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Showing records 28995 to 29019 of 43292. [First] Page: 1 1157 1158 1159 1160 1161 1162 1163 1164 1165 Last
28995. LAPSE:2023.10139
Experimental Study on Effects of RCSL and RCTL Combustion Chamber for Combustion Process of Highly Intensified Diesel Engine
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: combustion process, highly intensified single-cylinder diesel Engine, RCSL, RCTL
In order to optimize the combustion chamber of a highly intensified single-cylinder diesel engine, including improvement of the air utilization rate in the combustion chamber, optimization of the fuel/air mixture process, reduction of the soot emission in the cylinder, and obtainment of the optimal combustion performance parameters, a re-entrant combustion chamber with step-typed lip (RCSL) and a re-entrant combustion chamber with tilted lip (RCTL) were innovatively designed and the effects of the throat diameter on the combustion process was obtained through experiments. When the RCSL with a diameter of 72 mm worked, target for the Brake Mean Effective Pressure (BMEP) of 2.6 MPa could be achieved under the condition of excess air coefficient of 1.5~1.7. At the same time, this had the advantages of lower fuel consumption, lower exhaust temperature, lower smoke level, and shorter combustion duration. Under the same BMEP, the RCTL had lower fuel consumption, exhaust gas temperature and m... [more]
28996. LAPSE:2023.10138
Study on the Bending Effect and Rock Burst Mechanism of Middle Rock Pillars in Extremely Thick Subvertical Coal Seams
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: bending effect, high stress concentration, mining disturbance, nearly vertical coal seams, rock burst
Rock bursts occur in nearly vertical coal seam mines at shallow to moderate burial depths, which endangers safe mining. To study the rock burst mechanisms of nearly vertical and extremely thick coal seams, the characteristics of rock bursts were studied via on-site investigation, and a field test of in situ stress was carried out. The mechanical behavior of rock pillars in the middle of the B1+2 and B3+6 coal seams was analyzed using theoretical and numerical simulation methods. The results show that the horizontal maximum principal stress orientation and the nearly vertical coal seam strike were both 82°. The bending of the rock pillars occurred due to the horizontal unbalanced force, and a large amount of bending energy was accumulated within 50 m above the mining level. Rock pillars were bent toward the B1+2 mining goaf and exerted a reverse bending and squeezing effect on the B3+6 coal seam below the mining levels. In addition to the inclination and compression of the B3+6 coal sea... [more]
28997. LAPSE:2023.10137
Closed-Loop Agricultural Production and Its Environmental Efficiency: A Case Study of Sheep Wool Production in Northwestern Kyrgyzstan
February 27, 2023 (v1)
Subject: Environment
Keywords: Kyrgyzstan, management, quality systems, renewable energy sources, sheep wool, sustainable development
As a country with not only significant production potential but also fragmented land ownership, the Kyrgyz Republic struggles with environmental efficiency, which is a strategic element of environmental management in agricultural production. The objective of this study was to assess the environmental efficiency of sheep’s wool when used as a fertilizer in bean production in northern Kyrgyzstan. In this study, the efficiency indicator was taken to be GHG emissions per functional unit of product, using a proprietary methodology for calculating GHG emissions to determine the true value of this material as a source of soil nutrients and organic matter. Two experimental factors were used in the experiment: fertilizer type and fertilizer rate. Fertilization with sheep wool resulted in a 15% higher bean yield compared to when fertilized with mineral fertilizers at a comparable rate, converted to pure nitrogen. By using sheep wool as a source of mineral nutrients for the plants, the carbon foo... [more]
28998. LAPSE:2023.10136
Improved Frequency Control Strategy for Offshore Wind Farm Integration via VSC-HVDC
February 27, 2023 (v1)
Subject: Process Control
Keywords: DC capacitor, frequency regulation, kinetic energy, offshore wind farm, VSC-HVDC
Voltage source converter based high voltage DC system (VSC-HVDC) has become a very promising solution to integrate offshore wind farm. However, the equivalent inertia of the modern power system with large renewable energy integration becomes small, which will arouse some frequency stability problems. To tackle this problem, this paper proposes an improved frequency regulation strategy for VSC-HVDC integrated offshore wind farm. Firstly, in the frequency decrease stage, the rotor kinetic energy of wind turbines (WTs) is used to suppress the decrease of the frequency, and the control parameters are determined to make full use of the mechanical power and rotor kinetic energy of WTs, the frequency nadir is improved. Secondly, in the rotor speed recovery stage, the DC capacitors of VSC-HVDC are used to release power to compensate the deficiency value of wind farm output power and avoid the secondary frequency drop (SFD) problem. Lastly, the simulation is conducted in PSCAD/EMTDC to validate... [more]
28999. LAPSE:2023.10135
Microorganisms as New Sources of Energy
February 27, 2023 (v1)
Subject: Biosystems
Keywords: bioenergy, biomass waste, Hydrogen, microorganisms, renewable energy sources
The use of fossil energy sources has a negative impact on the economic and socio-political stability of specific regions and countries, causing environmental changes due to the emission of greenhouse gases. Moreover, the stocks of mineral energy are limited, causing the demand for new types and forms of energy. Biomass is a renewable energy source and represents an alternative to fossil energy sources. Microorganisms produce energy from the substrate and biomass, i.e., from substances in the microenvironment, to maintain their metabolism and life. However, specialized microorganisms also produce specific metabolites under almost abiotic circumstances that often do not have the immediate task of sustaining their own lives. This paper presents the action of biogenic and biogenic−thermogenic microorganisms, which produce methane, alcohols, lipids, triglycerides, and hydrogen, thus often creating renewable energy from waste biomass. Furthermore, some microorganisms acquire new or improved... [more]
29000. LAPSE:2023.10134
Research on the Topology and Control Strategy of a Novel Three-Port Converter
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: DC-DC converter, PR controller, Renewable and Sustainable Energy, three-port converter
A novel three-port converter (TPC) is proposed to meet the diversity of demand for electrical equipment in this paper. It interfaces a single input power port and two output ports. The proposed TPC can be viewed as two bidirectional DC-DC converters. With a different operation mode, the proposed TPC can output two DC voltages or a single DC and a single AC voltage. The topology and operation principal of the TPC is analyzed in detail. Moreover, the mathematic model of the TPC is derived. Then, by considering the dynamic response and disturbance suppression, a step by step PI and PR controller design process for TPC is also presented. Both the simulation and the experimental results validate the proposed method.
29001. LAPSE:2023.10133
Comparative Analysis on the Performance and Exhaust Gas Emission of Cars with Spark-Ignition Engines
February 27, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: combustion engines, emissions CO2, engine capacity, statistical analysis
Conventional fuels commonly used in cars with combustion engines and the effects of their combustion have a very negative impact on the state of the environment. The combustion of liquid fuels causes the introduction of many thousands of tons of CO2 and other harmful substances into the atmosphere every year. That is why the authorities of many countries are introducing more and more stringent emission standards for cars with internal combustion engines, and car manufacturers are trying to meet these standards. Therefore, the aim of the undertaken research was to compile and analyze the power of spark engines in individual capacity ranges, compression ratios, efficiency, CO2 emissions, dependence of combustion on engine capacity, dependence of CO2 emissions on engine capacity, and dependence of combustion on engine power. The conducted research also compared the level of average selected variables related to CO2 emission in terms of engine displacement by country of production using st... [more]
29002. LAPSE:2023.10132
New Liquid Chemical Hydrogen Storage Technology
February 27, 2023 (v1)
Subject: Materials
Keywords: ammonia borane, formic acid, hydrazine hydrate, hydrogen storage, metal catalysts
The liquid chemical hydrogen storage technology has great potentials for high-density hydrogen storage and transportation at ambient temperature and pressure. However, its commercial applications highly rely on the high-performance heterogeneous dehydrogenation catalysts, owing to the dehydrogenation difficulty of chemical hydrogen storage materials. In recent years, the chemists and materials scientists found that the supported metal nanoparticles (MNPs) can exhibit high catalytic activity, selectivity, and stability for the dehydrogenation of chemical hydrogen storage materials, which will clear the way for the commercial application of liquid chemical hydrogen storage technology. This review has summarized the recent important research progress in the MNP-catalyzed liquid chemical hydrogen storage technology, including formic acid dehydrogenation, hydrazine hydrate dehydrogenation and ammonia borane dehydrogenation, discussed the urgent challenges in the key field, and pointed out t... [more]
29003. LAPSE:2023.10131
Fractal Characteristics of Pore-Throats Structure and Quality Evaluation of Carbonate Reservoirs in Eastern Margin of Pre-Caspian Basin
February 27, 2023 (v1)
Subject: Environment
Keywords: capillary pressure, carbonate rock, fractal dimension, pore-throats structure, reservoir classification and evaluation
The Carboniferous reservoir KT-II layer in the Eastern margin of the Pre-Caspian Basin was formed in the open platform sedimentary environment and marked by a complicated pore-throats structure. Understanding the main controls on the carbonate reservoir quality is of great significance for reservoir classification and a relevant production prediction. This study focuses on revealing reservoir pore-throats structure’s fractal characteristics by analyzing the mercury intrusion capillary pressure (MICP), with the integration of the pore-throats radius’ distribution data. The relationship between fractal dimensions and reservoir parameters such as physical properties, mercury median saturation pressure (Pc50) and the proportion of large-size (radius > 0.1 μm) pores demonstrate that the lower fractal dimension corresponds not only to core plug samples with higher permeability, but also to lower Pc50 and a higher proportion of large pore-throats. Three classes of carbonate reservoir with dif... [more]
29004. LAPSE:2023.10130
Fault Detection and Identification of Furnace Negative Pressure System with CVA and GA-XGBoost
February 27, 2023 (v1)
Subject: System Identification
Keywords: canonical variable residual analysis, Fault Detection, furnace negative pressure, reconstructed variable contribution, XGBoost
The boiler is an essential energy conversion facility in a thermal power plant. One small malfunction or abnormal event will bring huge economic loss and casualties. Accurate and timely detection of abnormal events in boilers is crucial for the safe and economical operation of complex thermal power plants. Data-driven fault diagnosis methods based on statistical process monitoring technology have prevailed in thermal power plants, whereas the false alarm rates of those methods are relatively high. To work around this, this paper proposes a novel fault detection and identification method for furnace negative pressure system based on canonical variable analysis (CVA) and eXtreme Gradient Boosting improved by genetic algorithms (GA-XGBoost). First, CVA is used to reduce the data redundancy and construct the canonical residuals to measure the prediction ability of the state variables. Then, the fault detection model based on GA-XGBoost is schemed using the constructed canonical residual va... [more]
29005. LAPSE:2023.10129
Experimental Study on the Effect of Bedding on the Fracture Process Zone of Shale
February 27, 2023 (v1)
Subject: Materials
Keywords: DIC, fracture process zone, high shear strain, NSCB, shale
The conventional fracture in shale hydraulic fracturing belongs to the type-I fracture, and the size of the fracture process zone (FPZ) is an important index to measure the fracability of rock mass. This index is also one of the feasible entry points to study the complexity of the fracture network. In order to visually observe the type-I FPZ at the tip of shale fractures, and to study the relationship between the mechanical properties, the shape and size of the FPZ, and the bedding structure, Notched Semi-Circular Bend (NSCB) tests were conducted with three typical fracture direction-bedding orientations (splitter, arrester, divider). The digital image correlation (DIC) method was used to realize the intuitive observation of the real fracture process and the FPZ near the fracture tip. The test found that the FPZ of shale is narrow and long as a whole and is “flame-like”. The height-to-length ratio of the FPZ at the fracture tip determines whether bending and deflection happen between t... [more]
29006. LAPSE:2023.10128
Experimental Thermal Response Study of Multilayered, Encapsulated, PCM-Integrated Building Construction Materials
February 27, 2023 (v1)
Subject: Materials
Keywords: building construction material, convective heating and cooling, experimental investigation, phase change material (PCM), thermal analysis, thermal energy storage (TES), thermal test rig
Thermal energy storage integration using phase change materials (PCMs) in buildings has great potential for energy conservation and greenhouse gas (GHG) emission reduction. Cutting-edge research and innovative ideas are required when using multilayered PCMs within typical construction materials to take advantage of their heat storage capability over a wide temperature range within buildings. This current study was carried out to experimentally test the efficacy of using dual PCMs RT28HC and RT21HC with different melting temperature ranges (28 °C and 21 °C) under variable thermal loading. The transient thermal response of various PCM-based configurations of concrete and cement blocks at different temperature inputs was obtained to determine the effectiveness of dual PCMs and their optimized configuration under experimental laboratory conditions. The range of the temperature input was varied from 22 °C to 50 °C, suitable for hot climatic conditions such as those in Pakistan. Laboratory a... [more]
29007. LAPSE:2023.10127
Adaptive PI and RBFNN PID Current Decoupling Controller for Permanent Magnet Synchronous Motor Drives: Hardware-Validated Results
February 27, 2023 (v1)
Subject: Process Control
Keywords: adaptive control, parameter uncertainties, PID control, PMSM, proportional-integral (PI) control, RBFNN-PID term
This study presents an adaptive proportional-integral (PI) and radial basis function neural network proportional-integral-derivative (PID) current control solution for permanent magnet synchronous motor (PMSM) drives. The proposed controller includes four controls: a decoupling term, a PI term, a supervision term, and a radial basis neural network-PID (RBFNN-PID) term. The first control term makes up the nonlinear factors, the second automatically adjusts the control gains, the third guarantees the system stability, and the fourth optimizes the PID parameters to achieve optimal system performance. Unlike off-line tuned PID controllers, the adaptive controller includes an adaptive tuning method for the on-line adjustment of control gain based on the gradient descent strategy. Therefore, it can be adjusted and handle the uncertainty of any system parameters. The program is not only simple and easy to be implemented but also ensures the accuracy and rapidity of the tracking speed. The con... [more]
29008. LAPSE:2023.10126
Tariff Menus to Avoid Rebound Peaks: Results from a Discrete Choice Experiment with Swiss Customers
February 27, 2023 (v1)
Subject: Process Control
Keywords: choice experiment, demand response, demand side management, direct load control, dynamic electricity tariff, electricity, rebound peak, time-of-use tariff, willingness to accept
While automation helps to increase load-shifting, the combination of automation with time-of-use (TOU) or critical-peak prices (CPP) may lead to rebound peaks at the beginning of low-tariff periods which may exceed the original peak. Using a discrete choice experiment with a representative sample of 696 Swiss consumers, we find that a tariff menu including (i) a flat price with direct load control (DLC) and (ii) a time-of-use tariff without direct load control could avoid this problem. The majority (57%) of mostly younger customers, which could be interested in automation would likely sign up for a DLC with flat prices, while the remaining customers would either chose a TOU tariff with manual load control (28%) or avoid any form of load-shifting incentives (15%).
29009. LAPSE:2023.10125
Analysis, Design, and Experimental Verification of a Parallel Wireless Power and Data Transmission Method for Rotary Steering Systems
February 27, 2023 (v1)
Subject: Process Design
Keywords: crosstalk interference, data transfer, rotary steering system, wireless power transfer (WPT)
In the rotary steering system of oil drilling, both power and data transmission are needed. This paper presents a parallel power and data transmission method for a rotating steering system with output voltage control. To reduce the size of the system, power and data are transmitted through the same rotational coupling mechanism. A power transfer resonance circuit is used to suppress the influence of the power transfer on data transmission. Therefore, crosstalk interference between the power and the data transmission channel is negligible. The experimental prototype is built, and the feasibility of the data transfer method and the closed-loop control method is verified. The experimental results are in good agreement with the theoretical analysis.
29010. LAPSE:2023.10124
A Review of Thermochemical Conversion of Waste Biomass to Biofuels
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: Biofuels, gasification, liquefaction, pyrolysis, torrefaction, transesterification
Biofuels are sustainable alternatives to fossil fuels because of their renewable and low-cost raw materials, environmentally friendly conversion technologies and low emissions upon combustion. In addition, biofuels can also be upgraded to enhance their fuel properties for wide applicability in power infrastructures. Biofuels can be produced from a wide variety of biomasses through thermochemical and biological conversion processes. This article provides insights into the fundamental and applied concepts of thermochemical conversion methods such as torrefaction, pyrolysis, liquefaction, gasification and transesterification. It is important to understand the physicochemical attributes of biomass resources to ascertain their potential for biofuel production. Hence, the composition and properties of different biomass resources such as lignocellulosic feedstocks, oilseed crops, municipal solid waste, food waste and animal manure have been discussed. The properties of different biofuels such... [more]
29011. LAPSE:2023.10123
Synthesis of Ultra-Thin Two-Dimensional SiC Using the CVD Method
February 27, 2023 (v1)
Subject: Materials
Keywords: 2D materials, boron additives, CVD, SiC
Two-dimensional materials have shown great potential for applications in many research areas because of their unique structures, and many 2D materials have been investigated since graphene was discovered. Ultra-thin SiC layers with thicknesses of 8−10 nm and multi-layer SiC films were designed and fabricated in this study. First, the multi-layer SiC films were obtained by the chemical vapor deposition (CVD) method with the addition of boron elements. We found that boron additives showed novel effects in the CVD process. Boron can promote the formation and crystallization of SiC films at low temperatures (1100 °C), resulting in the separation of SiC films into multi-layers with thicknesses of several nanometers. In addition, a formation mechanism for the 2D SiC layers is proposed. The boron mostly aggregated spontaneously between the thin SiC layers. Photoluminescence spectroscopy results showed that the SiC films with multi-layer structures had different bandgaps to normal SiC films. T... [more]
29012. LAPSE:2023.10122
Low−Harmonic Control Strategy of a Dual Three−Phase Synchronous Reluctance Motor Based on Three−Vector Synthesis
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: direct torque control, dual three–phase synchronous reluctance motor, flywheel battery, harmonic suppression, three–vector synthesis
Dual three−phase synchronous reluctance motors (DTP−SynRM) have the advantages of simple structure, high power density, fast dynamic response, and small torque ripple, and have broad application prospects in flywheel batteries. However, the synchronous reluctance motor has no permanent magnet, and the inductance value will change with the current change in actual operation. Direct torque control (DTC) is more suitable for the control strategy of dual three−phase synchronous reluctance motors because of its low dependence on motor parameters. However, traditional direct torque control uses a large vector control motor within one control period, which can not suppress the inherent 5th and 7th current harmonics in the motor. A new harmonic suppression method is proposed in this paper: that is, using a low harmonic vector to replace a large vector in traditional direct torque control, which can be synthesized by adjusting the action time and order of three adjacent large vectors within one... [more]
29013. LAPSE:2023.10121
Numerical Investigation on Thermal−Hydraulic Performance of a Printed Circuit Heat Exchanger for Liquid Air Energy Storage System
February 27, 2023 (v1)
Subject: Modelling and Simulations
Keywords: compressed air–water heat transfer, Computational Fluid Dynamics, printed circuit heat exchanger, thermal–hydraulic performance, wavy channel
A printed circuit heat exchanger (PCHE) is utilized to cool the compressor inlet air to increase the compression efficiency in a liquid air energy storage and liquid natural gas (LNG) coupled system, which can offer large-scale energy storage with significantly improved exergy efficiency and round-trip efficiency. In this work, the effect of pressure of air, incline angle, and hydraulic diameter on the performance of a compressed air−water PCHE with a semicircle cross-section was studied. The results show that PCHE can realize the intermediate cooling of air compression in the liquid air energy storage system, and the pressure variation of air shows a limited effect on the heat transfer of PCHE; however, the hydraulic diameter and the incline angle both affect the heat transfer and the flow resistance of PCHE, and the best incline angle is 15°.
29014. LAPSE:2023.10120
Impact of Passive-Components’ Models on the Stability Assessment of Inverter-Dominated Power Grids
February 27, 2023 (v1)
Subject: Modelling and Simulations
Keywords: inverter-based resources, line modelling, load modelling, modular multilevel converters, power system analysis, small-signal stability, transient stability
Power systems are experiencing some profound changes, which are posing new challenges in many different ways. One of the most significant of such challenges is the increasing presence of inverter-based resources (ibrs), both as loads and generators. This calls for new approaches and a wide reconsideration of the most commonly established practices in almost all the levels of power systems’ analysis, operation, and planning. This paper focuses specifically on the impacts on stability analyses of the numerical models of power system passive components (e.g., lines, transformers, along with their on-load tap changers). Traditionally, loads have been modelled as constant power loads, being this both a conservative option for what concerns stability results and a computationally convenient simplification. However, compared to their counterparts above, in some operating conditions ibrs can effectively be considered real constant power loads, whose behaviour is much more complex in terms of t... [more]
29015. LAPSE:2023.10119
Modular Multilevel Converter for a Linear Generator for Wave Energy Converter
February 27, 2023 (v1)
Subject: Process Control
Keywords: linear generator, modular multilevel converter, wave energy converter
In this paper we propose a modular multilevel converter for a linear generator for a wave energy converter. The coils of this generator are individually controlled to improve energy harvesting performance. This topology involves two stages. The first stage uses a full-bridge to control the harvested current with a reference generated by means of an MPPT method. The second stage uses a half-bridge to control the voltage of the DC-link and the output current. Furthermore, multilevel modular converters allow the generation of a medium DC voltagethat reduces the losses in energy transmission lines from offshore to a coupling common point on the shore.
29016. LAPSE:2023.10118
Theoretical Prediction on Hydraulic Lift of a Coandă Effect-Based Mining Collector for Manganese Nodule
February 27, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Coandă effect, collector, curved wall jets, deep-sea mining, manganese nodules, pick-up device
The undersea collecting vehicle is one of the three main parts in the deep-sea exploitation system. The Coandă effect-based collector picks up manganese nodules by providing an adverse pressure difference over the nodule, through the jet flowing around a curved wall. In order to overcome the drawbacks of repeated prototyping and experimenting in the traditional design procedure of the Coandă effect-based collector, the theoretical guide should be well placed to ensure correct design of the strongly related parameters of the collector. In this paper, a simplified model of curved wall jets was developed and the solution of approximate closed form was obtained to predict the lift force of the nodules. The variational tendencies of velocity, pressure and single-particle lift index perpendicular to the curved wall were investigated and the Coandă effects were found to be stronger with higher initial velocity, higher non-dimensional jet slot height and lower non-dimensional wall height. A CF... [more]
29017. LAPSE:2023.10117
Flexible Short-Term Electricity Certificates—An Analysis of Trading Strategies on the Continuous Intraday Market
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: bidding strategies, day-ahead market, electricity prices, intraday electricity market, renewable energies
The most important price for short-term electricity trading in Germany is the day-ahead auction price, which is provided by EPEX SPOT. Basically, short-term fluctuating electricity prices allow cost-optimized production planning by shifting electricity-intensive processes to times of favorable electricity prices. However, the day-ahead price as the outcome of an auction is not directly tradeable afterwards. We propose short-term flexible electricity certificates that pass on the day-ahead auction prices plus a premium for the supplier, enabling users to plan electricity consumption based on realized day-ahead auction prices. We analyze the supplier’s problem of delivering electricity based on such certificates. The supplier can adjust the required electricity volume after the close of the day-ahead auction on the continuous intraday market. We analyze the price fluctuations in this market in relation to the day-ahead price and propose different trading strategies. Using the order book... [more]
29018. LAPSE:2023.10116
Using Mathematical Modeling to Evaluate the Performance of a Passenger Car When Operating on Various Fuels
February 27, 2023 (v1)
Subject: Environment
Keywords: Alternative Fuels, environmental performance, fuel economy, LPG, mathematical model, spark ignition engine
This article presents the results of experimental and computational studies of the performance of a car with a gasoline engine with spark ignition when retrofitted with a system of liquefied petroleum gas (LPG). To analyze the impact of the use of LPG instead of gasoline, the mathematical model of the car’s movement according to the modes of the European driving cycle has been refined. It was established that when using LPG for a car in the driving cycle, fuel consumption in energy units decreases by 10.38%. Gas consumption, determined in mass units, is lower than gasoline consumption. In load modes, this difference is about 8% and in idle mode, it reaches 16−18%. The adequacy of the mathematical model is confirmed by experimental studies of the car on modern equipment with the measurement of fuel efficiency and environmental performance in motion, according to the specified cycle. The deviation of the calculated fuel consumption from the results of experimental studies does not exceed... [more]
29019. LAPSE:2023.10115
Recent Advances in Methane Pyrolysis: Turquoise Hydrogen with Solid Carbon Production
February 27, 2023 (v1)
Subject: Energy Systems
Keywords: catalytic decomposition of methane, methane pyrolysis, turquoise hydrogen
Beside steam reforming, methane pyrolysis is an alternative method for hydrogen production. ‘Turquoise’ hydrogen with solid carbon is formed in the pyrolysis process, contrary to ‘grey’ or ‘blue’ hydrogen via steam methane reforming, where waste carbon dioxide is produced. Thermal pyrolysis is conducted at higher temperatures, but catalytic decomposition of methane (CDM) is a promising route for sustainable hydrogen production. CDM is generally carried out over four types of catalyst: nickel, carbon, noble metal and iron. The applied reactors can be fixed bed, fluidized bed, plasma bed or molten-metal reactors. Two main advantages of CDM are that (i) carbon-oxide free hydrogen, ideal for fuel cell applications, is formed and (ii) the by-product can be tailored into carbon with advanced morphology (e.g., nanofibers, nanotubes). The aim of this review is to reveal the very recent research advances of the last two years achieved in the field of this promising prospective technology.
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