The environmental impact from the use of fossil fuel cum depletion of the known fossil oil reserves has led to increasing interest in liquid biofuels made from renewable biomass. This study presents the first experimental report on the catalytic pyrolysis of Napier grass, an underutilized biomass source, using ZSM-5, 0.3HZSM-5 and zinc exchanged zeolite-A catalyst. Pyrolysis was conducted in fixed bed reactor at 600 °C, 30 °C/min and 7 L/min nitrogen flow rate. The effect of catalyst-biomass ratio was evaluated with respect to pyrolysis oil yield and composition. Increasing the catalyst loading from 0.5 to 1.0 wt % showed no significant decrease in the bio-oil yield, particularly, the organic phase and thereafter decreased at catalyst loadings of 2.0 and 3.0 wt %. Standard analytical methods were used to establish the composition of the pyrolysis oil, which was made up of various aliphatic hydrocarbons, aromatics and other valuable chemicals and varied greatly with the surface acidity... [more]

Surfactant-polymer (SP) flooding has been demonstrated to be an effective method to recover oil in the enhanced oil recovery (EOR) stage when water flooding is no longer relevant. Theoretically, adding surfactant causes the reduction of the interfacial tension between oil and water in pores, therefore reducing the residual oil saturation, whereas the sweep efficiency will be significantly improved by the polymer injection as a result of proper mobility control. With regard to the well patterns, water flooding has demonstrated a high productivity in horizontal wells. Recently, other EOR processes have been increasingly applied to the horizontal wells in various well patterns. In this study, the efficiency of SP flooding applied to horizontal wells in various well configurations is investigated in order to select the best EOR performance in terms of either a technical or economical point of view. Furthermore, the reservoir is assumed to be anisotropic with four different layers that have... [more]

In power systems, the secondary control is a very useful way to restore the system frequency and voltage to the rated value. This paper tries to propose a secondary frequency and voltage control of islanded microgrids based on the distributed synergetic control of multi-agent systems. In the proposed control, since each distributed generation only requires its own information and that of the neighbors, the secondary control is fully distributed. The system is more reliable because the central controller and complex communication network are reduced in the distributed structure. Based on multi-agent systems, the dynamic model is established, and distributed synergetic control algorithms are given to design the secondary control of the islanded microgrid. Meanwhile, the system has globally asymptotic stability under the proposed control, which is proved by the direct Lyapunov method. Simulation results about a test microgrid are given to verify the effectiveness of the proposed control.

Overhead high voltage power line (HVPL) online monitoring equipment is playing an increasingly important role in smart grids, but the power supply is an obstacle to such systems’ stable and safe operation, so in this work a hybrid wireless power supply system, integrated with inductive energy harvesting and wireless power transmitting, is proposed. The energy harvesting device extracts energy from the HVPL and transfers that from the power line to monitoring equipment on transmission towers by transmitting and receiving coils, which are in a magnetically coupled resonant configuration. In this paper, the optimization design of online energy harvesting devices is analyzed emphatically by taking both HVPL insulation distance and wireless power supply efficiency into account. It is found that essential parameters contributing to more extracted energy include large core inner radius, core radial thickness, core height and small core gap within the threshold constraints. In addition, there... [more]

A novel family of iodide salts and ionic liquids based on different carbohydrate core units is herein described for application in dye-sensitized solar cell (DSC). The influence of the molecular skeleton and the cationic structure on the electrolyte properties, device performance and on interfacial charge transfer has been investigated. In combination with the C106 polypyridyl ruthenium sensitizer, power conversion efficiencies lying between 5.0% and 7.3% under standard Air Mass (A.M.) 1.5G conditions were obtained in association with a low volatile methoxypropionitrile (MPN)-based electrolyte.

Electric vehicles have become increasingly popular in recent years due to our limited natural resources. As a result, interest in climate control systems for electric vehicles is rising rapidly. According to a variety of research sources, the heat pump air conditioning system seems to be a potential climate control system for electric vehicles. In this paper, an extensive literature review has been performed on the progress in heat pump air conditioning systems for electric vehicles. First, a review of applications of alternative environmentally friendly refrigerants in electric vehicles is introduced. This is followed by a review of other advanced technologies, such as the inverter technology, innovative components and the system structure of the heat pump air conditioning system for electric vehicles. Lastly, recent developments in multiple source heat pump systems are presented. The use of these advanced technologies can provide not only sufficient refrigerating capacity for the ele... [more]

Micro combined heating and power (micro-CHP) systems are becoming more than important, and even essential, if we pretend to take full advantage of available energy. The efficiency of this kind of systems reaches 90% and important savings in energy transport processes can occur. In this research, an internal combustion engine (ICE)-based micro-CHP system was developed and tested under specific constraints. The system uses a two cylinder Otto engine as prime mover, coupled to an electrical alternator, and it uses exhaust gases and engine cooling circuit heat. The micro-CHP system was developed to match the electrical power of a typical Stirling engine (SE)-based micro-CHP unit, in order to later compare both systems’ performance under similar circumstances. Different operating modes were tested under different engine speeds, in order to find the optimum operating point. A stand-alone portable application of this system was performed using recreational sailing boats as mobile homes. Speci... [more]

As a substitute for graphite, the negative electrode material commonly used in Li-ion batteries, hydrides have the theoretical potential to overcome performance limits of the current state-of-the-art Li-ion cells. Hydrides can operate through a conversion process proved for some interstitial hydrides like MgH₂: MxAy + n Li = x M + y LimA, where m = n/y. Even if far from optimization, outstanding performances were observed, drawing the attention to the whole hydride family. Looking for high capacity systems, lightweight complex metal hydrides, such as borohydrides, deserve consideration. Capacities in the order of 2000⁻4000 mAh/g can be theoretically expected thanks to the very low formula unit weight. Although the potential technological impact of these materials can lead to major breakthroughs in Li-ion batteries, this new research field requires the tackling of fundamental issues that are completely unexplored. Here, our recent findings on the incorporation of borohydrides are presen... [more]

This is the second part of a companion paper on variable reverse power flow (VRPF) in active distribution networks (ADNs) with wind stations (WSs). Here, we propose an electricity market model considering agreements between the operator of a medium-voltage active distribution network (MV-ADN) and the operator of a high-voltage transmission network (HV-TN) under different scenarios. The proposed model takes, simultaneously, active and reactive energy prices into consideration. The results from applying this model on a real MV-ADN reveal many interesting facts. For instance, we demonstrate that the reactive power capability of WSs will be never utilized during days with zero wind power and varying limits on power factors (PFs). In contrast, more than 10% of the costs of active energy losses, 15% of the costs of reactive energy losses, and 100% of the costs of reactive energy imported from the HV-TN, respectively, can be reduced if WSs are operated as capacitor banks with no limits on PFs... [more]

We report the synergistic optimization of the thermoelectric properties in p-type Bi0.48Sb1.52Te₃ by the additional graphene. Highly dense Bi0.48Sb1.52Te₃ + graphene (x wt%, x = 0, 0.05, 0.1 and 0.15) composites have been synthesized by zone-melting followed by spark plasma sintering. With the help of scanning electron microscopy, the graphene has been clearly observed at the edge of the grain in the composites. Due to the additional graphene, the composites show an improved power factor of 4.8 × 10−3 Wm−1K−2 with modified carrier concentration and suppressed lattice thermal conductivity. Consequently, synergistic optimization in electrical and lattice properties by additional graphene leads to a great improvement in the figure of merit ZT (1.25 at 320 K).

Recently, there has been a rapid growth of interest in quadrotors with electric variable-pitch propellers. The control and optimization of such propellers are important factors for improving the flight performance of the vehicles. Therefore, the steady-state identification method to estimate the parameters of the mathematical model of the electric variable-pitch propeller is developed. The steady-state control and optimization scheme with minimum power consumption and the adaptive compensation scheme for the variable-pitch propeller are then proposed, based on which the response performance of the lift force produced by the variable-pitch propeller can be greatly improved by using a cascade compensation scheme. Furthermore, the direct lift-based flight control strategy is presented, which can significantly contribute to the improvement of the flight performance, precisely because the roll, pitch, yaw and vertical channels of the variable-pitch quadrotor are approximately linearized and... [more]

Understanding the properties of CdSTe ternary alloys is important because they always form at the interface between the CdS window layer and CdTe absorber layer in CdS/CdTe solar cells due to the intermixing. This interdiffusion is necessary because it improves the device performance. Experimental work has been devoted to studying Te rich p-type CdSxTe1−x alloys, but there is a lack of studies on S-rich n-type CdS1−yTey solid solutions. In this work, a review of the structure, morphology, and optical properties of the S-rich n-type CdS1−yTey thin films produced by the spray pyrolysis technique on glass substrates is presented.

Cavitation is a common flow phenomena in most hydraulic turbines and has the potential to cause vibration, blade surface damage and performance loss. Despite the fact that crossflow turbines have been used in small-scale hydropower systems for a long time, cavitation has not been studied in these turbines. In this paper, we present the findings of a computational study on cavitation inception in crossflow turbines. Cavitation inception was assessed using three-dimensional (3D) Reynolds-Averaged Navier⁻Stokes (RANS) computations. A homogeneous, free-surface two-phase flow model was used. Pressure distributions on the blades were examined for different flow rates, heads and impeller speeds to assess cavitation inception. The results showed that cavitation occurs in the second stage of the turbine and was observed on the suction side near the inner edge of the blades. For the particular turbine studied, cavitation always occurred at shaft speeds greater than that, giving the maximum effic... [more]

The growing number of vehicles on the road has led to a rapid increase in fuel consumption and toxic gas emissions, so the challenges in fuel efficiency improvement and reduction of CO₂ and NOx emissions have always been on the top agenda of the automotive industry. The paper presents a feasibility study of recovering the low-pressure exhaust gas energy via by-pass connection of a scroll expander to the engine system exhaust. The paper starts with the description of the proposed new exhaust energy recycling scheme and the mathematical modelling of the system. A feasibility study is carried out to investigate whether this new scheme can work with the engine operation conditions specified by the engine test data. The initial study indicated that the scroll expander structure needs to be modified; otherwise, it cannot be used for exhaust energy recovery. The experimental test and simulation results presented in this paper indicate that it is feasible to recover the low-pressure exhaust ga... [more]

The electricity generation/supply and transportation sectors are the two largest contributors to greenhouse gas (GHG) emissions in the U.S., and vehicle-to-grid (V2G) technology is a rapidly emerging solution to reduce these emissions with the adoption of battery-electric (BE) vehicles. Deployments of BE transit and school buses are expected to have larger battery capacities than passenger vehicles, making them more feasible candidates for V2G service. Five electricity generation regions are considered for cash flow analysis of BE and diesel transit and school buses over their entire respective lifetimes with the allowance of V2G services’ net revenue. Besides, the environmental benefits of using the V2G system are studied in place of combustion power generation plants for the regulation services of each study region. Air emission externalities are another crucial issue for bus operations because buses are operated near highly populated areas, so these externalities are also studied in... [more]

A bidirectional converter able to manage storage is a basic power electronics device, and it is a major component of renewable energy sources, micro grid and also the smart grid concept. In this paper, single-phase bidirectional converter topology is discussed. The state space model has been derived, and a simple model based predictive current controller has been utilized to control the inverter. Control block diagrams have been designed with MATLAB and simulation results are presented and compared with experimental ones, giving credibility to the derived model and the designed control method.

Mass transfer phenomena in polymeric electrolyte membrane fuel cells (PEMFC) electrodes has already been analyzed in terms of the interactions between diffusive and forced flows. It was demonstrated that the whole phenomenon could be summarized by expressing the Sherwood number as a function of the Peclet number. The dependence of Sherwood number on Peclet one Sh(Pe) function, which was initially deduced by determining three different flow regimes, has now been given a more accurate description. A comparison between the approximate and the accurate results for a reference condition of diluted reactant and limit current has shown that the former are useful for rapid, preliminary calculations. However, a more precise and reliable estimation of the Sherwood number is worth attention, as it provides a detailed description of the electrochemical kinetics and allows a reliable comparison of the various geometrical arrangements used for the distribution of the reactants.

We present a thermo-economic analysis of an Organic Rankine Cycle (ORC) for waste heat recovery. A case study for a heat source temperature of 150 °C and a subcritical, saturated cycle is performed. As working fluids R245fa, isobutane, isopentane, and the mixture of isobutane and isopentane are considered. The minimal temperature difference in the evaporator and the condenser, as well as the mixture composition are chosen as variables in order to identify the most suitable working fluid in combination with optimal process parameters under thermo-economic criteria. In general, the results show that cost-effective systems have a high minimal temperature difference ΔTPP,C at the pinch-point of the condenser and a low minimal temperature difference ΔTPP,E at the pinch-point of the evaporator. Choosing isobutane as the working fluid leads to the lowest costs per unit exergy with 52.0 €/GJ (ΔTPP,E = 1.2 K; ΔTPP,C = 14 K). Considering the major components of the ORC, specific costs range betw... [more]

As drivers of climate action, cities are taking measures to reduce greenhouse gas (GHG) emissions, which if left unabated pose a challenge to meeting long-term climate targets. The economics of climate action needs to be at the forefront of climate dialogue to prioritize investments among competing mitigation measures. A marginal abatement cost (MAC) curve is an effective visualization of climate action that initiates a technical and economic discussion of the cost-effectiveness and abatement potential of such actions among local leaders, policy makers, and climate experts. More commonly demonstrated for countries, MAC curves need to be developed for cities because of their heterogeneity, which vary in their urban activities, energy supply, infrastructure stock, and commuting patterns. The methodology for constructing bottom-up MAC curves for cities is presented for technologies that offer fuel switching and/or energy efficiencies, while considering technology lifetimes, city-specific... [more]

The rapid development of modern society has resulted in an increased demand for energy, mainly from fossil fuels. The use of this source of energy has led to the accumulation of carbon dioxide (CO₂) in the atmosphere. In this context, microalgae culturing may be an effective solution to reduce the CO₂ concentration in the atmosphere, since these microorganisms can capture CO₂ and, simultaneously, produce bioenergy. This work consists of a techno-economic assessment of a microalgal production facility integrated in a petrochemical complex, in which established infrastructure allows efficient material and energy transport. Seven different scenarios were considered regarding photosynthetic, lipids extraction and anaerobic digestion efficiencies. This analysis has demonstrated six economically viable scenarios able to: (i) reduce CO₂ emissions from a thermoelectric power plant; (ii) treat domestic wastewaters (which were used as culture medium); and (iii) produce lipids and electrical and... [more]

A ground-coupled heat pump (GCHP) system used to provide the space heating for an office room is a renewable, high performance technology. This paper discusses vapour compression-based HP systems, briefly describing the thermodynamic cycle calculations, as well as the coefficient of performance (COP) and CO₂ emissions of a HP with an electro-compressor and compares different heating systems in terms of energy consumption, thermal comfort and environmental impact. It is focused on an experimental study performed to test the energy efficiency of the radiator or radiant floor heating system for an office room connected to a GCHP. The main performance parameters (COP and CO₂ emissions) are obtained for one month of operation of the GCHP system, and a comparative analysis of these parameters is presented. Additionally, two numerical simulation models of useful thermal energy and the system COP in heating mode are developed using the Transient Systems Simulation (TRNSYS) software. Finally, t... [more]

Nanoscale FeS₂ was synthesized via a simple hydrothermal method and was decorated by hydrothermal carbonization (FeS₂@C). The structural properties of the synthesized materials detected by X-ray diffraction (XRD), together with the morphologies characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) indicated that the hydrothermal carbonization only had an impact on the morphology of pyrite. Additionally, the electrochemical performance of the coated pyrite in Li/FeS₂ batteries was evaluated by galvanostatic discharge-charge tests and electrochemical impedance spectroscopy (EIS). The results showed that the initial capacity of FeS₂@C was 799.2 mAh·g−1 (90% of theoretical capacity of FeS₂) and that of uncoated FeS₂ was only 574.6 mAh·g−1. XRD and ultraviolet (UV) visible spectroscopy results at different depths of discharge-charge for FeS₂ were discussed to clarify the electrochemical mechanism, which play an important part in Li/FeS₂ batteries.

Natural gas hydrate accumulations were confirmed in the Dongsha Area of the South China Sea by the Guangzhou Marine Geological Survey 2 (GMGS2) scientific drilling expedition in 2013. The drilling sites of GMGS2-01, -04, -05, -07, -08, -09, -11, -12, and -16 verified the existence of a hydrate-bearing layer. In this work gas production behavior was evaluated at GMGS2-8 by numerical simulation. The hydrate reservoir in the GMGS2-8 was characterized by dual hydrate layers and a massive hydrate layer. A single vertical well was considered as the well configuration, and depressurization was employed as the dissociation method. Analyses of gas production sensitivity to the production pressure, the thermal conductivity, and the intrinsic permeability were investigated as well. Simulation results indicated that the total gas production from the reference case is approximately 7.3 × 10⁷ ST m³ in 30 years. The average gas production rate in 30 years is 6.7 × 10³ ST m³/day, which is much higher... [more]

This paper describes the reduced capacity of the inrush current suppressor using a matrix converter (MC) in a large-capacity wind power generation system (WPGS) with two squirrel-cage induction machines (SCIMs). These SCIMs are switched over depending on the wind speed. The input side of the MC is connected to the source in parallel. The output side of the MC is connected in series with the SCIM through matching transformers. The modulation method of the MC used is direct duty ratio pulse width modulation. The reference output voltage of the MC is decided by multiplying the SCIM current with the variable control gain. Therefore, the MC performs as resistors for the inrush current. Digital computer simulation is implemented to confirm the validity and practicability of the proposed inrush current suppressor using PSCAD/EMTDC (power system computer-aided design/electromagnetic transients including DC). Furthermore, the equivalent resistance of the MC is decided by the relationship betwee... [more]

Electric load forecasting is an important issue for a power utility, associated with the management of daily operations such as energy transfer scheduling, unit commitment, and load dispatch. Inspired by strong non-linear learning capability of support vector regression (SVR), this paper presents an SVR model hybridized with the differential empirical mode decomposition (DEMD) method and quantum particle swarm optimization algorithm (QPSO) for electric load forecasting. The DEMD method is employed to decompose the electric load to several detail parts associated with high frequencies (intrinsic mode function—IMF) and an approximate part associated with low frequencies. Hybridized with quantum theory to enhance particle searching performance, the so-called QPSO is used to optimize the parameters of SVR. The electric load data of the New South Wales (Sydney, Australia) market and the New York Independent System Operator (NYISO, New York, USA) are used for comparing the forecasting perfor... [more]