Soot particles in diesel engine exhaust is one of the main reasons for hazy weather and elimination of them is urgent for environmental protection. At present, it is still a challenge to develop new catalysts with high efficiency and low cost. In this paper, a kind of K modified three-dimensionally ordered macroporous (3DOM) MnCeOx/Ti0.7Si0.3O2 catalysts are designed and synthesized by a sample method. Due to the macroporous structure and synergistic effect of K, Mn, and Ce, the KnMnCeOx/Ti0.7Si0.3O2 (KnMnCeOx/M-TSO) catalysts exhibit good catalytic performance for soot combustion. The catalytic activity of K0.5MnCeOx/M-TSO was the best, and the T10, T50, and T90 are 287, 336, and 367 °C, respectively. After the prepared catalyst was doped with K, the physicochemical properties and catalytic performance changed significantly. In addition, the K0.5MnCeOx/M-TSO catalyst also somewhat exhibits sulfur tolerance owing to it containing Ti. Because of its simple synthesis, high activity, and... [more]

Bacterial cell immobilization offers considerable advantages over traditional biotreatment methods using free bacteria. Bacillus velezensis was underwented isolation and genetic identification as COD-degrading bacteria in slaughter wastewaterand immobilized on the surface of polyvinyl alcohol (PVA) microsphere with the adhesion to bio-carrier through direct physical adsorption. The removal CODMn rates of microsphere (PVA) immobilized cells were 16.99%, increased 9.38% from a 50% concentration of slaughter wastewater within 24 h at 37 °C, pH 7.0, and 120 rpm, which was about 2.2 times that of the free bacteria. A significant difference was found in two groups (p < 0.01 p value less than 0.01 means statistical significance), and the COD degradation rate of the microsphere immobilized Bacillus velezensis strain was higher than the control group (PVA: control vs 20.08: 10.81), with the processing time reaching 36 h (p < 0.05). Additionally, similar results were obtained from a 20% co... [more]

Serious traffic-related pollution and high population density during the spring festival (Chinese new year) travel rush (SFTR) increases the travelers’ exposure risk to pollutants and biohazards. This study investigates personal exposure to particulate matter (PM) mass concentration when commuting in five transportation modes during and after the 2020 SFTR: China railway high-speed train (CRH train), subway, bus, car, and walking. The routes are selected between Nanjing and Xuzhou, two major transportation hubs in the Yangtze Delta. The results indicate that personal exposure levels to PM on the CRH train are the lowest and relatively stable, and so it is recommended to take the CRH train back home during the SFTR to reduce the personal PM exposure. The exposure level to PM2.5 during SFTR is twice as high as the average level of Asia, and it is higher than the WHO air quality guideline (AQG).

It is with great pleasure that we present to you the output of the Special Issue Study of Biodegradation and Bioremediation [...]

One of the greatest challenges of the 21st century is to fulfill the growing energy needs sustainably and cost-effectively. Among the different sources of energy, biodiesel is one of the alternative energy sources that has tremendous potential to become a major mainstream renewable energy mix. Jatropha is an important raw input for biodiesel that provides an ecological and sustainable solution for emerging greenhouse gas emissions over the other biomass feedstock. This paper critically evaluates different factors and presents a SWOT analysis (strengths, weaknesses, opportunities, and threats) and barriers to the adoption of Jatropha biodiesel. In Pakistan, the estimated production of Jatropha biodiesel is expected to be 2.93 million tons, that are calculated from available barren land and possible shortlisted suitable areas for Jatropha plantation. It is ~25% of the total import (11.84 million tons) of petroleum products, which can save ~$2 billion USD reserves of Pakistan. The cultiva... [more]

This study verified the environmental effectiveness of potentially less aggressive routes for the synthesis of poly(propylene/ethylene oxide) glycol (PPG). The analysis was developed in two stages. Firstly, the environmental performance of the conventional PPG processing route was compared to alternative variants—vegetal PPG and CO2-based PPG—applying the life cycle assessment technique to measure the primary energy demand, global warming potential, acidification, photochemical oxidation, and freshwater ecotoxicity impact categories. The synthesis of vegetable polyols from bio-based assets, such as vegetable oils, and the application of CO2 conversion routes as an alternative to technologies supported by petroleum and natural gas were studied. The use of CO2 recovered through carbon capture and usage practices resulted in environmental gains for PPG production. The processing routes within vegetal assets were not an environmentally attractive option as the performance was worse than th... [more]

The environmental issue has become a global problem that needs to be examined frequently, motivating researchers to investigate it. Thus, the present study has investigated the asymmetric impact of globalization, economic growth and natural resources on the ecological footprint in the presence of environmental Kuznets curve (EKC) in Thailand. The study has used annual time series data from 1970 to 2018. The study applied a novel method of nonlinear autoregressive distributive lag (ARDL). In particular, the current study has investigated the effect of positive and negative shocks on the independent variable on the dependent variable. The findings have confirmed that the effect of globalization and natural resources are significant and nonlinear. However, the effect of negative shocks of globalization and natural resources is more dominant on the ecological footprint in Thailand than the positive shocks of both variables. Moreover, the present study has also tested the presence of EKC in... [more]

High concentrations of particulate COD (pCOD) in the influent of aerobic granular sludge (AGS) systems are often associated to small granule diameter and a large fraction of flocculent sludge. At high particulate concentrations even granule stability and process performance might be compromised. However, pilot- or full-scale studies focusing on the effect of real wastewater particulates on AGS are scarce. This study describes a 3-month period of increased particulate loading at a municipal AGS wastewater treatment plant. The pCOD concentration of the influent increased from 0.5 g COD/L to 1.3 g COD/L, by adding an untreated slaughterhouse wastewater source to the influent. Sludge concentration, waste sludge production and COD and nutrient removal performance were monitored. Furthermore, to investigate how the sludge acclimatises to a higher influent particulate content, lipase and protease hydrolytic activities were studied, as well as the microbial community composition of the sludge.... [more]

Currently, people worldwide, in the period from September to April, observe with their own eyes and feel the pollution of the air, called smog, in their own breath. The biggest cause of smog and the source of air pollution is burning rubbish in stoves. Other causes include exhaust fumes from large factories, burning coal in furnaces, and car exhaust fumes. Smog is an unnatural phenomenon, directly related to human activity. The weather is becoming worse. On no-wind, foggy days, the smog phenomenon is the most troublesome for city dwellers. Smog persists in European countries from November to April, during the heating season. The harmful effect of smog affects almost the entire human body. Every year, air pollution causes the death of approximately 26,000−48,000 people. At the same time, poor air quality reduces life expectancy by up to a year. The purpose of this article is to present buildings and finishing elements that can help in the fight against air pollution.

Soil aggregates are among crucial factors for determining both the quality and erosion resistance of soils. Biochar is a soil amendment that has seen increasing use to improve specific soil properties, mainly the physical structure and the preserving capacity of water and nutrients, as well as sequestration of soil organic carbon. In this study, we applied the rice husk biochar (RHB) and cattle manure compost (COM) in a sandy loam rural soil, which is widely distributed in southern Taiwan, to investigate the combined effects of the biochar and compost on soil aggregation and dynamic change of organic carbon fractions. Through our incubation experiment, both biochar and compost could promote the soil aggregation after eight weeks incubation. The total amounts of macroaggregates (MaAs, >2.0 mm) and mesoaggregates (MeAs, 0.25−2.0 mm) increased by 1.3−9%. During aggregation processes, a considerably greater amount of the soil organic carbon was found to enrich mainly in MaAs and MeAs in al... [more]

Electric vehicles (EVs) are regarded as an effective method for dealing with serious environmental pollution. The Chinese government has implemented a series of incentives to accelerate the promotion of EV. However, the increasing production of EVs gives rise to a greater demand for better quality charging station. This study aimed to certify the impact of the production of EVs on charging station research and development (R&D) in China, with mediating effect methods and a panel fixed effect model. The conclusions derived from the study were: (1) Statistically, the production of EVs positively and significantly impacts charging station R&D; (2) the mediating role of investment in charging stations is verified in the relationship between the production of EVs and charging station R&D; (3) environmental tax can moderate the relationship between the production of EVs and charging station R&D. These results implicate, for the first time, that the production of EVs can enhance charging stat... [more]

Heavy metal-containing wastewater with high salinity challenges wastewater treatment plants (WWTPs) where the conventional activated sludge process is widely applied. Bioremediation has been proven to be an effective, economical, and eco-friendly technique to remove heavy metals from various wastewaters. The newly developed algal-bacterial aerobic granular sludge (AGS) has emerged as a promising biosorbent for treating wastewater containing heavy metals, especially Cr(VI). In this study, two identical cylindrical sequencing batch reactors (SBRs), i.e., R1 (Control) and R2 (with 1% additional salinity), were used to cultivate algal-bacterial AGS and then to evaluate the effect of salinity on the performance of the two SBRs. The results reflected that less filamentation and a rougher surface could be observed on algal-bacterial AGS when exposed to 1% salinity, which showed little influence on organics removal. However, the removals of total inorganic nitrogen (TIN) and total phosphorus (... [more]

Bioethanol has many environmental and practical benefits as a transportation fuel. It is one of the best alternatives to replace fossil fuels due to its liquid nature, which is similar to the gasoline and diesel fuels traditionally used in transportation. In addition, bioethanol production technology has the capacity for negative carbon emissions, which is vital for solving the current global warming dilemma. However, conventional bioethanol production takes place based on an inland site and relies on freshwater and edible crops (or land suitable for edible crop production) for production, which has led to the food vs. fuel debate. Establishing a coastal marine biorefinery (CMB) system for bioethanol production that is based on coastal sites and relies on marine resources (seawater, marine biomass and marine yeast) could be the ultimate solution. In this paper, we aim to evaluate the environmental impact of using seawater for bioethanol production at coastal locations as a step toward... [more]

The increasing trends in gas pollution, water pollution, and solid waste pollution have an adverse impact on human health and ecological habitats [...]

The article summarizes the arguments within the scientific discussion about performance management in mining companies and their significance for obtaining competitiveness in the market of mining companies in the direction of sustainable development and economic growth. The main goal of the paper is to evaluate the performance indicators of mining processes after the implementation of strategic innovation—a new layout of the mining area focused on a combination of stationary and mobile mining equipment and their influence on the environment in a selected mining company in Slovakia in area of mining of limestone. Methods of research were focused on using economic indicators for the valuation of the efficiency and functionality of the mining processes. We used Pareto analysis for evaluation that points to critical mining processes and their significance in the financial area with orientation to costs, revenues. This research was used economic analysis with direction to efficiency, an ind... [more]

Rare earth elements (REEs) are strategic materials widely used in different applications from Information and Communication Technologies (ICT) to catalysis, which are expected to grow more in the future. In order to reduce the impact of market price and reduce the environmental effect from soil extraction, recovery/purification strategies should be exploited. This paper presents a combined acid-leaching/oxalate precipitation process to recover lanthanum from spent FCC catalyst using nitric acid. Preferred to hydrochloric and sulphuric acid (preliminary assessed), HNO3 showed a good capability to completely leach lanthanum. The combination with an oxalate precipitation step allowed demonstrating that a highly pure (>98% w/w) lanthanum solid can be recovered, with a neglectable amount of poisoning metals (Ni, V) contained into the spent catalyst. This could open a reliable industrial perspective to recover and purify REE in the view of a sustainable recycling strategy.

In this research work, MFe2O4/CNS was prepared using the hydrothermal−microwave method. The influence of cations (M) toward functional groups of composites and their performance in pesticide degradation were studied. Rice husk was pyrolyzed hydrothermally (200 °C, 6 h) and by microwave (800 W, 40 min). Each product was mixed with MCl2 (Zn, Ni, Mn), FeCl3, KOH, and water, and calcined (600 °C, 15 min) to obtain a composite. Characterization by XRD confirmed the MFe2O4/CNS structure. The FTIR spectra of the composites showed different band sharpness related to C-O and M-O. A mixture of dried paddy farm soil, composite, BPMC (buthylphenylmethyl carbamate) pesticide solution (0.25%), and H2O2 solution (0.15%) was kept under dark conditions for 48 h. The solution above the soil was filtered and measured with a UV-Vis spectrophotometer at 217 nm. Applications without the composite and composite−H2O2 were also conducted. The results reveal that dark BPMC degradation with the composite was 7.5... [more]

The long-term field experiment on the Kastanozem showed that the standard moldboard plowing to a depth of 22 cm (control), chiseling to a depth of 35 cm, and three-tier plowing (machine type PTN−40) to a depth of 45 cm was incapable of providing a stable soil structure and aggregate system. The transcendental Biogeosystem Technique (BGT*) methodology for intra-soil milling of the 20−45 cm layer and the intra-soil milling PMS−70 machine were developed. The PMS−70 soil processing provided the content of 1−3 mm sized aggregate particle fraction in the illuvial horizon of about 50 to 60%, which was 3-fold higher compared to standard plowing systems. Soil bulk density reduced in the layer 20−40 cm to 1.35 t m−3 compared to 1.51 t m−3 in the control option. In the control, the rhizosphere developed only in the soil upper layer. There were 1.3 roots per cm2 in 0−20 cm, and 0.2 roots per cm2 in 20−40 cm. The rhizosphere spreads only through the soil crevices after chilling. After three-tier pl... [more]

Analyzing the entire liquefaction cycle, using a large temperature span with many degrees of freedom, may not always result in a practical solution. The objective of this paper is to investigate the feasibility of using an environmentally friendly refrigerant compound, ammonia, in the mixed refrigerant (MR) for the liquefied natural gas (LNG) pre-cooling cycle through thermodynamic performance, economic analyses and environmental impact. Fifteen cases studies within three major mixed refrigerants groups of MR-1, MR-2 and MR-3 were developed by adding ammonia to various molar compositions of lighter and heavier hydrocarbons. The thermodynamic analysis shows increasing ammonia’s concentrations in the mixed refrigerant by 10% had the largest enhancement on coefficient of performance (COP) of MR-1 by 0.67 and decreased the specific energy consumption of the pre-cooling cycle by 128 kJ/kg compared to the base case. Economic analyses revealed that the mixed refrigerant MR-1, with ammonia, me... [more]

Soil contamination by mercury, which is one of the most toxic heavy metals due to its bioaccumulative capacity, poses a risk to the environment as well as health. The Almadén mining district in Ciudad Real, Spain is one of the most heavily-polluted sites in the world, making the soils unusable. Bioremediation, and more specifically phyto-rhizoremediation, based on the synergistic interaction established between plant and Plant Growth Promoting Rhizobacteria (PGPR), improves the plant’s ability to grow, mobilize, accumulate, and extract contaminants from the soil. The objective of this study is to evaluate the plant growth-promoting ability of four PGPR strains (and mixtures), isolated from the bulk soil and rhizosphere of naturally grown plants in the Almadén mining district, when they are inoculated in emerged seeds of Lupinus albus, var. Dorado in the presence of high concentrations of mercury. After 20 days of incubation and subsequent harvesting of the seedlings, biometric measurem... [more]

Attachment of particles and droplets to bubbles—the latter being of various fine sizes and created by different techniques (as described in detail)—forms the basis of flotation, a process which indeed was originated from mineral processing. Nevertheless, chemistry often plays a significant role in this area, in order for separation to be effective, as stressed. This (brief) review particularly discusses wastewater treatment applications and the effect of bubble size (from nano- to micro-) on the flotation process.

Waste generated during regeneration of Ion Exchanger (IX), used for deionizing water, needs to be neutralized before it can be discharged back to a clean water source. An efficient and novel process is disclosed that minimizes the neutralization volume and chemicals required for pH adjustment. The currently employed neutralization setups in the industry are environmentally unsustainable. Various neutralization setups were studied for treating waste generated from IX regeneration. From the collected plant data, the treatment requirements of waste streams generated during regeneration of IX beds were analyzed. An efficient neutralization setup was developed to lower the operating and capital costs by eliminating the need of some equipment and by lowering the neutralization volume. The new process results in considerable savings compared to currently used processes in the industry and is environmentally benign. The improved neutralization setup proposed in this work has achieved a 63% red... [more]

This study was performed to investigate the distribution characteristics of airborne bacteria emitted from swine manure composting plants. The types of swine manure composting plants selected for the survey in this study were as follows: screw type, rotary type, and natural dry type. Mean levels of airborne bacteria in swine manure composting plants were 7428 (±1024) CFU m−3 for the screw type, 3246 (±1407) CFU m−3 for the rotary type, and 5232 (±1217) CFU m−3 for the natural dry type, respectively. Based on the results obtained from this study, the swine manure composting plant operated by screw type showed the highest concentration of airborne bacteria, followed by the natural dry type and rotary type. The monthly concentration of airborne bacteria was the highest in August and the lowest in November, regardless of the type of swine manure composting plant. The respirable size of airborne bacteria accounted for about 50% of the total. The ratio of respirable to the total quantity of... [more]

Industries are nowadays not only expected to produce goods and provide services, but also to do this sustainably. What qualifies a company as sustainable implies that its activities must be defined according to the social and ecological responsibilities that are meant to protect the society and the environment in which they operate. From now on, it will be necessary to consider and measure the impact of industrial activities on the environment, and to do so, one key parameter is the carbon footprint. This paper demonstrates the utility of the LCI as a tool for immediate application in industries. Its application shall facilitate decision making in industries while choosing amongst different scenarios to industrialize a certain product with the lowest environmental impact possible. To achieve this, the carbon footprint of a given product was calculated by applying the LCI method to several scenarios that differed from each other only in the supply-chain model. As a result of this LCI ca... [more]

Many studies have found that FDI can reduce the pollutant emissions of host countries. At the same time, the intensity of environmental regulation would affect the emission reduction effect of FDI in the host country. This study aims to reveal the internal mechanisms of this effect. Specifically, this paper studies the impact of FDI on technological innovation in China’s industrial sectors from the perspective of technology transactions from 2001 to 2019, and then analyzes whether the intensity of environmental regulation can promote the relationship. Results indicate that FDI promotes technological innovation through technology transactions. In addition, it finds that the intensity of environmental regulation significantly positively moderates the relationship between FDI and technological innovation, which is achieved by positively moderating the FDI−technology transaction relationship. Regional heterogeneity analysis is further conducted, and results show that in the eastern and wes... [more]