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Records with Type: Published Article
11877. LAPSE:2023.27259
Ultrasonically-Assisted Dissolution of Sugarcane Bagasse during Dilute Acid Pretreatment: Experiments and Kinetic Modeling
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: bioenergy, biofuel, Biomass, hydrolysis, pretreatment, sonochemistry, sugarcane bagasse
Ultrasonic irradiation is known to enhance various physicochemical processes. In this work, the effect of ultrasound on the dissolution of sugarcane bagasse was studied, with the specific aims of quantifying the effect at low solids loading and mild reaction conditions, and determining whether the enhancement of dissolution by ultrasound is independent of temperature. The effects of agitation speed, reaction time, and sonication were examined on the dissolution of the biomass substrate at varying reaction temperatures during the pretreatment process. Sugarcane bagasse was mixed with a 0.3 M solution of sulfuric acid in a reaction vessel to undergo pretreatment. A kinetic model was applied to the mass dissolution of the biomass, as sonicated runs showed higher mass losses at each reaction time, compared to the non-sonicated runs. The ultrasonic enhancement in mass dissolution was seen to increase for an increase in the reaction time. It was observed that the induction period for the dis... [more]
11878. LAPSE:2023.27258
Generation Capacity Expansion Planning Considering Hourly Dynamics of Renewable Resources
April 4, 2023 (v1)
Subject: Planning & Scheduling
Keywords: energy economics, power system expansion, Renewable and Sustainable Energy, solar PV, stochastic generation planning
As more generation capacity using renewable sources is accommodated in the power system, methods to represent the uncertainty of renewable sources become more important, and stochastic models with different methods for uncertainty representation are introduced. This paper investigates the impacts of hourly variability representation of random variables on a stochastic generation capacity expansion planning model. In order to represent the hourly variability as well as uncertainty of the random parameters such as wind power availability, solar irradiance, and load, AutoRegressive-To-Anything (ARTA) stochastic process is applied. By using autocorrelations and marginal distributions of the random parameters, a stochastic process with hourly intervals is generated, where generated random sample paths are used for scenarios. A mathematical formulation using stochastic programming is presented, and a modified IEEE 300-bus system with transmission line constraints is employed to the mathemati... [more]
11879. LAPSE:2023.27257
Passive Fault-Tolerant Control Strategies for Power Converter in a Hybrid Microgrid
April 4, 2023 (v1)
Subject: Process Control
Keywords: fault-tolerant control, fuzzy logic, microgrid, Model Predictive Control, PWM converters, renewable energy resources
Control of AC/DC pulse-width modulation (PWM) power electronic converter, referred to as “AC/DC PWM converter”, is vital to the efficient regulation of power flow between AC and DC parts of a hybrid microgrid. Given the importance of such converters in AC/DC microgrids, this paper investigates the design of fault-tolerant control for AC/DC PWM converters in the presence of microgrid faults. In particular, two novel fault-tolerant schemes based on fuzzy logic and model predictive control are proposed and implemented in an advanced hybrid microgrid benchmark in MATLAB/Simulink environment. The considered hybrid microgrid consists of dynamic loads and distributed energy resources including solar photovoltaic arrays, wind turbines, and battery energy storage systems. The proposed schemes especially target the fault effects due to common power-loss malfunctions in solar photovoltaic arrays in the presence of microgrid uncertainties and disturbances. The effectiveness of proposed fault-toler... [more]
11880. LAPSE:2023.27256
Carbon Monoxide Formation during Aerobic Biostabilization of the Organic Fraction of Municipal Solid Waste: The Influence of Technical Parameters in a Full-Scale Treatment System
April 4, 2023 (v1)
Subject: Environment
Keywords: aeration rate, aerobic biostabilization, carbon monoxide, municipal waste, organic fraction
The present study sought to investigate the formation of carbon monoxide (CO) during aerobic biostabilization (AB) of the organic fraction of municipal solid waste (OFMSW) in forced aerated piles. Understanding the factors influencing CO formation may be important not only for safety, but also for environmental and technical reasons. The objective of the study was to determine the effect of the technical parameters of the piles on the concentration of CO in the process gas during AB of the OFMSW in a full-scale waste treatment system: rate of waste aeration (from 3365 to 12,744 m3∙Mg−1), waste mass loads in the pile (from 391 to 702 Mg), thermal conditions, application of sidewalls as an element of pile bioreactor construction, concentration of O2 and CO2 in the waste piles and the duration of the process from 6 to 9 weeks. The temperature and concentration of O2, CO2, CO, CH4 were measured in each pile at weekly intervals. All six reactors provide stable thermal and aerobic conditions... [more]
11881. LAPSE:2023.27255
Conventional and Advanced Exergy and Exergoeconomic Analysis of a Spray Drying System: A Case Study of an Instant Coffee Factory in Ecuador
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: advanced exergoeconomic analysis, exergy destruction cost rate, spray dryer
Instant coffee is produced worldwide by spray drying coffee extract on an industrial scale. This production process is energy intensive, 70% of the operational costs are due to energy requirements. This study aims to identify the potential for energy and cost improvements by performing a conventional and advanced exergy and exergoeconomic analysis to an industrial-scale spray drying process for the production of instant coffee, using actual operational data. The study analyzed the steam generation unit, the air and coffee extract preheater, the drying section, and the final post treatment process. The performance parameters such as exergetic efficiency, exergoeconomic factor, and avoidable investment cost rate for each individual component were determined. The overall energy and exergy efficiencies of the spray drying system are 67.6% and 30.6%, respectively. The highest rate of exergy destruction is located in the boiler, which amounts to 543 kW. However, the advanced exergoeconomic a... [more]
11882. LAPSE:2023.27254
Analysis of Wind Turbine Aging through Operation Curves
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: performance analysis, technical systems aging, wind energy, wind turbines
The worsening with age of technical systems performance is a matter of fact which is particularly timely to analyze for horizontal-axis wind turbines because they constitute a mature technology. On these grounds, the present study deals with the assessment of wind turbine performance decline with age. The selected test case is a Vestas V52 wind turbine, installed in 2005 at the Dundalk Institute of Technology campus in Ireland. Operation data from 2008 to 2019 have been used for this study. The general idea is analyzing the appropriate operation curves for each working region of the wind turbine: in Region 2 (wind speed between 5 and 9 m/s), the generator speed−power curve is studied, because the wind turbine operates at fixed pitch. In Region 2 12 (wind speed between 9 and 13 m/s), the generator speed is rated and the pitch control is relevant: therefore, the pitch angle−power curve is analyzed. Using a support vector regression for the operation curves of interest, it is observed tha... [more]
11883. LAPSE:2023.27253
Testing Platforms as Drivers for Positive-Energy Living Laboratories
April 4, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: factsheets, positive energy districts labs, statistical studies, testing facilities
The development of city-driven urban laboratories was considered a priority by the European Commission through Action 3.2 of the Strategic Energy Technology Plan. In this context, positive-energy districts laboratories could take the role of urban drivers toward innovation and sustainability in cities. These urban labs can provide real-life facilities with innovative co-creation processes and, at the same time, provide testing, experimenting, and prototyping of innovative technologies. In this scope, the authors of this work want to share the very first results of an empirical study using the testing facilities provided by the members of the Joint Program on Smart Cities of the European Energy Research Alliance as positive-energy districts laboratories. Six climatic regions are studied as boundary conditions, covering temperate and continental climates. Four scales of action are analyzed: Building, campus, urban, and virtual, with building and campus scales being the most frequent. Mos... [more]
11884. LAPSE:2023.27252
Power Exchange Prices: Comparison of Volatility in European Markets
April 4, 2023 (v1)
Subject: Energy Management
Keywords: Power price volatility, Southeast European power markets, volatility comparison
Power exchanges in Europe have been operating since the 1990s, while in the region of Southeast Europe (SEE) they are only a few years old. Volatility is considered to be one of the indicators that define the level of market development. In this paper, the authors examine 15 power markets in Europe with the novelty of special attention dedicated to the SEE markets, in terms of their volatility. The aim of this paper is to investigate volatility on SEE markets, and their correlation with developed European markets. Power price volatility is measured by price velocity concepts, the daily velocity based on daily/monthly/quarterly/yearly and overall average power prices. The outcomes reveal that power price volatility is higher in new SEE markets than in more mature European markets. The least volatile market is the Greek pool, followed by Switzerland and Austria. The Bulgarian market is the most volatile, followed by that of Romania, and these markets are nearly twice as volatile as the o... [more]
11885. LAPSE:2023.27251
Optimization of a 660 MWe Supercritical Power Plant Performance—A Case of Industry 4.0 in the Data-Driven Operational Management. Part 2. Power Generation
April 4, 2023 (v1)
Subject: Numerical Methods and Statistics
Keywords: Artificial Intelligence, combustion, generator power, industry 4.0 for the power sector, supercritical power plant
Modern data analytics techniques and computationally inexpensive software tools are fueling the commercial applications of data-driven decision making and process optimization strategies for complex industrial operations. In this paper, modern and reliable process modeling techniques, i.e., multiple linear regression (MLR), artificial neural network (ANN), and least square support vector machine (LSSVM), are employed and comprehensively compared as reliable and robust process models for the generator power of a 660 MWe supercritical coal combustion power plant. Based on the external validation test conducted by the unseen operation data, LSSVM has outperformed the MLR and ANN models to predict the power plant’s generator power. Later, the LSSVM model is used for the failure mode recovery and a very successful operation control excellence tool. Moreover, by adjusting the thermo-electric operating parameters, the generator power on an average is increased by 1.74%, 1.80%, and 1.0 at 50%... [more]
11886. LAPSE:2023.27250
Drivers for and Barriers to the Take up of Floating Offshore Wind Technology: A Comparison of Scotland and South Africa
April 4, 2023 (v1)
Subject: Energy Policy
Keywords: decarbonisation, floating offshore wind energy, global energy transition, offshore wind, whole systems approach
Offshore wind could both play a significant role in decarbonising the global energy system and supporting the energy needs of cities. Recent trends in offshore wind have seen the installation of turbines in deeper and more remote waters due to the presence of stronger and more consistent wind resources. This has led to the development of floating foundations for turbine mounting in water depths above 40 m, where conventional bottom-fixed foundations are not considered economically feasible. However, due to its emerging nature, floating wind must attain market maturity to be considered cost competitive. It is a widely accepted belief that market expansion yields technological maturity. Therefore, this paper adopts a systems approach to investigate the viability of floating offshore wind power generation in Scotland and South Africa. It does this through a content analysis of relevant secondary documentation, including policy documents, industry reports, press releases, online publicatio... [more]
11887. LAPSE:2023.27249
Origin and Biodegradation of Crude Oils from the Northernmost Fields in the Bolivar Coastal Complex (Zulia State, Venezuela)
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: biodegradation scales, Bolivar Coastal Complex, mixed oils, QEDA analysis, source facies
The organic geochemical features of 30 sampled oils from the northern Bolivar Coastal Complex (Lake Maracaibo Basin, NW Venezuela) were examined by combining carbon isotope, classical biomarker, and extended diamondoid analyses to clarify source facies and to assess the thermal maturity and extent of biodegradation of the oils analyzed. In this work, oils are understood as a mixture of two episodes of petroleum generation from the La Luna Formation: a paleobiodegraded oil pulse during Paleogene times and a late pulse having a higher maturity in the post-Oligocene. For the oil samples analyzed, results revealed a mixing composed of different proportions of almost a terrestrially derived siliciclastic-sourced and a purely marine carbonate-sourced oil pulse. Moreover, two main groups of oils were identified by means of hierarchical cluster analysis. Finally, inter- and intrafield variations in the extent of biodegradation were also assessed using two classification schemes (Peters and Mol... [more]
11888. LAPSE:2023.27248
Quantifying the Flexibility of Electric Vehicles in Germany and California—A Case Study
April 4, 2023 (v1)
Subject: Optimization
Keywords: charging strategy, electric vehicle, electricity pricing, flexibility, flexibility market, home energy management system, Optimization
The adoption of electric vehicles is incentivized by governments around the world to decarbonize the mobility sector. Simultaneously, the continuously increasing amount of renewable energy sources and electric devices such as heat pumps and electric vehicles leads to congested grids. To meet this challenge, several forms of flexibility markets are currently being researched. So far, no analysis has calculated the actual flexibility potential of electric vehicles with different operating strategies, electricity tariffs and charging power levels while taking into account realistic user behavior. Therefore, this paper presents a detailed case study of the flexibility potential of electric vehicles for fixed and dynamic prices, for three charging power levels in consideration of Californian and German user behavior. The model developed uses vehicle and mobility data that is publicly available from field trials in the USA and Germany, cost-optimizes the charging process of the vehicles, and... [more]
11889. LAPSE:2023.27247
Hydrothermal Investigation of a Microchannel Heat Sink Using Secondary Flows in Trapezoidal and Parallel Orientations
April 4, 2023 (v1)
Subject: Process Design
Keywords: flow disruption, microchannels, secondary flow, thermal performance
Thermal performance enhancement in microchannel heat sinks has recently become a challenge due to advancements in modern microelectronics, which demand compatibility with heat sinks able to dissipate ever-increasing amounts of heat. Recent advancements in manufacturing techniques, such as additive manufacturing, have made the modification of the microchannel heat sink geometry possible well beyond the conventional rectangular model to improve the cooling capacity of these devices. One such modification in microchannel geometry includes the introduction of secondary flow channels in the walls between adjacent mainstream microchannels. The present study computationally models secondary flow channels in regular trapezoidal and parallel orientations for fluid circulation through the microchannel walls in a heat sink design. The heat sink is made of silicon wafer, and water is used as the circulating fluid in this study. Continuity, momentum, and energy equations are solved for the fluid fl... [more]
11890. LAPSE:2023.27246
Numerical Framework for Aerodynamic Characterization of Wind Turbine Airfoils: Application to Miniature Wind Turbine WiRE-01
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: large eddy simulation, low Reynolds number airfoil, OpenFOAM, WALE model, wind turbine aerodynamics
A numerical framework for the aerodynamic characterization of wind turbine airfoils is developed and applied to the miniature wind turbine WiRE-01. The framework is based on a coupling between wall-resolved large eddy simulation (LES) and application of the blade element momentum theory (BEM). It provides not only results for the airfoil aerodynamics but also for the wind turbine, and allows to cover a large range of turbine operating conditions with a minimized computational cost. In order to provide the accuracy and the flexibility needed, the unstructured finite volume method (FVM) and the wall-adapting local eddy viscosity (WALE) model are used within the OpenFOAM toolbox. With the purpose of representing the turbulence experienced by the blade sections of the turbine, a practical turbulent inflow is proposed and the effect of the inflow turbulence on the airfoil aerodynamic performance is studied. It is found that the consideration of the inflow turbulence has a strong effect on t... [more]
11891. LAPSE:2023.27245
The Major Driving Forces of the EU and US Ethanol Markets with Special Attention Paid to the COVID-19 Pandemic
April 4, 2023 (v1)
Subject: Materials
Keywords: correlation, COVID, Ethanol, oil, price analysis
Ethanol is a widely produced fuel, as well as a fuel additive. Its price is closely related to the price of gasoline, its major substitute. This paper focuses on the impacts of the related variables on regional ethanol prices. Additionally, the length of the price dataset made it possible to isolate the impacts of COVID-19 on the ethanol prices. Using multiple regression and Confirmatory Factor Analyses, we found no significant correlation between the European and US ethanol prices because the major influencing factors were regionally different. In the case of the European ethanol markets, the positive factors were wheat, maize, and potassium chloride prices, while the European sugar and diammonium phosphate prices were negative. In the US markets, gasoline, sugar, and most of the artificial fertilizer prices were positive, while wheat prices were negative. Based on factor analysis, artificial fertilizers and maize factors proved to be important to the European markets, while US ethano... [more]
11892. LAPSE:2023.27244
Discrete-Time DC-Link Voltage and Current Control of a Grid-Connected Inverter with LCL-Filter and Very Small DC-Link Capacitance
April 4, 2023 (v1)
Subject: Process Control
Keywords: current control, dc-link voltage control, discrete controller, discrete linear-quadratic regulator (DLQR), grid connected inverter, LCL-filter, low sampling frequency, PI voltage controller, small dc-link capacitance, stability analysis
The paper presents a controller design for grid-connected inverters (GCI) with very small dc-link capacitance that are coupled to the grid via an LCL filter. The usual controller designs would fail and result in instability. The proposed controller has a cascaded structure with a current controller as inner control loop and an outer dc-link voltage controller. The controller design is performed in discrete time and it is based on a detailed stability analysis of the dc-link voltage controller to determine the controller parameters which guarantee stability for all operating points. The inner loop is a state-feedback current controller that is designed based on the discrete linear-quadratic regulator (DLQR) theory. An additional integral error feedback assures steady-state accuracy of the current control loop. The simulation and experimental results validate performance and stability of proposed controller design.
11893. LAPSE:2023.27243
Sensitivity Based Order Reduction of a Chemical Membrane Degradation Model for Low-Temperature Proton Exchange Membrane Fuel Cells
April 4, 2023 (v1)
Subject: Modelling and Simulations
Keywords: chemical membrane degradation, fuel cell, Modelling, PEMFC, perfluorinated sulfonic acid membrane, reactive oxygen species, sensitivity analysis
The chemical degradation of the perfluorinated sulfonic acid (PFSA) ion-exchange membrane as a result of an attack from a radical species, originating as a by-product of the oxygen reduction reaction, represents a significant limiting factor in a wider adoption of low-temperature proton exchange membrane fuel cells (LT-PEMFCs). The efficient mathematical modeling of these processes is therefore a crucial step in the further development of proton exchange membrane fuel cells. Starting with an extensive kinetic modeling framework, describing the whole range of chemical processes leading to the membrane degradation, we use the mathematical method of sensitivity analysis to systematically reduce the number of both chemical species and reactions needed to efficiently and accurately describe the chemical degradation of the membrane. The analysis suggests the elimination of chemical reactions among the radical species, which is supported by the physicochemical consideration of the modeled rea... [more]
11894. LAPSE:2023.27242
Performance Assessment of an Islanded Hybrid Power System with Different Storage Combinations Using an FPA-Tuned Two-Degree-of-Freedom (2DOF) Controller
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: diesel generation set, flower pollination technique, organic Rankine cycle, power system optimization, Wind
During the past few decades, there has been significant growth in the renewable energy market because of increased concern over global warming and the continuous depletion of fossil fuel resources. There is a promising solar thermal technology that utilizes low-temperature heat to generate electricity. The conversion process of thermal energy to electricity is based on the principle of an organic Rankine cycle (ORC). This study investigated a novel islanded hybrid power system consisting of an ORC low temperature solar thermal system, wind (WTG), diesel generation (DEG) set, and combined application of an energy storage system (ESS), such as a battery (BESS), super magnetic energy storage (SMES), and an ultracapacitor (UC) unit. Furthermore, the hybrid system was employed with a single controller (one of proportional-integral (PI), PI with derivative (PID), two-degree-of-freedom (2DOF) PI, and 2DOF PID controllers) with proportionate gains to the DEG, and the ESS, which is another uniq... [more]
11895. LAPSE:2023.27241
Study of a Combined Demagnetization and Eccentricity Fault in an AFPM Synchronous Generator
April 4, 2023 (v1)
Subject: Other
Keywords: axial flux, demagnetization, finite element analysis, permanent magnet, static eccentricity, synchronous generator
This article investigates the combined partial demagnetization and static eccentricity fault in an Axial Flux Permanent Magnet (AFPM) Synchronous Generator. The machine is simulated using 3D FEM, while the EMF spectrum is analyzed in order to export the fault related harmonics using the FFT analysis. Firstly, the partial demagnetization fault, without the coexistence of eccentricity, and both the static angular and axis eccentricity faults, without the coexistence of partial demagnetization, are studied. In the case of eccentricity fault, the phase EMF sum spectrum has also been used as a diagnostic mean, because, when only eccentricity fault exists in the generator (either angular or axis) new harmonics do not appear in the EMF spectrum. Secondly the combination of partial demagnetization fault with static axis and static angular eccentricity is investigated and different comparisons are made when the demagnetization and the eccentricity level changes. The investigation revealed that... [more]
11896. LAPSE:2023.27240
Laser Scanner-Based 3D Digitization for the Reflective Shape Measurement of a Parabolic Trough Collector
April 4, 2023 (v1)
Subject: Process Control
Keywords: concentrated solar power, finite element analysis, laser scanning, parabolic trough collector, quality control, shape measurement, three-dimensional digitization
In concentrated solar power technology, the precise shape of the reflective surfaces is crucial for efficiency. Considering the geometry and size of a parabolic trough collector, measuring the actual shape is not trivial and some techniques can only be adopted during the assembly operations, evaluating only the manufacturing and alignment processes. The method proposed and tested in this work exploits a laser scanner-based three-dimensional digitization technique that can be used without any marker or other tools, and is attached to the structure. This technique is particularly suitable for assessing the behavior and the optical efficiency of the collectors under load and for validating a finite element model of the structure. The method defines the shape of the parabolic surface by collecting a 3D point cloud of the parabolic surface using a laser scanner. The measured form can then be compared with the ideal shape obtained from a finite element analysis of the structure subject to th... [more]
11897. LAPSE:2023.27239
Design and Implementation of Solar OLED Lighting Driver Circuit with Frequency Modulation Control
April 4, 2023 (v1)
Subject: Process Control
Keywords: frequency modulation, maximum power point tracking, SEPIC converter, triangular current mode, zero voltage switching
This paper proposes a single-stage single-ended primary inductor converter (SEPIC) converter circuit, which is applied to the organic light-emitting diodes (OLED) driver circuit. The circuit proposed in this paper replaces the output Schottky diode from the original SEPIC with a power switch. Deadtime is added to prevent the on-state overlapping of two switches with zero voltage switching (ZVS), and the circuit operates in triangular current mode. The digital control methods are maximum power point tracking and frequency modulation using a battery to supply the converter and illuminate the OLED at night. Finally, a prototype is implemented to show the feasibility under the DC input voltage range of 10−40 V. The DC output is 12 V/1 A/12 W, and the conversion efficiency is up to 96.3%.
11898. LAPSE:2023.27238
Characteristic Analysis and Predictive Torque Control of the Modular Three-Phase PMSM for Low-Voltage High Power Application
April 4, 2023 (v1)
Subject: Other
Keywords: modular three-phase permanent magnet synchronous motor (PMSM), finite element analysis, mutual inductances, predictive torque control
In this study, a novel modular three-phase permanent magnet synchronous motor (PMSM) is proposed for low-voltage high power applications. The proposed modular three-phase PMSM has an independent segregated three-phase winding configuration, facilitating the implementation of the control algorithm. Firstly, on the basis of the electromagnetic properties, the mathematical model of the modular three-phase PMSM is established, considering the asymmetrical mutual inductances investigated by finite element analysis (FEA). Then, the predictive torque control (PTC) method combining the inductance characteristics of modular three-phase PMSM is developed, and excellent performance is obtained by adjusting the stator flux and torque. Finally, simulation and experiment are performed, and the results show that the proposed novel modular three-phase PMSM with the PTC method exhibits excellent control performance, and small stator current total harmonic distortion (THD).
11899. LAPSE:2023.27237
Legal Pathways to Coal Phase-Out in Italy in 2025
April 4, 2023 (v1)
Subject: Energy Systems
Keywords: coal phase-out, coal-fired generation, de-carbonization, energy regulation
This contribution aims to provide an in-depth outlook of the phase-out of coal-fired energy generation in Italy. In particular, this article analyzes the state-of-the-art with regard to both the current role of coal generation and the performance of the main legal and regulatory tools as implemented in Italy thus far to ensure the closure of all coal power plants by 2025 as announced in the Italian National Climate and Energy Plan. Based on existing data and scenarios on both electricity production and demand trends, this article unfolds the marginal role played by coal-fired generation in the Italian energy mix. In addition, this paper aims to highlight the outstanding technical uncertainties and regulatory hurdles in the way towards de-carbonization of energy generation in Italy. This paper argues that several remarkable improvements are needed in order to avoid over-generation (especially through natural gas), to upscale the penetration of renewable energy sources, and develop the n... [more]
11900. LAPSE:2023.27236
Setting up Energy Efficiency Management in Companies: Preliminary Lessons Learned from the Petroleum Industry
April 4, 2023 (v1)
Subject: Process Design
Keywords: design science research, energy efficiency management, energy use efficiency, pilot implementation
In the era of expensive energy carriers and care for the climate, companies are keen to take action towards bolstering energy efficiency. Businesses often lack data on actual energy consumption to date, are rarely equipped with adequate analytical tools, and do not have the know-how regarding the transition itself. Developing energy efficiency management (EEM) for a given enterprise requires many steps, which ultimately unleash analytical potential and seamlessly integrate the EEM framework with the business model of a given company. This study scrutinizes and formalizes a reference process of pilot EEM implementation that involves external business partners in a multi-facility organization. The process is tailored to the specificity of the company’s operations as well as its technical and management capabilities regarding energy efficiency. The proposed approach, phased in time and involving multiple stakeholders, should be especially useful for practitioners running EEM-related proje... [more]
11901. LAPSE:2023.27235
Structural, Optical and Photocatalytic Characterization of ZnxCd1−xS Solid Solutions Synthetized Using a Simple Ultrasonic Radiation Method
April 4, 2023 (v1)
Subject: Materials
Keywords: H2 production, photocatalyst, sonochemical coprecipitation, ZnxCd1−xS
A simple ultrasonic radiation method was employed for the preparation of zinc and cadmium sulfide solid solution (ZnxCd1−xS; x = 0−0.25 wt.%) with the aim to investigate its efficiency for H2 production via a visible light-driven water-splitting reaction. The catalyst characterization by X-ray diffraction confirmed the formation of solid solution (ZnxCd1−xS) between CdS and ZnS phases. All catalysts exhibited hierarchical morphology (from SEM and TEM) formed by aggregated nanoparticles of ZnxCd1−xS solid solution with crystals showing mainly (111) planes of cubic CdS phase. The crystal size linearly decreased with an increase in Zn incorporation in the crystal lattice (from 4.37 nm to 3.72 nm). The ZnxCd1−xS photocatalysts showed a gradual increase in the H2 evolution, with an increase in the Zn concentration up to 0.2 wt.% making the most effective Zn0.2Cd0.8S catalyst toward H2 production. From the catalyst activity−structure correlation, it has been concluded that the twin-like CdS... [more]
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