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Records with Subject: Energy Systems
Showing records 3413 to 3437 of 9566. [First] Page: 1 134 135 136 137 138 139 140 141 142 Last
Influence of Valorization of Sewage Sludge on Energy Consumption in the Drying Process
Ewa Siedlecka, Jarosław Siedlecki
March 28, 2023 (v1)
Keywords: alternative fuel, energy saving, organic matter, sewage sludge, valorization
Valorization of digested sewage sludge generated in a medium-sized sewage treatment plant and the effect of valorization on energy consumption during sludge drying used for energy recovery are presented. Anaerobic digestion of sewage sludge reduces dry matter content compared to raw sludge. This lowers its calorific value leading to the lower interest of consumers in using it as fuel. The aim of the study was to valorize digested sewage sludge prior to drying with high-energy waste with low moisture content. The procedure led to the reduction in moisture content by about 50% in the substrate supplied for solidification and drying. The calorific value of digested sewage sludge increased by 50−80%, and the energy consumption of the drying process decreased by about 50%. Physical and chemical properties of sewage sludge and moisture content of substrates and mixtures after valorization were determined. The heat of combustion of valorized sewage sludge mixtures, their elemental composition... [more]
A New Device Hypothesis for Water Extraction from Air and Basic Air Condition System in Developing Countries
Paolo Maria Congedo, Cristina Baglivo, Giulia Negro
March 28, 2023 (v1)
Keywords: condensate water, developing countries, earth-to-air heat exchanger, geothermal, passive cooling, Peltier cell, storage, torrid climate, unconventional air handling units, water generation
This work proposes a new device for air treatment with dehumidification and water recovery/storage, with possible mitigation of indoor environmental conditions. The system is based on Peltier cells coupled with a horizontal earth-to-air heat exchanger, it is proposed as an easy-to-implement alternative to the heat pumps and air handling units currently used on the market, in terms of cost, ease of installation, and maintenance. The process provides the water collection from the cooling of warm-humid air through a process that leads to condensation and water vapor separation. The airflow generated by a fan splits into two dual flows that lap the two surfaces of the Peltier cells, one flow laps the cold surfaces undergoing sensible, latent cooling with dehumidification; the other flow laps the hot surfaces and heats up. The airflow undergoes thermal pre-treatment through the underground horizontal geothermal pipe that precedes the Peltier cells. In the water storage tank, which also work... [more]
Nexus between Financial Development, Renewable Energy Consumption, Technological Innovations and CO2 Emissions: The Case of India
Muhammad Qayyum, Minhaj Ali, Mir Muhammad Nizamani, Shijie Li, Yuyuan Yu, Atif Jahanger
March 28, 2023 (v1)
Keywords: ARDL, CO2 emissions, financial development, India, Renewable and Sustainable Energy, technological innovations
Concerns regarding environmental sustainability have generally been an important element in achieving long-term development objectives. However, developing countries struggle to deal with these concerns, which all require specific treatment. As a result, this study explores the interaction between financial development, renewable energy consumption, technological innovations, and CO2 emissions in India from 1980 to 2019, taking into account the critical role of economic progress and urbanization. The Autoregressive Distributed Lag (ARDL) model is used to quantify long-run dynamics, while the Vector Error Correction Model is used to identify causal direction (VECM). According to the study’s conclusions, financial development has a considerable positive impact on CO2 emissions. The coefficient of renewable energy consumption and technical innovations, on the other hand, is strongly negative in both the short and long run, indicating that increasing these measures will reduce CO2 emission... [more]
Special Issue [Energies] “Clean Utilization and Conversion Technology of Coal”
Marek Sciazko, Aleksander Sobolewski
March 28, 2023 (v1)
Clean Utilization and Conversion Technology of Coal has at least 40 years of history, beginning with the USA-born Clean Coal Technology program and at the same time the European Thermie research and development program was started [...]
Performance Evaluation of Solar PV Power Plants in Taiwan Using Data Envelopment Analysis
June Raymond Leonen Mariano, Mingyu Liao, Herchang Ay
March 28, 2023 (v1)
Keywords: data envelopment analysis, performance evaluation, solar PV power plant
Due to the worldwide impact of industrialization, renewable sources of energy from solar play a huge role in supplying the domestic demand in Taiwan. This paper aims to impart an unbiased performance evaluation of different solar photovoltaic (PV) power plants around Taiwan. This study utilized data envelopment analysis (DEA) using the epsilon-based measure (EBM) model to compute the performance efficiency and ranking of the solar PV power plants. Additionally, the model is used for its advantage of combined radial and non-radial measures to achieve a more precise measure of efficiency. The results show that among nine selected solar PV plants, the top-performing DMU was I (8200051) from the southern part of Taiwan. Therefore, this study recommends that EBM can be a useful tool to evaluate the performance of solar PV power plants using multiple inputs and outputs. Additionally, this study will contribute to sustaining and developing the existing solar PV power capacity while achieving... [more]
Modelling Yawed Wind Turbine Wakes: Extension of a Gaussian-Based Wake Model
De-Zhi Wei, Ni-Na Wang, De-Cheng Wan
March 28, 2023 (v1)
Keywords: analytical wake model, streamwise velocity deficit, transverse velocity, wake deflection, yawed wind turbine
Yaw-based wake steering control is a potential way to improve wind plant overall performance. For its engineering application, it is crucial to accurately predict the turbine wakes under various yawed conditions within a short time. In this work, a two-dimensional analytical model is proposed for far wake modeling under yawed conditions by taking the self-similarity assumption for the streamwise velocity deficit and skewness angle at hub height. The proposed model can be applied to predict the wake center trajectory, streamwise velocity, and transverse velocity in the far-wake region downstream of a yawed turbine. For validation purposes, predictions by the newly proposed model are compared to wind tunnel measurements and large-eddy simulation data. The results show that the proposed model has significantly high accuracy and outperforms other common wake models. More importantly, the equations of the new proposed model are simple, the wake growth rate is the only parameter to be specif... [more]
Miscanthus to Biocarbon for Canadian Iron and Steel Industries: An Innovative Approach
Trishan Deb Abhi, Omid Norouzi, Kevin Macdermid-Watts, Mohammad Heidari, Syeda Tasnim, Animesh Dutta
March 28, 2023 (v1)
Keywords: biocarbon, blast furnace (BF), CO2 emission mitigation, hydrothermal carbonization (HTC), miscanthus, pulverized coal injection (PCI), slow pyrolysis
Iron-based industries are one of the main contributors to greenhouse gas (GHG) emissions. Partial substitution of fossil carbon with renewable biocarbon (biomass) into the blast furnace (BF) process can be a sustainable approach to mitigating GHG emissions from the ironmaking process. However, the main barriers of using biomass for this purpose are the inherent high alkaline and phosphorous contents in ash, resulting in fouling, slagging, and scaling on the BF surface. Furthermore, the carbon content of the biomass is considerably lower than coal. To address these barriers, this research proposed an innovative approach of combining two thermochemical conversion methods, namely hydrothermal carbonization (HTC) and slow pyrolysis, for converting biomass into suitable biocarbon for the ironmaking process. Miscanthus, which is one of the most abundant herbaceous biomass sources, was first treated by HTC to obtain the lowest possible ash content mainly due to reduction in alkali matter and... [more]
Effect of Methanol/Water Mixed Fuel Compound Injection on Engine Combustion and Emissions
Changchun Xu, Haengmuk Cho
March 28, 2023 (v1)
Keywords: diesel engine, emissions, injection position, Methanol, MSR
Due to the recent global increase in fuel prices, to reduce emissions from ground transportation and improve urban air quality, it is necessary to improve fuel efficiency and reduce emissions. Water, methanol, and a mixture of the two were added at the pre-intercooler position to keep the same charge and cooling of the original rich mixture, reduce BSFC and increase ITE, and promote combustion. The methanol/water mixing volume ratios of different fuel injection strategies were compared to find the best balance between fuel consumption, performance, and emission trends. By simulating the combustion mechanism of methanol, water, and diesel mixed through the Chemkin system, the ignition delay, temperature change, and the generation rate of the hydroxyl group (−OH) in the reaction process were analyzed. Furthermore, the performance and emission of the engine were analyzed in combination with the actual experiment process. This paper studied the application of different concentration ratios... [more]
Co-Design Optimization of Direct Drive PMSGs for Offshore Wind Turbines Based on Wind Speed Profile
Linh Dang, Serigne Ousmane Samb, Ryad Sadou, Nicolas Bernard
March 28, 2023 (v1)
Keywords: co-design optimization, flux weakening control, MTPA control, offshore wind energy, PMSG, wind speed profile
This paper presents a new method to optimize, from a working cycle defined by torque and speed profiles, both the design and the control strategy of permanent magnet synchronous generators (PMSGs). The case of a 10 MW direct-drive permanent magnet generator for an Offshore wind turbine was chosen to illustrate this method, which is based on the d−q axis equivalent circuit model. It allows to optimize, with a reduced computation time, the design, considering either a flux weakening control strategy (FW) or a maximum torque per Ampere control (MTPA) strategy, while respecting all the constraints—particularly the thermal constraint, which is characterized by a transient regime. The considered objective is to minimize the mass and the average electric losses over all working points. Thermal and magnetic analytical models are validated by a 2D finite element analysis (FEA).
Advanced Manufacturing in Civil Engineering
Ana S. Guimarães, João M. P. Q. Delgado, Sandra S. Lucas
March 28, 2023 (v1)
Keywords: 3D printing, additive manufacturing, building automation, civil engineering
The main goal of this work is the analysis of potential energy and green benefits of 3D printing on building construction. Current literature reports a considerable number of benefits for 3D printing, namely, reduction of material use, lower operational costs and time-saving. The authors also mention design freedom, higher efficiency, productivity and quality. This work presents the latest developments in 3D printing in civil engineering, namely, a review of the last 3D printing projects and the limitations of construction 3D printing with a focus on large-scale applications, technology costs, mix development and optimisation and thermal behaviour.
Energy and Exergy Analysis of the Air Source Transcritical CO2 Heat Pump Water Heater Using CO2-Based Mixture as Working Fluid
Yikai Wang, Yifan He, Yulong Song, Xiang Yin, Feng Cao, Xiaolin Wang
March 28, 2023 (v1)
Keywords: ambient temperature, case study, CO2-based mixture, energy analysis, exergy analysis, transcritical CO2 heat pump
Given the large demand nowadays for domestic hot water, and its impact on modern building energy consumption, air source transcritical CO2 heat pumps have been extensively adopted for hot water production. Since their system efficiency is limited by significant irreversibility, a CO2-based mixture could offer a promising drop-in technology to overcome this deficiency without increasing system complexity. Although many CO2 blends have been studied in previously published literature, little has been presented about the CO2/R32 mixture. Therefore, a proposed mixture for use in transcritical CO2 heat pumps was analyzed using energy and exergy analysis. Results showed that the coefficient of performance and exergy efficiency variation displayed an “M” shape trend, and the optimal CO2/R32 mixture concentration was determined as 0.9/0.1 with regard to flammability and efficiency. The irreversibility of the throttling valve was reduced from 0.031 to 0.009 kW⋅kW−1 and the total irreversibility... [more]
Modification of Canola Oil Physicochemical Properties by Hexane and Ethanol with Regards of Its Application in Diesel Engine
Rafał Longwic, Przemysław Sander, Bronisław Jańczuk, Anna Zdziennicka, Katarzyna Szymczyk
March 28, 2023 (v1)
Keywords: alternative fuel, canola oil, combustion, common rail, diesel engine, diesel fuel, ethyl alcohol, injection, n-hexane
A mixture of canola oil (Co), n-hexane (Hex), and ethyl alcohol (Et) was proposed as a new energy material for powering diesel engines. For this purpose, surface tension, density, and viscosity measurements, as well as engine tests, were performed for 88%Co10%Hex2%Et and 83%Co15%Hex2%Et mixtures at 20 °C. The adsorption and volumetric properties of these mixtures were compared to those of individual mixture components, as well as diesel fuel (Df) and oleic, linoleic, α-linolenic, palmitic, and stearic acids. It was revealed that the values of surface tension, viscosity, and density of Co were higher than those of the Co components. The addition of 10% Hex and 2% Et to Co caused a more than twofold decrease in its viscosity, while the addition of 15% Hex and 2% Et caused a more than fourfold reduction of Co viscosity. In addition, a mixture of Co with 2% Et and 10% Hex had a density similar to that of Df. In turn, theoretical calculations showed that the addition of n-hexane and ethanol... [more]
An Assessment of the Efficiency and Emissions of a Pellet Boiler Combusting Multiple Pellet Types
Marta Jach-Nocoń, Grzegorz Pełka, Wojciech Luboń, Tomasz Mirowski, Adam Nocoń, Przemysław Pachytel
March 28, 2023 (v1)
Keywords: agrobiomass pellets utilization, efficiency of pellet boiler, pellet boiler, pellet boiler emissions comparison
With sustainable energy being the key to reaching climate neutrality, the utilization of non-wooden biomass is a necessity. This article compares the emissions and efficiency of combusting a number of types of agrobiomass and wood pellets. A comparison was made on a moving grate pellet burner mounted in a boiler, where flue gas had a vertical flow via two pass heat exchangers with turbulization elements. Tests were conducted on wood pellets (ENPlus), miscanthus straw pellets, sunflower husk pellets, and corn stover pellets. During combustion, both wood and miscanthus pellets met the PN-EN 303-5:2012 emission and efficiency requirements. Corn stover pellets met the requirement on the nominal capacity. Sunflower husk pellets are characterized by excessive CO and particulate matter emissions. Sunflower husk pellets were the most problematic fuel from the point of view of the results of this research. During combustion of the miscanthus straw pellets there was a need to decrease the nomina... [more]
Stacked: In Their Favour? The Complexities of Fuel Stacking and Cooking Transitions in Cambodia, Myanmar, and Zambia
Martin Price, Melinda Barnard-Tallier, Karin Troncoso
March 28, 2023 (v1)
Keywords: Cambodia, clean cooking, culture, electric cooking, fuel stacking, Myanmar, perceptions, urban, Zambia
It remains unclear whether the decision to cook with both polluting and cleaner-burning fuels (‘fuel stacking’) serves as a transition phase towards the full adoption of clean-cooking practices, or whether stacking allows households to enhance fuel security and choose from a variety of cooking technologies and processes. This paper offers a unique contribution to the debate by positioning fuel stacking as the central research question in the exploration of existing household survey data. This research analyses the World Bank’s Multi-Tier Framework survey data concerning energy access and cooking practices in Cambodia, Myanmar, and Zambia. Its novel approach uses fuel expenditure data to group urban households according to the intensity of biomass consumption (wood, charcoal) relative to modern fuel consumption (electricity, gas). The research explores how different fuel-stacking contexts are associated with factors related to household finances, composition, experiences of electricity,... [more]
A Theoretical Optimum Tilt Angle Model for Solar Collectors from Keplerian Orbit
Tong Liu, Li Liu, Yufang He, Mengfei Sun, Jian Liu, Guochang Xu
March 28, 2023 (v1)
Keywords: coordinate transformation, Kepler orbit, solar collector, tilt angle
Solar energy has been extensively used in industry and everyday life. A more suitable solar collector orientation can increase its utilization. Many studies have explored the best orientation of the solar collector installation from the perspective of data analysis and local-area cases. Investigating the optimal tilt angle of a collector from the perspective of data analysis, or guiding the angle of solar collector installation, requires an a priori theoretical tilt angle as a support. However, none of the current theoretical studies have taken the real motion of the Sun into account. Furthermore, a complete set of theoretical optimal tilt angles for solar energy is necessary for worldwide locations. Therefore, from the view of astronomical mechanics, considering the true orbit of the Sun, a mathematical model that is universal across the globe is proposed: the Kepler motion model is constructed from the solar orbit and transformed into the local Earth coordinate system. After that, th... [more]
Using an Analytical Hierarchy Process to Analyze the Development of the Green Energy Industry
Wen-Hsiang Chiu, Wen-Cheng Lin, Chun-Nan Chen, Nien-Ping Chen
March 28, 2023 (v1)
Keywords: analytical hierarchy process, green energy industry, green finance
With global climate change and resource scarcity becoming increasingly serious issues, the green energy economy is transforming on a global scale. There are an increasing number of large-scale green energy development projects. However, these are often beset with risks; thus, this study conducted an analysis of the renewable energy risks in Taiwan using the analytical hierarchy process technique. Accordingly, a comprehensive study focusing into the current energy situation and potential development is needed. Renewable energy status and the availability by its main types, including, wind, solar, thermal, and biomass energies, were critically reviewed and discussed in this study. The findings of this study include the top 10 key operating risks recognized by specific green energy companies, as well as an assessment of which risks have been addressed and which have caused losses.
Examining the Role of Disruptive Innovation in Renewable Energy Businesses from a Cross National Perspective
Hokey Min, Yohannes Haile
March 28, 2023 (v1)
Keywords: cross cultural study, disruptive innovation, moderated mediation analysis, Renewable and Sustainable Energy, structural equation model, Sustainability
With a growing demand for safe, clean, and affordable energy, countries across the world are now seeking to create and rapidly develop renewable energy (RE) businesses. The success of these businesses often hinges on their ability to translate RE into sustainable value for energy consumers and the multiple stakeholders in the energy industry. Such value includes low production costs due to an abundance of natural resources (e.g., wind, water, sunlight), and public health benefits from reduced environmental pollution. Despite the potential for value creation, many RE businesses have struggled to create affordable energy as abundant as that which is produced by traditional fossil fuels. The rationale being that traditional RE sources emanating from natural resources tend to rely on unpredictable weather conditions. Therefore, to help RE businesses deliver sustainable value, we should leverage disruptive innovation that is less dependent on natural resources. This paper is one of the firs... [more]
Low-Speed Marine Diesel Engine Modeling for NOx Prediction in Exhaust Gases
Branko Lalić, Andrijana Poljak, Gojmir Radica, Antonija Mišura
March 28, 2023 (v1)
Keywords: chemical kinetics, combustion stoichiometry, fuel injection timing, influential engine parameters, mathematical engine model
Knowing the process of generating exhaust emissions and the determination of influential parameters are important factors in improving two-stroke slow-speed marine engines, particularly for further reductions in fuel consumption and stringent regulations on the limitation of nitrogen oxide emissions. In this article, a model of a marine low-speed two-stroke diesel engine has been developed. Experimental and numerical analyses of the nitrogen monoxide formations were carried out. When measuring the concentration of nitrogen oxides in the exhaust emissions, the amount of nitrogen dioxide (NO2) is usually measured, because nitrogen monoxide is very unstable, and due to the large amount of oxygen in the exhaust gases, it is rapidly converted into nitrogen dioxide and its amount is included in the total emission of nitrogen oxides. In this paper, the most significant parameters for the formation of nitrogen monoxide have been determined. Model validation was performed based on measured comb... [more]
Resilience Assessment of Wind Farms in the Arctic with the Application of Bayesian Networks
Albara M. Mustafa, Abbas Barabadi
March 28, 2023 (v1)
Keywords: Arctic black swan, Arctic conditions, Bayesian network, resilience, wind farms, wind turbines
Infrastructure systems, such as wind farms, are prone to various human-induced and natural disruptions such as extreme weather conditions. There is growing concern among decision makers about the ability of wind farms to withstand and regain their performance when facing disruptions, in terms of resilience-enhanced strategies. This paper proposes a probabilistic model to calculate the resilience of wind farms facing disruptive weather conditions. In this study, the resilience of wind farms is considered to be a function of their reliability, maintainability, supportability, and organizational resilience. The relationships between these resilience variables can be structured using Bayesian network models. The use of Bayesian networks allows for analyzing different resilience scenarios. Moreover, Bayesian networks can be used to quantify resilience, which is demonstrated in this paper with a case study of a wind farm in Arctic Norway. The results of the case study show that the wind farm... [more]
A Synergetic Sliding Mode Controller Applied to Direct Field-Oriented Control of Induction Generator-Based Variable Speed Dual-Rotor Wind Turbines
Habib Benbouhenni, Nicu Bizon
March 28, 2023 (v1)
Keywords: direct field-oriented control, induction generators, maximum power point tracking, synergetic sliding mode, variable speed dual-rotor wind power
A synergetic sliding mode (SSM) approach is designed to address the drawbacks of the direct field-oriented control (DFOC) of the induction generators (IGs) integrated into variable speed dual-rotor wind power (DRWP) systems with the maximum power point tracking (MPPT) technique. Using SSM controllers in the DFOC strategy, the active power, electromagnetic torque, and reactive power ripples are reduced compared to traditional DFOC using proportional-integral (PI) controllers. This proposed strategy, associated with SSM controllers, produces efficient state estimation. The effectiveness of the designed DFOC strategy has been evaluated on variable speed DRWP systems with the MPPT technique.
Exploring the Grid Value of Offshore Wind Energy in Oregon
Travis C. Douville, Dhruv Bhatnagar
March 28, 2023 (v1)
Keywords: complementarity, marine renewable energy, offshore wind energy, Oregon, production cost modelling, system integration, transmission of ocean energy, Western Interconnection
The significant offshore wind energy potential of Oregon faces several challenges, including a power grid which was not developed for the purpose of transmitting energy from the ocean. The grid impacts of the energy resource are considered through the lenses of (i) resource complementarity with Variable Renewable Energy resources; (ii) correlations with load profiles from the four balancing authorities with territory in Oregon; and (iii) spatial value to regional and coastal grids as represented through a production cost model of the Western Interconnection. The capacity implications of the interactions between offshore wind and the historical east-to-west power flows of the region are discussed. The existing system is shown to accommodate more than two gigawatts of offshore wind interconnections with minimal curtailment. Through three gigawatts of interconnection, transmission flows indicate a reduction of coastal and statewide energy imports as well as minimal statewide energy export... [more]
Pore-Filled Proton-Exchange Membranes with Fluorinated Moiety for Fuel Cell Application
Hyeon-Bee Song, Jong-Hyeok Park, Jin-Soo Park, Moon-Sung Kang
March 28, 2023 (v1)
Keywords: hydrogen-fueled electric vehicles, partially fluorinated ionomer, pore-filled proton-exchange membranes, porous polytetrafluoroethylene, proton-exchange membrane fuel cell
Proton-exchange membrane fuel cells (PEMFCs) are the heart of promising hydrogen-fueled electric vehicles, and should lower their price and further improve durability. Therefore, it is necessary to enhance the performances of the proton-exchange membrane (PEM), which is a key component of a PEMFC. In this study, novel pore-filled proton-exchange membranes (PFPEMs) were developed, in which a partially fluorinated ionomer with high cross-linking density is combined with a porous polytetrafluoroethylene (PTFE) substrate. By using a thin and tough porous PTFE substrate film, it was possible to easily fabricate a composite membrane possessing sufficient physical strength and low mass transfer resistance. Therefore, it was expected that the manufacturing method would be simple and suitable for a continuous process, thereby significantly reducing the membrane price. In addition, by using a tri-functional cross-linker, the cross-linking density was increased. The oxidation stability was greatl... [more]
Medium- and High-Tech Export and Renewable Energy Consumption: Non-Linear Evidence from the ASEAN Countries
Cong Khai Dinh, Quang Thanh Ngo, Trung Thanh Nguyen
March 28, 2023 (v1)
Keywords: ASEAN, economic growth, employment, inflation, medium- and high-tech export, Renewable and Sustainable Energy
Sustaining economic growth while reducing dependence on fossil fuels remains a challenge for our world to fight against climate change and therefore finding a way to promote economic growth and increase renewable energy use is needed. This paper uses a 22-year panel dataset (1994−2015) of 9 countries in the Association of Southeast Asian Nations provided by the World Bank World Development Indicators to examine the impact of medium- and high-tech export on renewable energy use. We employ a fixed-effects regression model with the Driscoll−Kraay nonparametric covariance matrix estimator to account for sectoral and temporal dependence. We also control for inflation, employment, population growth, and gross domestic product per capita in our estimations. Our results demonstrate a U-shaped association between medium- and high-tech export and renewable energy consumption of these economies. The results propose that enhancing medium- and high-tech export could be a feasible solution for promo... [more]
A Comparison of Time-Domain Implementation Methods for Fractional-Order Battery Impedance Models
Brian Ospina Agudelo, Walter Zamboni, Eric Monmasson
March 28, 2023 (v1)
Keywords: battery impedance model, equivalent circuit model, fractional-order model, time- domain implementation
This paper is a comparative study of the multiple RC, Oustaloup and Grünwald−Letnikov approaches for time domain implementations of fractional-order battery models. The comparisons are made in terms of accuracy, computational burden and suitability for the identification of impedance parameters from time-domain measurements. The study was performed in a simulation framework and focused on a set of ZARC elements, representing the middle frequency range of Li-ion batteries’ impedance. It was found that the multiple RC approach offers the best accuracy−complexity compromise, making it the most interesting approach for real-time battery simulation applications. As for applications requiring the identification of impedance parameters, the Oustaloup approach offers the best compromise between the goodness of the obtained frequency response and the accuracy−complexity requirements.
Anion Coordination Improves High-Temperature Performance and Stability of NaPF6-Based Electrolytes for Supercapacitors
J. Landon Tyler, Robert L. Sacci, Jagjit Nanda
March 28, 2023 (v1)
Keywords: high-temperature electrolyte, Na-ion electrolytes, supercapacitors
Electrolyte stability can be improved by incorporating complexing agents that bind key decomposition intermediates and slow down decomposition. We show that hexamethyl-phosphoramide (HMPA) extends both the thermal stability threshold of sodium hexafluorophosphate (NaPF6) in dimethoxyethane (DME) electrolyte and the cycle life of double-layer capacitors. HMPA forms a stable complex with PF5, an intermediate in PF6 anion thermal degradation. Unbound, this intermediate leads to autocatalytic degradation of the electrolyte solution. The results of electrochemical impedance spectroscopy (EIS) and galvanostatic cycling measurements show large changes in the cell without the presence of HMPA at higher temperatures (≥60 °C). Fourier transform infrared spectroscopy (FTIR) on the liquid and gas phase of the electrolyte shows without HMPA the formation of measurable amounts of PF5 and HF. The complimentary results of these measurements proved the usefulness of using Lewis bases such as HMPA to in... [more]
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