Pyrolysis is an excellent method for recovering mixed and contaminated plastics that are no longer recyclable. Special attention must be paid to the stability of the fuel to avoid the formation of undesirable products. This can be achieved by additives such as antioxidants. In this study, high-density polyethylene, polypropylene, and polystyrene plastic waste are slowly pyrolyzed to a maximum of 470 degrees Celsius. A gasoline fraction (0−190 °C) and a diesel fraction (190−320 °C) are then obtained from these. Three antioxidants are added to these fractions: pyrocatechol, phenol, and freshly produced algal pyrolysis oil; the latter is described in the literature as containing particularly high levels of antioxidants. The oxidation stability of these mixtures and the change in the iodine number over time are measured using a newer method than the commonly used method of Wijs. Phenol improves the oxidation stability best, followed successively by algae pyrolysis oil and pyrocatechol. The... [more]

The CFD/DEM approach was used for investigating the forces playing a role in a furnace raceway formation and stability. The configuration is an actual pilot-scale hot blast furnace filled only with coke particles. In such a system, the raceway was unstable, with successively a growing phase and a collapse. The CFD/DEM numerical simulations were coupled with a core-shrinking model to mimic coke particle combustion. However, the kinetic reactions and heat transfers were not numerically predicted. Instead, the characteristic combustion timescale of one coke particle was imposed, and the combustion zone was adjusted to match the global combustion measured in the pilot-scale experiment. The results showed that the standard contact model was not enough to resist the pressure exerted by the granular weight on the raceway. However, the addition of a cohesive force, through the Johnson-Kendall-Roberts (JKR) model, allowed the qualitative reproduction of the gas pressure fluctuations and the col... [more]

Utilizing voids of insoluble sediment (IS) to store gas is an effective way to improve the efficiency of salt cavern gas storage (SCGS) in China. In this study, a suitable method for predicting the void volume of insoluble sediments (VVISs) is established. This study explores three key factors affecting the VVISs through laboratory experiments. Firstly, in order to make the experimental results more in line with production realities, an analysis of the characteristics of IS in X SCGS was conducted to provide a basis for setting parameters for subsequent experiments. Secondly, experimental setups and methods for measuring the VVISs were designed. Finally, the experimental results were used to predict the VVISs in on-site cavity wells. The results indicate that the higher the proportion of quartz, illite, and large-grain particles in IS, the larger the VVISs. Under different parameters, the VVISs can account for approximately 10−40% of the IS accumulation volume. Different particle sizes... [more]

The aging processes of microplastics (MPs) are prevalent in natural environments. Understanding the aging mechanisms of MPs is crucial for assessing their environmental behavior and potential risks. In this study, we selected polylactic acid (PLA) and polyethylene (PE) as representatives of biodegradable and conventional plastics, respectively, to examine changes in their physicochemical properties induced by water and UV light exposure. Laboratory aging resulted in significant fragmentation, characterized by cracks and pores on the surfaces, for both types of MPs, with PLA MPs exhibiting more severe changes, particularly under combined UV and water exposure. Notably, PLA MPs tended to become progressively smaller after aging, whereas PE MPs did not show significant size changes. Chemical analyses of aged MPs using micro-Fourier-transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) revealed a substantial increase in the carbonyl index (CI) and oxygen content... [more]

The use of edible oils and fats in dairy products is becoming increasingly important in the food industry because of their complementary functional properties. Most of these products are produced using food-grade enzymes as processing aids because processes involving enzymes are considered mild and environmentally friendly for regulatory purposes. The poor stability and recovery of enzymes in their native state limit their performance, and to enhance their activity, stability, and reusability, enzymes are often immobilised—a process that involves attaching them to a solid support. Additionally, immobilisation enables enzymes to selectively target specific substrates or products, making them highly efficient. These features have led to the increased use of immobilised enzymes in dairy and lipid processing and enzymes have been used to produce a broad range of products such as whey protein concentrates and isolates, peptide−lipid conjugates, lipid concentrates, structured lipids, and hum... [more]

The production of tight gas wells decreases rapidly, and the traditional method is difficult to accurately predict the production of tight gas wells. At present, intelligent algorithms based on big data have been applied in oil and gas well production prediction, but there are still some technical problems. For example, the traditional error back propagation neural network (BP) still has the problem of finding the local optimal value, resulting in low prediction accuracy. In order to solve this problem, this paper establishes the output prediction method of BP neural network optimized with the sparrow search algorithm (SSA), and optimizes the hyperparameters of BP network such as activation function, training function, hidden layer, and node number based on examples, and constructs a high-precision SSA-BP neural network model. Data from 20 tight gas wells, the SSA-BP neural network model, Hongyuan model, and Arps model are predicted and compared. The results indicate that when the prop... [more]

Vat photopolymerization is renowned for its high flexibility, efficiency, and precision in ceramic additive manufacturing. However, due to the impact of random defects during the recoating process, ensuring the yield of finished products is challenging. At present, the industry mainly relies on manual visual inspection to detect defects; this is an inefficient method. To address this limitation, this paper presents a method for ceramic vat photopolymerization defect detection based on a deep learning framework. The framework innovatively adopts a dual-branch object detection approach, where one branch utilizes a fully convolution network to extract the features from fused images and the other branch employs a differential Siamese network to extract the differential information between two consecutive layer images. Through the design of the dual branches, the decoupling of image feature layers and image spatial attention weights is achieved, thereby alleviating the impact of a few abnor... [more]

In order to apply precipitated calcium carbonate (PCC) in the detergent industry, its ability to deposit calcium ions in hard water is an important process. In this work, the calcium ion deposition in the presence of PCC from different sources is investigated to reveal the influencing factors and mechanism of nucleation and crystal growth of CaCO3. SEM, XRD, Malvern particle size analysis, and calcium electrodes are used to evaluate the effects of PCC morphology, saturation of Ca2+, and PCC additive amount on the deposition behavior of CaCO3. Through SEM and Malvern particle size analysis, it is found that the precipitation of calcium ions is obviously accelerated by PCC acting as seeds. Moreover, calcium ions are effectively adsorbed on (211) crystal facets, thus prismatic and scalenohedral PCC crystals exhibit better adsorption performance than irregular cubic PCC ones. In addition, XRD demonstrates that PCC reduces or even eliminates the formation of crystals such as vaterite, displ... [more]

This study examines the connections between various fracture indicators and production data with an example from one of the giant fields in the Middle East producing complex fractured carbonate lithologies. The field under study hosts two reservoirs with a long development and production history, including carbonates from the Asmari and Bangestan Formations. A fracture intensity map was generated based on the interpretation of image logs from 28 wells drilled within the field. Mud loss data were collected and mapped based on the geostatistical Gaussian Random Function Simulation (GRFS) algorithm. Maximum curvature maps were generated based on Asmari structural surface maps. Comparing the results shows a good agreement between the curvature map, fault distribution model, mud loss map, fracture intensity map, and productivity index. The results of image log interpretations led to the identification of four classes of open fractures, including major open fractures, medium open fractures,... [more]

This study presents a numerical simulation of a pump’s performance during a power-cut event and connected hazards resulting from the failure of non-return flap valves. The vertical mixed-flow pumps with suction bells were mounted inside the suction basins of a pumping station. Different regimes of the pump operation during the time were analyzed based on the pump’s 4-quadrant characteristics and the dynamics of rotating parts in the pump, gearbox and electric engine. The resulting development of flow rates, rotor speed and forces in the course of time were used to analyze the hazards of failure of any pumping system component and the flooding of the suction object and its surroundings. The presented results show a deep insight into the flow phenomena in vertical mixed-flow pumps with suction bells during the runaway process and confirm that the developed methodology can be successfully applied to monitor the critical regimes in a pumping station in real time. The simulations were verif... [more]

An integrated energy system (IES) breaks down barriers between different energy subsystems, enhancing energy reliability and efficiency. However, issues such as uneven equipment capacity allocation and suboptimal scheduling persist in multi-energy flow IES. To maximize economic benefits while ensuring energy balance and the operational characteristics of the equipment, a capacity matching optimization and scheduling strategy model for IES was developed. Firstly, mathematical models for the electricity, gas, and thermal networks within the IES were established. Secondly, considering the efficiency of energy conversion between different forms and constraints of energy storage in the electricity−thermal−gas interconnected energy system, optimization solutions were obtained using regional contraction algorithms and sequential quadratic programming methods. Finally, case studies conducted in a real park demonstrated that, through optimized capacity matching, unit prices for electricity, hea... [more]

Aiming at the problems of low detection efficiency and complexity of aircraft gear tooth surfaces, a path optimization algorithm based on an improved genetic algorithm is proposed. The detection area of the tooth surface is planned, the sampling points of the tooth surface are determined based on the digital technology of the tooth surface, and the sampling mesh is obtained by the truncated plane method to reduce the sampling distortion of the shape and improve the sampling efficiency. Adaptive crossover and mutation probability are used to improve the convergence speed and accuracy of the genetic algorithm. The selected individuals of the binary tournament are used to guide the global optimal search by a simulated annealing algorithm, and the local optimal is avoided by the Metropolis criterion. In the simulation experiment, the proposed method and other algorithms are used to optimize the detection path. The optimized tooth-surface-detection path has the shortest distance and the sho... [more]

This study investigates the phase equilibria of the Al-Mo-Hf ternary system at 400 °C and 600 °C using X-ray diffraction (XRD) and electron probe microanalysis (EPMA/WDS) techniques. Seven three-phase and five two-phase regions were identified at 400 °C, while eight three-phase and four two-phase regions were identified at 600 °C. Despite variations in the solid solubility ranges of certain compounds, the distribution of phase zones in the isothermal cross-section remained consistent at both temperatures. Using the experimental results and logical deductions, isothermal cross-sections were constructed for the Al-Mo-Hf ternary system at 600 °C and 400 °C.

This study aimed to assess the sorption capacity of a natural sorbent, specifically birch bark (BB), and its modification using chemical reagents, including nitric and hydrochloric acid, sodium hydroxide, and chloride. The objective of the chemical modification was to enhance the sorption capacity of the heavy metals cadmium(II), chromium(VI), and manganese(II). The most effective modification for adsorbing cadmium and manganese from aqueous solutions was achieved by treating the sorbent with a 0.1 M sodium hydroxide solution (BBNa). Conversely, in the case of chromium, each modification adversely affected its adsorption by the sorbent. Concentrations of the solutions were analyzed using atomic absorption spectrometry at appropriate time intervals. The adsorption process was described using Langmuir, Freundlich, and Temkin isotherms. The Freundlich isotherm provided the best fit for cadmium and chromium (R2 = 0.988 and 0.986, respectively), while the Langmuir isotherm was most suitable... [more]

In response to the unclear drilling resistance characteristics of rocks in the Ji’yang Depression, low drilling efficiency of PDC drill bits, and difficulties in drill bit selection, this study selected rock samples from different depths in the area for indoor drilling resistance analysis testing. Based on logging data, a prediction model was established for drilling resistance characteristics parameters of the strata in the area, and a graph of drilling resistance characteristic parameters of the rocks in the area was drawn. The study showed that the uniaxial compressive strength of the strata rocks was 50−110 MPa, with a hardness of 500−1300 MPa, a plasticity coefficient ranging from 1 to 2, a rock drillability grade of 8−20, and an abrasiveness index of 5−20. Combining the analysis of on-site drilling bit failures, PDC drill bits adapted to the strata in the area were selected, and the mechanical drilling speed of the selected bits reached 12.58 m/h, successfully drilling through th... [more]

Lactic acid bacteria (LAB) are commonly consumed as probiotics to improve gut barrier function and boost the immune system. This study aimed to screen LAB with high immunomodulatory activity using RAW264.7 macrophages. According to the results, Limosilactobacillus reuteri AUc2301 was selected from 84 screened strains that can stimulate RAW264.7 cell proliferation. Limosilactobacillus reuteri AUc2301 significantly enhanced the phagocytosis activity of RAW264.7 cells. In the ELISA test, Limosilactobacillus reuteri AUc2301 significantly promoted the release of interleukin-6, IL-1β, the tumor necrosis factor, and nitric oxide in RAW264.7 macrophages. In addition, Limosilactobacillus reuteri AUc2301 significantly inhibited the excessive release of IL-6, IL-1β, TNF-α, prostaglandin E2 as well as NO and the high expression of cyclooxygenase-2 in RAW264.7 macrophages induced by lipopolysaccharide. In further mechanism studies, Limosilactobacillus reuteri AUc2301 could regulate the nuclear fact... [more]

The Paleogene system of the Zhuyi Depression exhibits a pronounced mechanical compaction background. Despite this compaction, remarkable secondary porosity is observed in deep clastic rocks due to dissolution processes, with well-developed hydrocarbon reservoirs persisting in deeper strata. We conducted a comprehensive study utilising various analytical techniques to gain insights into the dissolution and transformation mechanisms of deep clastic rock reservoirs in the steep slope zone of the Lufeng Sag. The study encompassed the collection and analysis of the rock thin sections, XRD whole-rock mineralogy, and petrophysical properties from seven wells drilled into the Eocene. Our findings reveal that the nature of the parent rock, tuffaceous content, dominant sedimentary facies, and the thickness of individual sand bodies are crucial factors that influence the development of high-quality reservoirs under intense compaction conditions. Moreover, the sustained modification and efficient... [more]

In order to detect abnormal heat generation in time, a reversible color-changing coating temperature measurement method is proposed for self-detection of temperature by power equipment, and its adhesion characteristics and aging performance were analyzed. The results showed that the reversible color-changing coating prepared with crystalline violet lactone as the colorant, bisphenol A as the color developer, octadecanol as the solvent, and RTV-II as the base paint can meet the requirements of self-detection of temperature by power equipment with its adhesion performance. The accelerated aging tests using high temperature, light and humidity were carried out in the laboratory, and we concluded that the deterioration degree of the color-changing coating was positively correlated with the temperature. Light can accelerate the aging rate of reversible color-changing coatings, and the degradation process of the coating was significantly accelerated under UV light. The effect of humidity on... [more]

A comparative metabolomic study of three varieties of alfalfa (Medicago varia Mart.) was performed via extraction with supercritical carbon dioxide modified with ethanol (EtOH) and the detection of bioactive compounds via tandem mass spectrometry. Several experimental conditions were investigated in the pressure range of 50−250 bar, with ethanol used as a co-solvent in an amount of 1% of the total volume in the liquid phase at a temperature in the range of 31−70 °C. The most effective extraction conditions were as follows: a pressure of 250 Bar and a temperature of 60 °C for M. varia. M. varia contains various phenolic compounds and sulfated polyphenols with valuable biological activity. Tandem mass spectrometry (HPLC-ESI−ion trap) was applied to detect the target analytes. A total of 103 bioactive compounds (59 polyphenols and 44 compounds belonging to other chemical groups) were tentatively identified in extracts from aerial parts of alfalfa. For the first time, twenty-one chemical c... [more]

Forest fires have emerged as a significant global concern, exacerbated by both global warming and the expanding human population. Several adverse outcomes can result from this, including climatic shifts and greenhouse effects. The ramifications of fire incidents extend widely, impacting human communities, financial resources, the natural environment, and global warming. Therefore, timely fire detection is essential for quick and effective response and not to endanger forest resources, animal life, and the human economy. This study introduces a forest fire detection approach utilizing transfer learning with the YOLOv8 (You Only Look Once version 8) pretraining model and the TranSDet model, which integrates an improved deep learning algorithm. Transfer Learning based on pre-trained YoloV8 enhances a fast and accurate object detection aggregate with the TranSDet structure to detect small fires. Furthermore, to train the model, we collected 5200 images and performed augmentation techniques... [more]

During the hydraulic-fracturing process, stress interference occurs among multiple wells and fractures, potentially affecting the trajectory of hydraulic fracture propagation. Previous studies have largely overlooked the influence of proppant support stresses on the trajectories of fracture propagation. This paper establishes a mathematical model, grounded in the boundary element method, designed to compute the propagation of multiple fractures, considering both proppant support on the fracture surface and dynamic perturbations within the local stress field. The findings of this research reveal that the stress field induced by hydraulic fracturing exhibits dynamic evolution characteristics, necessitating a comprehensive study of the fracture initiation and extension across the entire fracturing time domain. The effect of the residual fracture width under proppant action on the in situ stress field cannot be ignored. During simultaneous fracturing, hydraulic fractures are inclined to pr... [more]

This study investigated how welding affects the thermal deformation of square cells produced for casks, which are dry storage containers for spent nuclear fuel. We aimed to minimize structural deformation by utilizing STS316L as the material for the square cells. We explored a method of subdividing the square cells and joining them through butt welding. Keeping the upper plate thickness constant, GTA butt welding was conducted while varying the column’s wall thickness, followed by measurement with a laser vision sensor. The heat conduction and thermal strain were then calculated using a finite element analysis (FEM). Both experimental and analytical results confirmed that there was significant thermal deformation in the cases of thick-walled columns due to variations in heat conduction distribution, with the resulting deformation patterns depending on thickness.

In order to improve the accuracy of a solar-powered punch card car’s movement on a designated route and reduce positional deviations during its operation, a solar-powered punch card car with a single cam as the steering guidance mechanism was designed. The car adopts a three-wheel structure. The transmission mechanism, steering mechanism, driving mechanism, and regulating mechanism of the car were analyzed. The kinematics model of the car was established and the motion characteristics of the car were obtained. By analyzing the relationship between the steering angle of the car and the curvature radius of its travel route, the front wheel angle of the car at each position was calculated using MATLAB R2020a. This allowed us to establish the relationship between the front wheel angle and the displacement of the steering push rod, which was further converted into the theoretical contour line of the cam. Subsequently, the theoretical contour line of the cam was completed and envelope correc... [more]

The piston-type accumulator is an energy storage device in hydraulic−pneumatic systems, playing a significant role in industries such as petrochemicals, heavy machinery, and steel metallurgy. The displacement parameters of the piston-type accumulator are vitally important for fault diagnosis and early warning in hydraulic systems. Traditional displacement measurement methods cannot meet the requirements of the internal testing environment of the accumulator. Therefore, this paper proposes an accumulator piston displacement signal compensation method based on rotational factors and support vector regression. Firstly, empirical mode decomposition is utilized to denoise the signal. Then, rotational factors are used to generate a delay compensation module to compensate for the signal attenuation and time delay caused by metallic reflection and scattering within the cylinder of the radar signal. The support vector regression model is improved based on a hash table to enhance its computation... [more]

Red ginseng extract is one of the most widely used herbal medicines to prevent and cure various diseases. Among the processed products derived from red ginseng, the water-insoluble part as red ginseng residual (RGR) becomes waste, even though it contains important ingredients. TEMPO-oxidation (TO) can be used as a pre-treatment with different degrees of oxidation (DO) (0 to 0.4) in red ginseng residual (RGR-TO) by introducing chemical oxidation and high-pressure homogenizer (HPH) as a nanofibrillation process. 1H NMR was used to determine the carbohydrate composition and calculate DO, size was examined using a nanoparticle analyzer, and the zeta potential was used to determine surface charge density. RGR-TO with different concentrations had different compositions; glucose and uronic acid were the main ingredients. All treated RGR-TO showed higher oxidant levels than the untreated counterpart (RGR-TO 0). As the oxidant levels increased, the zeta potential and uronic acid increased, but... [more]