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Records with Subject: Modelling and Simulations
1611. LAPSE:2023.26435
Research on the Volumetric Efficiency of 2D Piston Pumps with a Balanced Force
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: 2D piston pump, backflow, leakage, volumetric losses.
Axial piston pumps with high rotational speeds are required in many fields to increase the power-to-weight ratio. However, three main sliding friction pairs in the pump restrict the increase in rotational speed. To solve this problem, we propose a 2D piston pump with a balanced force that contains a sliding friction pair. Firstly, the mechanical structure and working principle of the pump are described. Then, the pump volumetric efficiency is studied by mathematical modeling, and volumetric losses containing backflow and leakage are analyzed and discussed from the perspectives of load pressure and rotational speed. A test bench that verifies the mathematical model is built to measure the volumetric efficiency of the tested pump. We have found that the increase in rotational speed can help to increase the pump volumetric efficiency, and the mathematical model is consistent with the tested data for 1000 rpm but demonstrates a remarkable difference from the tested data for 3000 rpm. Thus,... [more]
1612. LAPSE:2023.26432
Data-Based RC Dynamic Modelling to Assessing the In-Situ Thermal Performance of Buildings. Analysis of Several Key Aspects in a Simplified Reference Case toward the Application at On-Board Monitoring Level
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: building energy performance, building envelope, dynamic analysis, in-situ tests, outdoor testing, performance indicators, thermal parameters.
This paper reports the application of RC dynamic models for assessing thermal performance of buildings from in-situ tests (obtaining the U value for the walls, and the UA value and gA value for the whole buildings). The following aspects which are relevant to this approach have been systematically analyzed: The effect of the solar radiation on the heat flux through the opaque walls versus the performance of the models including this effect, the optimum number of nodes required to represent the thermal systems, the assignment of inputs and outputs and the length of the test period. Additionally, several options modelling relevant effects using unmeasured variables were studied to evaluate the feasibility to reduce the cost and intrusiveness of the measurement devices required to obtain accurate results. Data series recorded under different experimental conditions were considered to analyze the robustness and validity of the results. The performance of the models for each of these differ... [more]
1613. LAPSE:2023.26428
A Local Protection and Local Action Strategy of DC Grid Fault Protection
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: DC circuit breaker, DC grids, fault protection, local action, local detection.
Fast detection and isolation of direct current (DC) faults are key issues for DC grids. Therefore, it is very necessary to study the fault protection principle for DC grids. This paper firstly presents the main difficulties in DC fault protection. Then, a local protection and local action strategy for isolating the DC faults is proposed. To illustrate the performance of the proposed protection strategy, a four-terminal DC grid with the hybrid high voltage direct current (HVDC) circuit breakers (HVDC CBs) is constructed in the time-domain simulation software PSCAD/EMTDC as the test system. The systematical comparison between the ordinary protection strategy and the proposed strategy is carried out. The protection selectivity of the proposed local detection and local action strategy is thoroughly studied through complete DC line fault scanning of the test system. The simulation results show that the proposed strategy is of high protection selectivity and speed. In addition, the current r... [more]
1614. LAPSE:2023.26421
An Artificial Neural Network for the Low-Cost Prediction of Soot Emissions
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: artificial neural network, combustion, Computational Fluid Dynamics, estimator, soot concentration, soot emissions.
Soot formation in combustion systems is a growing concern due to its adverse environmental and health effects. It is considered to be a tremendously complicated phenomenon which includes multiphase flow, thermodynamics, heat transfer, chemical kinetics, and particle dynamics. Although various numerical approaches have been developed for the detailed modeling of soot evolution, most industrial device simulations neglect or rudimentarily approximate soot formation due to its high computational cost. Developing accurate, easy to use, and computationally inexpensive numerical techniques to predict or estimate soot concentrations is a major objective of the combustion industry. In the present study, a supervised Artificial Neural Network (ANN) technique is applied to predict the soot concentration fields in ethylene/air laminar diffusion flames accurately with a low computational cost. To gather validated data, eight different flames with various equivalence ratios, inlet velocities, and bu... [more]
1615. LAPSE:2023.26415
A Comparison of Various Bottom-Up Urban Energy Simulation Methods Using a Case Study in Hangzhou, China
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: bottom-up approach, multi-zone models, urban energy simulation method.
Urban energy simulation can provide valuable information to urban planning, urban energy management, and urban emission reduction. Therefore, urban energy simulation has become an active research discipline. Various urban energy simulation methods and techniques have been developed and applied to cities on different scales. A review is conducted to categorize these methods and techniques and to analyze their pros and cons. Several representative methods and techniques are compared for their data inputs, suitable scales, accuracy, and computing speeds. Hangzhou South Railway Station area, which contains 522 buildings, is used as the case to evaluate the effectiveness and challenges of different urban energy simulation methods.
1616. LAPSE:2023.26414
Demand-Response Application in Wastewater Treatment Plants Using Compressed Air Storage System: A Modelling Approach
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: anaerobic digestion, demand response, energy consumption optimization, multi-objective model, wastewater treatment, water-energy nexus.
Wastewater treatment plants (WWTPs) are known to be one of the most energy-intensive industrial sectors. In this work, demand response was applied to the biological phase of wastewater treatment to reduce plant electricity cost, considering that the daily peak in flowrate typically coincides with the maximum electricity price. Compressed air storage system, composed of a compressor and an air storage tank, was proposed to allow energy cost reduction. A multi-objective modelling approach was applied by analyzing different scenarios (with and without anaerobic digestion, AD), considering both plant characteristics (in terms of treated flowrate and influent chemical oxygen demand, COD, concentration) and storage system properties (volume, air pressure), together with the current Italian market economic conditions. The results highlight that air tank volume has a strong positive influence on the obtainable economic savings, with a less significant impact held by air pressure, COD concentra... [more]
1617. LAPSE:2023.26411
Performance Assessment of Large Photovoltaic (PV) Plants Using an Integrated State-Space Average Modeling Approach
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: distributed converters, large photovoltaic fields, state-space average modeling.
Distributed power converters represent a technical solution to improve the performance of large or utility-scale photovoltaic (PV) plants. Unfortunately, evaluation of the yield obtained in large PV fields by using distributed converters is a difficult task because of recurring partial unavailability, inaccuracy of power analyzers, operating constraints imposed by the Power Plant Controller and so on. To overcome such issues in real operating scenarios, a new modeling strategy has been introduced and validated in terms of computational complexity and accuracy. This approach is based on the state-space averaging technique which is applied to large PV plants with multiple conversion stages by performing some elaborations in order to get a final integrated model. The new modeling strategy has been tested in MatLab Simulink environment using data coming from a 300 MW PV plant located in Brazil representing the case study of this work. In this plant, one subfield is equipped with central in... [more]
1618. LAPSE:2023.26401
Computational and Experimental Study of Convection in a Vanadium Redox Flow Battery Strip Cell Architecture
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Computational Fluid Dynamics, convective mass transport, current distribution, model validation, strip cell, vanadium redox flow battery.
The impact of convection on electrochemical performance, performance distribution, and local pressure drop is investigated via simple strip cell architecture, a cell with a single straight channel. Various channel depths (0.25, 0.5, 1, 2.5 mm) and flow rates (10−50 mL min−1 cm−2) are employed to induce a wide range of electrolyte velocities within the channel and electrode. Computational flow simulation is utilized to assess velocity and pressure distributions; experimentally measured in situ current distribution is quantified for the cell. Although the total current in the cell is directly proportional to electrolyte velocity in the electrode, there is no correlation detected between electrolyte velocity in the channel and the total current. It is found that the maximum achievable current is limited by diffusion mass transport resistance between the liquid electrolyte and the electrode surfaces at the pore level. Low electrolyte velocity induces large current gradients from inlet to o... [more]
1619. LAPSE:2023.26399
Temperature Distribution in Insulated Temperature-Controlled Container by Numerical Simulation
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: cold chain, cold-storage container, Computational Fluid Dynamics, numerical analysis, Optimization, temperature distribution.
Cold-storage containers are widely used in cold-chain logistics transportation due to their energy saving, environmental protection, and low operating cost. The uniformity of temperature distribution is significant in agricultural-product storage and transportation. This paper explored temperature distribution in the container by numerical simulation, which included ventilation velocity and the fan location. Numerical model/numerical simulation showed good agreement with experimental data in terms of temporal and spatial air temperature distribution. Results showed that the cooling rate improved as velocity increased, and temperature at 45 min was the lowest, when velocity was 16 m/s. Temperature-distribution uniformity in the compartment became worse with the increase in ventilation velocity, but its lowest temperature decreased with a velocity increase. With regard to fan energy consumption, the cooling rate of the cooling module, and temperature-field distribution in the product are... [more]
1620. LAPSE:2023.26396
IoT-Based Digital Twin for Energy Cyber-Physical Systems: Design and Implementation
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: cyber-physical systems, digital twin, distributed resources, industrial internet of things.
With the emergence of distributed energy resources (DERs), with their associated communication and control complexities, there is a need for an efficient platform that can digest all the incoming data and ensure the reliable operation of the power system. The digital twin (DT) is a new concept that can unleash tremendous opportunities and can be used at the different control and security levels of power systems. This paper provides a methodology for the modelling of the implementation of energy cyber-physical systems (ECPSs) that can be used for multiple applications. Two DT types are introduced to cover the high-bandwidth and the low-bandwidth applications that need centric oversight decision making. The concept of the digital twin is validated and tested using Amazon Web Services (AWS) as a cloud host that can incorporate physical and data models as well as being able to receive live measurements from the different actual power and control entities. The experimental results demonstra... [more]
1621. LAPSE:2023.26389
Steady-State Performance Prediction for a Variable Speed Direct Expansion Air Conditioning System Using a White-Box Based Modeling Approach
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: DX A/C system, steady-state performance, variable speed, white-box modeling.
When using a certain type of Heating, Ventilation & Air Conditioning (HVAC) systems, it is primary to obtain their steady-state operating behaviors for achieving a better indoor thermal environment. This paper reports a development of a white-box-based dynamic model for a direct expansion (DX) air conditioning (A/C) system to predict its steady-state operating performance under variable speed operation. The established model consists of five sub-models, i.e., a compressor, an electronic expansion valve, an evaporator, a condenser and a conditioned space. Each sub-model was developed based on partial lumped parameter approach. Using the available data generated from an experimental DX A/C system, both transient and steady-state behaviors predictions agreed well with the experimental ones. With the help of the validated white-box model, the inherent steady-state operating performance expressed in terms of the relationship among total cooling capacity (TCC), equipment sensible heat ratio... [more]
1622. LAPSE:2023.26375
Development of a Eulerian Multi-Fluid Solver for Dense Spray Applications in OpenFOAM
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Computational Fluid Dynamics, Euler multi-fluid, liquid spray, OpenFOAM, WAVE breakup.
The new generation of internal combustion engines is facing various research challenges which often include modern fuels and different operating modes. A robust modeling framework is essential for predicting the dynamic behavior of such complex phenomena. In this article, the implementation, verification, and validation of a Eulerian multi-fluid model for spray applications within the OpenFOAM toolbox are presented. Due to its open-source nature and broad-spectrum of available libraries and solvers, OpenFOAM is an ideal platform for academic research. The proposed work utilizes advanced interfacial momentum transfer models to capture the behavior of deforming droplets at a high phase fraction. Furthermore, the WAVE breakup model is employed for the transfer of mass from larger to smaller droplet classes. The work gives detailed instructions regarding the numerical implementation, with a dedicated section dealing with the implementation of the breakup model within the Eulerian multi-flu... [more]
1623. LAPSE:2023.26372
Mathematical Modeling and Pointwise Validation of a Spouted Bed Using an Enhanced Bed Elasticity Approach
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: CFD modeling, elasticity modulus, Euler-two-phase model, spouted bed, validation experiments.
With a Euler−Euler (E2P) approach, a mathematical model for predicting the pointwise hydrodynamic behavior of a spouted bed was implemented though computational fluid dynamics (CFD) techniques. The model considered a bed elasticity approach in order to reduce the number of required sub-models to provide closure for the solids stress strain-tensor. However, no modulus of elasticity sub-model for a bed elasticity approach has been developed for spouted beds, and thus, large deviations in the predictions are obtained with common sub-models reported in literature. To overcome such a limitation, a new modulus of elasticity based on a sensitivity analysis was developed and implemented on the E2P model. The model predictions were locally validated against experimental measurements obtained in previous studies. The experimental studies were conducted using our in-house developed advanced γ-ray computed tomography (CT) technique, which allows to obtain the cross-sectional time-averaged solids h... [more]
1624. LAPSE:2023.26364
A Model to Improve Granular Temperature in CFD-DEM Simulations
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: CFD-DEM, drag force, fluidized beds, granular temperature.
CFD-DEM (computational fluid dynamic-discrete element method) is a promising approach for simulating fluid−solid flows in fluidized beds. This approach generally under-predicts the granular temperature due to the use of drag models for the average drag force. This work develops a simple model to improve the granular temperature through increasing the drag force fluctuations on the particles. The increased drag force fluctuations are designed to match those obtained from PR-DNSs (particle-resolved direct numerical simulations). The impacts of the present model on the granular temperatures are demonstrated by posteriori tests. The posteriori tests of tri-periodic gas−solid flows show that simulations with the present model can obtain transient as well as steady-state granular temperature correctly. Moreover, the posteriori tests of fluidized beds indicated that the present model could significantly improve the granular temperature for the homogenous or slightly inhomogeneous systems, whi... [more]
1625. LAPSE:2023.26362
Unsteady Numerical Calculation of Oblique Submerged Jet
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: numerical simulation, submerged jet, unsteady flow.
A water jet is a kind of high-speed dynamic fluid with high energy, which is widely used in the engineering field. In order to analyze the characteristics of the flow field and the change of law of the bottom impact pressure of the oblique submerged impinging jet at different times, its unsteady characteristics at different Reynolds numbers were studied by using the Wray−Agarwal (W-A) turbulence model. It can be seen from the results that in the process of jet movement, the pressure at the peak of velocity on the axis was the smallest, and the velocity, flow angle, and pressure distribution remain unchanged after a certain time. In the free jet region, the velocity, flow angle, and pressure remained unchanged. In the impingement region, the velocity and flow angle decreased rapidly, while the pressure increased rapidly. The maximum pressure coefficient of the impingement plate changed with time and was affected by the Reynolds number, but the distribution trend remained the same. In th... [more]
1626. LAPSE:2023.26361
Detection of Non-Technical Losses in Power Utilities—A Comprehensive Systematic Review
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: Artificial Intelligence, electricity theft, Machine Learning, non-technical loss, power utilities.
Electricity theft and fraud in energy consumption are two of the major issues for power distribution companies (PDCs) for many years. PDCs around the world are trying different methodologies for detecting electricity theft. The traditional methods for non-technical losses (NTLs) detection such as onsite inspection and reward and penalty policy have lost their place in the modern era because of their ineffective and time-consuming mechanism. With the advancement in the field of Artificial Intelligence (AI), newer and efficient NTL detection methods have been proposed by different researchers working in the field of data mining and AI. The AI-based NTL detection methods are superior to the conventional methods in terms of accuracy, efficiency, time-consumption, precision, and labor required. The importance of such AI-based NTL detection methods can be judged by looking at the growing trend toward the increasing number of research articles on this important development. However, the autho... [more]
1627. LAPSE:2023.26343
Dynamic Pore-Scale Network Modeling of Spontaneous Water Imbibition in Shale and Tight Reservoirs
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: dynamic pore network modeling, shale reservoirs, water imbibition.
Spontaneous water imbibition plays an imperative role in the development of shale or tight oil reservoirs. Spontaneous water imbibition is helpful in the extraction of crude oil from the matrix, although it decreases the relative permeability of the hydrocarbon phase dramatically. The dynamic pore-scale network modeling of water imbibition in shale and tight reservoirs is presented in this work; pore network generation, local capillary pressure function, conductance calculation and boundary conditions for imbibition are all presented in detail in this paper. The pore network is generated based on the characteristics of Barnett shale formations, and the corresponding laboratory imbibition experiments are matched using this established dynamic pore network model. The effects of the wettability, throat aspect ratio, viscosity, shape factor, micro-fractures, etc. are all investigated in this work. Attempts are made to investigate the water imbibition mechanisms from a micro-scale perspecti... [more]
1628. LAPSE:2023.26340
Comparison of Electricity Spot Price Modelling and Risk Management Applications
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: conditional value at risk, electricity pricing, risk management.
In dealing with sharp changes in electricity prices, contract planning is considered as a vital risk management tool for stakeholders in deregulated power markets. In this paper, dynamics of spot prices in Turkish electricity market are analyzed, and predictive performance of several models are compared, i.e., time series models and regime-switching models. Different models for derivative pricing are proposed, and alternative portfolio optimization problems using mean-variance optimization and conditional value at risk (CVaR) are solved. Expected payoff and risk structure for different hedging strategies for a hypothetical electricity company with a given demand are analyzed. Experimental studies show that regime-switching models are able to capture electricity characteristics better than their standard counterparts. In addition, evaluations with various risk management models demonstrate that those models are highly competent in providing an effective risk control practice for electri... [more]
1629. LAPSE:2023.26335
Modelling of the Long-Term Acid Gas Sequestration and Its Prediction: A Unique Case Study
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: gas sequestration, geological structure, leakage risk, reservoir modelling, sequestration capacity, trapping mechanisms.
A twenty-four-year on-going project of acid gas sequestration in a deep geological structure was subject to detailed modelling based upon a large set of geological, geophysical, and petrophysical data. The model was calibrated against available operational and monitoring data and used to determine basic characteristics of the sequestration process, such as fluid saturations and compositions, their variation in time due to fluid migrations, and the gas transition between free and aqueous phases. The simulation results were analysed with respect to various gas leakage risks. The contribution of various trapping mechanisms to the total sequestrated amount of injected gas was estimated. The observation evidence of no acid gas leakage from the structure was confirmed and explained by the simulation results of the sequestration process. The constructed and calibrated model of the structure was also used to predict the capacity of the analysed structure for increased sequestration by finding... [more]
1630. LAPSE:2023.26333
Numerical Modelling and Experimental Validation of Twin-Screw Expanders
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: air, built-in volume ratio, chamber model, Computational Fluid Dynamics, expander, optimisation, performance, twin screw, validation.
Positive displacement machines have been identified as appropriate expanders for small-scale power generation systems such as Organic Rankine Cycles (ORCs). Screw expanders can operate with good efficiency in working fluids under both dry and two-phase conditions. Detailed understanding of the fluid expansion process is required to optimise the machine design and operation for specific applications, and accurate design tools are therefore essential. Using experimental data for air expansion, both CFD and chamber models have been applied to investigate the influence of port flow and leakage on the expansion process. Both models are shown to predict pressure variation and power output with good accuracy. The validated chamber model is then used to identify the optimal volume ratio and rotational speed for experimental conditions.
1631. LAPSE:2023.26326
HV Transformer Protection and Stabilization under Geomagnetically Induced Currents
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: differential protection, geomagnetic disturbance, geomagnetically induced current, power transformer, protection stabilization.
This paper presents the results of research related to the issues arising from DC excitation of power transformers due to geomagnetically induced currents (GIC). First, the GIC phenomena and their influence on power system operation are discussed. Then, a recorded case of tripping of the transformer differential protection due to geomagnetic disturbances (GD), as well as simulation signals from a developed model of a transformer subjected to a GD are analyzed. Next, two algorithms for GIC detection utilizing the rate of change of transformer differential currents and the DC component in the neutral current are proposed, thoroughly tested, and recommended.
1632. LAPSE:2023.26324
Modeling of an Integrated Thermoelectric Generation−Cooling System for Thermoelectric Cooler Waste Heat Recovery
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: cold end temperature, heat source, nonlinear, thermoelectric generation–cooling, transient analysis.
This paper focuses on the problem of thermoelectric cooler waste heat recovery and utilization, and proposes taking the waste heat together with the original heat source as the input heat source of the integrated thermoelectric generation−cooling system. By establishing an analytic model of this integrated thermoelectric generation−cooling system, the steady-state and transient thermal effects of this system are analyzed. The steady-state analysis results show that the thermoelectric generator’s actual heat source is about 20% larger than the intrinsic heat source. The transient analysis results prove that the current of thermoelectric power generation and the cold end temperature of the system show a nonlinear change rate with time. The cold end temperature of the system has a maximum value. Under different intrinsic heat sources, this maximum value can be reached between 1 s and 2.5 s.
1633. LAPSE:2023.26323
Validating CFD Predictions of Flow over an Escarpment Using Ground-Based and Airborne Measurement Devices
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: complex terrain, mesoscale-microscale coupling, tower measurements, unmanned aircraft systems (UAS).
Micrometeorological observations from a tower, an eddy-covariance (EC) station and an unmanned aircraft system (UAS) at the WINSENT test-site are used to validate a computational fluid dynamics (CFD) model, driven by a mesoscale model. The observation site is characterised by a forested escarpment in a complex terrain. A two-day measurement campaign with a flow almost perpendicular to the escarpment is analysed. The first day is dominated by high wind speeds, while, on the second one, calm wind conditions are present. Despite some minor differences, the flow structure, analysed in terms of horizontal wind speeds, wind direction and inclination angles shows similarities for both days. A real-time strategy is used for the CFD validation with the UAS measurement, where the model follows spatially and temporally the aircraft. This strategy has proved to be successful. Stability indices such as the potential temperature and the bulk Richardson number are calculated to diagnose atmospheric b... [more]
1634. LAPSE:2023.26322
System Design and Modeling of a High Temperature PEM Fuel Cell Operated with Ammonia as a Fuel
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: ammonia, fuel cell, high temperature PEM.
Ammonia is a hydrogen-rich compound that can play an important role in the storage of green hydrogen and the deployment of fuel cell technologies. Nowadays used as a fertilizer, NH3 has the right peculiarities to be a successful sustainable fuel for the future of the energy sector. This study presents, for the first time in literature, an integration study of ammonia as a hydrogen carrier and a high temperature polymer electrolyte membrane fuel cell (HT-PEMFC) as an energy conversion device. A system design is presented, that integrates a reactor for the decomposition of ammonia with an HT-PEMFC, where hydrogen produced from NH3 is electrochemically converted into electricity and heat. The overall system based on the two technologies is designed integrating all balance of plant components. A zero-dimensional model was implemented to evaluate system efficiency and study the effects of parametric variations. Thermal equilibrium of the decomposition reactor was studied, and two different... [more]
1635. LAPSE:2023.26308
Reactant Feeding Strategy Analysis of Sodium Borohydride Hydrolysis Reaction Systems for Instantaneous Hydrogen Generation
April 3, 2023 (v1)
Subject: Modelling and Simulations
Keywords: feeding strategy, hydrogen-on-demand, hydrolysis reaction, sodium borohydride, start-up.
In this study, the operational procedure of an experiment and simulation for a hydrogen-on-demand system using sodium borohydride hydrolysis is proposed. For an isothermal operating condition of a packed-bed reactor, the dynamic response between the input NaBH4 feed (FNaBH) and the output hydrogen flowrate (FH) of the reactor can be analytically derived and is a first-order transfer function. The time constant of this transfer function is a function of the reciprocal of the product of the reaction rate constant and the catalyst weight into the liquid volume of the reactor. The kinetic parameters of Co-B/IR-200 catalysts are regressed from the experimental NaBH4 hydrolysis reaction. The result shows a 30 °C operating temperature increase (from 40 °C till 70 °C) can shorten the dynamic response time of the hydrogen generation rate by around two-thirds. From theoretical derivation, a feeding strategy which supplies the combination of impulse function and step function of the NaBH4 feed fl... [more]
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