As a subdivision of the hydrogen energy application field, ship-borne hydrogen fuel cell systems have certain differences from vehicle or other application scenarios in terms of their structural type, safety, environmental adaptability, and test verification. The connection method of the ship-borne hydrogen storage cylinder (SHSC) is very important for the hydrogen fuel cell ship, and the structural parameters of the SHSC are particularly important in the hydrogen refueling process. To ensure the safe and reliable operation of the hydrogen-powered ship, research on the filling of the SHSC under different connection modes was carried out during refueling. In our study, a thermal flow physical model of the SHSC was established to research the hydrogen refueling process of the series and parallel SHSCs. The influence of series and parallel modes of the SHSCs on the hydrogen refueling process was explored, and the evolution law of the internal flow field, pressure, and temperature of serie... [more]

In catalysis, the design and application of supported nanoparticle catalysts is a cornerstone for addressing contemporary challenges in environmental remediation, sustainable synthesis, and analytical methodologies [...]

The rising number of natural gas purification plants has raised concerns about safety and environmental issues related to VOC (Volatile Organic Compounds) leakage. Therefore, it is crucial to conduct in-depth research on oil vapor emission patterns in these plants. Taking a typical natural gas purification plant as an example, a 1:1 scale model was established. Using methanol as the simulated medium, a study was conducted to investigate the impact of multiple leaks on the dispersion process of VOCs at the plant, combining field sampling with numerical simulation. The results indicate that wind speed influences the concentration of oil vapor, particularly on the leeward side, where vortex and reflux phenomena occur. The area of high concentration of oil vapor at v = 4 m·s−1 is eight times that at v = 8 m·s−1. Gravity and eddy currents contribute to the accumulation of oil vapor, especially closer to the central area of the plant where surrounding buildings obstruct dispersion. Smaller d... [more]

A full understanding of the fluid flow and heat transfer behaviors within a single fracture is important for geothermal heat extraction. In this study, models of single fractures with varying aperture and inner surface roughness (characterized by fractal dimension) are constructed, and a compound fracture aperture (CFA) is proposed to describe the coupled effect of fracture aperture and inner surface roughness. The effect of the fluid flow Reynolds number on heat transfer was investigated as it ranged from 4.84 to 145.63. The results show that the overall heat transfer coefficient (OHTC) in a single fracture significantly increases with the rise in fluid velocity and the compound fracture aperture. Particularly, the OHTC in a single fracture with an inner surface fractal dimension of 2.09 can be up to 1.215 times that of a parallel flat fracture when the flow velocity reaches 0.18 m/s. Moreover, for a fracture with a smaller CFA, enhancing the fracture aperture plays a decisive role in... [more]

Horizontal well cavern completion and stress release is considered a potential technique for efficient development of coalbed methane in tectonically deformed coal (TDC). Pulsating loading and unloading is a key technique for the controlled expansion of caverns and broader stress release within the reservoir. However, current understanding of the mechanical characteristics and pore network structure evolution of TDC under cyclic loading and unloading conditions is still limited. This paper employs numerical simulation methods to study the mechanical behavior and damage characteristics of TDC under cyclic loading and unloading. After obtaining a set of micromechanical parameters reflecting the behavior of TDC samples under triaxial compression in high-stress states, the effects of different stress gradients and cyclic amplitudes on the stress−strain curve, porosity changes, and crack propagation in TDC samples were analyzed. The study results indicate that under various cyclic loading a... [more]

Carbon containing waste has a certain calorific value and utilization value due to the presence of carbon elements. However, the current treatment methods are mostly traditional landfill disposal, incineration, or expensive physical and chemical reaction methods, which clearly do not comply with the rules of the current clean and resource-saving society. In this paper, a new technology and system for carbon containing wastes is proposed, which comprehensively treats and recycles carbon containing wastes, including solid waste, wastewater, waste gas, etc., using pyrolysis−gasification two-stage-cycle technology. The calculation results indicate that the technical scheme proposed in this article is feasible and can achieve the recycling of intermediate and final products, the efficient and clean utilization of carbon containing waste, and the graded utilization of energy. The clean utilization rate of carbon containing waste can be effectively improved, the energy consumption and cost of... [more]

Conventional fluid loss additives have difficultly controlling the water loss of cement−metakaolin slurry with semi-saturated brine cement slurry and limiting it to less than 50 mL (30 min)−1. This paper describes the development of an anti-salt fluid loss additive for metakaolin−cement systems. This study adopted the aqueous solution polymerization method; selected four kinds of monomers, namely 2-Acrylamido-2-methylpropane sulfonic acid (AMPS), N,N-Dimethylacrylamide (DMAA), acrylamide (AM), and methyl acrylate (MA); and performed a single-factor experiment on the proportion of monomer, reaction temperature, initiator dosage, and developed fluid loss additive, which has a high salt tolerance and temperature tolerance. This fluid loss additive can resist salt until saturation, and it can control fluid loss in 24 mL·(30 min)−1 when its dosage is 2%. The fluid loss additive can achieve the effect of fluid loss reduction by increasing the filtrate viscosity, forming a flexible elastic ad... [more]

Improving diesel engine performance requires a comprehensive understanding of fuel atomization and air−fuel mixing within the combustion chamber. Numerous studies have been conducted to reduce emissions and enhance diesel engines. However, further investigation is required on the detailed diesel spray process. In this study, we adopted extinction measurement to analyze the effects of a fuel injection pressure range of 300 to 700 bar on spray morphology. For the extinction imaging setup, we utilized a high-intensity continuous LED source along with a diffuser to ensure uniform light distribution. The high-speed extinction and image processing results indicate that increasing the injection pressure from 300 to 700 bar effectively produced a smaller particulate size (15% reduction) and a better air−fuel mixing process. Especially at the end of injection, our results show smaller liquid ligaments (50% reduction) and droplets around the injector tip with higher injection pressure cases.

Food waste, particularly animal-derived waste, presents a significant challenge globally, prompting the need for sustainable management strategies. In 2022, the amount of food waste per capita reached 131 kg/capita in the EU (European Union), which is why the search for environmentally friendly ways to manage food waste through thermochemical conversion processes has gained momentum in recent years. Animal-derived waste is a good source of organic matter (proteins, lipids, and polysaccharides) and mineral compounds (calcium phosphate, mostly hydroxyapatite). This composition makes animal-derived waste valuable for the extraction of chemical compounds, such as hydroxyapatite (HAp), which constitutes up to 70 wt% of animal bones; keratin; collagen; and hyaluronic acid (HA), to produce pharmaceutical, medical, or industrial by-products. The thermochemical conversion of chicken bones through pyrolysis and gasification creates a new opportunity to valorize this type of waste by reintroducin... [more]

Since the discovery of the vast Jimusaer shale oilfield in the southeastern Junggar Basin in 2012, there has been considerable interest in neighboring areas around Bogeda Mountain that have shale oil potential. The primary productive interval in the basin, the Middle Permian Lucaogou Formation (P2l), is well-developed in the areas of Qitai, Mulei, Shiqiantan, Chaiwopu, and Miquan. In this study, we conducted an assessment of the hydrocarbon generation potential of the P2l in these five areas and compared it with that of the P2l in the Jimusaer oilfield, which were determined by GC-MS, total organic carbon (TOC) and vitrinite reflectance (Ro) measurements, Rock-Eval pyrolysis, and organic petrology to investigate the type, origin, thermal maturity, hydrocarbon potential, and oil/gas proneness of organic matter in the P2l. Additionally, we applied open-system pyrolysis of hydrocarbon generation kinetics to explore differences in hydrocarbon generation and expulsion across various P2l mud... [more]

An experimental study and dimensional analysis of the effective heat transfer coefficient in a continuous-indirect rotatube dryer using forest biomass as the granular material isare developed in the present work. The study employed a factorial design 33 to investigate the effects of feed flow frequency (20−35−50 (Hz)), drum rotational velocity (6−8−10 (rpm)), and saturated vapor pressure (4−5−6 (bar)) on the heat transfer coefficient. During steady state conditions, the moisture content profiles and inlet and outlet temperatures were measured within the experimental region, and parameters, such as the effective heat transfer coefficient, solid retention change, and moisture content ratio were studied. The results showed that heat transfer was optimized with high solid feeding rates, low pressure, and low rotation, with solid feeding being the predominant factor. The moisture content profiles revealed a change in the hydrodynamic behavior, with the center point of the experimental regio... [more]

In July 2023, the International Maritime Organization (IMO) presented an updated strategy for decarbonizing maritime transport and achieving net-zero greenhouse gas emissions by 2050. It is therefore imperative to explore innovative solutions to achieve a blue economy and maximize energy efficiency on-board ships. For this reason, the current study aims to integrate the organic Rankine cycle (ORC) and thermoelectric generator (TEG) on board a container ship to generate electrical energy and reduce fuel consumption. The combined system will benefit from the waste heat of a marine diesel engine installed on board. The current study uses R245fa as the organic liquid and analyzes the effects of varying the evaporation pressure on the energetic and economic performance indicators by modeling the combined system in Engineering Equation Solver (EES) software. The results show that the energy efficiency of the ORC system increases from 12.3% at 3.5 bar to 17.3% at 8 bar. In comparison, the ene... [more]

Nonwoven fabrics with appropriate hydrophilicity and potent antimicrobial properties hold important promise for hygiene applications. However, existing materials with certain limitations and complex manufacturing steps, along with the unavoidable use of chemicals in the process, are limited to a certain extent in terms of the balance between comfort and antimicrobial properties. In this paper, a polyimide (PI) fiber was reported to be used for the preparation of PI composite nonwoven fabrics (5-P), which can effectively enhance the surface hydrodynamic and antimicrobial properties of the nonwoven by a one-step plasma treatment on one side. After treatment, the one-sided water contact angle (WCA) changed from 121.5° to 68.5°, and the permeation volume from 0.7 to 2.1 g, with a relative increase of 181.9%. Meanwhile, the reverse osmosis amount was only 0.5 g, achieving rapid permeation while keeping a low reverse osmosis amount. The antimicrobial experiment showed that plasma-treated 5-P... [more]

As the core power element of a centrifugal fan, the impeller’s structural parameters are important factors affecting the aerodynamic performance of the fan. Therefore, to improve the aerodynamic performance of centrifugal fans, in this study, we take the Powered Air-Purifying Respirator (PAPR) power system as the object of research and use a combination of computational fluid dynamics (CFD) and experimental validation to investigate the effects of the number of blades, blade inlet angle, blade outlet angle, blade height, and blade thickness on the aerodynamic performance of the fan. A five-factor, four-level orthogonal test table L16 (45) was selected to obtain the optimal combination of structural parameters for the impeller. In addition, in order to identify and visualize the features of the vortex, Q Criterion Normalized is applied to the simulation on the basis that the minimum pressure appears in the vortex core. In this study, Q Criterion Normalized is used to compare the interna... [more]

The focus of this review article is to present a retrospective analysis of copper applications focusing on ions and nanoparticles as broad-spectrum antimicrobials. Copper nanoparticles are presented as an alternative to rising antibiotic resistance. The basic mechanisms of bacterial, fungal, and viral inactivation, which explain their potential, are presented. The green biosynthesis of copper nanoparticles using biomaterials is also presented and considered a very promising trend for future biotechnology and medical applications.

Based on PetroChina’s status and situation of low-permeability oil reservoir development, this paper analyzes the key common issues in the production capacity construction of new oilfields, the stable production of old oilfields, and enhanced oil recovery, and, in connection with the progress made in major development technologies and the results of major development tests for low-permeability oil reservoirs in recent years, puts forward the technical countermeasures and development directions. For optimizing the development of low-grade reserves, a comprehensive life-cycle development plan is essential, alongside experimenting with gas injection and energy supplementation in new fields. Addressing challenges in reservoir classification, multidisciplinary sweet spot prediction, and displacement−imbibition processes can significantly boost well productivity. In fine water flooding reservoirs, the focus should shift to resolving key technological challenges like dynamic heterogeneity cha... [more]

Municipal wastewater treatment plants (WWTPs) are exposed to high concentrations of micropollutants that can impact conventional activated sludge treatment. The consequences of this include failure to meet discharge standards and the disintegration of flocs, leading to poor sludge settleability. This lab-scale study focuses on the influence of doxycycline, an antibiotic widely used against human and animal diseases, on protozoa, metazoa, and bacterial communities under sludge growing conditions. Doxycycline was added to the mixed liquor of a communal WWTP up to 0, 100, 200, and 400 mg of doxycycline L−1 and incubated in batch conditions for 23 days. The regular addition of nutrient and carbon sources was preformed every 2 days to prevent sludge starvation. Sludge growth, conductivity, and settleability were measured and compared to sludge microbial community structure, determined by microscopic observations and high-throughput 16S rDNA sequencing. The high doxycycline concentration neg... [more]

The widespread use of plastic materials poses significant environmental challenges, which have promoted a growing call for a circular approach to such materials, emphasizing waste reintegration into production. From this perspective, the present study focuses on analyzing a post-industrial recycled stream of chrome-plated automotive scraps composed of acrylonitrile−butadiene−styrene (ABS), polycarbonate (PC), and a commercial PC/ABS blend. The batch-to-batch varying proportions of these constituents make control of the recycled materials’ quality challenging. To address this problem, we formulated an I-optimal mixture design model using the infrared absorbance ratio of selected peaks and Izod impact resistance results for injection-molded samples as inputs to determine the composition of each batch quickly. The two model equations (adjusted R2 > 0.97) obtained, based on cubic expression and regressed from data obtained from 27 mixtures with known compositions, were combined into a sing... [more]

In some applications of microgrids and distributed generation, it is necessary to feed islanded or stand-alone loads with high-quality voltage to provide low total harmonic distortion (THD). To fulfil these demands, an LC filter is usuallyconnected to the output terminals of power electronics converters. A cascaded voltage and current control loop with pulse-width modulation schemes are used to regulate the voltages and currents in these systems. However, these strategies have some drawbacks, particularly when multiple-input−multiple-output plants (MIMO) are controlled using single-input−single-output (SISO) design methods. This methodology usually produces a sluggish transient response and cross−coupling between different control loops and state variables. In this paper, a model predictive control (MPC) strategy based on the concept of optimal switching sequences (OSS) is designed to control voltage and current in an LC filter connected to a three-level neutral-point clamped converter... [more]

In recent years, the development of two offshore low-permeability oil fields has revealed unexpected challenges. The actual productivity of these fields significantly deviates from the designed capacity. Some wells even outperform the expectations for low-permeability limestone fields. This discrepancy primarily stems from a lack of accurate understanding of natural fractures before and after drilling, resulting in substantial errors in capacity assessment. This paper addresses these challenges by proposing a new production capacity model and evaluation method for both vertical and horizontal wells in low-permeability limestone reservoirs. The method leverages logging curve data, incorporating vertical gradation and fractal analysis to effectively represent the fracture’s complexity and connectivity. It uniquely considers factors such as fracture fractal dimensions, threshold pressure, and stress sensitivity, significantly enhancing prediction accuracy. Furthermore, by analyzing the lo... [more]

With the proportion of renewable energy power in the electricity market gradually increasing, coal-fired power is transforming from primary to basic power, with it providing peak and frequency shaving. However, most current methods for peaking below 50% load have been applied industrially, sacrificing the efficiency of the unit. This is not in line with the goals of energy conservation and emission reduction. Therefore, this study proposes a new preheating-based peaking method. This study experimentally and simulatively explores the flow characteristics, pyrolysis gas law, and NOx emission characteristics of a preheating burner at 40−100% load. The results show that the burner has a significant preheating effect, producing high-temperature char and large amounts of pyrolysis gas. As the load decreases, the burner exit temperature increases, whereas the airflow stiffness decreases. There is little variation in the pyrolysis gas concentration between 40% and 100% loads. The NOx concentra... [more]

This study aimed to investigate the effect of combined Free Nitrous Acid (FNA)-Heat (i.e., FNH) pretreatment on single- and two-stage anaerobic digestion (AD) of thickened waste-activated sludge (TWAS). Single-stage AD was conducted in batches, while two-stage AD involved acidogenic fermentation under semi-continuous flow followed by batch methanogenesis. FNH pretreatment was applied before the acidogenic stage, using 1.4 mg HNO2-N/L FNA concentration at 25 °C, 37 °C, and 60 °C for 24 h. Among the scenarios, the most promising results were observed with two-stage AD fed with FNH-pretreated TWAS at 60 °C, showing higher COD solubilization and a reduction in volatile solids. Combined FNA-Heat pretreatment in two-stage AD yielded elevated methane production (363−415 mL CH4/g VS added) compared to single-stage digestion. Methane yields from FNA-Heat pretreated single-stage ranged from 332 to 347 mL CH4/g VS added, contrasting with 212 mL CH4/g VS added for untreated TWAS. Methane generatio... [more]

The coal mine ground gas transportation system is widely used for gas transportation and mixing preheating in the gas storage and oxidation utilization system. However, gas or coal dust explosions may occur, which could result in heavy casualties and significant economic losses. To prevent accidents in the gas transportation system, the present study takes the gas transportation system of Shanxi Yiyang Energy Company as an example to identify the composition and hazardous factors of the gas transportation system. Fault tree analysis (FTA) models were established with pipeline gas and coal dust explosions as the top events, and the importance of each basic event was quantitatively analyzed using the fuzzy fault tree analysis (FFTA) method. The results show that gas and coal dust explosion accidents are mostly caused by the combination of high-temperature ignition sources and explosive materials. The uneven mixing gas and the ventilation carrying a large amount of coal dust are the funda... [more]

Proteins are complex molecules, which play a vital role in our body’s function, the building of tissues, and the regulation of metabolic activity. They are crucial to children’s growth and serve as a key component in the body’s process of distributing oxygen. Proteins fuel the body by supplying the required nutrition and energy. Currently, there is an increasing demand for proteins on large scales with no detrimental effects. The adverse health effects of animal proteins have resulted in a growing preference for plant-based proteins, which offer a healthier daily dosage. Valuable proteins can be extracted from various parts of the plant, including stems, leaves, seeds, fruits, vegetables, and roots. Notably, protein extraction from waste plant and mushroom parts minimizes the product wastage and improves the overall production to support economic sustainability. There are several protein extraction techniques available, where the replacement of non-thermal methods with thermal ones is... [more]

This study explores the efficacy of 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and 1-hexyl-3-methylimidazolium chloride as cleaning agents for aged cellulosic artifacts. A 10% v/v acetone solution of these ionic liquids (ILs) effectively removes the brownish-yellow color of aged paper in a 10 min immersion treatment. Colorimetric analysis shows a remarkable increase in lightness (L*) by up to 40% and a decrease in red/brownish tones (b*) after IL treatment. The cleaning process also deacidifies the paper, shifting the pH to neutral-slightly basic levels and enhancing its long-term stability. Optimal pH outcomes are achieved, with ionic liquid consumption values of 0.4−0.6 g/g of paper. The FTIR analysis revealed structural changes in cellulose induced by the washing step, which is mainly due to the reorganization effect imparted by the ionic liquids. Furthermore, ILs mobilized degraded compounds and acidic species, aiding in their extraction during the restoration pr... [more]