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Records with Type: Published Article
4201. LAPSE:2023.35319
Unusual Water Flow in Ultra-Tight Porous Media: Integration of Profession and Innovation
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: nanoconfinement, pore network, Simulation, viscosity, wettability
Hydraulic fracturing is an effective method for stimulating reservoirs, making the economic development of ultra-tight shale gas and coalbed methane reservoirs possible. These formations are rich in nanopores, in which the fracturing fluid, such as fresh water, the flow, and the behavior of this flow differ significantly from those described in the classic Navier-Stokes formula. In bulk space, the interaction force exerted by the solid phase can be ignored, but the solid−fluid interaction plays a dominant role in nanoconfinement spaces in which the pore size is comparable to the molecular diameter. Nanoconfined water molecules tend to approach the water-wet pore surface, enhancing the water viscosity, which is a key parameter affecting the water flow capacity. Conversely, water molecules tend to stay in the middle of nanopores when subjected to a hydrophobic surface, leading to a decrease in viscosity. Thus, nanoconfined water viscosity is a function of the strength of the surface−flui... [more]
4202. LAPSE:2023.35318
Multi-Point Flux MFE Decoupled Method for Compressible Miscible Displacement Problem
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: compressible miscible displacement, decoupled method, error analysis, multi-point flux MFE, numerical experiments
In this paper, a multi-point flux mixed-finite-element decoupled method was considered for the compressible miscible displacement problem. For this compressible problem, a fully discrete backward Euler scheme was proposed, in which the velocity and pressure equations were decoupled by a multi-point flux MFE method using BDM1 elements combined with a trapezoidal quadrature rule. The concentration equation was handled by a standard FE method. The error analysis for velocity, pressure, and concentration were rigorously derived. Numerical experiments to verify the convergence rates and simulate the miscible displacement problem of a water−oil system were presented.
4203. LAPSE:2023.35317
Microwave-Assisted Phytochemical Extraction from Walnut Hull and Process Optimization Using Box−Behnken Design (BBD)
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: antioxidant, conventional method, microwave-assisted extraction, walnut hull
The walnut green hull is an agro-waste, a source of natural dye and volatile compounds with various biological activities, but the main challenge with the conventional extraction method is the quality and quantity of the volatile compound (dye) extraction from walnut hull waste. The objective of this research work is to use microwave-assisted extraction (MAE) as an emerging technology. Further, the MAE process was optimized using a Box−Behnken Design (BBD) of response surface methodology (RSM). The variables in MAE process optimization were microwave power, microwave time, solvent volume, and raw material particle size. The result indicated that MAE produces a higher extraction yield compared to the conventional method. The RSM analyses showed an increase in extract yield, total phenolic content, and total flavonoid content, along with antioxidant activity. The optimized condition parameters of MAE were reported to be 363.64-watt microwave power, 3.133 min, 39.999 mL/g solvent volume,... [more]
4204. LAPSE:2023.35316
A Method of Reducing Friction and Improving the Penetration Rate by Safely Vibrating the Drill-String at Surface
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: drill-string mechanics, friction reduction, petroleum drilling, vibration
Drill-string axial vibration at the surface technology is proposed to reduce the friction between the drill-string and the borehole wall, and to improve load transfer efficiency, the rate of penetration (ROP), and the extended-reach limit of a horizontal well. An analytical framework utilizing the “soft-string” model is constructed. The results obtained from numerical simulations reveal that during the slide drilling operation, the drill-string experiences an axial stick−slip motion, and the weight on bit (WOB) undergoes periodic oscillations. The conventional calibration method of the WOB in the weight indicator gauge is not applicable when the ROP is low. After applying axial vibration on the drill-string at the surface, the WOB increases and becomes smooth because of a release of friction. The amplitude and frequency of the exciting force are the main factors affecting surface vibration effectiveness. There is an optimal frequency for a given case (10 Hz in this paper). This means t... [more]
4205. LAPSE:2023.35315
Circuit Breaker Fault Diagnosis Method Based on Coil Current Time Sequence Phase Trajectory Characteristics
April 28, 2023 (v1)
Subject: Process Control
Keywords: breaking coil current signal, circuit breaker, first-order forward differencing, phase space reconstruction, phase trajectory
The traditional circuit breaker fault diagnosis method suffers from insufficient feature information extraction and is easily affected by abnormal signal acquisition. To address this, this paper introduces the phase space reconstruction algorithm to reconstruct the current signal for fault diagnosis based on phase trajectory features. The proposed method uses a first-order forward differencing method and mutual information method to process abnormal data and select the parameters of the reconstruction, then extract overall and local inflection point features to construct a fault feature set. The support vector machine algorithm-based model is trained and tested using actual samples, and the results show that the proposed method can adaptively sample anomalous signals, exhibit strong robustness, and significantly improve the accuracy of fault classification.
4206. LAPSE:2023.35314
An Enhanced Version of MDDB-GC Algorithm: Multi-Density DBSCAN Based on Grid and Contribution for Data Stream
April 28, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: clustering analysis, contribution, data stream, DBSCAN, grid density, MDDSDB-GC
With the continuous enrichment of big data technology application scenarios, the clustering analysis of a data stream has become a research hotspot. However, the existing data stream clustering algorithms usually have some defects, such as inability to cluster arbitrary shapes, difficulty determining some important parameters, and “static” clustering. In this study, a novel algorithm MDDSDB-GC is innovated. It selected MDDB-GC as the original algorithm that cannot deal with a data stream. In MDDSDB-GC, the calculation methods of contribution, grid density, and migration factor are effectively improved, and other parts are adjusted accordingly. The experiments show that MDDSDB-GC retains the advantage of MDDB-GC and obtains the ability to cluster an analysis for a data stream. At the same time, it effectively overcomes the above conventional defects, and its overall performance is better.
4207. LAPSE:2023.35313
Analysis of Dynamic Load Characteristics of Accelerated Pavement Testing Equipment Based on Virtual Prototype Model
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: accelerated pavement test, dynamic axle load, multi-body dynamics, Simulation
The purpose of this paper is to study the actual dynamic load characteristics of a full-scale Accelerated Pavement Test (APT) device called Natural Environment-Automatically Loaded Track (NE-ALT) during its operation. The NEALT uses hydraulic and support reaction forces to apply axle loads, which are somewhat different from real trucks. Therefore, in order to ensure the accuracy of the loading parameters of the device, it is necessary to analyze the dynamic load characteristics of the device during operation. In this paper, a virtual prototype model of the device was established, and the important parameters, including vehicle speed and axle load, were set. The dynamic axle load, dynamic load coefficient, and influential factors of the NE-ALT were analyzed using the model at different speeds, hydraulic pressures, and road roughness. The results have shown that the dynamic axle load accuracy was most affected by speed, followed by road roughness, and then hydraulic cylinder pressure. Co... [more]
4208. LAPSE:2023.35312
Optimization of Spray-Drying Conditions of Microencapsulated Habanero Pepper (Capsicum chinense Jacq.) Extracts and Physicochemical Characterization of the Microcapsules
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: antioxidant capacity, Capsicum chinense, Optimization, polyphenols, spray drying
The Habanero pepper (Capsicum chinense Jacq.) is recognized worldwide for its unique organoleptic characteristics, as well as for its capsaicin content; however, other bioactive compounds, such as phenolic compounds with bioactive properties (mainly antioxidant capacity), have been extracted (ultrasound) and identified in this fruit. Moreover, the extracts obtained by ultrasound present a high sensitivity to environmental conditions, making spray drying a viable option to avoid the degradation of bioactive compounds while maintaining their properties after microencapsulation. Response surface methodology (RSM) has been used to optimize spray-drying conditions such as the inlet temperature (IT) and maltodextrin:extract (M:E) ratio. Thus, the objective of this work was to establish the optimal spray-drying conditions (IT and M:E) of a Habanero pepper extract with a final characterization of the spray-dried product. Results showed that the optimal spray-drying conditions included an IT =... [more]
4209. LAPSE:2023.35311
Single Particle Inductively Coupled Plasma Time-of-Flight Mass Spectrometry—A Powerful Tool for the Analysis of Nanoparticles in the Environment
April 28, 2023 (v1)
Subject: Materials
Keywords: ICP-TOFMS, nanoparticles, single particle analysis
Single-particle inductively coupled plasma-mass spectrometry (SP-ICP-MS) has emerged as an important tool for the characterization of inorganic nanoparticles (NPs) in the environment. Although most SP-ICP-MS applications rely on the quadrupole ICP-MS (ICP-QMS), it is limited by the slow scanning speed of the quadrupole. Recent advancements in instrumentation have led to the development of inductively coupled plasma time-of-flight mass spectrometry (ICP-TOF-MS) which offers a viable solution. In this review, we discuss the recent advances in instrumentation and methodology of ICP-TOF-MS, followed by a detailed discussion of the applications of SP-ICP-TOFMS in analyzing NPs in the environment. SP-ICP-TOFMS has the potential to identify and quantify both anthropogenic and natural NPs in the environment, providing valuable insights into their occurrence, fate, behavior, and potential environmental risks.
4210. LAPSE:2023.35310
Advancing Process Intensification with High-Frequency Ultrasound: A Mini-Review of Applications in Biofuel Production and Beyond
April 28, 2023 (v1)
Subject: Process Design
Keywords: biodiesel, biofuel, high-frequency ultrasound, microalgae cell disruption
High-frequency ultrasound (HFU) is an ultrasound technology with a frequency higher than 1000 kHz. It has become increasingly recognized as an emerging process intensification technology in various fields, such as biofuel production, carbon dioxide absorption, and wastewater treatment. HFU is seen as a potential intensifier technology for biofuel production, as its mechanisms, such as cavitational phenomena, microstreaming, and fountain formation, can benefit biofuel production. Previous research has shown that HFU can decrease the reaction time required for biofuel production, aid in lipid extraction, increase carbon dioxide absorption rates, and be effective in destroying pathogens in wastewater treatment. However, despite the potential benefits, there are limited reports on the use of HFU technology for biofuel production, which has led to uncertainties and constraints in its industrial deployment. These constraints include equipment design, economic analysis, and safety concerns, w... [more]
4211. LAPSE:2023.35309
The Optimization of Segmented Reaming Parameters and the Analysis of the Pressure Relief Effect in Impacted Coal Seams
April 28, 2023 (v1)
Subject: Materials
Keywords: impact ground pressure, large-diameter drilling, parameter optimization, roadway deformation, segmental reaming
This work focused on the insufficient or excessive pressure relief in large-diameter pressure relief by drilling. The influence of large-diameter pressure relief by drilling on the 6307 working face of the Tangkou coal mine on the roadway deformation was taken as the research background, with numerical simulations, indoor experiments, and on-site applications used. The influence of pressure relief drilling on roadway deformation was studied to propose segmented reaming pressure relief. The influences of parameters (e.g., reaming diameter, reaming depth, and borehole spacings) on the evolution characteristics of segmented reaming cracks and pressure relief were further investigated. The results showed that segmented reaming pressure relief reduced the roadway deformation and the peak elastic energy of coal in the impacted hazard area and improved the energy accumulation of the surrounding rocks of the roadway. The effect of segmented reaming pressure relief was positively correlated wit... [more]
4212. LAPSE:2023.35308
State Estimation in a Biodigester via Nonlinear Logistic Observer: Theoretical and Simulation Approach
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: bioreactor, observers, virtual sensors
The state variables in a biodigester are predicted using an unstructured model, and this study offers an analytical design of a Non-Linear Logistic Observer (NLLO), subsequently comparing its performance to that of other prominent state estimators. Because of variables such as temperature, pH, high pressure, volumetric organic load (VOC), and hydraulic retention time (HRT), among others, biodigester samples can be affected by the use of physical sensors, which are not always practical owing to their sensitivity to the type of sampling and external disturbances. The use of virtual sensors represents one approach to solving this issue. In this work, we suggest experimentally validating a mathematical model, then analytically designing a novel NLLO observer, and finally comparing the results to those obtained using a sliding-mode estimator and a Luenberger observer. By including online CH4 and CO2 measurements as inputs to the proposed observer, the local observability analysis demonstrat... [more]
4213. LAPSE:2023.35307
Layering Vibration Transfer Path Analysis of a Flexible Supported Gear System Based on the Vibration Power Flow Theory
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: gear dynamics, mechanical impedance, transfer path analysis, vibration isolation, vibratory power flow
In the marine gear system, the vibration of gears is transmitted to the ship foundation through shafts, bearings, housing, and isolators, and then the underwater noise is generated. Analyzing the vibration transfer properties and identifying the critical path can provide guidance to the low-noise design of the gear system. In this paper, a coupled gear-housing-foundation dynamic model is proposed for a flexible supported gear system, in which the flexibility of each subsystem and the coupling relationship between them are taken into account. The transferring process of gear vibration is divided into different layers between gears, shafts, bearings, housing, isolators, and ship foundation. Based on the vibration power flow (VPF) theory, detailed layering vibration transfer path analyses of the gear isolation coupled system are carried out for both location path and direction path, and the main paths are identified in a broad speed range. The results indicate that though the gear vibrati... [more]
4214. LAPSE:2023.35306
Economic Dispatch of Combined Heat and Power Plant Units within Energy Network Integrated with Wind Power Plant
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: CHP economic dispatch (CHPED), CHP process management, CHPED process, combined heat and power (CHP) system, wind energy system
Cogeneration, also known as a combined heat and power (CHP) system, produces both power and heat simultaneously. It reduces the operating costs and emissions by utilising waste heat from steam turbines and contributes to incapacitating the intermittency of renewable energy. The CHP-economic dispatch (CHP-ED) is needed to overcome the load dynamics as well as renewable intermittency. In this work, a CHP system connected with a wind power plant is considered for analysing the CHPED within a typical power system area. This study examines, the CHPED with and without a wind integrated energy network. The main objective of this work is to minimise the total operating cost, while meeting the generators’ constraints and prioritising the wind power output. The feasible operating region, valve point loading impact, and prohibited working regions of the CHP plants are taken while finding a CHPED solution with an integrated wind turbine. To find a CHPED solution, an optimisation algorithm was appl... [more]
4215. LAPSE:2023.35305
Research on the Failure Mechanisms and Strength Characteristics of Deeply Buried Mudstone under the Interaction of Water and Stress
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: deep mining, failure mechanism, mudstone, strength characteristic, Water
Mudstone is a widely occurring type of rock in deep mining, and it is crucial to understand its failure mechanisms and strength characteristics under the interaction of water and high stress to ensure the stability of deeply buried engineered mudstone. In this study, the composition and the structure of mudstone were obtained, and triaxial tests were conducted on mudstone under five different water contents and four different confining pressures using a triaxial servo press. The variation rules for the peak strength and residual strength were obtained, and the applicability of the strength criteria was analyzed through fitting. The results showed that both the peak strength and the residual strength decreased linearly with increasing water content, with the peak strength decreasing more rapidly. Both the peak strength and the residual strength increased with increasing confining pressure, with the residual strength increasing more rapidly. The decrease in strength was primarily due to... [more]
4216. LAPSE:2023.35304
An Innovative Sensor-Based Approach for Evaluating Performance of Flotation Circuit at the Expansion of Toromocho Copper Mine
April 28, 2023 (v1)
Subject: Materials
Keywords: bubble size, cell characterization, hydrodynamics, Optimization
Chinalco’s Toromocho mine, located in the Morococha district of Peru, treated 117,200 mtpd ores during last 10 years. It is currently undergoing expansion, treating approximately 52,740 mtpd of chalcopyrite ore since 2021. As with the commissioning of most large plants, the metallurgical performance levels produced after stability was achieved were below the design criteria; more specifically, the Cu overall recoveries were 80−82% compared with the design value of 85%, and the final concentrate Cu grades were 20−23% compared with the design value of 24% over the past 2 years. It is clear that the copper losses in the fine size fraction (<10 µm) were due to unoptimized hydrodynamics. To overcome this obstacle and improve overall performance, an innovative approach for flotation circuit evaluation was designed and set up, to improve understanding of the nature of the mineral losses, benchmark the cell hydrodynamics as a platform to improve flotation cell operation, and link the circui... [more]
4217. LAPSE:2023.35303
The Effect of Spray-Drying Conditions on the Characteristics of Powdered Pistacia lentiscus Leaf Extract
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: antioxidant activity, carrier type, phenolic content, Pistacia lentiscus, spray drying
is an evergreen shrub widely used in folk medicine due to the high biological potential of the leaves’ phenolic compounds. Since phenolic compounds are susceptible to degradation under different heat, light and oxygen conditions, various microencapsulation techniques, such as spray drying, can be used to increase their stability. The objective of this study was to examine the influence of different carriers (gum arabic (GA), maltodextrin 13−17 DE (MD), β-cyclodextrin (BCD) and their mixtures), carrier concentrations in feed (12.8, 16 and 19.2% (m/V)) and drying temperatures (120, 150 and 180 °C) on the physiochemical properties, total phenolic content (TPC) and antioxidant activity (AOA) of Pistacia lentiscus leaf extract powders. Product yields of powders ranged from 23.53 to 65.51%, moisture content from 2.89 to 12.03%, hygroscopicity up to 4.45 g/100 g, solubility from 27.11 to 86.84% and bulk density from 0.24 to 0.45 g/mL. All obtained powders had satisfactory physicochemical prop... [more]
4218. LAPSE:2023.35302
Prediction, Application, and Mechanism Exploration of Liquid−Liquid Equilibrium Data in the Extraction of Aromatics Using Sulfolane
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: aromatics extraction, COSMO-RS model, liquid–liquid equilibrium, quantum chemistry calculation, UNIQUAC model
Liquid−liquid equilibrium (LLE) data are critical for the design and optimization of processes for extracting aromatics. Partial LLE data for the non-aromatic−aromatic−sulfolane ternary system were acquired at 313.15 K and 101.3 kPa. The LLE data for the extraction of aromatics using sulfolane were predicted using the COSMO-RS model. Correspondingly, the predicted and experimental data were analyzed using the root mean square deviation (RMSD), distribution coefficient (D), and separation factor (S). The COSMO-RS model could better predict the LLE data for the extraction of aromatics by sulfolane. The results of quantum chemical calculation show that hydrogen bonds and van der Waals interactions between sulfolane−benzene and sulfolane−toluene were responsible for the strong selectivity of sulfolane for benzene and toluene over alkanes. The LLE data predicted by the COSMO-RS method using the UNIQUAC thermodynamic model were subjected to correlation analysis. The calculated RMSD values we... [more]
4219. LAPSE:2023.35301
Thermal Performance Evaluation for Two Designs of Flat-Plate Solar Air Heater: An Experimental and CFD Investigations
April 28, 2023 (v1)
Subject: Modelling and Simulations
Keywords: air gap, CFD modeling and thermal efficiency, natural convection, solar air heaters
The main objective of this research was to create two different configurations of a flat-plate solar air heater, namely, Conventional-Case A and Modified-Case B, and develop a three-dimensional computational fluid dynamics (CFD) model using ANSYS R15.0. The purpose of the CFD model was to simulate the heat transfer behavior of the proposed solar air heaters under unsteady conditions. The RNG k-ε turbulence model was employed for this CFD study. The experiments were conducted on sunny days, under the same conditions as the Egyptian climate. The results of the experiments show that the simulated CFD model and the measured outlet airflow temperatures, relative humidity, and velocities of the two tested solar air heaters were compared. The developed model made very satisfactory predictions. Moreover, the deviations between the average CFD outlet air temperatures and the experimental results were 7% and 7.8% for Case B and Case A, respectively. The CFD-simulated average relative humidity wa... [more]
4220. LAPSE:2023.35300
Modified Whale Algorithm-Based Optimization for Fractional Order Concurrent Diminution of Torque Ripple in Switch Reluctance Motor for EV Applications
April 28, 2023 (v1)
Subject: Process Control
Keywords: cosine adapted modified whale algorithm optimized fractional order proportional integral (MWAO FO-PI) control, speed tracking, switched reluctance motor (SRM), torque ripple
This work proposes a new multi-objective optimization technique for concurrent diminution of torque ripple with the regulation of the speed of a 75 Kilowatt, 8/6, 4-phase SRM based on a double close loop, modified whale algorithm optimized fractional order proportional integral (MWAO FO-PI) control with a commutation angle controller. The system is analyzed and designed in MATLAB/SIMULINK environment. First, the performance of MWAO is tested on 30-dimensional standard benchmark functions. It is found that MWAO performance is better when examined on 30-dimensional standard benchmark functions, compared with WOA, and another six recently proposed state-of-art functions. Then, a double loop control based on the MWAO FO-PI controller is designed and implemented for concurrent diminution of torque ripple with the regulation of the speed of a 75 Kilowatt, 8/6, 4-phase SRM with a commutation angle controller. It was found that the percentage improvement achieved in the combined objective opti... [more]
4221. LAPSE:2023.35299
An Analysis of Renewable Energy Sources for Developing a Sustainable and Low-Carbon Hydrogen Economy in China
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: China, fuzzy AHP, fuzzy TOPSIS, hydrogen economy, low-carbon energy, renewable energy sources
A significant effort is required to reduce China’s dependency on fossil fuels while also supporting worldwide efforts to reduce climate change and develop hydrogen energy systems. A hydrogen economy must include renewable energy sources (RESs), which can offer a clean and sustainable energy source for producing hydrogen. This study uses an integrated fuzzy AHP−fuzzy TOPSIS method to evaluate and rank renewable energy sources for developing a hydrogen economy in China. This is a novel approach because it can capture the uncertainty and vagueness in the decision-making process and provide a comprehensive and robust evaluation of the alternatives. Moreover, it considers multiple criteria and sub-criteria that reflect the environmental, economic, technical, social, and political aspects of RESs from the perspective of a hydrogen economy. This study identified five major criteria, fifteen sub-criteria, and six RES alternatives for hydrogen production. This integrated approach uses fuzzy AHP... [more]
4222. LAPSE:2023.35298
Good Practices Contributing to Cleaner Food Production? A Preliminary Survey Analysis Involving Wrocław-Poland Food Retail Sector
April 28, 2023 (v1)
Subject: Food & Agricultural Processes
Keywords: agrofood industry, good practices, product improvement, productivity, Sustainability
Good practices are among the direct/indirect components that influence agrofood safety knowledge, and occupying quality assurance control facets within the (agrofood) product industry. Cleaner production involves an integrated preventive environmental strategy applied to processes, products, and services, which increases overall efficiency, and reduces risks to humans/environment. However, ‘cleaner food production’ appears neither yet clearly defined nor well established. In this preliminary survey analysis, how good practices would contribute towards achieving cleaner food production in the context of food retail sector was performed. Specifically, Wrocław-Poland served as a case reference targeting managers/supervisors given their expected service, experience, and expertise. The sampling technique used was the judgment/purposive type, and the research instrument took the form of a questionnaire. Managers’/supervisors’ responses revealed significant differences (p < 0.05) across va... [more]
4223. LAPSE:2023.35297
Effect of Processing Technology on Mechanical Properties of HRB500 High-Strength Steel Bar Threading
April 28, 2023 (v1)
Subject: Materials
Keywords: cutting technology, high-strength steel bar, necking formation process, thread rolling process, unidirectional tensile test
The processing quality of steel bar thread has a large influence on its performance. Using the traditional thread processing technology, it is difficult to meet the requirements of steel bar thread processing with large diameter and high strength. A technical process for HRB500 high-strength steel bar thread processing, including face milling, rib stripping, chamfering, necking formation, and thread rolling, was proposed. The influences of cutting parameters on the cutting force of steel bar surface in face milling were analyzed by the finite element method. For the necking formation process, the effect of springback amount on necking formation was studied. The main parameters in rolling formation were analyzed and calculated, including extrusion pressure, rolling speed, and rolling feed. Experiments for uniaxial tensile of the processed high-strength steel bar threads were carried out. The results showed that cutting depth has the largest influence on the cutting force; the second is... [more]
4224. LAPSE:2023.35296
Isolation and Characterization of Novel Butachlor-Degrading Bacteria from Rice Paddy Soils
April 28, 2023 (v1)
Subject: Materials
Keywords: biodegradation, butachlor, degradation pathway, pesticide, soil bacteria
Four different bacteria capable of degrading butachlor, as well as five different syntrophic pairs of bacteria able to break down butachlor, were isolated from rice paddy soils in Korea. Genetic and phenotypic analyses were conducted to better understand their characteristics and behavior. All single isolates and syntrophic pairs were able to utilize butachlor as a sole carbon and energy source. Analysis of the 16S rRNA sequence showed that the isolates were related to members of the genus Rhodococcus and a new type of butachlor-degrading genus Sphingobium. The chromosomal DNA fingerprinting patterns of the butachlor-degrading bacteria and syntrophic pairs were analyzed using a technique called repetitive-sequence-based PCR (REP-PCR). The results showed that there were two different REP-PCR patterns found among the four independent butachlor-degrading bacteria, and ten strains of five different syntrophic pairs produced a total of eight distinct DNA fingerprints. Through the use of gas... [more]
4225. LAPSE:2023.35295
SAR-AD Method to Characterize Eight SARA Fractions in Various Vacuum Residues and Follow Their Transformations Occurring during Hydrocracking and Pyrolysis
April 28, 2023 (v1)
Subject: Energy Systems
Keywords: asphaltene solubility profile, hydrocracking, intercriteria analysis, SAR-AD, SARA composition, vacuum residue
Model compounds were used to provide some chemical boundaries for the eight-fraction SAR-ADTM characterization method for heavy oils. It was found that the Saturates fraction consists of linear and highly cyclic alkanes; the Aro-1 fraction consists of molecules with a single aromatic ring; the Aro-2 fraction consists of mostly 2 and 3-ring fused aromatic molecules, the pericondensed 4-ring molecule pyrene, and molecules with 3−5 rings that are not fused; and the Aro-3 fraction consists of 4-membered linear and catacondensed aromatics, larger pericondensed aromatics, and large polycyclic aromatic hydrocarbons. The Resins fraction consists of mostly fused aromatic ring systems containing polar functional groups and metallated polar vanadium oxide porphyrin compounds, and the Asphaltene fraction consists of both island- and archipelago-type structures with a broad range of molecular weight variation, aromaticity, and heteroatom contents. The behavior of the eight SAR-ADTM fractions during... [more]
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