Long term stability is one of the decisive properties of solid oxide fuel cell (SOFC) as well as solid oxide electrolysis cell (SOEC) materials from the commercialization perspective. To improve the understanding about degradation mechanisms solid oxide cells with different electrode compositions should be studied. In this work, Ni-Zr0.92Y0.08O2-δ (Ni-YSZ)| Zr0.92Y0.08O2-δ (YSZ)|Ce0.9Gd0.1O2-δ (GDC)|Pr0.6Sr0.4CoO3-δ (PSC) cells are tested in the SOFC regime for 17,820 h at 650 °C, and in the SOEC regime for 860 h at 800 °C. The SOFC experiment showed a degradation speed of 2.4% per 1000 h at first but decreased to 1.1% per 1000 h later. The electrolysis test was performed for 860 h at 800 °C. The degradation speed was 16.3% per 1000 h. In the end of the stability tests, an electrode activity mapping was carried out using a novel 18O tracing approach. Average Ni grain sizes were measured and correlated with the results of the oxygen isotope maps. Results indicate that Ni coarsening is d... [more]

Medium and heavy-duty battery electric trucks (BETs) may play a key role in mitigating greenhouse gas (GHG) emissions from road freight transport. However, technological challenges such as limited range and cargo carrying capacity as well as the required charging time need to be efficiently addressed before the large-scale adoption of BETs. In this study, we apply a geospatial data analysis approach by using a battery electric vehicle potential (BEVPO) model with the datasets of road freight transport surveys for analyzing the potential of large-scale BET adoption in Finland and Switzerland for trucks with gross vehicle weight (GVW) of over 3.5 t. Our results show that trucks with payload capacities up to 30 t have the most potential for electrification by relying on the currently available battery and plug-in charging technology, with 93% (55% tkm) and 89% (84% tkm) trip coverage in Finland and Switzerland, respectively. Electric road systems (ERSs) would be essential for covering 51%... [more]

This study proposes a simple ground heat exchanger design capacity that is applicable in the schematic-design stage for several configurations used for borehole heat exchangers (BHEs). Three configurations—single, compact, and irregular types—were selected, and the heat transfer rate per unit BHE was calculated considering heat interference. In a case study with a typical configuration and general range of ground thermal conductivity, the BHE heat transfer rate of the compact configuration decreased owing to heat interference as the number of BHEs increased. However, with respect to the irregular configuration, the heat transfer rate increased as the same number increased. This was attributed to the relatively large increment rate of the distance between the boreholes in the irregular configurations, making the heat recovery factor more dominant than the heat interference. The results show that the average heat transfer rate values per BHE applicable to each configuration type in the s... [more]

As the most abundant element in the world, hydrogen is a promising energy carrier and has received continuously growing attention in the last couple of decades. At the very moment, hydrogen fuel is imagined as the part of a sustainable and eco-friendly energy system, the “hydrogen grand challenge”. Among the large number of storage solutions, solid-state hydrogen storage is considered to be the safest and most efficient route for on-board applications via fuel cell devices. Notwithstanding the various advantages, storing hydrogen in a lightweight and compact form still presents a barrier towards the wide-spread commercialization of hydrogen technology. In this review paper we summarize the latest findings on solid-state storage solutions of different non-equilibrium systems which have been synthesized by mechanical routes based on severe plastic deformation. Among these deformation techniques, high-pressure torsion is proved to be a proficient method due to the extremely high applied s... [more]

The detonability of polyethylene pyrolysis products (pyrogas) in mixtures with air is determined for the first time in a standard pulsed detonation tube based on the measured values of deflagration-to-detonation transition run-up time. The pyrogas is continuously produced in a gas generator at decomposition temperatures ranging from 650 to 850 °C. Chromatographic analysis shows that at a high decomposition temperature (850 °C) pyrogas consists mainly of hydrogen, methane, ethylene, and ethane, and has a molecular mass of about 10 g/mol, whereas at a low decomposition temperature (650 °C), it mainly consists of ethylene, ethane, methane, hydrogen, propane, and higher hydrocarbons, and has a molecular mass of 24−27 g/mol. In a pulsed detonation mode, the air mixtures of pyrogas with the fuel-to-air equivalence ratio ranging from 0.6 to 1.6 at normal pressure are shown to exhibit the detonability close to that of the homogeneous air mixtures of ethylene and propylene. On the one hand, thi... [more]

The paper presents the results of research aimed at evaluating the possibility of using selected tree leaf species to produce solid biofuels. The possibility of production of qualitative solid biofuels from urban tree leaves meets the expectations of the municipal sector. Collection of tree leaves in urban areas is very often necessary for road safety reasons, the need to collect biomass rich in dust and pollution as well as biomass infested with pests. The production of solid biofuels from tree leaves allows for effective management of this raw material with energy recovery. The performed research indicates such a possibility, and the obtained ash is used as a soil improver. The conducted research showed that the biomass of leaves of five tree species used in the experiment can be a source of raw materials for production of qualitative biofuels. The obtained pellets were characterized by properties comparable to those of classical wood pellets. The lower heating value of the obtained... [more]

Noble metal-TiO2 nanohybrids, NM0-TiO2, (NM0 = Pt0, Pd0, Au0, Ag0) have been engineered by One-Nozzle Flame Spray Pyrolysis (ON-FSP) and Double-Nozzle Flame Spray Pyrolysis (DN-FSP), by controlling the method of noble metal deposition to the TiO2 matrix. A comparative screening of the two FSP methods was realized, using the NM0-TiO2 photocatalysts for H2 production from H2O/methanol. The results show that the DN-FSP process allows engineering of more efficient NM0-TiO2 nanophotocatalysts. This is attributed to the better surface-dispersion and narrower size-distribution of the noble metal onto the TiO2 matrix. In addition, DN-FSP process promoted the formation of intraband states in NM0-TiO2, lowering the band-gap of the nanophotocatalysts. Thus, the present study demonstrates that DN-FSP process is a highly efficient technology for fine engineering of photocatalysts, which adds up to the inherent scalability of Flame Spray Pyrolysis towards industrial-scale production of nanophotocata... [more]

The need of clean energy is constantly increasing, and Building Integrated PhotoVoltaic (BIPV) technologies represent valuable assets to expand even further the photovoltaic market. Thanks to BIPVs. a new concept of local electric microgrid will probably emerge as this kind of technology can turn buildings from energy wells to energy sources. Luminescent Solar Concentrator (LSC) panels are perfect to achieve this goal, indeed, contrary to standard flat PhotoVoltaic (PV) modules, they can be exploited in transparent or semi-transparent building façades. Thus, the purpose of this work was the optimization of the performance of LSC panels for BIPV applications. Being an application-oriented study, we paid particular attention to the scalability of the assembling process and the use of LSC slabs functionalized only with widely available organic commercial dyes and high-performance commercial silicon solar cells. The electrical and optical performance of the LSC panels were firstly simulate... [more]

Dynamic pointing and tracking accuracy are the most relevant indicators of dynamic performance for the satellite antenna driving mechanism. Multi-clearance coupling in the joints will incur high-frequency vibration and dynamic errors of the system. Joints of existing analytical models are generally oversimplified as planar revolute hinges, which ignore the coupling effect of multi-clearance. It cannot proficiently predict the dynamic behavior of the driving mechanism with multi-clearance on the orbit. To address this problem, a typical 2K-H planetary gear joint model with multi-clearance coupling has been developed by considering radial clearance, backlash, tooth profile error, time-varying meshing stiffness, and damping. A dynamic model of a typical dual-axis driving mechanism is established to analyze the dynamic characteristics of multibody systems with planetary gear joints. The effects of rotational speed, radial clearance, backlash, and their coupling on the dynamic performance o... [more]

The diffuser total efficiency was formulated and defined based on the generalized actuator disc model for the index of the efficiency of the diffuser-alone of the diffuser-augmented wind turbines. An optimization method to maximize the diffuser total efficiency was developed using a genetic algorithm and axisymmetric computational fluid dynamics. A case study was conducted for a 10% chord-to-diameter ratio, 2% thickness-to-chord plate, and the crest position at 50% chord of the diffuser. The optimal result showed a diffuser total efficiency of 1.087. Furthermore, 1392 (=48 population × 29 generations) simulation cases of the optimization process showed that high diffuser total efficiency appears at a low-drag coefficient, high-lift coefficient, and 15−25% low diffuser height-to-chord ratio.

This paper derives the optimal investment policy of an electricity producer during a pandemic. We consider three problems: (1) investing in a gas-fired plant, (2) investing in a wind plant, and (3) investing in the best of a gas plant and a wind plant. Optimal investment boundaries are characterized and valuation formulas derived. For single technology projects, a pandemic postpones wind investment, but can accelerate gas investment when the relative price of gas decreases. For choices between the two technologies, a substitution effect can reinforce the single technology effects, accelerating gas investment under certain conditions. The paper examines the impact of pandemic parameters, economic parameters and policy parameters on the investment boundaries, the values of projects and the premium for green energy.

This study explores the impact of clean energy and non-renewable energy consumption on CO2 emissions and economic growth within two phases (formative and expansion) of renewable energy diffusion for three selected countries (France, Spain, and Sweden). The vector autoregression (VAR) model is estimated on the basis of annual data disaggregated into quarterly data. The Granger causality results reveal distinctive differences in the causality patterns across countries and two phases of renewables diffusion. Clean energy consumption contributes to a decline of emissions more clearly in the expansion phase in France and Spain. However, this effect seems to be counteracted by the increases in emissions due to economic growth and non-renewable energy consumption. Therefore, clean energy consumption has not yet led to a decoupling of economic growth from emissions in France and Spain; in contrast, the findings for Sweden evidence such a decoupling due to the neutrality between economic growth... [more]

Partial shading is widely considered to be a limiting factor in the performance of photovoltaic (PV) systems applied in urban environments. Modern system architectures, combined with per module deployment of power electronics, have been used to improve performance, especially at heterogeneous irradiance conditions, but they come with a high investment cost. In this paper, another approach is used to evaluate the selective deployment of power optimizers (SDPO), which can operate with a variety of string inverters and can be retrofitted in PV systems suffering from high shading losses. A combination of modelling and outdoor field testing showed the benefits and drawbacks of SDPOs in a variety of shading scenarios. Results suggest that there is an energy yield increase of 1−2% on an annual basis compared to that of a reference system. The exact level of increase depends on the shading patterns and combination scenarios used in this paper.

In order to reduce fuel consumption and reduce the deviation between the final battery state-of-charge (SOC) value and the target value at the same time, a novel double-layer multi-objective optimization method is proposed, which adopts an improved ant colony optimization (ACO) algorithm and the equivalent fuel consumption minimization strategy (ECMS) considering mode switching. The proposed strategy adopts a two-layer structure. In the inner layer, the ECMS considering mode switching was adopted to optimize the working mode and working point, so as to achieve the goal of reducing fuel consumption. In the outer layer, aiming at the shortcomings of traditional ACO, the heuristic factor and adaptive volatilization factor were introduced. An improved ACO method was proposed to optimize the equivalent factor, so as to achieve the goal of reducing the deviation between the final value of SOC and the target value. In order to verify the effectiveness of the proposed algorithm, it is compared... [more]

Initial temperature has a promoting effect on laminar burning velocity, while initial pressure and dilution rate have an inhibitory effect on laminar burning velocity. Equal laminar burning velocities can be obtained by initial condition coupling with different temperatures, pressures and dilution rates. This paper analysed the equivalent distribution pattern of laminar burning velocity and the variation pattern of an equal weight curve using the coupling effect of the initial pressure (0.1−0.3 MPa), initial temperature (323−423 K) and dilution rate (0−16%). The results show that, as the initial temperature increases, the initial pressure decreases and the dilution rate decreases, the rate of change in laminar burning velocity increases. The equivalent effect of initial condition coupling can obtain equal laminar burning velocity with an dilution rate increase (or decrease) of 2% and an initial temperature increase (or decrease) of 29 K. Moreover, the increase in equivalence ratio lead... [more]

Residential demand response (DR) programs are generally administered through an electricity distribution utility, or an electric grid operator. These programs typically reduce electricity consumption by inducing behavioral changes in the occupants of participating households. We propose implementing a wholesale-price-sensitive residential DR program through the retail electricity provider (REP), who has more naturally aligned incentives to avoid high wholesale electricity prices and maintain customer satisfaction, as compared to distribution utilities, grid operators, and the average residential consumer. Retail electricity providers who serve residential consumers are exposed to substantial price risk as they generally have a portion of their portfolio exposed to variable real-time wholesale electricity prices, despite charging their residential customers a fixed retail electricity price. Using Monte Carlo simulations, we demonstrate that demand response, executed through internet-con... [more]

Climate change is emerging as an issue of progressive attention, and therefore awareness, in societies. In this work, the problem is addressed from a generational perspective in Spanish society and is carried out from the approaches of awareness, human action, and self-responsibility. All this from the search of the subjective well-being and the citizens’ happiness, as one of the bases of sustainable development initiatives. With data from the European Social Survey R8, from EUROSTAT, we work in two phases: (1) descriptive and inferential on possible associations of the items with the variable Age, and (2) calculation of probabilities between groups through logistic regression. The results confirm a general awareness, but with apparent statistical differences between age groups. In general, the youngest are the most aware, blame human activity most intensely, are the most concerned, and are the most willing to act. And it is the older people who are less aware of all these issues. Base... [more]

Decarbonising heavy-duty trucks is challenging due to high journey power and energy requirements. With a growing fleet of commercial vehicles in the UK, biomethane can provide significant reductions in greenhouse gas (GHG) emissions compared to fossil diesel. Methane is a potent GHG with a global warming potential (GWP) of 23−36, therefore reducing levels in the atmosphere can have a significant impact on climate change. There are a range of anthropogenic sources of methane that could be collected and processed to provide sustainable energy (upcycled), e.g., agricultural waste and the waste water system. This paper explores the impact of using upcycled methane in transport in South East England, evaluating local sources of anthropogenic methane and the environmental and economic impact of its use for a heavy-duty truck compared to fossil and battery electric alternatives. Analysis concludes that the use of upcycled methane in transport can provide significant reductions in lifecycle GH... [more]

Solid fuelization technology can increase the heating value of sewage sludge such that it can be utilised as a fossil fuel substitutes. Reducing landfilling of bottom and fly ash resulting from heavy metals contained in sewage sludge is challenging. Hence, combustion melting technology (CMT), which can discharge bottom ash in the form of slag, has been proposed herein as an alternative to the conventional incineration technology. However, further research is required to improve the flowability of slag. Applicability of CMT for the stable treatment of heavy metals in the ash generated during the energisation of sewage sludge solid fuel has been reviewed. The change in the degree of fluidity was identified via a laboratory-scale fluidity measurement experiment following changes in melting temperature, mixing ratio of sewage sludge and sawdust, and basicity. The pouring index (PI) of sewage sludge solid fuel (pellet) was maintained at a level of about 60% at a basicity index of 0.8. Based... [more]

Natural gas hydrate is a new clean energy source in the 21st century, which has become a research point of the exploration and development technology. Acoustic well logs are one of the most important assets in gas hydrate studies. In this paper, an improved Carcione−Leclaire model is proposed by introducing the expressions of frame bulk modulus, shear modulus and friction coefficient between solid phases. On this basis, the sensitivities of the velocities and attenuations of the first kind of compressional (P1) and shear (S1) waves to relevant physical parameters are explored. In particular, we perform numerical modeling to investigate the effects of frequency, gas hydrate saturation and clay on the phase velocities and attenuations of the above five waves. The analyses demonstrate that, the velocities and attenuations of P1 and S1 are more sensitive to gas hydrate saturation than other parameters. The larger the gas hydrate saturation, the more reliable P1 velocity. Besides, the atten... [more]

This article presents an estimation of the temperature decrease in the vicinity of a salt cavern due to its leaching. The one-dimensional radially symmetry models of a salt cavern were considered and described. The initial temperature of rock salt massif was assumed as 50 ∘C and temperature of leaching water varied seasonally from 6 ∘C to 20 ∘C. A significant influence of the season of the leaching process, beginning on the final temperature distribution was found. The model takes into account: convection coefficient changes depending on temperature of brine and rock formation and heat effects caused by salt dissolution. Numerical results are compared with measurements data on the field of cavern volume increasing with time as the function of flow of leaching water and its temperature. The accuracy of the cavern volume increasing versus time was assumed as good—both quantitative and qualitative.

In building thermal energy characterisation, the relevance of proper modelling of the effects caused by solar radiation, temperature and wind is seen as a critical factor. Open geospatial datasets are growing in diversity, easing access to meteorological data and other relevant information that can be used for building energy modelling. However, the application of geospatial techniques combining multiple open datasets is not yet common in the often scripted workflows of data-driven building thermal performance characterisation. We present a method for processing time-series from climate reanalysis and satellite-derived solar irradiance services, by implementing land-use, and elevation raster maps served in an elevation profile web-service. The article describes a methodology to: (1) adapt gridded weather data to four case-building sites in Europe; (2) calculate the incident solar radiation on the building facades; (3) estimate wind and temperature-dependent infiltration using a single-... [more]

Forecasting energy demand within a distribution network is essential for developing strategies to manage and optimize available energy resources and the associated infrastructure. In this study, we consider remote communities in the Arctic located at the end of the radial distribution network without alternative energy supply. Therefore, it is crucial to develop an accurate forecasting model to manage and optimize the limited energy resources available. We first compare the accuracy of several models that perform short-and medium-term load forecasts in rural areas, where a single industrial customer dominates the electricity consumption. We consider both statistical methods and machine learning models to predict energy demand. Then, we evaluate the transferability of each method to a geographical rural area different from the one considered for training. Our results indicate that statistical models achieve higher accuracy on longer forecast horizons relative to neural networks, while t... [more]

Stirling units are a viable option for micro-cogeneration applications, but they operate often with multiple daily startups and shutdowns due to the variability of load profiles. This work focused on the experimental and numerical study of a small-size commercial Stirling unit when subjected to cycling operations. First, experimental data about energy flows and emissions were collected during on−off operations. Second, these data were utilized to tune an in-house code for the economic optimization of cogeneration plant scheduling. Lastly, the tuned code was applied to a case study of a residential flat in Northern Italy during a typical winter day to investigate the optimal scheduling of the Stirling unit equipped with a thermal storage tank of diverse sizes. Experimentally, the Stirling unit showed an integrated electric efficiency of 8.9% (8.0%) and thermal efficiency of 91.0% (82.2%), referred to as the fuel lower and, between parenthesis, higher heating value during the on−off cycl... [more]

Many applications (electric vehicles, renewable energies, low-voltage DC grids) require simple, high-power density and low-current ripple-boost converters. Traditional step-up converters are limited when large transformation ratios are involved. In this work is proposed a step-up converter that brings together the characteristics of high gain, low ripple, and high-power density. From the converter proposal, a mathematical analysis of its operation is first performed, including its static transfer function, stress of components, and voltage and current ripples. Furthermore, it provides a design example for an application of Vin = 48 V to Vo = 270 V and 500 W. For its implementation, two different wide bandgap (WBG) semiconductor models have been used, hybrid GaN cascodes and SiC MOSFETs. Finally, the experimental results of the produced prototypes are shown, and the results are discussed.