two innovative techniques for producing lithium niobate-coated CAMs are presented and evaluated. Particularly, Atomic Layer Deposition (ALD) and Physical Vapor Deposition (PVD) techniques for coating NCM811 particles are investigated. The methodology for environmental and technical feasibility assessments at an early stage of development is further presented and discussed. Based on process-specific data and expert knowledge, an environmental assessment is conducted and further supported with a qualitative technical feasibility assessment. The results help guide early-stage decision-making regarding the identification of promising process routes with relatively low impacts.
Research on All-Solid-State Batteries (ASSBs) currently focuses on the development of innovative materials, cell concepts, and production processes, aiming to achieve higher energy densities compared to other battery technologies. For example, it is been demonstrated that coating the Cathode Active Material (CAM) can enhance the rate capability and cycle life and reduce the interfacial resistance of an ASSB cell. For this reason, various techniques for coating the CAM have been explored, along with a variety of coating materials, including lithium niobate. Since ASSBs are still an emerging technology, more research is needed to determine how their production processes will perform from a technical, economic, and environmental perspective. In this paper, two innovative techniques for producing lithium niobate-coated CAMs are presented and evaluated. Particularly, Atomic Layer Deposition (ALD) and Physical Vapor Deposition (PVD) techniques for coating NCM811 particles are investigated. The methodology for environmental and technical feasibility assessments at an early stage of development is further presented and discussed. Based on process-specific data and expert knowledge, an environmental assessment is conducted and further supported with a qualitative technical feasibility assessment. The results help guide early-stage decision-making regarding the identification of promising process routes with relatively low impacts.
Record ID
Keywords
All-Solid-State Batteries, Atomic Layer Deposition, Cathode Active Material coating, environmental assessment, lithium niobate, NCM811, Physical Vapor Deposition, prospective assessment, technical assessment
Subject
Suggested Citation
Wolff D, Weber S, Graumann T, Zebrowski S, Mainusch N, Dilger N, Cerdas F, Zellmer S. An Environmental and Technical Evaluation of Vacuum-Based Thin Film Technologies: Lithium Niobate Coated Cathode Active Material for Use in All-Solid-State Battery Cells. (2023). LAPSE:2023.3545
Author Affiliations
Wolff D: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany [ORCID]
Weber S: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Graumann T: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Zebrowski S: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Mainusch N: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Dilger N: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Cerdas F: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany [ORCID]
Zellmer S: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Weber S: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Graumann T: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Zebrowski S: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Mainusch N: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Dilger N: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Cerdas F: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany [ORCID]
Zellmer S: Fraunhofer Institute for Surface Engineering and Thin Films IST, 38108 Braunschweig, Germany
Journal Name
Energies
Volume
16
Issue
3
First Page
1278
Year
2023
Publication Date
2023-01-25
ISSN
1996-1073
Version Comments
Original Submission
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PII: en16031278, Publication Type: Journal Article
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LAPSE:2023.3545
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https://doi.org/10.3390/en16031278
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Feb 22, 2023
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