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Records with Type: Published Article
24417. LAPSE:2023.14717
Optimized Configuration of Diesel Engine-Fuel Cell-Battery Hybrid Power Systems in a Platform Supply Vessel to Reduce CO2 Emissions
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: diesel engine, fuel cell, hybrid power systems, hydrogen storage, Li-ion battery, ship power systems
The main objective of this paper is to select the optimal configuration of a ship’s power system, considering the use of fuel cells and batteries, that would achieve the lowest CO2 emissions also taking into consideration the number of battery cycles. The ship analyzed in this work is a Platform Supply Vessel (PSV) used to support oil and gas offshore platforms transporting goods, equipment, and personnel. The proposed scheme considers the ship’s retrofitting. The ship’s original main generators are maintained, and the fuel cell and batteries are installed as complementary sources. Moreover, a sensitivity analysis is pursued on the ship’s demand curve. The simulations used to calculate the CO2 emissions for each of the new hybrid configurations were developed using HOMER software. The proposed solutions are auxiliary generators, three types of batteries, and a proton-exchange membrane fuel cell (PEMFC) with different sizes of hydrogen tanks. The PEMFC and batteries were sized as contai... [more]
24418. LAPSE:2023.14716
High Specific Capacity of Lithium−Sulfur Batteries with Carbon Black/Chitosan- and Carbon Black/Polyvinylidene Fluoride-Coated Separators
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: Batteries, Carbon, chitosan, lithium–sulfur battery, polysulfides, polyvinylidene fluoride, separators
In this research, the shuttle effect and the low sulfur activation of lithium−sulfur batteries were mitigated by coating the cathode side of Celgard 2400 separators with mixtures of carbon black/chitosan or carbon black/polyvinylidene fluoride using the simple slurry technique. Carbon nanoparticles and the polar groups of the polymers were responsible for boosting the reaction kinetics of sulfur and the chemical and physical trapping of lithium polysulfides. The adsorption of sulfur species in the coated separators was confirmed by the morphologic changes observed in the AFM and SEM images and by the new elements presented in the EDX spectra after 100 charge/discharge cycles. The high intensity of the peaks in the cyclic voltammograms and the long plateaus in the discharge profiles support the improvement in the reaction kinetics. The batteries with the carbon black/chitosan- and carbon black/polyvinylidene fluoride-coated separators reached high specific discharge capacities of 833 an... [more]
24419. LAPSE:2023.14715
Immobilizing Enzymes on a Commercial Polymer: Performance Analysis of a GOx-Laccase Based Enzymatic Biofuel Cell Assembly
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: covalent immobilization, direct electron transfer, electrochemical stability, enzymatic biofuel cell, enzymes, glucose oxidase, green power, laccase, low-cost polymer, power generation
Enzymatic Biofuel Cell (EBC) represents a promising green source since it is capable of harvesting electricity from renewable and abundantly available biofuels using enzymes as catalysts. Nevertheless, nowadays long-term stability and low power output are currently the main concerns. To this end, several research studies focus on using complex tridimensional and highly expensive nanostructures as electrode support for enzymes. This increases cell performance whilst drastically reducing the economic feasibility needed for industrial viability. Thus, this paper analyzes a novel flow-based EBC consisting of covalent immobilized GOx (bioanode) and Laccase (biocathode) on a commercial flat conductive polymer. A suitable immobilization technique based on covalent ligands is carried out to enhance EBC durability. The experimental characterization demonstrates that the cell generates power over three weeks, reaching 590 mV and 2.41 µW cm−2 as maximum open circuit voltage and power density, res... [more]
24420. LAPSE:2023.14714
Numerical Simulation on the Structural Design of a Multi-Pore Water Diffuser during the External Ice Melting Process of an Ice Storage System
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: external ice melting system, heat transfer, ice storage system, VOF method, water diffuser
A water diffuser is a critical auxiliary equipment for an ice storage system during the external ice melting process. This paper proposes a linear multi-pore water diffuser for an ice storage system with 500 t of refrigeration capacity to enhance the performance of external ice melting. By establishing a three-dimensional two-phase volume of fluid (VOF) model, different structural designs of water diffusers for the ice storage device are numerically examined regarding the degree of turbulence, flow velocity, and pressure drop. The results show that the optimal water diffuser with five rows of trunk pipe and six perforated pores arranged in per row of branch pipe with a 4 mm diameter of perforated pores exhibiting a relatively lower degree of turbulence with a lower pressure drop compared with the other designs in this study. Meanwhile, the influence of the flow velocity on the ice melting process is also investigated by a numerical model of ice melting. It is found that the fed flow ve... [more]
24421. LAPSE:2023.14713
Best Practice in Government Use and Development of Long-Term Energy Transition Scenarios
March 1, 2023 (v1)
Subject: Planning & Scheduling
Keywords: clean energy transition, climate scenarios, energy modelling, energy planning, long-term energy scenarios
Long-term energy scenarios (LTES) have been serving as an important planning tool by a wide range of institutions. This article focuses on how LTES have been used (and also devised in some cases) in the government sector, and specifically how the new challenges and opportunities brought by the aspiration for the clean energy transition change the way that governments use LTES. The information tends to remain tacit, and a gap exists in understanding the way to enhance LTES use and development at the government level. To address this gap, we draw on the experience from national institutions that are leading the improvement in official energy scenario planning to articulate a set of overarching best practices to (i) strengthen LTES development, (ii) effectively use LTES for strategic energy planning and (iii) enhance institutional capacity for LTES-based energy planning, all in the context of new challenges associated with the clean energy transition. We present implementation experience... [more]
24422. LAPSE:2023.14712
The Strategy of Considering the Participation of Doubly-Fed Pumped-Storage Units in Power Grid Frequency Regulation
March 1, 2023 (v1)
Subject: Optimization
Keywords: chaotic particle swarm optimization, doubly-fed pumped-storage units, frequency regulation, unit combination
Facing the challenges of grid stability brought by the large-scale access of new energy to the grid, as one of the important means of frequency regulation of the grid, the doubly-fed pumped-storage units (DFPSU) have great practical significance in the study of the joint frequency regulation strategy with the thermal power unit (TPU). In order to reduce the frequency regulation pressure on the grid caused by the large-scale entry of new energy sources, this paper proposes a joint frequency regulation strategy for the TPU and DFPSU. Based on establishing the optimal scheduling model of the system, taking into account the minimum total operating cost and the optimal time as goals, the chaotic particle swarm optimization (CPSO) is proposed to solve the model. Finally, through MATLAB simulation, the relevant examples are studied and analyzed, and the simulation results verify that the joint frequency regulation strategy in this paper can effectively improve the frequency regulation perform... [more]
24423. LAPSE:2023.14711
In-Situ Synthesis of Sm0.5Sr0.5Co0.5O3-δ@Sm0.2Ce0.8O1.9 Composite Oxygen Electrode for Electrolyte-Supported Reversible Solid Oxide Cells (RSOC)
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: in-situ SSC@SDC, oxygen electrode, reversible solid oxide cell
Oxygen electrode has a crucial impact on the performance of reversible solid oxide cells (RSOC), especially in solid oxide electrolysis cell (SOEC) mode. Herein, Sm0.5Sr0.5Co0.5O3-δ@Sm0.2Ce0.8O1.9 (5SSC@5SDC) composite material has been fabricated by the in-situ synthesis method and applied as the oxygen electrode for RSOCs with scandium stabilized zirconia (SSZ) electrolyte. The phase structures, thermal expansion coefficients, and micromorphologies of 5SSC@5SDC have all been further analyzed and discussed. 5SSC@5SDC is composed of a skeleton with large SDC particles in the diameter range of 200~300 nm and many fine SSC nanoparticles coated on the skeleton. Thanks to the special microstructure of 5SSC@5SDC, the electrolyte-supported RSOC with SSC@SDC oxygen electrode shows a polarization resistance of only 0.69 Ω·cm2 and a peak power density of 0.49 W·cm−2 at 800 °C with hydrogen as the fuel in solid oxide fuel cell (SOFC) mode. In addition, the electrolysis current density of RSOC wi... [more]
24424. LAPSE:2023.14710
Grid-Connected PV System with Reactive Power Management and an Optimized SRF-PLL Using Genetic Algorithm
March 1, 2023 (v1)
Subject: Process Control
Keywords: Genetic Algorithm, grid-connected PV system, phase-locked loop, reactive power compensation
This paper presents a two-stage grid-connected PV system with reactive power management capability. The proposed model can send phase-shifted current to the grid during a low-voltage ride through (LVRT) to recover the voltage levels of the grid’s feeders. The novelty of the proposed algorithm, unlike the common methods, is that it does not need to disable the maximum power point tracking (MPPT) state while managing active and reactive power injection simultaneously. Moreover, the new method promotes a safety factor by offering overcurrent protection to the PV inverter. The phase-locked loop based on the synchronous reference frame (SRF-PLL) is optimized using a genetic algorithm (GA). The settling time of SRF-PLL’s step response is minimized, and the frequency dynamics are improved to enhance synchronization during LVRT. The system’s performance is tested and verified using MATLAB/Simulink simulations. The obtained results prove the effectiveness of the proposed control algorithm in ma... [more]
24425. LAPSE:2023.14709
Analysis and Design of a High-Efficiency SiC MOSFET 6-Phase Boost Rectifier
March 1, 2023 (v1)
Subject: Process Design
Keywords: AC–DC converter, multi-phase boost rectifier, offshore wind, SiC power semiconductors
In this paper, the analysis and the design of a high-efficiency power electronic conversion system for offshore wind applications are presented. This system is composed of a 6-phase AC−DC converter based on the SiC power semiconductors, to be used to control the achievable power from the wind turbine electrical generator. Thanks to the phase redundancy, the proposed boost rectifier is suitable for applications where reliability and fault tolerance capability are the main targets. To select the appropriate power semiconductor devices, voltage and current ratings have to be determined. After that, the power loss equations are derived in order to evaluate the conversion efficiency. To design the appropriate DC-bus capacitor configuration, an analytical investigation is carried out by estimating the DC-bus RMS current and the voltage ripple. Finally, the thermal sizing of the system is calculated to identify a suitable heatsink. To validate the proposed analysis, the analytical results are... [more]
24426. LAPSE:2023.14708
Automated Detection of Electric Energy Consumption Load Profile Patterns
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: dynamic clustering, time series analysis, user load profiles
Load profiles of energy consumption from smart meters are becoming more and more available, and the amount of data to analyse is huge. In order to automate this analysis, the application of state-of-the-art data mining techniques for time series analysis is reviewed. In particular, the use of dynamic clustering techniques to obtain and visualise temporal patterns characterising the users of electrical energy is deeply studied. The performed review can be used as a guide for those interested in the automatic analysis and groups of behaviour detection within load profile databases. Additionally, a selection of dynamic clustering algorithms have been implemented and the performances compared using an available electric energy consumption load profile database. The results allow experts to easily evaluate how users consume energy, to assess trends and to predict future scenarios.
24427. LAPSE:2023.14707
Ammonia and Biogas from Anaerobic and Sewage Digestion for Novel Heat, Power and Transport Applications—A Techno-Economic and GHG Emissions Study for the United Kingdom
March 1, 2023 (v1)
Subject: Process Design
Keywords: ammonia, anaerobic digestion, Fuel Cells, Hydrogen, nutrient recovery, sewage digestion, techno-economics, wastewater treatment plants
Anaerobic digestion (AD) and sewage sludge digestion (SD) plants generate significant quantities of ammoniacal nitrogen in their digestate liquor. This article assesses the economic viability and CO2 abatement opportunity from the utilisation of this ammonia under three scenarios and proposes their potential for uptake in the United Kingdom. Each state-of-the-art process route recovers ammonia and uses it alongside AD-produced biomethane for three different end goals: (1) the production of H2 as a bus transport fuel, (2) production of H2 for injection to the gas grid and (3) generation of heat and power via solid oxide fuel cell technology. A rigorous assessment of UK anaerobic and sewage digestion facilities revealed the production of H2 as a bus fleet transport fuel scenario as the most attractive option, with 19 SD and 42 AD existing plants of suitable scale for process implementation. This is compared to 3 SD/1 AD and 13 SD/23 AD existing plants applicable with the aim of grid inje... [more]
24428. LAPSE:2023.14706
Multi-Disciplinary Optimisation of Road Vehicle Chassis Subsystems
March 1, 2023 (v1)
Subject: Energy Systems
Keywords: analytical target cascading, collaborative optimisation, electric vehicle powertrain, multi-disciplinary optimisation, passive suspension
Two vehicle chassis design tasks were solved by decomposition-based multi-disciplinary optimisation (MDO) methods, namely collaborative optimisation (CO) and analytical target cascading (ATC). A passive suspension system was optimised by applying both CO and ATC. Multiple parameters of the spring and damper were selected as design variables. The discomfort, road holding, and total mass of the spring−damper combination were the objective functions. An electric vehicle (EV) powertrain design problem was considered as the second test case. Energy consumption and gradeability were optimised by including the design of the electric motor and the battery pack layout. The standard single-level all-in-one (AiO) multi-objective optimisation method was compared with ATC and CO methods. AiO methods showed some limitations in terms of efficiency and accuracy. ATC proved to be the best choice for the design problems presented in this paper, since it provided solutions with good accuracy in a very ef... [more]
24429. LAPSE:2023.14705
Effects of Hydrogeological Heterogeneity on CO2 Migration and Mineral Trapping: 3D Reactive Transport Modeling of Geological CO2 Storage in the Mt. Simon Sandstone, Indiana, USA
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: geochemical reactions, geological CO2 storage, hydrogeological heterogeneity, reactive transport simulation
We used three-dimensional (3D), high-resolution simulations facilitated by parallel computation to assess the effect of hydrogeological heterogeneity in the Mt. Simon Sandstone on CO2 plume evolution and storage and geochemical reactions in a portion of the Illinois Basin, Indiana. Two scenarios were selected to investigate the effects of the hydrogeological heterogeneity in 3D reactive transport simulations: a heterogeneous case with variable porosity and permeability, and a homogenous case with constant porosity and permeability. The initial pressure, temperature, and mineralogical distributions are consistently applied in both the heterogeneous case and the homogeneous case. Results indicate that including hydrogeological heterogeneity in 3D reservoir simulations for geological CO2 storage significantly impacts modeling results for plume migration patterns, CO2-water-mineral interaction, reservoir quality, and CO2 plume containment. In particular, results indicate that (1) the CO2 p... [more]
24430. LAPSE:2023.14704
Low-Carrier-Ratio Modulation Strategy Based on Improved Flux Ripple Model
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: current ripple suppression, improved flux ripple model, low-carrier-ratio modulation strategy, SPMSM
Since the quality of the direct and quadrature axis current (dq-axis) is an important performance indicator of a motor, the technique of flux ripple analysis is necessary to determine the appropriate working conditions for various voltage sequences and reduce current fluctuations. However, the traditional flux ripple model cannot analyze dq-axis flux ripples (except under no-load conditions). Therefore, it is unable to calculate the modulation ratio and voltage angle (angle between the reference vector and the q-axis) ranges to satisfy the given q-axis (or d-axis) current fluctuation requirement based on this model. To solve this problem, in this paper, we derived an improved flux ripple model by applying coordinate transformation to the traditional flux ripple model, which can be used to calculate the RMS (root mean square) value of the q-axis and the total flux ripple distribution within sector I under different modulation ratios and voltage angle ranges. The modulation ratio and vol... [more]
24431. LAPSE:2023.14703
EE-ISAC—Practical Cybersecurity Solution for the Energy Sector
March 1, 2023 (v1)
Subject: Energy Management
Keywords: applicability, cybersecurity, information sharing, organisational management, situational awareness, threat intelligence
A recent survey of cybersecurity assessment methods proposed by the scientific community revealed that their practical adoption constitutes a great challenge. Further research that aimed at identifying the reasons for that situation demonstrated that several factors influence the applicability, including the documentation level of detail, the availability of supporting tools, and the continuity of support. This paper presents the European Energy Information Sharing and Analysis Centre (EE-ISAC)—a cybersecurity platform for the energy sector that has been adopted by multiple organisations. The platform facilitates sharing information about cybersecurity incidents, countermeasures, and assessment results. Prospectively, it is envisaged to be integrated with the threat intelligence platform that enables real-time situational awareness. By considering both fault and attack scenarios together, threat awareness can be mapped onto operational contexts to prioritise decisions and responses. Th... [more]
24432. LAPSE:2023.14702
Analysis of Circuit Parameters of New Graphene Partial Discharge Sensor Electrode Plate Based on Transmission Line Model
March 1, 2023 (v1)
Subject: Materials
Keywords: capacitance characteristics, electrode plate, graphene, inductance characteristics, least-square, partial discharge sensor, resistance characteristics
Partial discharge (PD) sensors have been widely used in PD detection of power equipment. In order to adapt to the development of the new power system, the new PD sensor should not only have a wide response band but also have a large dynamic range. PD measurement devices currently used in smart grids are mainly based on traditional metal materials, which face difficulty in fully meeting these technical requirements. Graphene has a variety of excellent properties, and it is introduced to improve PD sensor materials in this paper. Based on the transmission line model, the circuit parameters of graphene PD sensor electrode plate material are theoretically derived. Various factors affecting its resistance characteristics, inductance characteristics, and capacitance characteristics are analyzed. Next, the variation curves of circuit parameters under different influencing factors are obtained. Linear regression models based on the least-square method were developed for circuit parameters. Fin... [more]
24433. LAPSE:2023.14701
Assessing the Siting Potential of Low-Carbon Energy Power Plants in the Yangtze River Delta: A GIS-Based Approach
March 1, 2023 (v1)
Subject: Planning & Scheduling
Keywords: analytic hierarchy process, carbon neutrality, energy planning, low-carbon energy, power plant, spatial suitability
China announced a target of achieving carbon neutrality by 2060. As one of the most promising pathways to minimize carbon emissions, the low-carbon electricity supply is of high consideration in China’s future energy planning. The main purpose of this study is to provide a comparative overview of the regional siting potential of various low-carbon power plants in the Yangtze River Delta of China. First, unsuitable zones for power plants are identified and excluded based on national regulations and landscape constraints. Second, we evaluate the spatial siting potential of the seven low-carbon energy power plants by ranking their suitability with geographic information system (GIS)-based hierarchical analysis (AHP). The results revealed that around 78% of the area is suitable for power plant siting. In summary, biomass power plants have high siting potential in over half of the spatial areas. Solar photovoltaic and waste-to-electricity are encouraged to establish in the long-term future.... [more]
24434. LAPSE:2023.14700
Smart Cities and Positive Energy Districts: Urban Perspectives in 2020
March 1, 2023 (v1)
Subject: System Identification
This Special Issue of Energies, “Smart Cities and Positive Energy Districts: Urban Perspectives in 2021”, introduces contemporary research on Smart Cities and on Positive Energy Districts. The present Special Issue, namely the fourth Special Issue, Smart Cities and Positive Energy Districts: Urban Perspectives in 2021, has been dedicated to tools, technologies, and system integration for Smart Cities and for Positive Energy Districts. The topic highlights the variety of research within this field, including research on: tools facilitating the evaluation of Sustainable Plus Energy neighborhoods, of enabling-technologies and procedures for Positive Energy Districts, and of multicriteria assessment for the identification of Positive Energy Districts; system integration related to optimized energy and air quality management in the COVID-19 scenario; system integration upgrading existing residential areas to the status of Positive Energy Districts; and renovation models for large scale acti... [more]
24435. LAPSE:2023.14699
Semi-Empirical Approach to Gas Flow Velocity Measurement by Means of the Thermal Time-of-Flight Method—Further Investigation
March 1, 2023 (v1)
Subject: Process Design
Keywords: low flow velocity, thermal anemometer, thermal time-of-flight (TTOF), thermal wave
This paper describes a study to expand the knowledge as to whether a thermal wave anemometer can be used to measure the velocity of flowing gases or gas mixtures in situ. For this purpose, several series of measurements were performed in laboratory conditions using both the previously used probe and other probes of similar design. The probes were not modified mechanically or electrically in any way. The obtained results were compared with each other, and on this basis, the optimal, though purely empirical, form of the calibration function was determined (4). The analysis of the relative differences between the measured and set velocity values showed that they do not exceed 1% in the velocity range from 0.05 to 2.5 m/s. Lowering the sensitivity of the method for velocities below approx. 0.05 m/s results in a rapid increase in the observed deviations, reaching 15% for 0.015 m/s. The conducted research also revealed an increased resistance of the proposed measurement method to small flow... [more]
24436. LAPSE:2023.14698
Study on the Mechanism of Fiber Fracturing Fluid Controlling Pulverized Coal Transportation
March 1, 2023 (v1)
Subject: Process Control
Keywords: coal powder, critical particle size model, fiber fracturing fluid, space network structure
In view of the problems associated with coal powder production in the development of Coalbed Methane (CBM), a fiber fracturing fluid technology is proposed to control pulverized coal production. Based on a force analysis of coal powder in the fracture and the microstructure of fiber-proppant, a critical intercepted particle size model of coal powder is established. This model is primarily related to fiber properties, proppant particle size and flow rate. To verify this, an FCES-100 device (Nantong Yichuang Experimental Instrument Co., Ltd., Nantong, China) was used to study the influence of fibers on the transportation of pulverized coal in the proppant pack. Five groups of comparative experiments were set up using no fiber, 0.25 g undegraded fiber, 0.25 g degradable fiber, 0.5 g undegraded fiber and 0.5 g degraded fiber, with the flow rate and closure pressures controlled, and, finally, particle size analysis of the discharged pulverized coal was performed using a laser particle size... [more]
24437. LAPSE:2023.14697
Digitalization—The Engine of Sustainability in the Energy Industry
March 1, 2023 (v1)
Subject: Energy Systems
The goal of this paper is to conduct a bibliometric analysis of the scientific literature about the sustainability of digitalization in the energy sector in order to capture the main challenges and trends in the transition towards it. The bibliometric analysis of the scientific literature was carried out by interrogating the Scopus database, using a set of keywords considered relevant for the analyzed field and for the goal of the proposed research. The purpose of the study was, on the one hand, the depth of the research into these topics during the 2013−2021 period, in terms of the number of scientific papers, the topic, abstract and keywords associated, the geographical area of origin and the authors’ affiliation and on the other hand, an analysis of the existence of possible links between these topics formulated through three hypotheses. The results obtained reveal the researchers’ concerns for digitalization in the energy sector, the existing correlations between the keywords analy... [more]
24438. LAPSE:2023.14696
Modeling Residential Electricity Consumption from Public Demographic Data for Sustainable Cities
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: demographic data, energy transitions, information management, residential sector, smart cities
Demographic factors, statistical information, and technological innovation are prominent factors shaping energy transitions in the residential sector. Explaining these energy transitions requires combining insights from the disciplines investigating these factors. The existing literature is not consistent in identifying these factors, nor in proposing how they can be combined. In this paper, three contributions are made by combining the key demographic factors of households to estimate household energy consumption. Firstly, a mathematical formula is developed by considering the demographic determinants that influence energy consumption, such as the number of persons per household, median age, occupancy rate, households with children, and number of bedrooms per household. Secondly, a geographical position algorithm is proposed to identify the geographical locations of households. Thirdly, the derived formula is validated by collecting demographic factors of five statistical regions from... [more]
24439. LAPSE:2023.14695
A Study on Energy Tax Reform for Carbon Pricing Using an Input-Output Table for the Analysis of a Next-Generation Energy System
March 1, 2023 (v1)
Subject: Process Design
Keywords: carbon tax, equilibrium price model, fairness of tax burden, input-output table
Carbon pricing, such as a carbon tax, is an invisible hand that leads to the construction of a sustainable low-carbon society, and precise analysis of the impact of carbon pricing on each sector of the economy is indispensable for its design. In this study, an equilibrium price model based on the 2015 input-output table was used for the analysis of next-generation energy systems (2015 IONGES) and the effect of the introduction of a carbon tax on the price of the industrial sector was assessed. Based on the existing energy-related tax system in Japan, the introduction of a carbon tax is regarded as an increase in the tax for global-warming countermeasures (TGWC) in the petroleum and coal tax (PCT). While existing energy-related taxes are designed to place a relatively heavy burden on the transportation sector, tax reform of the petroleum and coal tax has a relatively large effect on raising prices in energy-conversion and energy-intensive sectors. As a result, the reform of the energy-r... [more]
24440. LAPSE:2023.14694
Thermochromic Materials as Passive Roof Technology: Their Impact on Building Energy Performance
March 1, 2023 (v1)
Subject: Materials
Keywords: Absorption, color, Energy Efficiency, reflection, roof coating, surface temperature, thermochromic
Over the last few years, new materials have been developed which a priori, appear to improve passive energy efficiency in buildings. This article focuses on chromogenic devices that allow changing their optical properties in a reversible manner through some external stimulus. The covering of the envelopes may have different textures or colors, which determine the amount of solar radiation absorbed by the material compared to the incident radiation. In buildings with a high percentage of roof relative to façade, the surface finish plays an interesting role in the energy demand. In the present work, the influence of the application of thermochromic materials to the roofs of commercial buildings is analyzed. It has been demonstrated that the application of a thermochromic surface finish can produce savings of annual energy demand between 1% and 12% in kilowatt-hours and kilograms of CO2 and they become more significant for construction solutions with higher transmittances values. Then, th... [more]
24441. LAPSE:2023.14693
A Lab on a Chip Experiment for Upscaling Diffusivity of Evolving Porous Media
March 1, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Archie’s law, lattice Boltzmann simulation, microfluidic experiments, porous media imaging, reactive transport modelling
Reactive transport modelling is a powerful tool to assess subsurface evolution in various energy-related applications. Upscaling, i.e., accounting for pore scale heterogeneities into larger scale analyses, remains one of the biggest challenges of reactive transport modelling. Pore scale simulations capturing the evolutions of the porous media over a wide range of Peclet and Damköhler number in combination with machine learning are foreseen as an efficient methodology for upscaling. However, the accuracy of these pore scale models needs to be tested against experiments. In this work, we developed a lab on a chip experiment with a novel micromodel design combined with operando confocal Raman spectroscopy, to monitor the evolution of porous media undergoing coupled mineral dissolution and precipitation processes due to diffusive reactive fluxes. The 3D-imaging of the porous media combined with pore scale modelling enabled the derivation of upscaled transport parameters. The chemical react... [more]
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